CN104163817A - 一种含呋喃自修复基团的环氧树脂及其制备方法 - Google Patents
一种含呋喃自修复基团的环氧树脂及其制备方法 Download PDFInfo
- Publication number
- CN104163817A CN104163817A CN201410049119.8A CN201410049119A CN104163817A CN 104163817 A CN104163817 A CN 104163817A CN 201410049119 A CN201410049119 A CN 201410049119A CN 104163817 A CN104163817 A CN 104163817A
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- CN
- China
- Prior art keywords
- epoxy resin
- group
- weight part
- selfreparing
- resin containing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003822 epoxy resin Substances 0.000 title claims abstract description 31
- 229920000647 polyepoxide Polymers 0.000 title claims abstract description 31
- 238000002360 preparation method Methods 0.000 title claims description 10
- YLQBMQCUIZJEEH-UHFFFAOYSA-N Furan Chemical compound C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 title abstract description 6
- LRWZZZWJMFNZIK-UHFFFAOYSA-N 2-chloro-3-methyloxirane Chemical compound CC1OC1Cl LRWZZZWJMFNZIK-UHFFFAOYSA-N 0.000 claims abstract description 8
- BOKGTLAJQHTOKE-UHFFFAOYSA-N 1,5-dihydroxynaphthalene Chemical compound C1=CC=C2C(O)=CC=CC2=C1O BOKGTLAJQHTOKE-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000002994 raw material Substances 0.000 claims abstract description 3
- 238000006243 chemical reaction Methods 0.000 claims description 16
- 150000002240 furans Chemical class 0.000 claims description 14
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 12
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- 238000004821 distillation Methods 0.000 claims description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 6
- 150000001412 amines Chemical class 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- KLWDDBHWNBBEBZ-UHFFFAOYSA-N 2-[[5-(oxiran-2-ylmethoxy)naphthalen-1-yl]oxymethyl]oxirane Chemical compound C1OC1COC(C1=CC=C2)=CC=CC1=C2OCC1CO1 KLWDDBHWNBBEBZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000004593 Epoxy Substances 0.000 claims description 4
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 claims description 4
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 claims description 4
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 4
- 229940043265 methyl isobutyl ketone Drugs 0.000 claims description 4
- 239000003444 phase transfer catalyst Substances 0.000 claims description 4
- 239000002904 solvent Substances 0.000 claims description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 3
- DPDMMXDBJGCCQC-UHFFFAOYSA-N [Na].[Cl] Chemical compound [Na].[Cl] DPDMMXDBJGCCQC-UHFFFAOYSA-N 0.000 claims description 3
- 238000005406 washing Methods 0.000 claims description 3
- UUZYBYIOAZTMGC-UHFFFAOYSA-M benzyl(trimethyl)azanium;bromide Chemical compound [Br-].C[N+](C)(C)CC1=CC=CC=C1 UUZYBYIOAZTMGC-UHFFFAOYSA-M 0.000 claims description 2
- KXHPPCXNWTUNSB-UHFFFAOYSA-M benzyl(trimethyl)azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CC1=CC=CC=C1 KXHPPCXNWTUNSB-UHFFFAOYSA-M 0.000 claims description 2
- 230000035484 reaction time Effects 0.000 claims description 2
- 239000008096 xylene Substances 0.000 claims description 2
- 239000002131 composite material Substances 0.000 abstract description 5
- 239000003795 chemical substances by application Substances 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 2
- 239000002253 acid Substances 0.000 abstract 1
- 125000003700 epoxy group Chemical group 0.000 abstract 1
- DDRPCXLAQZKBJP-UHFFFAOYSA-N furfurylamine Chemical compound NCC1=CC=CO1 DDRPCXLAQZKBJP-UHFFFAOYSA-N 0.000 abstract 1
- 150000003949 imides Chemical class 0.000 abstract 1
- 125000001624 naphthyl group Chemical group 0.000 abstract 1
- 239000000758 substrate Substances 0.000 abstract 1
- 239000000463 material Substances 0.000 description 7
- 238000000034 method Methods 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 238000005698 Diels-Alder reaction Methods 0.000 description 4
- 239000011159 matrix material Substances 0.000 description 4
- 238000005070 sampling Methods 0.000 description 4
- MQJKPEGWNLWLTK-UHFFFAOYSA-N Dapsone Chemical compound C1=CC(N)=CC=C1S(=O)(=O)C1=CC=C(N)C=C1 MQJKPEGWNLWLTK-UHFFFAOYSA-N 0.000 description 3
