CN104016726B - The manufacturing process of pottery accessories brick and the ceramic accessories brick made by this technique - Google Patents
The manufacturing process of pottery accessories brick and the ceramic accessories brick made by this technique Download PDFInfo
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Abstract
The present invention relates to the manufacturing process of ceramic accessories brick and ceramic accessories brick.This manufacturing process comprises: (1) at Low fire ceramic brick surface printing ground-coat enamel; (2) on printing ground glaze layer, spray ink Printing forms pattern; At the transparent dry granular of pattern layer surface twice charity, burn till, formed surface glass layer, surface glass layer is fluted; Adopt pad pasting location electrochemical plating, in surface glass layer groove plated metal look, burn till; (5) the product surface after (4) burning till step carries out polishing; (6) the accessories adobe after carrying out polishing is cut, make accessories brick.Pottery accessories brick structure by the patterned layer that the ground glaze layer of basic brick, basic brick surface printing, ground glaze layer adhere to, at the first transparent dry granulosa and the second transparent dry granulosa of pattern layer surface charity; Recessed groove or concave curve composition in the layer facing layer of the second transparent dry granulosa.Accessories brick kind comprises: ground flower, ground wire, stringcourse, corner etc., for the allocation function of ceramic wall and floor bricks.
Description
Technical field
The present invention relates to building ceramic tiles production field, particularly a kind of manufacturing process of ceramic accessories brick and the ceramic accessories brick made by this manufacturing process.
Background technology
Ceramic tile builds the requisite finishing material in living space, and it gives space with using function and decoration esthetic sentiment, and the important supporting composition that accessories product supporting is with it indispensable especially.
First-generation accessories brick, be twice firing ceramic product brick on the surface, adopt screen printed pattern, heap dry granular fires and form, it is only limitted to the decoration of plane brick; S-generation accessories brick have employed embossment die face, in conjunction with after operation by artificial colored drawing or low-temperature enamel firing, produce body of wall flower sheet and stringcourse accessories; Third generation accessories brick expands to the application of floor tile, and its base mateiral is also no longer limited to ceramic tile, also adds the ranks of ceramic accessories brick with the accessories product of the base mateiral such as stone material, resin.
The ceramic accessories brick of current high pressure waterjet, splicing is produced by ceramic tile production business organization mostly, by layout in advance, adopt carry out cutting without the finished bricks of look, combined and spliced, become accessories product, usual one group of ground accessories brick will be made up of tens even tens of unit; Its cutting quantity is large, splicing is complicated, and waste is large, efficiency is low, selected by the hall of Chang Zuowei flawless finish, hall.
CN201210112608.4 discloses a kind of metallizing and throws glaze ceramic tile goods, and it comprises, and brick body, brick surface are fluted, be filled with metal plating in groove, and it is incomplete that the metal cladding in groove forms metal cladding through processing treatment.The manufacture craft of this metal cladding goods is first at ceramic adobe surface impressing pattern layer, then to be left a blank formation groove at the skeletal lines of pattern edge by spreading frit powder, burn till, metal level is plated in whole surface of semi-finished, finally polished finish is carried out to the finished product ceramic brick surface of gained, grind off the layer of metal layer covering surface, retain the metal plating in groove, and the metal plating in groove is polished, form incomplete metal plating effect.Its weak point is, as ground paving attachment exterior material, long-time people tramples and removing surface, though it is positioned at groove without the metal plating burnt till, coating also can be caused to wear and tear.
CN200610090584.1 discloses a kind of metallization treating method of rosin products surface, relate to a kind of metallization treating method of rosin products surface, to obtain the surface metal texture of rosin products, the production for the stringcourse supporting with ceramic tile that the method is also more.Its weak point is, the complete processing of ceramic tile accessories material and employing resin based on resin, and its supporting tissue difficulty, quality product is difficult to ensure.
The invention provides a kind of manufacture method of ceramic accessories brick, it is the surperficial glazing in finished bricks, spray ink Printing forms pattern, again by dry method charity frit dry granular, enter roller kiln to burn till, again through the plating of pad pasting location, twice firing, form the accessories brick with solid, metalluster effect through cutting.
Summary of the invention
The object of the invention is the quality problems for the use procedure such as supporting tissue difficulty, material disunity adopting the base mateiral such as stone material, glass, resin to cause as ceramic tile accessory and provide one to carry out spray ink Printing, dry glazing on ceramic product brick surface, burn till, locate plating, burn till, the manufacturing process of the ceramic accessories brick of polishing and the ceramic accessories brick made by this technique.
