CN104262370B - 硫醚多羧酸配体合成的羧酸锌配位聚合物及其制备方法 - Google Patents
硫醚多羧酸配体合成的羧酸锌配位聚合物及其制备方法 Download PDFInfo
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- CN104262370B CN104262370B CN201410533782.5A CN201410533782A CN104262370B CN 104262370 B CN104262370 B CN 104262370B CN 201410533782 A CN201410533782 A CN 201410533782A CN 104262370 B CN104262370 B CN 104262370B
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- Prior art keywords
- ligand polymer
- carboxylic acid
- thioether
- synthesis
- poly carboxylic
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- 239000003446 ligand Substances 0.000 title claims abstract description 41
- 239000011701 zinc Substances 0.000 title claims abstract description 38
- 229920000642 polymer Polymers 0.000 title claims abstract description 34
- 229910052725 zinc Inorganic materials 0.000 title claims abstract description 19
- 230000015572 biosynthetic process Effects 0.000 title claims abstract description 17
- 238000003786 synthesis reaction Methods 0.000 title claims abstract description 17
- -1 zinc carboxylate Chemical class 0.000 title claims abstract description 17
- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims abstract description 17
- MWVTWFVJZLCBMC-UHFFFAOYSA-N 4,4'-bipyridine Chemical group C1=NC=CC(C=2C=CN=CC=2)=C1 MWVTWFVJZLCBMC-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000000126 substance Substances 0.000 claims abstract description 6
- 150000003751 zinc Chemical class 0.000 claims description 8
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 claims description 8
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 claims description 8
- 239000012153 distilled water Substances 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- 238000010438 heat treatment Methods 0.000 claims description 6
- 239000011259 mixed solution Substances 0.000 claims description 4
- 235000005074 zinc chloride Nutrition 0.000 claims description 4
- 239000011592 zinc chloride Substances 0.000 claims description 4
- 239000013110 organic ligand Substances 0.000 claims description 3
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims description 3
- 229960001763 zinc sulfate Drugs 0.000 claims description 3
- 229910000368 zinc sulfate Inorganic materials 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 2
- 238000010583 slow cooling Methods 0.000 claims description 2
- 230000001105 regulatory effect Effects 0.000 abstract description 3
- 150000001875 compounds Chemical class 0.000 abstract description 2
- 230000001276 controlling effect Effects 0.000 abstract description 2
- 125000006850 spacer group Chemical group 0.000 abstract description 2
- 150000001735 carboxylic acids Chemical class 0.000 abstract 1
- ROFVEXUMMXZLPA-UHFFFAOYSA-N Bipyridyl Chemical group N1=CC=CC=C1C1=CC=CC=N1 ROFVEXUMMXZLPA-UHFFFAOYSA-N 0.000 description 6
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 5
- 238000005406 washing Methods 0.000 description 5
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical group C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 4
- 125000004429 atom Chemical group 0.000 description 4
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 239000005864 Sulphur Substances 0.000 description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 3
- 229910007541 Zn O Inorganic materials 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000002050 diffraction method Methods 0.000 description 2
- 238000001027 hydrothermal synthesis Methods 0.000 description 2
- ZHUXMBYIONRQQX-UHFFFAOYSA-N hydroxidodioxidocarbon(.) Chemical compound [O]C(O)=O ZHUXMBYIONRQQX-UHFFFAOYSA-N 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 125000004433 nitrogen atom Chemical group N* 0.000 description 2
- 150000003568 thioethers Chemical class 0.000 description 2
- 230000009466 transformation Effects 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- MDZGSYBJDWTLGY-UHFFFAOYSA-N [S]C1=CC=CC=C1C#N Chemical compound [S]C1=CC=CC=C1C#N MDZGSYBJDWTLGY-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 239000013256 coordination polymer Substances 0.000 description 1
- 229920001795 coordination polymer Polymers 0.000 description 1
- RKTYLMNFRDHKIL-UHFFFAOYSA-N copper;5,10,15,20-tetraphenylporphyrin-22,24-diide Chemical compound [Cu+2].C1=CC(C(=C2C=CC([N-]2)=C(C=2C=CC=CC=2)C=2C=CC(N=2)=C(C=2C=CC=CC=2)C2=CC=C3[N-]2)C=2C=CC=CC=2)=NC1=C3C1=CC=CC=C1 RKTYLMNFRDHKIL-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 238000000844 transformation Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
- C07F3/06—Zinc compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B2200/00—Indexing scheme relating to specific properties of organic compounds
- C07B2200/13—Crystalline forms, e.g. polymorphs
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
Abstract
Description
Claims (7)
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CN201410533782.5A CN104262370B (zh) | 2014-10-12 | 2014-10-12 | 硫醚多羧酸配体合成的羧酸锌配位聚合物及其制备方法 |
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CN201410533782.5A CN104262370B (zh) | 2014-10-12 | 2014-10-12 | 硫醚多羧酸配体合成的羧酸锌配位聚合物及其制备方法 |
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CN104262370A CN104262370A (zh) | 2015-01-07 |
CN104262370B true CN104262370B (zh) | 2016-06-01 |
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Families Citing this family (6)
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CN105924653B (zh) * | 2016-05-06 | 2018-10-26 | 衡阳师范学院 | 一种有机金属锌(ⅱ)配位聚合物发光材料及其制备方法 |
CN106432292A (zh) * | 2016-09-28 | 2017-02-22 | 齐鲁工业大学 | 含混合配体的三维锌配位聚合物及其制备方法和应用 |
CN106478960A (zh) * | 2016-10-01 | 2017-03-08 | 桂林理工大学 | 以均苯三甲酸和双(4‑吡啶基)胺构筑的锌聚合物及制备方法 |
CN107629218A (zh) * | 2017-10-30 | 2018-01-26 | 重庆师范大学 | 一种Ni(II)配位聚合物及其制备方法和应用 |
CN107778492A (zh) * | 2017-10-30 | 2018-03-09 | 重庆师范大学 | 一种Co(II)配位聚合物及其制备方法和应用 |
CN108299475A (zh) * | 2018-02-06 | 2018-07-20 | 云南农业大学 | 基于5-氯噻吩-2-羧酸及4,4’-联吡啶的三维金属-有机骨架晶体材料及制备方法 |
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CN103772418A (zh) * | 2014-01-13 | 2014-05-07 | 刘国政 | 一种具有混合配体的配位聚合物及其制备方法 |
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CN103772418A (zh) * | 2014-01-13 | 2014-05-07 | 刘国政 | 一种具有混合配体的配位聚合物及其制备方法 |
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Effective date of registration: 20160413 Address after: 226100 Haimen Village, Haimen town, Haimen, Jiangsu, Nantong Applicant after: HAIMEN DONGYA ALUMINUM INDUSTRY CO., LTD. Address before: North shore village Huang Town Village 518104 ring of Guangdong province Dongguan City Road No. 17 Applicant before: Liu Guozheng |
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