CN104105736B - 生产聚对苯二甲酸乙二酯用的新催化剂络合物的合成方法 - Google Patents

生产聚对苯二甲酸乙二酯用的新催化剂络合物的合成方法 Download PDF

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Publication number
CN104105736B
CN104105736B CN201280061996.6A CN201280061996A CN104105736B CN 104105736 B CN104105736 B CN 104105736B CN 201280061996 A CN201280061996 A CN 201280061996A CN 104105736 B CN104105736 B CN 104105736B
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CN
China
Prior art keywords
catalyst
polyethylene terephthalate
reaction
pet
zinc salt
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Expired - Fee Related
Application number
CN201280061996.6A
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English (en)
Chinese (zh)
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CN104105736A (zh
Inventor
B·奥－法胡德
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Saudi Basic Industries Corp
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Saudi Basic Industries Corp
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Publication of CN104105736A publication Critical patent/CN104105736A/zh
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Expired - Fee Related legal-status Critical Current
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/84—Boron, aluminium, gallium, indium, thallium, rare-earth metals, or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/16—Dicarboxylic acids and dihydroxy compounds
    • C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
    • C08G63/181—Acids containing aromatic rings
    • C08G63/183—Terephthalic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/83—Alkali metals, alkaline earth metals, beryllium, magnesium, copper, silver, gold, zinc, cadmium, mercury, manganese, or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/20—Complexes comprising metals of Group II (IIA or IIB) as the central metal
    • B01J2531/26—Zinc

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CN201280061996.6A 2011-12-16 2012-12-13 生产聚对苯二甲酸乙二酯用的新催化剂络合物的合成方法 Expired - Fee Related CN104105736B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP11009910.8 2011-12-16
EP11009910 2011-12-16
PCT/EP2012/005135 WO2013087199A1 (en) 2011-12-16 2012-12-13 Process for synthesizing a new catalyst complex for the production of polyethylene terephthlate

Publications (2)

Publication Number Publication Date
CN104105736A CN104105736A (zh) 2014-10-15
CN104105736B true CN104105736B (zh) 2016-08-24

Family

ID=47469868

Family Applications (1)

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CN201280061996.6A Expired - Fee Related CN104105736B (zh) 2011-12-16 2012-12-13 生产聚对苯二甲酸乙二酯用的新催化剂络合物的合成方法

Country Status (5)

Country Link
US (1) US8629234B2 (https=)
EP (1) EP2791202B1 (https=)
JP (1) JP2015505882A (https=)
CN (1) CN104105736B (https=)
WO (1) WO2013087199A1 (https=)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105968332A (zh) * 2016-07-12 2016-09-28 安徽红太阳新材料有限公司 催化环酯聚合的苯并硼唑金属配合物及其应用
TWI664186B (zh) * 2017-10-05 2019-07-01 遠東新世紀股份有限公司 磷酸酯物質及其製備方法、含磷酸酯物質的聚酯樹脂及其製備方法
US20230312915A1 (en) * 2020-04-21 2023-10-05 Solvay Specialty Polymers Usa, Llc Production process of polyester micropowders
CN111423569B (zh) * 2020-04-22 2022-11-15 浙江恒逸石化研究院有限公司 一种抑菌可降解聚对苯二甲酸乙二醇酯共聚酯及其制备方法

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB804495A (en) * 1954-10-14 1958-11-19 Gevaert Photo Prod Nv Improvements in or relating to the preparation of poly-alkylene terephthalates and fibres and films made therefrom
US3530098A (en) * 1966-08-16 1970-09-22 Hoechst Ag Process for preparing linear polyesters using boron - containing mixed anhydrides as catalysts
US4254241A (en) * 1979-12-12 1981-03-03 Union Carbide Corporation Process for producing polyoxyalkylene glycol modified polyesters
CN1408001A (zh) * 1999-12-10 2003-04-02 陶氏环球技术公司 缩聚反应的催化剂体系
CN1630674A (zh) * 2002-02-14 2005-06-22 三井化学株式会社 聚酯树脂及聚酯制备用催化剂,用此催化剂制备聚酯树脂的方法,用此催化剂获得的聚酯树脂及含有此聚酯树脂的中空模制容器
CN1930210A (zh) * 2004-03-11 2007-03-14 沙特基础工业公司 由对苯二甲酸和乙二醇制备聚对苯二甲酸乙二醇酯的催化剂组合物，及其制备方法

