CN104232195B - 一种利用焦炉气联产甲醇和合成天然气的方法 - Google Patents
一种利用焦炉气联产甲醇和合成天然气的方法 Download PDFInfo
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- CN104232195B CN104232195B CN201310240935.2A CN201310240935A CN104232195B CN 104232195 B CN104232195 B CN 104232195B CN 201310240935 A CN201310240935 A CN 201310240935A CN 104232195 B CN104232195 B CN 104232195B
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- gas
- methanol
- methane
- synthesis
- natural gas
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- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 title claims abstract description 225
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 title claims abstract description 164
- 239000007789 gas Substances 0.000 title claims abstract description 145
- 238000000034 method Methods 0.000 title claims abstract description 58
- 239000000571 coke Substances 0.000 title claims abstract description 19
- 238000003786 synthesis reaction Methods 0.000 claims abstract description 77
- 230000015572 biosynthetic process Effects 0.000 claims abstract description 70
- 238000006243 chemical reaction Methods 0.000 claims abstract description 35
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims abstract description 20
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 17
- 238000004519 manufacturing process Methods 0.000 claims abstract description 17
- 239000003054 catalyst Substances 0.000 claims abstract description 14
- 238000006477 desulfuration reaction Methods 0.000 claims abstract description 12
- 230000023556 desulfurization Effects 0.000 claims abstract description 12
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000003949 liquefied natural gas Substances 0.000 claims abstract description 11
- 230000002194 synthesizing effect Effects 0.000 claims abstract description 6
- 229910052717 sulfur Inorganic materials 0.000 claims description 15
- 239000011593 sulfur Substances 0.000 claims description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 9
- 238000005057 refrigeration Methods 0.000 claims description 9
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 8
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 8
- 238000002485 combustion reaction Methods 0.000 claims description 6
- 238000007906 compression Methods 0.000 claims description 6
- 230000006835 compression Effects 0.000 claims description 5
- 239000008246 gaseous mixture Substances 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 4
- 229910021529 ammonia Inorganic materials 0.000 claims description 4
- 238000010521 absorption reaction Methods 0.000 abstract description 9
- -1 compound amine Chemical class 0.000 abstract description 4
- 239000002994 raw material Substances 0.000 abstract description 3
- 150000001335 aliphatic alkanes Chemical class 0.000 abstract description 2
- 239000000779 smoke Substances 0.000 abstract 3
- 230000003009 desulfurizing effect Effects 0.000 abstract 1
- 230000008014 freezing Effects 0.000 abstract 1
- 238000007710 freezing Methods 0.000 abstract 1
- 238000005984 hydrogenation reaction Methods 0.000 abstract 1
- 238000004064 recycling Methods 0.000 abstract 1
- 230000001105 regulatory effect Effects 0.000 abstract 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 34
- 238000000926 separation method Methods 0.000 description 15
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 14
- 229930195733 hydrocarbon Natural products 0.000 description 14
- 150000002430 hydrocarbons Chemical class 0.000 description 12
- 239000000047 product Substances 0.000 description 11
- 239000003546 flue gas Substances 0.000 description 10
- 239000003345 natural gas Substances 0.000 description 8
- 239000004215 Carbon black (E152) Substances 0.000 description 7
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 7
- 239000006227 byproduct Substances 0.000 description 6
