Summary of the invention
Based on this, the invention provides a kind of compositions with Whitening, spot effect.
The concrete technical scheme solving the problems of the technologies described above is as follows:
A compositions with Whitening, spot effect, described compositions is mainly comprised of the component of following weight parts:
Glycyrrhiza glabra L. root extract: 0.05-0.2 part,
Fructus Phyllanthi fruit extract: 0.1-2 part,
Ascorbic acid glucoside: 0.1-2 part,
Bisabolol: 0.1-0.5 part,
Fructus piperis nigrum extract: 0.1-0.4 part,
Yeast extract: 1-15 part.
In some embodiment, described compositions is mainly comprised of the component of following weight parts therein:
Glycyrrhiza glabra L. root extract: 0.08-0.12 part,
Fructus Phyllanthi fruit extract: 1.3-1.7 part,
Ascorbic acid glucoside: 0.8-1.2 part,
Bisabolol: 0.25-0.35 part,
Fructus piperis nigrum extract: 0.15-0.25 part,
Yeast extract: 8-12 part.
In some embodiment, described compositions also comprises the component of following weight parts therein: Fructus Rubi extract 0.1-2 part, Ramulus et Folium Mussaendae Pubescentis extract 0.1-2 part.
In some embodiment, the weight portion of described Fructus Rubi extract is that the weight portion of 0.1-0.5, Ramulus et Folium Mussaendae Pubescentis extract is 0.1-0.5 therein.
In some embodiment, described compositions also comprises that weight portion is the plants essential oil of 0.1-0.8 therein.
In some embodiment, the weight portion of described plants essential oil is 0.25-0.35 therein.
Therein in some embodiment, described plants essential oil is the mixture of vanilla chrysanthemum quintessence oil, red autumnal leaves Herba Oxalidis Corniculatae quintessence oil and Flos Camelliae Japonicae quintessence oil, and in described mixture, the weight portion proportioning of vanilla chrysanthemum quintessence oil, red autumnal leaves Herba Oxalidis Corniculatae quintessence oil and Flos Camelliae Japonicae quintessence oil is 0.9-1.1:0.9-1.1:4-6.
Another object of the present invention is to provide a kind of cosmetics with Whitening, spot effect, it is mainly comprised of the component of following weight percentage ratio:
The hard ester group glucoside of spermaceti: 1-3wt%,
Cetearyl alcohol: 0.5-4wt%,
Herba Rosmarini Officinalis leaf oil: 0.005-0.2wt%,
Vegetable oil: 6-15.5wt%,
HANSHENGJIAO: 0.05-0.5wt%,
Hyaluronate sodium: 0.01-0.1wt%,
Polyhydric alcohol: 3-10wt%,
The above-mentioned compositions with Whitening, spot effect: 1.4-25wt%,
Antiseptic: 1-3wt%,
Deionized water: surplus.
Therein in some embodiment, described in there are the cosmetics of Whitening, spot effect, it is mainly comprised of the component of following weight percentage ratio:
The hard ester group glucoside of spermaceti: 1.5-2.5wt%,
Cetearyl alcohol: 1.5-2.5wt%,
Herba Rosmarini Officinalis leaf oil: 0.01-0.03wt%,
Vegetable oil: 11-13wt%,
HANSHENGJIAO: 0.1-0.3wt%,
Hyaluronate sodium: 0.01-0.03wt%,
Polyhydric alcohol: 5-7wt%,
The above-mentioned compositions with Whitening, spot effect: 12-17wt%,
Antiseptic: 1-3wt%,
Deionized water: surplus.
Therein in some embodiment, described in to have each component in the compositions of Whitening, spot effect percentage by weight in cosmetics as follows:
Glycyrrhiza glabra L. root extract: 0.05-0.2wt%,
Fructus Phyllanthi fruit extract: 0.1-2wt%,
Ascorbic acid glucoside: 0.1-2wt%,
Bisabolol: 0.1-0.5wt%,
Fructus piperis nigrum extract: 0.1-0.4wt%,
Yeast extract: 1-15wt%.
Therein in some embodiment, described in to have in the compositions of Whitening, spot effect the percentage by weight of each component in cosmetics as follows:
Glycyrrhiza glabra L. root extract: 0.08-0.12wt%,
Fructus Phyllanthi fruit extract: 1.3-1.7wt%,
Ascorbic acid glucoside: 0.8-1.2wt%,
Bisabolol: 0.25-0.35wt%,
Fructus piperis nigrum extract: 0.15-0.25wt%,
Yeast extract: 8-12wt%.