Technical solution of the present invention is the manufacturing process of described ceramic accessories brick, and its special character is, comprises the steps:
(1) the ceramic brick surface printing ground-coat enamel burnt till;
(2) on printing ground glaze layer, form pattern by spray ink Printing;
At the transparent dry granular of twice charity in the surface of patterned layer, burn till, formed surface glass layer, surface glass layer is fluted;
Adopt pad pasting location electrochemical plating, in surface glass layer groove plated metal look, burn till;
(5) the product surface after (4) burning till step carries out polishing;
(6) the accessories adobe after carrying out polishing is cut, produce the accessories brick with male and fomale(M&F), metalluster or color changeable effect.
As preferably: the (1) described ground-coat enamel of step is made up of following component by weight percentage:
SiO
260％～70％Al
2O
35％～8％B
2O
33％～7％
CaO3％～9％BaO2％～8％KNaO3％～12％。
As preferably: the parameter of the described step (3) transparent dry granular of twice charity is:
For the first time: adopt the saturating net of 40 order all-pass, dry granular particle diameter 60 ~ 100 order, dry granule layer thickness 0.8 ~ 1 ㎜;
For the second time: adopt 40 orders to have the print silk screen of pattern texture, particle diameter 60 ~ 100 order of dry granular, dry granule layer thickness is 3 ~ 3.5 millimeters;
Described step (3) firing temperature is 900 DEG C ~ 950 DEG C, firing time 70 ~ 80 minutes, soaking time 7 ~ 9 minutes.
As preferably: (3) described step comprises further; Described transparent dry granular is prepared into frit particle by preparing burden, founding, pulverize, sieve, and this frit particle is made up of following component by weight percentage:
As preferably: (4) described step comprises further; Surface, brick face is not needed the oily paper-mulching in position plating pattern, need the part hollow out of plating pattern, adopt vacuum coating film equipment, in vacuum and under rare gas element state, metal titanium targets is ionized, metal titanium ionization deposition is attached in glass coating groove, forms the metal glossy layer of gold and silver look, and deposition is attached in glass coating groove the metal glossy layer presenting imitative gold, imitative silver; Firing temperature is 750 DEG C ~ 850 DEG C, and firing period is 70 ~ 75 minutes, and soaking time is 7 ~ 9 minutes.
As preferably: (4) described step comprises further; The formation of described surface glass layer groove is the sunk part formed by textured pattern in the transparent dry granular process of second time charity, then as the groove position of plated metal look after burning till; And do not need the position of plated pattern with oily paper-mulching on surface, brick face, need the part hollow out of plated pattern, adopt vacuum coating film equipment, in vacuum and under rare gas element state, metal titanium targets is ionized, metal titanium ionization deposition is attached in surface glass layer groove, forms metal glossy layer that is golden or silver color; Burnt till by the goods of plated metal, firing temperature is 750 DEG C ~ 850 DEG C, and firing period is 70 ~ 75 minutes, and soaking time is 7 ~ 9 minutes.
As preferably: (5) described step comprises further: just throwings, rough polishing, middle throwing, fine polishing, ultra-fine throwing, essence throwing, the burnishing parameters added lustre in process:
As preferably: (6) described step comprises further: according to the pattern-cut designed in advance become the accessories kind of colored, ground wire, stringcourse, corner.
Another technical solution of the present invention is the ceramic accessories brick that described manufacturing process is made, comprise: the patterned layer that the ground glaze layer of basic brick, basic brick surface printing, ground glaze layer adhere to, its special character is, at the first transparent dry granulosa and the second transparent dry granulosa of described pattern layer surface charity; And second transparent dry granulosa layer facing layer in recessed groove, the electroplated metal layer of described groove surfaces.
Compared with prior art, beneficial effect of the present invention:
(1) manufacturing process of the present invention adopts 3D inkjet technology to carry out the production of imitative high pressure waterjet accessories brick, realizes the pattern effect of the accessories brick such as ground flower, ground wire, stringcourse, corner of imitative high pressure waterjet; Compare silk screen and rubber roll stamp, the present invention is filled a prescription by ground-coat enamel and the research of dry granular, improve the color development ability of ink, the colouring effect of same base face polychrome system pattern texture can be realized, color gamut is wide, the effect of its parquets pattern realizes the seamless spliced of full brick by spray ink Printing, and this is that plane printing technique can not be compared.
