CN104093751B - 制备具有减少的冷流的聚二烯和聚二烯共聚物的方法 - Google Patents

制备具有减少的冷流的聚二烯和聚二烯共聚物的方法 Download PDF

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Publication number
CN104093751B
CN104093751B CN201280068432.5A CN201280068432A CN104093751B CN 104093751 B CN104093751 B CN 104093751B CN 201280068432 A CN201280068432 A CN 201280068432A CN 104093751 B CN104093751 B CN 104093751B
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polymer
neodymium
diisocyanate
triol
polymerization
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Chinese (zh)
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CN104093751A (zh
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凯文·麦考利
特伦斯·霍根
威廉·赫根洛泽
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Bridgestone Corp
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/67—Unsaturated compounds having active hydrogen
    • C08G18/69—Polymers of conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00—Chemical modification of rubber
    • C08C19/30—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule
    • C08C19/34—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with oxygen or oxygen-containing groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00—Chemical modification of rubber
    • C08C19/30—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule
    • C08C19/42—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with metals or metal-containing groups
    • C08C19/44—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with metals or metal-containing groups of polymers containing metal atoms exclusively at one or both ends of the skeleton
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F36/06—Butadiene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3203—Polyhydroxy compounds
    • C08G18/3206—Polyhydroxy compounds aliphatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/73—Polyisocyanates or polyisothiocyanates acyclic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L15/00—Compositions of rubber derivatives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00—Chemical modification of rubber
    • C08C19/22—Incorporating nitrogen atoms into the molecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2380/00—Tyres

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polyurethanes Or Polyureas (AREA)
CN201280068432.5A 2011-12-09 2012-12-10 制备具有减少的冷流的聚二烯和聚二烯共聚物的方法 Expired - Fee Related CN104093751B (zh)

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US201161568920P 2011-12-09 2011-12-09
US61/568,920 2011-12-09
PCT/US2012/068681 WO2013086480A2 (en) 2011-12-09 2012-12-10 Method for producing polydienes and polydiene copolymers with reduced cold flow

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CN104093751A CN104093751A (zh) 2014-10-08
CN104093751B true CN104093751B (zh) 2017-05-31

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US (1) US9512263B2 (OSRAM)
EP (1) EP2788394B1 (OSRAM)
JP (1) JP6144275B2 (OSRAM)
KR (1) KR101933751B1 (OSRAM)
CN (1) CN104093751B (OSRAM)
RU (1) RU2627705C2 (OSRAM)
SG (1) SG11201402844TA (OSRAM)
WO (1) WO2013086480A2 (OSRAM)

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US10730961B2 (en) 2015-07-29 2020-08-04 Bridgestone Corporation Processes for preparing functionahzed polymers, related functionalizing compound and preparation thereof
US10202474B2 (en) * 2015-09-11 2019-02-12 Bridgestone Corporation Process for producing polydienes
JP2020504205A (ja) 2016-12-28 2020-02-06 ファイヤーストーン ポリマーズ エルエルシー 低減された粘着性を有するポリマーを作製する方法、及びこれらのポリマーを組み込んだゴム組成物
WO2021201289A1 (ja) * 2020-04-03 2021-10-07 旭化成株式会社 共役ジエン系重合体、共役ジエン系重合体の製造方法、共役ジエン系重合体組成物、及びゴム組成物

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CN101475694A (zh) * 2007-12-31 2009-07-08 株式会社普利司通 改进聚合物耐冷流性的方法
CN101600737A (zh) * 2006-12-27 2009-12-09 Jsr株式会社 改性共轭二烯系聚合物的制造方法、改性共轭二烯系聚合物及橡胶组合物
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KR100792414B1 (ko) * 2006-07-20 2008-01-08 금호석유화학 주식회사 높은 1, 4-시스 함량을 지닌 폴리부타디엔 고무 나노복합재및 이의 제조방법
CN101600737A (zh) * 2006-12-27 2009-12-09 Jsr株式会社 改性共轭二烯系聚合物的制造方法、改性共轭二烯系聚合物及橡胶组合物
CN101874044A (zh) * 2007-10-12 2010-10-27 株式会社普利司通 用杂环腈化合物官能化的聚合物
CN101475694A (zh) * 2007-12-31 2009-07-08 株式会社普利司通 改进聚合物耐冷流性的方法
CN101665600A (zh) * 2008-08-05 2010-03-10 株式会社普利司通 改进聚合物耐冷流性的方法

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JP2015500374A (ja) 2015-01-05
EP2788394B1 (en) 2016-04-06
WO2013086480A2 (en) 2013-06-13
RU2014127902A (ru) 2016-01-27
US9512263B2 (en) 2016-12-06
SG11201402844TA (en) 2014-07-30
WO2013086480A3 (en) 2013-08-01
US20140357795A1 (en) 2014-12-04
JP6144275B2 (ja) 2017-06-07
KR20140100566A (ko) 2014-08-14
KR101933751B1 (ko) 2018-12-28

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