Therein in some embodiment, described in have in the compositions of Whitening, spot effect and also comprise following component, the percentage by weight of this component in cosmetics is: Fructus Rubi extract 0.1-2wt%, Ramulus et Folium Mussaendae Pubescentis extract 0.1-2wt%.
Therein in some embodiment, described in have in the compositions of Whitening, spot effect and also comprise following component, the percentage by weight of this component in cosmetics is: Fructus Rubi extract 0.1-0.5wt%, Ramulus et Folium Mussaendae Pubescentis extract 0.1-0.5wt%.
Therein in some embodiment, in the described compositions with Whitening, spot effect, also comprise plants essential oil, the percentage by weight of described plants essential oil in cosmetics is 0.1-0.8wt%, described plants essential oil is the mixture of vanilla chrysanthemum quintessence oil, red autumnal leaves Herba Oxalidis Corniculatae quintessence oil and Flos Camelliae Japonicae quintessence oil, and in described mixture, the weight portion proportioning of vanilla chrysanthemum quintessence oil, red autumnal leaves Herba Oxalidis Corniculatae quintessence oil and Flos Camelliae Japonicae quintessence oil is 0.9-1.1:0.9-1.1:4-6.
In some embodiment, the percentage by weight of described plants essential oil in cosmetics is 0.25-0.35wt% therein.
In some embodiment, the percentage by weight of described vegetable oil is 11-13wt% therein.
In some embodiment, described vegetable oil is at least one in Oleum Vitis viniferae, Rosehips oil, Radix Oenotherae erythrosepalae oil, Semen Tritici aestivi germ oil, Semen Maydis oil, Testa oryzae oil, Semen pruni armeniacae oil, olive oil, Jojoba oil, macadamia nut oil, shea butter or Camellia oil therein.
In some embodiment, described vegetable oil is Rosehips oil and Radix Oenotherae erythrosepalae oil therein, and the percentage by weight of described Radix Oenotherae erythrosepalae oil in cosmetics is 0.5-15wt%, and the percentage by weight of Rosehips oil is 0.5-15wt%.
In some embodiment, described polyhydric alcohol is at least one in glycerol, 1,3-PD or sorbitol therein.
Of the present invention a kind ofly have the compositions of Whitening, spot and cosmetics have the following advantages and beneficial effect:
1, the present invention is through a large amount of experiment of inventor and research, draw the compositions with Whitening, spot effect, it mainly comprises 6 kinds of components: Glycyrrhiza glabra L. root extract, Fructus Phyllanthi fruit extract, ascorbic acid glucoside, bisabolol, Fructus piperis nigrum extract and yeast extract, these 6 kinds of components are composite has significant Whitening, spot effect, can see through rapidly epidermis and reach deep skin tissue, focus on the activity of restraint of tyrosinase, each stage that melanin is formed is all played inhibitory action, inflammation-inhibiting, and provide sufficient its metabolism of Nutrients uptake for skin, integral body plays the synergy of light speckle from inside to outside, in addition, it also can composite Ramulus et Folium Mussaendae Pubescentis extract, Fructus Rubi extract and plants essential oil, further to improve the effect of Whitening, spot.
2, the raw material that the compositions of Whitening, spot of the present invention adopts is all natural origin, and it is safe and effective, and the while has also represented respect environment, respect consumer and rationally utilized the new trend of natural resources.
The specific embodiment
The hard ester group glucoside of spermaceti of the present invention is that primary emulsion, cetearyl alcohol are auxiliary emulsifying agent.The hard ester group glucoside of spermaceti is a kind of naturally occurring emulsifying agent, by spermol, stearyl alcohol and glucoside direct reaction under acidic catalyst condition, is made, and quality is gentle, and human body skin and eyes are not stimulated; Cetearyl alcohol is also a kind of raw material of natural origin, and by Oleum Gossypii semen, Petiolus Trachycarpi oil, through ester exchange, then high pressure adds hydrogen reduction and make, and has the effect that strengthens mastic sophistication, thickening, alleviates the greasy feeling of mastic.