- 239000001257 hydrogen Substances 0.000 description 6
- 229910052739 hydrogen Inorganic materials 0.000 description 6
- 239000012263 liquid product Substances 0.000 description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 5
- 238000001179 sorption measurement Methods 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 239000003502 gasoline Substances 0.000 description 4
- 239000012528 membrane Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 125000001741 organic sulfur group Chemical group 0.000 description 4
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 3
- 230000003197 catalytic effect Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- DLINORNFHVEIFE-UHFFFAOYSA-N hydrogen peroxide;zinc Chemical compound [Zn].OO DLINORNFHVEIFE-UHFFFAOYSA-N 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 239000002918 waste heat Substances 0.000 description 3
- 229940105296 zinc peroxide Drugs 0.000 description 3
- WFCQTAXSWSWIHS-UHFFFAOYSA-N 4-[bis(4-hydroxyphenyl)methyl]phenol Chemical compound C1=CC(O)=CC=C1C(C=1C=CC(O)=CC=1)C1=CC=C(O)C=C1 WFCQTAXSWSWIHS-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000003245 coal Substances 0.000 description 2
- 238000004939 coking Methods 0.000 description 2
- 239000000567 combustion gas Substances 0.000 description 2
- 239000002283 diesel fuel Substances 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 235000003642 hunger Nutrition 0.000 description 2
- 238000005201 scrubbing Methods 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000004148 unit process Methods 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000006298 dechlorination reaction Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000037351 starvation Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002912 waste gas Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310240935.2A CN104232195B (zh) | 2013-06-18 | 2013-06-18 | 一种利用焦炉气联产甲醇和合成天然气的方法 |
| JP2014125647A JP6347995B2 (ja) | 2013-06-18 | 2014-06-18 | コークス炉ガスによりメタノール及び合成天然ガスを同時生産する方法並びに該方法を達成するためのプラント |
| UAA201406869A UA118650C2 (uk) | 2013-06-18 | 2014-06-18 | Спосіб спільного виробництва метанолу і синтезованого природного газу з коксового газу та установка для здійснення цього способу |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310240935.2A CN104232195B (zh) | 2013-06-18 | 2013-06-18 | 一种利用焦炉气联产甲醇和合成天然气的方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104232195A CN104232195A (zh) | 2014-12-24 |
| CN104232195B true CN104232195B (zh) | 2017-02-08 |
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| CN201310240935.2A Active CN104232195B (zh) | 2013-06-18 | 2013-06-18 | 一种利用焦炉气联产甲醇和合成天然气的方法 |
Country Status (3)
| Country | Link |
|---|---|
| JP (1) | JP6347995B2 (enExample) |
| CN (1) | CN104232195B (enExample) |
| UA (1) | UA118650C2 (enExample) |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104418703B (zh) * | 2013-09-04 | 2017-02-15 | 中国石油化工股份有限公司 | 一种以焦炉气为原料的串联甲醇、甲烷合成工艺 |
| CN104447196B (zh) * | 2014-12-19 | 2016-03-30 | 北京宝塔三聚能源科技有限公司 | 一种以焦炉气为原料联产甲醇和甲烷的工艺 |
| JP6134347B2 (ja) * | 2015-03-30 | 2017-05-24 | 積水化学工業株式会社 | 有価物生成方法及び装置 |
| CN105016297B (zh) * | 2015-07-03 | 2017-09-19 | 赛鼎工程有限公司 | 一种合成气的制备方法 |
| CN105061142B (zh) * | 2015-07-31 | 2018-02-06 | 赛鼎工程有限公司 | 一种由焦炉煤气合成低碳醇并副产氢气的工艺 |
| FR3050206B1 (fr) | 2016-04-15 | 2018-05-11 | Engie | Dispositif et procede d'hydrogenation pour produire du methanol et dispositif et procede de cogeneration de methanol et de methane de synthese |
| FR3050123B1 (fr) * | 2016-04-15 | 2021-01-22 | Engie | Dispositif et procede d'hydrogenation du co2 pour produire du methanol et dispositif et procede de cogeneration de methanol et de methane de synthese |
| CN106281519B (zh) * | 2016-10-21 | 2021-09-14 | 山西高碳能源低碳化利用研究设计院有限公司 | 带有膜分离器的焦炉煤气甲烷化装置和方法 |
| CN106753628A (zh) * | 2017-01-19 | 2017-05-31 | 上海华西化工科技有限公司 | 一种焦炉煤气制lng联产甲醇的方法及装置 |
