CN104292247A - 一种具有混合配体的含镉二维聚合物及其制备方法 - Google Patents
一种具有混合配体的含镉二维聚合物及其制备方法 Download PDFInfo
- Publication number
- CN104292247A CN104292247A CN201410451719.7A CN201410451719A CN104292247A CN 104292247 A CN104292247 A CN 104292247A CN 201410451719 A CN201410451719 A CN 201410451719A CN 104292247 A CN104292247 A CN 104292247A
- Authority
- CN
- China
- Prior art keywords
- cadmium
- preparation
- polymer
- mixed ligand
- handkerchief
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920000642 polymer Polymers 0.000 title claims abstract description 36
- 239000003446 ligand Substances 0.000 title claims abstract description 35
- 229910052793 cadmium Inorganic materials 0.000 title claims abstract description 25
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 title claims abstract description 23
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- 239000000126 substance Substances 0.000 claims abstract description 9
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims description 20
- HBSOMQPAIFVKGZ-UHFFFAOYSA-N 3-imidazol-1-ylpyridine Chemical class C1=NC=CN1C1=CC=CN=C1 HBSOMQPAIFVKGZ-UHFFFAOYSA-N 0.000 claims description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- VNHBYKHXBCYPBJ-UHFFFAOYSA-N 5-ethynylimidazo[1,2-a]pyridine Chemical compound C#CC1=CC=CC2=NC=CN12 VNHBYKHXBCYPBJ-UHFFFAOYSA-N 0.000 claims description 9
- 150000001661 cadmium Chemical class 0.000 claims description 8
- YKYOUMDCQGMQQO-UHFFFAOYSA-L cadmium dichloride Chemical compound Cl[Cd]Cl YKYOUMDCQGMQQO-UHFFFAOYSA-L 0.000 claims description 8
- 239000012153 distilled water Substances 0.000 claims description 7
- 239000002904 solvent Substances 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 4
- XIEPJMXMMWZAAV-UHFFFAOYSA-N cadmium nitrate Inorganic materials [Cd+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XIEPJMXMMWZAAV-UHFFFAOYSA-N 0.000 claims description 4
- NMHMNPHRMNGLLB-UHFFFAOYSA-N phloretic acid Chemical compound OC(=O)CCC1=CC=C(O)C=C1 NMHMNPHRMNGLLB-UHFFFAOYSA-N 0.000 claims description 4
- 239000000843 powder Substances 0.000 claims description 4
- QNRATNLHPGXHMA-XZHTYLCXSA-N (r)-(6-ethoxyquinolin-4-yl)-[(2s,4s,5r)-5-ethyl-1-azabicyclo[2.2.2]octan-2-yl]methanol;hydrochloride Chemical group Cl.C([C@H]([C@H](C1)CC)C2)CN1[C@@H]2[C@H](O)C1=CC=NC2=CC=C(OCC)C=C21 QNRATNLHPGXHMA-XZHTYLCXSA-N 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
- 239000013110 organic ligand Substances 0.000 claims description 2
- 230000035484 reaction time Effects 0.000 claims description 2
- 239000013078 crystal Substances 0.000 abstract description 4
- 238000006555 catalytic reaction Methods 0.000 abstract description 3
- 230000007547 defect Effects 0.000 abstract description 2
- 238000004020 luminiscence type Methods 0.000 abstract description 2
- 239000013256 coordination polymer Substances 0.000 abstract 2
- 229920001795 coordination polymer Polymers 0.000 abstract 2
- 210000002858 crystal cell Anatomy 0.000 abstract 1
- 238000002425 crystallisation Methods 0.000 abstract 1
- 230000008025 crystallization Effects 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 238000004729 solvothermal method Methods 0.000 abstract 1
- 238000001308 synthesis method Methods 0.000 abstract 1
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 11