(2), by the electroplating technology of ceramic, plated metal look also carries out second time to the goods after metallizing and burns till, and makes the glaze paint melting of coating and ceramic tile, improves coating associativity.
(3) the accessories brick of the present invention's manufacture, there is concavo-convex, the decorative effect such as metalluster, flashing color-variable, through cutting the requirement that can meet accessories brick paving pattern and specification, as accessories such as ground flower, ground wire, corner, stringcourses, for whole decoration space works the effect of interspersing.
Manufacturing process of the present invention adopt pad pasting location electrochemical plating in surface glass layer groove plated metal look, burn till, then polishing; Pad pasting location electroplated metal layer targetedly, a large amount of saving plated materials, and decrease the workload of polishing, make the metal plating in groove not by the impact of rear polishing process, it is more firm that metal plating merges with ceramic tile surface glaze layer after again burning till, and use procedure wear resistance is better.
(5) the polishing abrasive tool that adopts of manufacture method of the present invention, be utilize the granular arrangement abrading block of two-dimentional intercommunication, under the swing effect of elasticity rubber with grinding head of polishing machine, profiling can be strong, can avoid Lou throwing defect.
(6) the present invention is for the supporting level improving ceramic tile, meets the demand of market to accessories brick, reduces accessories brick product cost, improves added value of product significant.
Accompanying drawing explanation
Fig. 1 is the schema of the present invention's pottery accessories brick manufacturing process.
Fig. 2 to Fig. 9 is the series product schematic diagram of the imitative high pressure waterjet accessory of the present invention's pottery accessories brick manufacturing process.
Figure 10 is accessories frog position of the present invention cross-section structure schematic diagram.
Embodiment
The present invention is further detailed in conjunction with the accompanying drawings below:
Refer to shown in Fig. 1, the manufacturing process of this ceramic accessories brick, comprises the steps:
(1) the ceramic brick surface printing ground-coat enamel burnt till; Wherein:
The (1) described ground-coat enamel of step is made up of following component by weight percentage:
SiO
260％～70％Al
2O
35％～8％B
2O
33％～7％
CaO3％～9％BaO2％～8％KNaO3％～12％。
(2) on printing ground glaze layer, form pattern by spray ink Printing;
At the transparent dry granular of twice charity in the surface of patterned layer, burn till, formed surface glass layer, surface glass layer is fluted;
The parameter of described step (3) twice transparent dry granular of charity cloth is:
For the first time: adopt the saturating net of 40 order all-pass, dry granular particle diameter 60 ~ 100 order, dry granule layer thickness 0.8 ~ 1 ㎜;
For the second time: adopt 40 orders to have the print silk screen of pattern texture, particle diameter 60 ~ 100 order of dry granular, dry granule layer thickness is 3 ~ 3.5 millimeters;
Described step (3) firing temperature is 900 ~ 950 DEG C, firing time 70 ~ 80 minutes, soaking time 7 ~ 9 minutes;
Described transparent dry granular is prepared into frit particle by preparing burden, founding, pulverize, sieve, and this frit particle is made up of following component by weight percentage:
Adopt pad pasting location electrochemical plating, in surface glass layer groove plated metal look, burn till;
(4) described step comprises further; The formation of described surface glass layer groove is the sunk part formed by textured pattern in the transparent dry granular process of second time charity, then as the groove position of plated metal look after burning till; And do not need the position of plated pattern with oily paper-mulching on surface, brick face, need the part hollow out of plated pattern, adopt vacuum coating film equipment, in vacuum and under rare gas element state, metal titanium targets is ionized, metal titanium ionization deposition is attached in surface glass layer groove, forms metal glossy layer that is golden or silver color; Burnt till by the goods of plated metal, firing temperature is 750 DEG C ~ 850 DEG C, and firing period is 70 ~ 75 minutes, and soaking time is 7 ~ 9 minutes.
(5) the product surface after (4) burning till step carries out polishing; Comprise further: just throwing, rough polishing, middle throwing, fine polishing, ultra-fine throwing, essence throwing, process of adding lustre to; Burnishing parameters:
(6) the accessories adobe after carrying out polishing is cut, produce the accessories brick with male and fomale(M&F), metalluster or color changeable effect.
(6) described step comprises further: according to the pattern-cut that designs in advance become the accessories kind of colored, ground wire, stringcourse, corner.