Family Cites Families (16)

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Publication number Priority date Publication date Assignee Title
NL97835C (https=) 1953-04-06 1900-01-01
GB805534A (en) * 1955-03-18 1958-12-10 Gevaert Photo Prod Nv Improvements in or relating to catalytic condensation of diglycolesters of dicarboxylic acids
US2973339A (en) 1955-08-11 1961-02-28 Linear terephthalate polyesters of
US3047536A (en) 1957-02-05 1962-07-31 Dow Chemical Co Polyesters
US3133113A (en) 1960-09-27 1964-05-12 Jefferson Chem Co Inc Method for preparing polycarbonate esters
JPS568431A (en) 1979-07-03 1981-01-28 Nippon Ester Co Ltd Production of polyester
JPH0781002B2 (ja) 1988-12-09 1995-08-30 三菱レイヨン株式会社 共重合ポリエステルの製造方法
US5017680A (en) 1990-07-03 1991-05-21 Eastman Kodak Company Process and catalyst-inhibitor systems for preparing poly(ethylene terephthalate)
JPH10330466A (ja) * 1997-06-04 1998-12-15 Polyplastics Co ポリエステル樹脂の製造法
US6133404A (en) 1998-12-26 2000-10-17 National Institute Of Technology And Quality Polyester and formation process thereof
DE60102079T2 (de) * 2000-08-22 2004-12-09 Mitsui Chemicals, Inc. Katalysatoren für die herstellung von polyester, verfahren zur herstellung von polyester, und polyester
US6489433B2 (en) 2001-02-23 2002-12-03 E. I. Du Pont De Nemours And Company Metal-containing composition and process therewith
JP2004217887A (ja) * 2002-12-27 2004-08-05 Mitsubishi Chemicals Corp ポリエステル製造用触媒およびそれを用いるポリエステルの製造方法
JP2011526876A (ja) 2008-06-30 2011-10-20 エムイーエムシー・エレクトロニック・マテリアルズ・インコーポレイテッド アンバランス磁場及び同方向回転を用いた成長シリコン結晶の融液−固体界面形状の制御方法
TWI473832B (zh) 2009-03-13 2015-02-21 Saudi Basic Ind Corp 聚對酞酸乙二酯的製造方法
EP2287225A1 (en) 2009-08-20 2011-02-23 Saudi Basic Industries Corporation Process for making polyethylene terephthalate

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB804495A (en) * 1954-10-14 1958-11-19 Gevaert Photo Prod Nv Improvements in or relating to the preparation of poly-alkylene terephthalates and fibres and films made therefrom
US3530098A (en) * 1966-08-16 1970-09-22 Hoechst Ag Process for preparing linear polyesters using boron - containing mixed anhydrides as catalysts
US4254241A (en) * 1979-12-12 1981-03-03 Union Carbide Corporation Process for producing polyoxyalkylene glycol modified polyesters
CN1408001A (zh) * 1999-12-10 2003-04-02 陶氏环球技术公司 缩聚反应的催化剂体系
CN1630674A (zh) * 2002-02-14 2005-06-22 三井化学株式会社 聚酯树脂及聚酯制备用催化剂,用此催化剂制备聚酯树脂的方法,用此催化剂获得的聚酯树脂及含有此聚酯树脂的中空模制容器
CN1930210A (zh) * 2004-03-11 2007-03-14 沙特基础工业公司 由对苯二甲酸和乙二醇制备聚对苯二甲酸乙二醇酯的催化剂组合物，及其制备方法

Also Published As

Publication number Publication date
WO2013087199A1 (en) 2013-06-20
EP2791202A1 (en) 2014-10-22
US8629234B2 (en) 2014-01-14
JP2015505882A (ja) 2015-02-26
EP2791202B1 (en) 2019-05-08
CN104105736A (zh) 2014-10-15
US20130158227A1 (en) 2013-06-20
WO2013087199A8 (en) 2014-07-31

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