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 5
- 125000004429 atom Chemical group 0.000 description 4
- 239000002253 acid Substances 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 238000012937 correction Methods 0.000 description 2
- 230000005595 deprotonation Effects 0.000 description 2
- 238000010537 deprotonation reaction Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- HDXMHOPCDXSIED-UHFFFAOYSA-N 3-pyridin-3-ylimidazo[1,2-a]pyridine Chemical compound N1=CC(=CC=C1)C1=CN=C2N1C=CC=C2 HDXMHOPCDXSIED-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000004071 biological effect Effects 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 125000002883 imidazolyl group Chemical group 0.000 description 1
- 239000008204 material by function Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000001338 self-assembly Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 238000010189 synthetic method Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
- C07F3/003—Compounds containing elements of Groups 2 or 12 of the Periodic Table without C-Metal linkages
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Plural Heterocyclic Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polyamides (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
Abstract
Description
Claims (9)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201410451719.7A CN104292247B (zh) | 2014-09-09 | 2014-09-09 | 一种具有混合配体的含镉二维聚合物及其制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201410451719.7A CN104292247B (zh) | 2014-09-09 | 2014-09-09 | 一种具有混合配体的含镉二维聚合物及其制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN104292247A true CN104292247A (zh) | 2015-01-21 |
CN104292247B CN104292247B (zh) | 2016-08-31 |
Family
ID=52312231
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201410451719.7A Active CN104292247B (zh) | 2014-09-09 | 2014-09-09 | 一种具有混合配体的含镉二维聚合物及其制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN104292247B (zh) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105061518A (zh) * | 2015-08-20 | 2015-11-18 | 齐鲁工业大学 | 一种具有混合配体的金属有机配位聚合物及其制备方法 |
CN105085555A (zh) * | 2015-08-20 | 2015-11-25 | 齐鲁工业大学 | 含混合配体二维镉聚合物及其制备方法和应用 |
CN105646589A (zh) * | 2016-02-14 | 2016-06-08 | 罗永强 | 检测铅离子的含锰化合物及其制备方法和应用 |
CN106397783A (zh) * | 2016-09-12 | 2017-02-15 | 桂林理工大学 | 对苯二甲酸镉聚合物及其制备方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102659845A (zh) * | 2012-03-30 | 2012-09-12 | 常州大学 | 层状金属配位聚合物及其合成方法 |
CN103588799A (zh) * | 2013-12-05 | 2014-02-19 | 南开大学 | 一种镉配位聚合物及其制备方法和应用 |
-
2014
- 2014-09-09 CN CN201410451719.7A patent/CN104292247B/zh active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102659845A (zh) * | 2012-03-30 | 2012-09-12 | 常州大学 | 层状金属配位聚合物及其合成方法 |
CN103588799A (zh) * | 2013-12-05 | 2014-02-19 | 南开大学 | 一种镉配位聚合物及其制备方法和应用 |
Non-Patent Citations (3)
Title |
---|
LI WEI ET AL: ""Synthesis, Structure and Luminescence of Two Coordination Polymers Based on 1,4-Benzenedicarboxylate and 2-(3-Pyridyl)benzimidazole Ligands"", 《CHINESE JOURNAL OF CHEMISTRY》, vol. 26, no. 11, 31 December 2008 (2008-12-31), pages 2039 - 2044 * |
LIU S D ET AL: ""Tuning of net architectures of Ni(II) and Zn(II) coordination polymers using isomeric organic linkers"", 《CRYSTENGCOMM》, vol. 16, 30 July 2014 (2014-07-30), pages 8874 - 8884 * |
