CN104262369A - 一种腈基配体水解调控的配位聚合物及其制备方法 - Google Patents
一种腈基配体水解调控的配位聚合物及其制备方法 Download PDFInfo
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- CN104262369A CN104262369A CN201410533776.XA CN201410533776A CN104262369A CN 104262369 A CN104262369 A CN 104262369A CN 201410533776 A CN201410533776 A CN 201410533776A CN 104262369 A CN104262369 A CN 104262369A
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- ligand
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- coordination polymer
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- Granted
Links
- 239000003446 ligand Substances 0.000 title claims abstract description 56
- 230000007062 hydrolysis Effects 0.000 title claims abstract description 19
- 238000006460 hydrolysis reaction Methods 0.000 title claims abstract description 19
- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- 239000013256 coordination polymer Substances 0.000 title abstract 8
- 229920001795 coordination polymer Polymers 0.000 title abstract 8
- 150000002825 nitriles Chemical class 0.000 title abstract 3
- MGFJDEHFNMWYBD-OWOJBTEDSA-N 4-[(e)-2-pyridin-4-ylethenyl]pyridine Chemical group C=1C=NC=CC=1/C=C/C1=CC=NC=C1 MGFJDEHFNMWYBD-OWOJBTEDSA-N 0.000 claims abstract description 8
- 239000000126 substance Substances 0.000 claims abstract description 5
- 229920000642 polymer Polymers 0.000 claims description 32
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 16
- 150000003751 zinc Chemical class 0.000 claims description 8
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 claims description 8
- 239000012153 distilled water Substances 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- 238000010438 heat treatment Methods 0.000 claims description 6
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 claims description 6
- 239000011259 mixed solution Substances 0.000 claims description 4
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims description 4
- 229960001763 zinc sulfate Drugs 0.000 claims description 4
- 229910000368 zinc sulfate Inorganic materials 0.000 claims description 4
- 230000015572 biosynthetic process Effects 0.000 claims description 3
- 235000005074 zinc chloride Nutrition 0.000 claims description 3
- 239000011592 zinc chloride Substances 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 2
- 239000013110 organic ligand Substances 0.000 claims description 2
- 238000010583 slow cooling Methods 0.000 claims description 2
- 230000001105 regulatory effect Effects 0.000 abstract description 3
- 150000001875 compounds Chemical class 0.000 abstract description 2
- 239000002861 polymer material Substances 0.000 abstract description 2
- OUCOUDYWPABJBH-UHFFFAOYSA-N 2-(2-cyanophenoxy)sulfonylbenzoic acid Chemical compound C(#N)C1=C(C=CC=C1)OS(=O)(=O)C1=C(C(=O)O)C=CC=C1 OUCOUDYWPABJBH-UHFFFAOYSA-N 0.000 abstract 1
- 239000011701 zinc Substances 0.000 description 15
- 238000000034 method Methods 0.000 description 7
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 6
- 150000001732 carboxylic acid derivatives Chemical group 0.000 description 6
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 5
- 238000005406 washing Methods 0.000 description 5
- 238000002050 diffraction method Methods 0.000 description 4
- 125000004429 atom Chemical group 0.000 description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 3
- 229910021645 metal ion Inorganic materials 0.000 description 3
- 125000004646 sulfenyl group Chemical group S(*)* 0.000 description 3
- 239000002253 acid Substances 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 238000012512 characterization method Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000001027 hydrothermal synthesis Methods 0.000 description 2