- 238000004807 desolvation Methods 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 230000002441 reversible effect Effects 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 0 CC=CC=C(c1cc(OCC(CN(CC(COc2c(cccc3*CC4OC4)c3ccc2)O)Cc2ccc[o]2)O)ccc1)OCC1OC1 Chemical compound CC=CC=C(c1cc(OCC(CN(CC(COc2c(cccc3*CC4OC4)c3ccc2)O)Cc2ccc[o]2)O)ccc1)OCC1OC1 0.000 description 2
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000010907 mechanical stirring Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- 239000012265 solid product Substances 0.000 description 2
- 229920001187 thermosetting polymer Polymers 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- 241000219495 Betulaceae Species 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 238000007259 addition reaction Methods 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- -1 dissolve Chemical compound 0.000 description 1
- 238000010292 electrical insulation Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 125000005462 imide group Chemical group 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 150000002790 naphthalenes Chemical class 0.000 description 1
- HPOKESDSMZRZLC-UHFFFAOYSA-N propan-2-one;hydrochloride Chemical compound Cl.CC(C)=O HPOKESDSMZRZLC-UHFFFAOYSA-N 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000012815 thermoplastic material Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D407/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having oxygen atoms as the only ring hetero atoms, not provided for by group C07D405/00
- C07D407/14—Heterocyclic compounds containing two or more hetero rings, at least one ring having oxygen atoms as the only ring hetero atoms, not provided for by group C07D405/00 containing three or more hetero rings
Abstract
Description
Claims (5)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410049119.8A CN104163817B (zh) | 2014-02-12 | 2014-02-12 | 一种含呋喃自修复基团的环氧树脂及其制备方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410049119.8A CN104163817B (zh) | 2014-02-12 | 2014-02-12 | 一种含呋喃自修复基团的环氧树脂及其制备方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104163817A true CN104163817A (zh) | 2014-11-26 |
| CN104163817B CN104163817B (zh) | 2017-02-22 |
Family
ID=51907819
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410049119.8A Active CN104163817B (zh) | 2014-02-12 | 2014-02-12 | 一种含呋喃自修复基团的环氧树脂及其制备方法 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104163817B (zh) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108586708A (zh) * | 2018-05-14 | 2018-09-28 | 北京化工大学 | 一种热可逆自修复环氧树脂及制备方法 |
| CN109354829A (zh) * | 2018-11-05 | 2019-02-19 | 镇江市鑫泰绝缘材料有限公司 | 一种用于电气设备绝缘的自修复环氧树脂的制作方法 |
| CN109354830A (zh) * | 2018-11-05 | 2019-02-19 | 镇江市鑫泰绝缘材料有限公司 | 一种用于电气绝缘的自修复环氧树脂的制备及修复方法 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002284847A (ja) * | 2001-03-26 | 2002-10-03 | Nippon Kayaku Co Ltd | エポキシ樹脂組成物及びその硬化物 |
| CN103059265A (zh) * | 2013-01-20 | 2013-04-24 | 安徽善孚新材料科技有限公司 | 一种含萘环结构无卤阻燃环氧树脂及其制备方法 |
-
2014
- 2014-02-12 CN CN201410049119.8A patent/CN104163817B/zh active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002284847A (ja) * | 2001-03-26 | 2002-10-03 | Nippon Kayaku Co Ltd | エポキシ樹脂組成物及びその硬化物 |
| CN103059265A (zh) * | 2013-01-20 | 2013-04-24 | 安徽善孚新材料科技有限公司 | 一种含萘环结构无卤阻燃环氧树脂及其制备方法 |
Non-Patent Citations (2)
| Title |
|---|
| 凌俊利: "含呋喃基双酚型环氧树脂的制备及其固化机理的研究", 《北京化工大学硕士研究生学位论文》 * |
| 田巧: "热可逆型自修复环氧树脂", 《中山大学博士学位论文》 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108586708A (zh) * | 2018-05-14 | 2018-09-28 | 北京化工大学 | 一种热可逆自修复环氧树脂及制备方法 |
| CN109354829A (zh) * | 2018-11-05 | 2019-02-19 | 镇江市鑫泰绝缘材料有限公司 | 一种用于电气设备绝缘的自修复环氧树脂的制作方法 |
| CN109354830A (zh) * | 2018-11-05 | 2019-02-19 | 镇江市鑫泰绝缘材料有限公司 | 一种用于电气绝缘的自修复环氧树脂的制备及修复方法 |
| CN109354829B (zh) * | 2018-11-05 | 2020-11-10 | 镇江市鑫泰绝缘材料有限公司 | 一种用于电气设备绝缘的自修复环氧树脂的制作方法 |
| CN109354830B (zh) * | 2018-11-05 | 2021-02-26 | 镇江市鑫泰绝缘材料有限公司 | 一种用于电气绝缘的自修复环氧树脂的制备及修复方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104163817B (zh) | 2017-02-22 |
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