| CN108101749A (zh) * | 2017-07-19 | 2018-06-01 | 湖北申昙环保新材料有限公司 | 焦炉煤气生产甲醇的方法 |
| CN108409531A (zh) * | 2018-05-07 | 2018-08-17 | 陈峰华 | 利用兰炭尾气生产甲醇、天然气、合成氨的系统及方法 |
| CN110182761B (zh) * | 2019-05-05 | 2023-03-21 | 杨皓 | 一种焦炉气转化制合成气的工艺 |
| WO2021045101A1 (ja) * | 2019-09-03 | 2021-03-11 | 国立大学法人静岡大学 | メタンを製造する方法、及び製造システム |
| JP7628399B2 (ja) * | 2020-07-01 | 2025-02-10 | 大阪瓦斯株式会社 | メタノール及びメタンの併産方法並びにメタノール及びメタンの併産設備 |
| CN111925847A (zh) * | 2020-07-07 | 2020-11-13 | 中国石油集团工程股份有限公司 | 一种通过加氢脱除天然气中有机硫的工艺 |
| CN112742336B (zh) * | 2020-11-27 | 2022-12-02 | 中国煤层气集团有限公司 | 一种碳氢气化反应器 |
| CN113150849A (zh) * | 2021-05-26 | 2021-07-23 | 杨皓 | 一种焦炉气生产lng的改进工艺 |
| JP7692305B2 (ja) * | 2021-08-10 | 2025-06-13 | 大阪瓦斯株式会社 | 高発熱量燃料ガスの製造方法及び高発熱量燃料ガスの製造設備 |
| CN116179248B (zh) * | 2021-11-29 | 2025-05-09 | 中石化南京化工研究院有限公司 | 焦炉气甲烷化制天然气的方法和系统 |
| CN114317053B (zh) * | 2021-12-31 | 2025-10-17 | 北京北科欧远科技有限公司 | 焦炉气与二氧化碳制低碳甲醇联产液化天然气方法和设备 |
| CN114773154A (zh) * | 2022-06-09 | 2022-07-22 | 迁安市乾元科技有限公司 | 一种用焦炉煤气联产lng和甲醇的方法 |
| CN117736778A (zh) * | 2022-09-14 | 2024-03-22 | 中国石油化工股份有限公司 | 联产甲醇和天然气的方法及其装置 |
| CN115888313B (zh) * | 2022-11-11 | 2024-05-31 | 西南化工研究设计院有限公司 | 焦炉煤气制燃料电池氢气和管道天然气的产能调节工艺 |
| CN117756604A (zh) * | 2023-12-21 | 2024-03-26 | 太原理工大学 | 一种焦炉煤气耦合焦炉烟气co2制甲醇工艺 |
| CN118479957A (zh) * | 2024-07-12 | 2024-08-13 | 浙江吉利控股集团有限公司 | 一种甲醇制备工艺及制备系统 |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1373113A (zh) * | 2002-03-20 | 2002-10-09 | 郭拥军 | 一种焦炉气合成甲醇的方法 |
| CN101550052A (zh) * | 2008-11-19 | 2009-10-07 | 新奥新能(北京)科技有限公司 | 含甲烷合成气生产甲醇联产甲烷工艺 |
| CN101597527A (zh) * | 2009-07-07 | 2009-12-09 | 山西科灵环境工程设计技术有限公司 | 一种利用焦炉气制取合成天然气的方法 |
| CN101607859A (zh) * | 2009-07-21 | 2009-12-23 | 太原理工大学 | 一种焦炉气生产甲烷的工艺 |
| CN101704712A (zh) * | 2009-10-29 | 2010-05-12 | 山西焦化股份有限公司 | 焦炉煤气配水煤气低压合成甲醇工艺方法 |
| CN102585951A (zh) * | 2012-03-07 | 2012-07-18 | 四川天一科技股份有限公司 | 一种由焦炉气联产液化合成天然气、纯氢和甲醇的新工艺 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2729921C3 (de) * | 1977-07-02 | 1985-01-03 | Metallgesellschaft Ag, 6000 Frankfurt | Verfahren zur Erzeugung eines mit Erdgas austauschbaren Gases |
| JPH04243845A (ja) * | 1991-01-25 | 1992-08-31 | Nippon Steel Corp | 製鉄排ガスとコークス炉ガスを用いたメタノールの製造方法 |
| JP2000109440A (ja) * | 1998-08-06 | 2000-04-18 | Nippon Steel Corp | メタノ―ルの合成方法 |
| CN102079689B (zh) * | 2009-11-30 | 2012-04-25 | 四川达兴能源股份有限公司 | 生产甲醇的方法和设备 |
-
2013
- 2013-06-18 CN CN201310240935.2A patent/CN104232195B/zh active Active
-
2014
- 2014-06-18 JP JP2014125647A patent/JP6347995B2/ja active Active
- 2014-06-18 UA UAA201406869A patent/UA118650C2/uk unknown
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1373113A (zh) * | 2002-03-20 | 2002-10-09 | 郭拥军 | 一种焦炉气合成甲醇的方法 |
| CN101550052A (zh) * | 2008-11-19 | 2009-10-07 | 新奥新能(北京)科技有限公司 | 含甲烷合成气生产甲醇联产甲烷工艺 |
| CN101597527A (zh) * | 2009-07-07 | 2009-12-09 | 山西科灵环境工程设计技术有限公司 | 一种利用焦炉气制取合成天然气的方法 |
| CN101607859A (zh) * | 2009-07-21 | 2009-12-23 | 太原理工大学 | 一种焦炉气生产甲烷的工艺 |
| CN101704712A (zh) * | 2009-10-29 | 2010-05-12 | 山西焦化股份有限公司 | 焦炉煤气配水煤气低压合成甲醇工艺方法 |
| CN102585951A (zh) * | 2012-03-07 | 2012-07-18 | 四川天一科技股份有限公司 | 一种由焦炉气联产液化合成天然气、纯氢和甲醇的新工艺 |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2015007039A (ja) | 2015-01-15 |
| JP6347995B2 (ja) | 2018-06-27 |
| CN104232195A (zh) | 2014-12-24 |
| UA118650C2 (uk) | 2019-02-25 |
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Address after: Liuhe District of Nanjing City, Jiangsu province 210048 geguan Road No. 699 Patentee after: China Petroleum & Chemical Corp. Patentee after: SINOPEC NANJING CHEMICAL RESEARCH INSTITUTE Co.,Ltd. Address before: Liuhe District of Nanjing City, Jiangsu province 210048 geguan Road No. 699 Patentee before: China Petroleum & Chemical Corp. Patentee before: Nanhua Group Research Institute |
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