Refer to shown in Figure 10, by the ceramic accessories brick that above-mentioned manufacturing process is made, comprise: the patterned layer 3 of attachment on the ground glaze layer 2 of basic brick 1, basic brick 1 surface printing, ground glaze layer 2, patterned layer 3 is at its surperficial charity first transparent dry granulosa 41, second transparent dry granulosa 42; Groove 5 recessed in the layer facing layer of the second transparent dry granulosa 42, the surface of groove 5 is provided with electroplated metal layer 6.Groove 5 can be pit, also can be one or more compound use of depression, concave curve.Accessories brick kind comprises: ground flower, ground wire, stringcourse, corner, for the allocation function of ceramic wall and floor bricks.
Need to further illustrate:
1.1, the formula adjustment of ground-coat enamel should meet following principle:
(1) ground-coat enamel is close or consistent with the firing range of dry granular.
(2) there is not violent reaction at hot stage and basic brick and dry granular in ground-coat enamel.
(3) ground-coat enamel should contribute to the color development of marking ink, and have wider subject range with ink, loss on ignition is little, reduces the generation of pore in glaze layer.
1.2, ground-coat enamel screen printing glaze is made by silk-screen printing technique, to reduce the moisture drenching glaze and glaze spraying and bring into;
1.3, the formula of ground-coat enamel: YF3169 printing powder 100%; Wollastonite 4%;
The chemical composition ranges of ground-coat enamel: SiO260 ~ 70%, Al2O35 ~ 8%, B2O33 ~ 7%, CaO3 ~ 9%, BaO2 ~ 8%, KNa3 ~ 12%;
The proportion of ground-coat enamel: 1.63 ~ 1.70g/ml, adopts the saturating silk screen printing of 80 order all-pass.
Refer to shown in Fig. 1, design and patterning process:
Pattern is designed to accessory pattern, through cutting as the use such as stringcourse, corner, also can comprises imitative high pressure waterjet splicing element in whole pattern; Fig. 2-Fig. 6 is shown in by its pattern.This pattern be made up of different colour system is realized the effect of imitative high pressure waterjet discrete by spray ink Printing.Fig. 7, Fig. 9 are the schematic diagram of metallic design accessories brick of the present invention; Fig. 8 is the schematic diagram of technique accessories brick of groove of the present invention location metallizing, and its section of product formed through this technique as shown in Figure 10.
Refer to shown in Fig. 1, the selection of transparent dry granular (flash of light dry granular) and prepare cloth dry granular;
The proportioning of 3.1 dry granulars: cloth dry granular is based on transparent dry granular (can carry out proportioning by the transparent dry granular of 2 ~ 3 kinds of different coefficients of expansion), flash of light dry granular, metal dry granular are cosmetic decoration, mix above-mentioned dry granular and meet the matched performance with basic brick, ground glaze layer;
The proportioning of cloth dry granular is as follows: transparent dry granular 100%, flash of light dry granular 0.5%
Wherein, the composition of flash of light dry granular: flash black dry granular 80%; Dodge yellow dry granular 15%; Dodge silver-colored dry granular 5%;
The charity parameter of 3.2 dry granulars: the unreasonable meeting of dry granular performance, proportioning and size distribution is in the rising of sintering process with temperature, and make the moisture brought in ground-coat enamel and dry granular and gas have little time to discharge, surperficial dry granular has formed liquid phase and produced sealed porosity.Employing particle diameter is the dry granular between 60 ~ 100 orders, cloth at twice; First time 40 order all-pass saturating screen cloth material dry granule layer thickness 0.8 ~ 1 ㎜; Second time adopts 40 orders to have the silk screen of pattern texture, and the thickness of dry granule layer is 3 ~ 3.5 millimeters and forms dry granular groove; Spray fixing agent makes dry granular fix.
Refer to shown in Fig. 1, the accessories adobe with dry granule layer is entered roller kiln and burns till, printed patterns, dry granular and basic brick are merged, firing temperature 900 DEG C ~ 950 DEG C, firing time is 70 ~ 100 minutes, and goods kiln discharge sends into electroplating work procedure.
Refer to shown in Fig. 1, paste oilpaper film, need the part hollow out of plating, coating location is plated in the surface glass layer groove of hollow out, forms metalluster look; Accessories tile product through plating is delivered to roller kiln burn till, electrolytic coating and glass coating are merged, and firing temperature 750 DEG C ~ 850 DEG C, firing time is 70 ~ 75 minutes.