- ZHUXMBYIONRQQX-UHFFFAOYSA-N hydroxidodioxidocarbon(.) Chemical compound [O]C(O)=O ZHUXMBYIONRQQX-UHFFFAOYSA-N 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 125000004433 nitrogen atom Chemical group N* 0.000 description 2
- 150000003568 thioethers Chemical class 0.000 description 2
- 230000009466 transformation Effects 0.000 description 2
- LVFFZQQWIZURIO-MRVPVSSYSA-N 2-Phenylsuccinic acid Chemical compound OC(=O)C[C@@H](C(O)=O)C1=CC=CC=C1 LVFFZQQWIZURIO-MRVPVSSYSA-N 0.000 description 1
- -1 2-cyano-phenyl sulfo- Chemical class 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000004071 biological effect Effects 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- RKTYLMNFRDHKIL-UHFFFAOYSA-N copper;5,10,15,20-tetraphenylporphyrin-22,24-diide Chemical compound [Cu+2].C1=CC(C(=C2C=CC([N-]2)=C(C=2C=CC=CC=2)C=2C=CC(N=2)=C(C=2C=CC=CC=2)C2=CC=C3[N-]2)C=2C=CC=CC=2)=NC1=C3C1=CC=CC=C1 RKTYLMNFRDHKIL-UHFFFAOYSA-N 0.000 description 1
- 230000005595 deprotonation Effects 0.000 description 1
- 238000010537 deprotonation reaction Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 238000002329 infrared spectrum Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000008204 material by function Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000001338 self-assembly Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 125000006850 spacer group Chemical group 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000000844 transformation Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
- C07F3/06—Zinc compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Pyridine Compounds (AREA)
Abstract
Description
Claims (8)
Priority Applications (1)
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CN201410533776.XA CN104262369B (zh) | 2014-10-12 | 2014-10-12 | 一种腈基配体水解调控的配位聚合物及其制备方法 |
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CN201410533776.XA CN104262369B (zh) | 2014-10-12 | 2014-10-12 | 一种腈基配体水解调控的配位聚合物及其制备方法 |
Publications (2)
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CN104262369A true CN104262369A (zh) | 2015-01-07 |
CN104262369B CN104262369B (zh) | 2016-08-17 |
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CN201410533776.XA Expired - Fee Related CN104262369B (zh) | 2014-10-12 | 2014-10-12 | 一种腈基配体水解调控的配位聚合物及其制备方法 |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104628746A (zh) * | 2015-01-30 | 2015-05-20 | 郑州轻工业学院 | 一种蓝色荧光n,n-二(4-氰基苯基)氨基乙酸锌配合物及其制备方法 |
CN104628747A (zh) * | 2015-01-30 | 2015-05-20 | 郑州轻工业学院 | 一种绿色荧光n,n-二(4-氰基苯基)氨基乙酸锌配合物及其制备方法 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103772418A (zh) * | 2014-01-13 | 2014-05-07 | 刘国政 | 一种具有混合配体的配位聚合物及其制备方法 |
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- 2014-10-12 CN CN201410533776.XA patent/CN104262369B/zh not_active Expired - Fee Related
Patent Citations (1)
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CN103772418A (zh) * | 2014-01-13 | 2014-05-07 | 刘国政 | 一种具有混合配体的配位聚合物及其制备方法 |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104628746A (zh) * | 2015-01-30 | 2015-05-20 | 郑州轻工业学院 | 一种蓝色荧光n,n-二(4-氰基苯基)氨基乙酸锌配合物及其制备方法 |
CN104628747A (zh) * | 2015-01-30 | 2015-05-20 | 郑州轻工业学院 | 一种绿色荧光n,n-二(4-氰基苯基)氨基乙酸锌配合物及其制备方法 |
CN104628747B (zh) * | 2015-01-30 | 2016-04-20 | 郑州轻工业学院 | 一种绿色荧光n,n-二(4-氰基苯基)氨基乙酸锌配合物及其制备方法 |
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CN104262369B (zh) | 2016-08-17 |
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Inventor after: Zhang Fuping Inventor before: Liu Guozheng |
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Effective date of registration: 20160613 Address after: 226100, Jiangsu, Nantong Province town of Haimen Industrial Zone Applicant after: Haimen Fenglong S.S Pharmaceutical Equipment Co., Ltd. Address before: North shore village Huang Town Village 518104 ring of Guangdong province Dongguan City Road No. 17 Applicant before: Liu Guozheng |
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