Bisabolol of the present invention, is extracted from Chamomile, has remarkable antiinflammatory, antianaphylactic effect.
Herba Rosmarini Officinalis leaf oil of the present invention, is to extract and make from plant rosemary, can prevent that vegetable oil from becoming sour and the oxidized effect of effect thing.
At Radix Oenotherae erythrosepalae oil of the present invention, it is the oils and fats extracting from evening primrose seed; Rosehips oil, claims again Rosa Canina fruit oil, comes from a kind of Fruits of Wild Rosa Rugosa Thunb in South America.
HANSHENGJIAO of the present invention, claims again xanthan gum, by aerobic fermentation biotechnology, is made, and plant saccharide ferments through Xanthomonas campestris, and the outer heteropolysaccharide of a kind of acid born of the same parents of generation, in the present invention as thickening agent.
Hyaluronate sodium of the present invention, is to be mixed by the concentrated powder of glucose, peptone and yeast, and through fermentation, refining refinement makes, and is a kind of good biochemical wetting agent.
At glycerol of the present invention, by plant wet goods triglyceride cracking, obtain; 1,3-PD is that the sugar of originating by fermented maize makes, all on sale on the market.As the raw material of the commodity Zemea by name that DuPont Tate & Lyle Bio Products produces, Ke Sifa international trade (Guangzhou) company limited sells; Sorbitol is to be isolated in mountain strawberry.
Fructus Rubi extract of the present invention is provided by French Herbarom company, and the dry fruit extract of rosaceous plant rubus chingii Hu contains a large amount of containing organic acid, saccharide and ascorbic acid glucoside and cupreols.
Ramulus et Folium Mussaendae Pubescentis extract of the present invention is provided by French Herbarom company, and Ramulus et Folium Mussaendae Pubescentis is again acupuncture needle, China's special product.
Glycyrrhiza glabra L. root extract of the present invention is provided by Shanghai Ao Li Industrial Co., Ltd, is the multi-functional high purity effective component extracting from a kind of special Radix Glycyrrhizae-Glycyrrhiza glabra L..The Glycyrrhiza glabra L. root extract source that it adopts is to pluck from Glycyrrhiza glabra L. plantation, northwest, and artificial implantation passes through cleaning, oven dry, pulverizing, immersion, supercritical CO through choosing the root of 3 years raw Glycyrrhiza glabra L. after results
2extraction, alcohol extraction, chromatographic isolation, membrane filtration, secondarily purified, the dry Deng13 of spraying road technique, the working substance content obtaining surpasses 40% Glycyrrhiza glabra L. root extract, can guarantee substantially its effect.
Fructus Phyllanthi fruit extract of the present invention is provided by Merck (merck) company, derives from India's succession medical herbs simply of thousand, is the material of separation and Extraction from Fructus Phyllanthi fruit.
Fructus piperis nigrum extract of the present invention is provided by Xi'an Tianrui Bioisystech Co., Ltd, derives from Chinese traditional herbal medicines black pepper fruit.
Yeast extract of the present invention is provided by Angel Yeast Co.,Ltd, what adopt is the by-product bread leaven matricyte complicated thing that extracting obtains after breaking cellular wall during food industry is produced, through the orientation of enzyme, shear the aminoacid that is rich in forming again, small-molecular peptides, the yeast elite material of the active skull cap components such as nucleotide, mannan, glucosan.In certain embodiments, the molecular weight of the described contained polypeptide of yeast extract concentrates on below 1000KD.
Ascorbic acid glucoside of the present invention is the derivant of ascorbic acid glucoside, synthetic under the effect of enzyme by ascorbic acid and heteroside.
Quintessence oil of the present invention extracts from natural plants, and it extracts from vanilla chrysanthemum, Jizhou Island red autumnal leaves Herba Oxalidis Corniculatae and Jizhou Island Flos Camelliae Japonicae 3 kind of plant.
Antiseptic of the present invention is bright string coccus/Radix Raphani (RAPHANUS SATIVUS) root tunning filtrate, has natural antibacterial antisepsis.