YUE K F ET AL: ""Syntheses, Crystal Structures and Luminescence of Two Coordination Polymers Based on Isophthalic Acid and 2-(3-Pyridyl)benzimidazole Ligands"", 《ADVANCED MATERIALS RESEARCH VOLS》, vol. 399401, 22 November 2011 (2011-11-22), pages 896 - 899 * |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105061518A (zh) * | 2015-08-20 | 2015-11-18 | 齐鲁工业大学 | 一种具有混合配体的金属有机配位聚合物及其制备方法 |
CN105085555A (zh) * | 2015-08-20 | 2015-11-25 | 齐鲁工业大学 | 含混合配体二维镉聚合物及其制备方法和应用 |
CN105646589A (zh) * | 2016-02-14 | 2016-06-08 | 罗永强 | 检测铅离子的含锰化合物及其制备方法和应用 |
CN105646589B (zh) * | 2016-02-14 | 2018-02-13 | 曲晓辉 | 检测铅离子的含锰化合物及其制备方法和应用 |
CN106397783A (zh) * | 2016-09-12 | 2017-02-15 | 桂林理工大学 | 对苯二甲酸镉聚合物及其制备方法 |
Also Published As
Publication number | Publication date |
---|---|
CN104292247B (zh) | 2016-08-31 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN104230968B (zh) | 一种具有混合配体的含镉双核聚合物及其制备方法 | |
CN103772418B (zh) | 一种具有混合配体的配位聚合物及其制备方法 | |
CN105985362B (zh) | 一种制备沸石咪唑酯骨架结构材料的方法 | |
CN104292247A (zh) | 一种具有混合配体的含镉二维聚合物及其制备方法 | |
CN105218832A (zh) | 一种基于低对称四齿羧酸配体Cu的金属-有机骨架材料及其制备方法 | |
CN101914108B (zh) | 4-氨基-3,5-双(2-吡啶基)-1,2,4-三唑-银(i)配合物及其制备方法 | |
CN104693223A (zh) | 一种镉配位聚合物及制备方法及应用 | |
CN103626788A (zh) | 一种具有吸脱附碘的杂化材料及其合成方法 | |
CN103059011B (zh) | 三种基于Co(II)离子的金属有机框架、其合成方法和应用 | |
CN103159790B (zh) | 一种微孔聚合物发光材料及其制备方法 | |
CN103951708A (zh) | 一种多齿羧酸配位聚合物及其制备方法 | |
Sun et al. | Capturing a Metastable Silver (I) Compound of Pyrazine-2, 3-dicarboxylic Acid | |
Zhang et al. | Synthesis, structure and properties of novel 3-D porous lanthanide-3, 4′, 5-azobenzenetricarboxylate frameworks | |
CN104098595B (zh) | 一种双核含铜三维聚合物及其制备方法 | |
CN104130292B (zh) | 一种带双核结构的三维配位聚合物及其制备方法 | |
CN104447871A (zh) | 一种含锰双核二维聚合物及其制备方法 | |
CN104478937A (zh) | 一种含锰双核二维聚合物及其制备方法 | |
CN104130293A (zh) | 一种混合配体的三维配位聚合物及其制备方法 | |
CN104059108A (zh) | 一种具有三维结构含Mn的配位聚合物及其制备方法 | |
Yang et al. | Urothermal in situ ligand synthesis to fabricate a metal-organic framework with (3, 4)-connected tfi topology | |
CN104130291B (zh) | 一种具有混合配体的二维聚合物及其制备方法 | |
CN104151363A (zh) | 一种含簇结构的三维配位聚合物及其制备方法 | |
CN104262402A (zh) | 一种三维含锰配位聚合物及其制备方法 | |
CN113956493A (zh) | 非烷基锡氧簇合物及其合成方法及应用 | |
CN102898447B (zh) | 一种金属锌配合物三维有序多孔材料及其制备方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C41 | Transfer of patent application or patent right or utility model | ||
CB03 | Change of inventor or designer information |
Inventor after: Xu Xianzhen Inventor before: Duan Jingjing Inventor before: Wang Dawei |
|
COR | Change of bibliographic data | ||
TA01 | Transfer of patent application right |
Effective date of registration: 20160804 Address after: 266071 Qiingdao University, 7 East Hongkong Road, Laoshan District, Shandong, Qingdao Applicant after: Qingdao University Address before: 516000 Guangdong County of Longmen city in Huizhou Province Road in Xishi Village Applicant before: Duan Jingjing |
|
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20190605 Address after: 266034 Unit 3105, Building 2, 138 Shandong Road, North District, Qingdao City, Shandong Province Patentee after: Qingdao Boting Transportation Co., Ltd. Address before: 266071 Qiingdao University, 7 Hongkong East Road, Laoshan District, Qingdao, Shandong Patentee before: Qingdao University |