Refer to shown in Fig. 1, surface finish, edging, cut into accessories finished bricks:
Surface finish described in 6.1, comprise just throwing, rough polishing, middle throwing, fine polishing, ultra-fine throwing, essence throwing, process of adding lustre to, burnishing parameters is as follows:
Polishing abrasive tool is the abrading block adopting two-dimentional intercommunication granular arrangement, and under the swing effect of elasticity rubber with grinding head of polishing machine, its profiling ability is strong, can reduce over to greatest extent and throw and leak throwing defect.
Continue the goods edging after polishing and use needs according to design, goods being cut into the accessories kinds such as stringcourse, ground wire, corner.
The foregoing is only preferred embodiment of the present invention, all equalizations done according to the claims in the present invention scope change and modify, and all should belong to the covering scope of the claims in the present invention.
Claims (8)
1. a manufacturing process for ceramic accessories brick, is characterized in that, comprise the steps:
(1) the ceramic brick surface printing ground-coat enamel burnt till;
(2) on printing ground glaze layer, form pattern by spray ink Printing;
At the transparent dry granular of twice charity in the surface of patterned layer, burn till, formed surface glass layer, surface glass layer is fluted;
Adopt pad pasting location electrochemical plating, in surface glass layer groove plated metal look, burn till;
(5) the product surface after (4) burning till step carries out polishing;
(6) the accessories adobe after carrying out polishing is cut, produce the accessories brick with male and fomale(M&F), metalluster or color changeable effect.
2. the manufacturing process of ceramic accessories brick according to claim 1, is characterized in that: the (1) described ground-coat enamel of step is made up of following component by weight percentage:
SiO
260％～70％Al
2O
35％～8％B
2O
33％～7％
CaO3％～9％BaO2％～8％KNaO3％～12％。
3. the manufacturing process of ceramic accessories brick according to claim 1, is characterized in that: the parameter of the described step (3) transparent dry granular of twice charity is:
For the first time: adopt the saturating net of 40 order all-pass, dry granular particle diameter 60 ~ 100 order, dry granule layer thickness 0.8 ~ 1 ㎜;
For the second time: adopt 40 orders to have the print silk screen of pattern texture, particle diameter 60 ~ 100 order of dry granular, dry granule layer thickness is 3 ~ 3.5 millimeters;
Described step (3) firing temperature is 900 ~ 950 DEG C, firing time 70 ~ 80 minutes, soaking time 7 ~ 9 minutes.
4. the manufacturing process of ceramic accessories brick according to claim 3, is characterized in that: (3) described step comprises further; Described transparent dry granular is prepared into frit particle by preparing burden, founding, pulverize, sieve, and this frit particle is made up of following component by weight percentage:
5. the manufacturing process of ceramic accessories brick according to claim 1, is characterized in that: (4) described step comprises further; The formation of described surface glass layer groove is the sunk part formed by textured pattern in the transparent dry granular process of second time charity, then as the groove position of plated metal look after burning till; And do not need the position of plated pattern with oily paper-mulching on brick surface, need the part hollow out of plated pattern, adopt vacuum coating film equipment, in vacuum and under rare gas element state, metal titanium targets is ionized, metal titanium ionization deposition is attached in surface glass layer groove, forms metal glossy layer that is golden or silver color; Burnt till by the goods of plated metal, firing temperature is 750 DEG C ~ 850 DEG C, and firing period is 70 ~ 75 minutes, and soaking time is 7 ~ 9 minutes.
6. the manufacturing process of ceramic accessories brick according to claim 1, is characterized in that: (5) described step comprises further: just throwings, rough polishing, middle throwing, fine polishing, ultra-fine throwing, essence throwing, the burnishing parameters added lustre in process:
7. the manufacturing process of ceramic accessories brick according to claim 1, is characterized in that: (6) described step comprises further: according to the pattern-cut designed in advance become the accessories kind of colored, ground wire, stringcourse, corner.
8. the ceramic accessories brick made according to manufacturing process described in claim 1, comprise: the patterned layer that the ground glaze layer of basic brick, basic brick surface printing, ground glaze layer adhere to, it is characterized in that, at described pattern layer surface charity first transparent dry granulosa and the second transparent dry granulosa; Recessed groove in the layer facing layer of described second transparent dry granulosa, described groove surfaces electroplated metal layer.
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| IT202000021376A1 (en) * | 2020-09-10 | 2020-12-10 | Ri_Crea S R L S | Process for the creation of artistic works as an expression of the conformation of the architectural space on a ceramic support |
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| CN104016726A (en) | 2014-09-03 |
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