Cosmetics of the present invention can be prepared by conventional production technology, preferred following preparation method, and it comprises the following steps:
1) cetearyl alcohol, the hard ester group glucoside of spermaceti, bisabolol, Herba Rosmarini Officinalis leaf oil, vegetable oil are dropped into oil phase pot as A phase component, be heated to 70-85 ℃, heat preservation for standby use after dissolving to all components;
2) using HANSHENGJIAO, hyaluronate sodium, polyhydric alcohol and deionized water as B phase component, drop into emulsifying pot, be heated to 70-85 ℃, after stirring and dissolving, be incubated 15-30 minute;
3) by step 1) in A phase suction step 2) emulsifying pot in, homogenizing (homogenizing stir speed (S.S.) is 3000rpm) is after 3-5 minute, insulated and stirred (stir speed (S.S.) is 30rpm) 15-45 minute;
4) by step 3) in product be cooled to 40-45 ℃, add rest materials, stir, obtain cosmetics.
Below with reference to specific embodiment, the present invention will be further described.
Embodiment 1
A kind of compound with Whitening, spot effect of the present embodiment, its raw material by following weight percentage ratio forms:
The hard ester group glucoside of spermaceti: 1wt%,
Cetearyl alcohol: 4wt%,
Herba Rosmarini Officinalis leaf oil: 0.2wt%,
Radix Oenotherae erythrosepalae oil: 15wt%,
Rosehips oil: 0.5wt%,
HANSHENGJIAO: 0.5wt%,
Hyaluronate sodium: 0.01wt%,
Glycerol: 10wt%,
Glycyrrhiza glabra L. root extract: 0.05wt%,
Fructus Phyllanthi fruit extract: 2wt%,
Ascorbic acid glucoside: 0.1wt%,
Bisabolol: 0.1wt%,
Fructus piperis nigrum extract: 0.1wt%,
Yeast extract: 15wt%,
Antiseptic: 3wt%,
Deionized water: surplus.
Above-mentioned cosmetics make by conventional production process, and preferred following preparation method is specific as follows:
1) above-mentioned cetearyl alcohol, the hard ester group glucoside of spermaceti, bisabolol, Herba Rosmarini Officinalis leaf oil, vegetable oil (Radix Oenotherae erythrosepalae oil, Rosehips oil) are dropped into oil phase pot as A phase component, be heated to 70-85 ℃, wait all components to dissolve rear heat preservation for standby use;
2) using above-mentioned HANSHENGJIAO, hyaluronate sodium, polyhydric alcohol (glycerol) and deionized water as B phase component, drop into emulsifying pot, be heated to 70-85 ℃, after stirring and dissolving, be incubated 15-30 minute;
3), in the emulsifying pot that the suction of A phase is contained to B phase, homogenizing (homogenizing stir speed (S.S.) is 3000rpm) is insulated and stirred (stir speed (S.S.) is 30rpm) 15-45 minute after 3-5 minute;
4) by step 3) in product be cooled to 40-45 ℃, add above-mentioned Glycyrrhiza glabra L. root extract, Fructus Phyllanthi fruit extract, Fructus piperis nigrum extract, yeast extract, ascorbic acid glucoside and antiseptic, stir, obtain cosmetics.
Embodiment 2
A kind of compound with Whitening, spot effect of the present embodiment, its raw material by following weight percentage ratio forms:
The hard ester group glucoside of spermaceti: 3wt%,
Cetearyl alcohol: 0.5wt%,
Herba Rosmarini Officinalis leaf oil: 0.005wt%,
Radix Oenotherae erythrosepalae oil: 12wt%,
Rosehips oil: 0.5wt%,
HANSHENGJIAO: 0.05wt%,
Hyaluronate sodium: 0.1wt%,
Sorbitol: 3wt%,
Glycyrrhiza glabra L. root extract: 0.2wt%,
Fructus Phyllanthi fruit extract: 0.1wt%,
Ascorbic acid glucoside: 2wt%,
Bisabolol: 0.5wt%,
Fructus piperis nigrum extract: 0.4wt%,
Yeast extract: 1wt%,
Antiseptic: 1wt%,
Deionized water: surplus.
The preparation method of above-mentioned cosmetics is with embodiment 1.
