CN104093730A - 用于制备茂金属络合物的方法 - Google Patents

用于制备茂金属络合物的方法 Download PDF

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Publication number
CN104093730A
CN104093730A CN201280068063.XA CN201280068063A CN104093730A CN 104093730 A CN104093730 A CN 104093730A CN 201280068063 A CN201280068063 A CN 201280068063A CN 104093730 A CN104093730 A CN 104093730A
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CN
China
Prior art keywords
indenyl
formula
group
bis
compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
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CN201280068063.XA
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English (en)
Chinese (zh)
Inventor
A·H·阿尔-汉迈迪
A·阿布拉卡巴
C·格尔
H·奥特
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Saudi Basic Industries Corp
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Saudi Basic Industries Corp
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Publication date
Application filed by Saudi Basic Industries Corp filed Critical Saudi Basic Industries Corp
Priority to CN201711094062.3A priority Critical patent/CN107721797A/zh
Publication of CN104093730A publication Critical patent/CN104093730A/zh
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/72—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44
    • C08F4/74—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from refractory metals
    • C08F4/76—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from refractory metals selected from titanium, zirconium, hafnium, vanadium, niobium or tantalum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/32—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen
    • C07C1/321—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen the hetero-atom being a non-metal atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C13/00—Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
    • C07C13/28—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
    • C07C13/32—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C13/00—Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
    • C07C13/28—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
    • C07C13/32—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings
    • C07C13/36—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with a bicyclo ring system containing five carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C13/00—Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
    • C07C13/28—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
    • C07C13/32—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings
    • C07C13/38—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with a bicyclo ring system containing six carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Crystallography & Structural Chemistry (AREA)
CN201280068063.XA 2011-12-19 2012-12-13 用于制备茂金属络合物的方法 Pending CN104093730A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711094062.3A CN107721797A (zh) 2011-12-19 2012-12-13 用于制备茂金属络合物的方法

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP11009973 2011-12-19
EP11009973.6 2011-12-19
PCT/EP2012/005231 WO2013091836A1 (en) 2011-12-19 2012-12-13 Process for the preparation of metallocene complexes

Related Child Applications (1)

Application Number Title Priority Date Filing Date
CN201711094062.3A Division CN107721797A (zh) 2011-12-19 2012-12-13 用于制备茂金属络合物的方法

Publications (1)

Publication Number Publication Date
CN104093730A true CN104093730A (zh) 2014-10-08

Family

ID=47428556

Family Applications (2)

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CN201280068063.XA Pending CN104093730A (zh) 2011-12-19 2012-12-13 用于制备茂金属络合物的方法
CN201711094062.3A Pending CN107721797A (zh) 2011-12-19 2012-12-13 用于制备茂金属络合物的方法

Family Applications After (1)

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CN201711094062.3A Pending CN107721797A (zh) 2011-12-19 2012-12-13 用于制备茂金属络合物的方法

Country Status (5)

Country Link
US (1) US9234054B2 (https=)
EP (1) EP2800753B1 (https=)
JP (1) JP6454548B2 (https=)
CN (2) CN104093730A (https=)
WO (1) WO2013091836A1 (https=)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PT2800754T (pt) * 2011-12-19 2017-08-18 Saudi Basic Ind Corp (Sabic) Processo para a preparação de complexos metalocenos
EA032159B1 (ru) 2013-08-20 2019-04-30 Сауди Бейсик Индастриз Корпорейшн Способ получения 2,2'-бис-инденилбифенильных лигандов и их металлоценовых комплексов
EP3039028B1 (en) * 2013-08-30 2017-06-21 Saudi Basic Industries Corporation Bridged metallocene complex for olefin polymerization
US9758540B1 (en) 2016-05-25 2017-09-12 Chevron Phillips Chemical Company Lp Bicyclic bridged metallocene compounds and polymers produced therefrom
US9758600B1 (en) * 2016-05-25 2017-09-12 Chevron Phillips Chemical Company Lp Bicyclic bridged metallocene compounds and polymers produced therefrom

Citations (2)

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Publication number Priority date Publication date Assignee Title
CN1291986A (zh) * 1998-11-18 2001-04-18 蒙特尔技术有限公司 双(四氢茚基)金属茂作为烯烃聚合催化剂
US6342622B1 (en) * 1999-06-11 2002-01-29 Dsm B.V. Indenyl compounds for the polymerization of olefins

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IL85097A (en) 1987-01-30 1992-02-16 Exxon Chemical Patents Inc Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes
PL276385A1 (en) 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
US5055438A (en) 1989-09-13 1991-10-08 Exxon Chemical Patents, Inc. Olefin polymerization catalysts
DE69026907T2 (de) 1989-10-10 1996-10-10 Fina Technology Metallocenkatalysator mit Lewissäure und Alkylaluminium
ATE120768T1 (de) 1989-10-30 1995-04-15 Fina Technology Herstellung von metallocenkatalysatoren für olefinpolymerisation.
JP3115595B2 (ja) 1990-07-24 2000-12-11 三井化学株式会社 α―オレフィンの重合触媒及びそれを用いたポリ―α―オレフィンの製造方法
NL9101502A (nl) 1991-09-06 1993-04-01 Dsm Nv Werkwijze voor het bereiden van een gebrugde metalloceenverbinding alsmede een katalysatorcomponent en een werkwijze voor de polymerisatie van een olefinen.
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JPH08188610A (ja) * 1995-01-12 1996-07-23 Mitsui Petrochem Ind Ltd 新規な遷移金属化合物、オレフィン重合用触媒成分、オレフィン重合用触媒およびオレフィンの重合方法
IT1275777B1 (it) * 1995-07-06 1997-10-17 Enichem Spa Catalizzatore metallocenico per la (co)polimerizzazione delle olefine
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Also Published As

Publication number Publication date
US20140343238A1 (en) 2014-11-20
EP2800753B1 (en) 2018-05-23
CN107721797A (zh) 2018-02-23
JP6454548B2 (ja) 2019-01-16
WO2013091836A1 (en) 2013-06-27
US9234054B2 (en) 2016-01-12
EP2800753A1 (en) 2014-11-12
JP2015506916A (ja) 2015-03-05

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Application publication date: 20141008

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