Embodiment 3
A kind of compound with Whitening, spot effect of the present embodiment, its raw material by following weight percentage ratio forms:
The hard ester group glucoside of spermaceti: 2wt%,
Cetearyl alcohol: 2wt%,
Herba Rosmarini Officinalis leaf oil: 0.02wt%,
Radix Oenotherae erythrosepalae oil: 7wt%,
Rosehips oil: 5wt%,
HANSHENGJIAO: 0.2wt%,
Hyaluronate sodium: 0.02wt%,
Glycerol: 2wt%,
1,3-PD: 4wt%,
Glycyrrhiza glabra L. root extract: 0.1wt%,
Fructus Phyllanthi fruit extract: 1.5wt%,
Bisabolol: 0.3wt%,
Ascorbic acid glucoside: 1wt%,
Fructus piperis nigrum extract: 0.2wt%,
Yeast extract: 10wt%,
Antiseptic: 2wt%,
Deionized water: surplus.
The preparation method of above-mentioned cosmetics is with embodiment 1.
Embodiment 4
A kind of compound with Whitening, spot effect of the present embodiment, its raw material by following weight percentage ratio forms:
The hard ester group glucoside of spermaceti: 2wt%,
Cetearyl alcohol: 2wt%,
Herba Rosmarini Officinalis leaf oil: 0.02wt%,
Radix Oenotherae erythrosepalae oil: 7wt%,
Rosehips oil: 5wt%,
HANSHENGJIAO: 0.2wt%,
Hyaluronate sodium: 0.02wt%,
Glycerol: 2wt%,
1,3-PD: 4wt%,
Fructus Rubi extract: 0.1wt%,
Ramulus et Folium Mussaendae Pubescentis extract: 2wt%,
Glycyrrhiza glabra L. root extract: 0.1wt%,
Fructus Phyllanthi fruit extract: 1.5wt%,
Bisabolol: 0.3wt%,
Ascorbic acid glucoside: 1wt%,
Fructus piperis nigrum extract: 0.2wt%,
Yeast extract: 10wt%,
Antiseptic: 2wt%,
Deionized water: surplus.
The preparation method of above-mentioned cosmetics is with embodiment 1.
Embodiment 5
A kind of compound with Whitening, spot effect of the present embodiment, its raw material by following weight percentage ratio forms:
The hard ester group glucoside of spermaceti: 2wt%,
Cetearyl alcohol: 2wt%,
Herba Rosmarini Officinalis leaf oil: 0.02wt%,
Radix Oenotherae erythrosepalae oil: 7wt%,
Rosehips oil: 5wt%,
HANSHENGJIAO: 0.2wt%,
Hyaluronate sodium: 0.02wt%,
Glycerol: 2wt%,
1,3-PD: 4wt%,
Fructus Rubi extract: 2wt%,
Ramulus et Folium Mussaendae Pubescentis extract: 0.1wt%,
Glycyrrhiza glabra L. root extract: 0.1wt%,
Fructus Phyllanthi fruit extract: 1.5wt%,
Bisabolol: 0.3wt%,
Fructus piperis nigrum extract: 0.2wt%,
Yeast extract: 10wt%,
Ascorbic acid glucoside: 1wt%,
Plants essential oil: the mixture of vanilla chrysanthemum quintessence oil, Jizhou Island red autumnal leaves Herba Oxalidis Corniculatae quintessence oil and Jizhou Island Flos Camelliae Japonicae quintessence oil (weight ratio between three is 1:1:5): 0.3wt%,
Antiseptic: 2wt%,
Deionized water: surplus.
The preparation method of above-mentioned cosmetics is with embodiment 1.
Embodiment 6
Described in the present embodiment and embodiment 5, the raw material of cosmetics and consumption and preparation method are basic identical, and difference is: in described cosmetics, the percentage by weight of Fructus Rubi extract is 0.1wt%, and the percentage by weight of Ramulus et Folium Mussaendae Pubescentis extract is 0.1wt%.
Comparative example 1
A kind of cosmetics with Whitening, spot of this comparative example, comprise the component of following mass percent:
The hard ester group glucoside of spermaceti: 2wt%,
Cetearyl alcohol: 2wt%,
Herba Rosmarini Officinalis leaf oil: 0.02wt%,
Radix Oenotherae erythrosepalae oil: 7wt%,
Rosehips oil: 5wt%,
HANSHENGJIAO: 0.2wt%,
Hyaluronate sodium: 0.02wt%,
Glycerol: 2wt%,
1,3-PD: 4wt%,
Fructus Phyllanthi fruit extract: 1.5wt%,
Yeast extract: 10wt%,
Bisabolol: 0.3wt%,
Antiseptic: 2wt%,
Deionized water: surplus.
The preparation method of this comparative example is with embodiment 1.
Comparative example 2
A kind of cosmetics with Whitening, spot of this comparative example, comprise the component of following mass percent: the hard ester group glucoside of spermaceti: 2wt%,
Cetearyl alcohol: 2wt%,
Herba Rosmarini Officinalis leaf oil: 0.02wt%,
Radix Oenotherae erythrosepalae oil: 7wt%,
Rosehips oil: 5wt%,
HANSHENGJIAO: 0.2wt%,
Hyaluronate sodium: 0.02wt%,
Glycerol: 2wt%,
1,3-PD: 4wt%,
Glycyrrhiza glabra L. root extract: 0.1wt%,
Fructus piperis nigrum extract: 0.2wt%,
Ascorbic acid glucoside: 1wt%,
Antiseptic: 2wt%,
Deionized water: surplus.
The preparation method of this comparative example is with embodiment 1.
Comparative example 3
A kind of cosmetics with Whitening, spot of this comparative example, comprise the component of following mass percent:
The hard ester group glucoside of spermaceti: 2wt%,
Cetearyl alcohol: 2wt%,
Herba Rosmarini Officinalis leaf oil: 0.02wt%,
Radix Oenotherae erythrosepalae oil: 7wt%,
Rosehips oil: 5wt%,
HANSHENGJIAO: 0.2wt%,
Hyaluronate sodium: 0.02wt%,
Glycerol: 2wt%,
1,3-PD: 4wt%,
Fructus Phyllanthi fruit extract: 1.5wt%,
Fructus piperis nigrum extract: 0.2wt%,
Fructus Rubi extract: 2wt%,
Ramulus et Folium Mussaendae Pubescentis extract: 0.1wt%,
Antiseptic: 2wt%,
Deionized water: surplus.
The preparation method of this comparative example is with embodiment 1.
Test example 1 Whitening, spot effect assessment
One, experiment purpose
By relative analysis, evaluate the Whitening, spot effect of the prepared cosmetics of the various embodiments described above.
Two, experimental technique
Experiment grouping: this experiment is divided into experimental group and matched group, and wherein experimental group is above-described embodiment 1-embodiment 6 prepared cosmetics, and matched group is the prepared cosmetics of above-mentioned comparative example 1-comparative example 3 and the commercially available Whitening, spot product of comparative example 4 one.
Tested object: above-mentioned each group is 30 of female middle-ageds, 30-40 year, healthy, without dermatosis and irritated medical history, non-sensitive skin, can make to apply some make up by standard, and cooperating personnel complete appraisal on request, there is certain statement ability, the impression after can actual response using;
Test instrunment: VISA numeral skin analyzer (U.S.), Mexameter MX18 (CK Electronic GmbH, Germany);
Test zone: cheek region (as far as possible avoiding laugh line, retroreflective regions, melanotic nevus and hair); Using method: every day each 1 time sooner or later, continue to use 8 weeks;
Test analysis: before using by contrast and use 8 weeks speckle contrast figure afterwards, cosmetics Whitening, spot effect described in evaluation experimental group and matched group.
Three, experimental result
Concrete outcome is referring to table 1.
Table 1 Whitening, spot measure of merit result table
As known from Table 1, embodiment 1-6 Whitening, spot successful is better than matched group 1-4, the Whitening, spot effect of comparative example 1-3 and matched group 1-2 can draw: the Whitening, spot compositions that Glycyrrhiza glabra L. root extract, Fructus Phyllanthi fruit extract, ascorbic acid glucoside, bisabolol, Fructus piperis nigrum extract and yeast extract form, and it can play from integral body the synergy of Whitening, spot from inside to outside; The Whitening, spot effect of comparative example 4,5,6 and embodiment 3 is known, and composite Ramulus et Folium Mussaendae Pubescentis extract, Fructus Rubi extract, plants essential oil can play the effect of further raising Whitening, spot.
The above embodiment has only expressed several embodiment of the present invention, and it describes comparatively concrete and detailed, but can not therefore be interpreted as the restriction to the scope of the claims of the present invention.It should be pointed out that for the person of ordinary skill of the art, without departing from the inventive concept of the premise, can also make some distortion and improvement, these all belong to protection scope of the present invention.Therefore, the protection domain of patent of the present invention should be as the criterion with claims.