CN104405101B - A kind of transmutation Antique Imitation Tiles and its production method - Google Patents
A kind of transmutation Antique Imitation Tiles and its production method Download PDFInfo
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Abstract
The present invention relates to a kind of transmutation Antique Imitation Tiles and its production methods.Transmutation effect is dexterously combined with Antique Imitation Tiles in decorative effect, by in a wide range of process yellow of ceramic tile surface, it is coffee-like, the Sub-shine glaze of a variety of colour systems modelled after an antique such as kermesinus, form the distinctive simple and unsophisticated charm of Antique Imitation Tiles and style of missing old times or old friends, simultaneously in the metal dry granular of ceramic tile surface printing and mould flower cooperation, it is influenced at high temperature by glaze body itself and firing atmosphere using oxide in metal dry granular and generates complicated colour developing effect, there is Antique Imitation Tiles obtained strong corrosion of metal sense and vicissitudes to feel, its simple dignified style of missing old times or old friends has catered to modern and has advocated nature, the phychology recovered one's original simplicity, great decorative and artistry, it is more single to solve Antique Imitation Tiles decoration technique, not abundant enough the problem of level.
Description
Technical field
The present invention relates to the production method technical field of architectural pottery Antique Imitation Tiles, be specifically related to a kind of transmutation Antique Imitation Tiles and
Its production method.
Background technology
Antique Imitation Tiles belong to common ceramic tile, and it is artificial using acidleach, autoclaving and printing glaze modelled after an antique etc. to copy previous pattern
Mode makees old, the substantially ceramic tile of glazing.Its green body can also be Shi porcelains, thin Shi matter and Shi matter based on porcelain；Glaze with
Based on matt, tone is mainly based on yellow, coffee color, kermesinus, ashen, grey, grey black etc..The culture that Antique Imitation Tiles are contained
Inside information and historical connotation become the mainstream tile product of European & American Market, have also obtained rapid development at home.But it is modelled after an antique
Brick decoration technique is more single, level is not abundant enough, is always to have problem to be solved.
Since polished bricks are domestic product amount is big, consumption figure is big, its main feature is that color is simple and elegant, glossiness is higher, focuses on imitative
Stone texture, in recent years, the characteristics of decoration technique of Antique Imitation Tiles is also gradually introduced polished bricks, to increase new decorative effect.Such as
Chinese patent CN103159468A describes Persian jade fully-glazed Antique Imitation Tiles and its production technology, in porcelain billet upper roller stamp
Afterwards, full throwing glaze is imposed, after 1300 DEG C of high temperature firings, the strong stone material of three-dimensional sense is formed and spends face, finished product is obtained after polished.It should
Antique Imitation Tiles tone prepared by method is lucid and lively, and stone texture three-dimensional sense is strong, has strong Exotic styles, but whole face stamp is formed by
The still aobvious dullness of texture, level is not abundant enough, lacks the jump of color.
Invention content
In order to solve the problems, such as that existing Antique Imitation Tiles decoration technique is more single, level is not abundant enough, the present invention provides one
The production method of kind transmutation Antique Imitation Tiles.
It is a further object of the present invention to provide a kind of Antique Imitation Tiles produced with this method.
To realize first goal of the invention, the technical solution adopted by the present invention is such：A kind of life of transmutation Antique Imitation Tiles
Production method, it is characterised in that include the following steps：
1）Prepare adobe：Porcelain Antique Imitation Tiles green body powder is prepared according to a conventional method, is prepared using the tool compression moulding of mould embossing die
Adobe, it is spare；
2）Prepare metal dry granular：Glass frit preparation process routinely, selection are former containing lithium minerals, quartz and chemical industry
Material is melted by dispensing, 1200 ~ 1300 DEG C, water quenching, drying, broken, sieving, is classified process, and acquisition composition range is SiO2
22% ~ 30%, Al2O3 1% ~ 6%, Fe2O3 3 ~ 10%, Li2O 0.5 ~ 2%, B2O3 0.5% ~ 5%, ZnO 25% ~ 35%, PbO 10 ~
20%, surplus is fining agent and impurity, and the grain size of moisture≤0.5% is the frit of 100 ~ 200 mesh, spare；
3）Prepare metal cloud：With step 2）Based on the metal dry granular of preparation, appropriate suspending agent and degumming agent are introduced,
Water is added to grind, control glaze slip fineness is 325 mesh screen residues 0.05% hereinafter, obtaining the metal cloud that density is 1.1 ~ 1.4g/cm3；
4）Apply cloth cloud：In step 1）It with glaze spraying or gets rid of glaze mode in the adobe of preparation and applies cloth metal cloud, cloud applies cloth
Amount control is in 2.5 ~ 5.5g/m2；
5）Print overglaze：Overglaze density is 1.48 ~ 1.54g/cm3, and Shi Buliang is 13 ~ 18g/m2；
6）Printed patterns：Pattern decorative is carried out using silk-screen printing or ink jet printing；
7）Apply cloth metal dry granular：Using screen printing step 2）The metal dry granular of preparation, Shi Buliang are 35 ~ 45g/m2；
8）Dry firing：After adobe is well-dried, in 1180 ~ 1230 DEG C of firings, firing period is 50 ~ 80min；
9）Transmutation Antique Imitation Tiles finished product is made in edging.
To realize second goal of the invention, using the Antique Imitation Tiles produced by above-mentioned steps.
In the present invention, metal dry granular is the emphasis to form furnace transmutation decoration effect.Metal dry granular can form furnace transmutation decoration effect
Fruit, essentially consist in oxide in metal dry granular is influenced by glaze body itself and firing atmosphere and generates complicated show at high temperature
Chromatic effect.Fe2O3 in metal dry granular starts to decompose and discharge oxygen at 1000 DEG C or so, while forming and being in PbO-B2O3-
SiO2 ternarys not consolute area metal dry granular high temperature generate split-phase, induction Fe2O3 combined to form silicic acid with other elements in glaze
The crystal such as iron, iron aluminate could, with the transformation of iron atom valence state, crystalline phase in the brown a series of color such as black of blueness-Huang-congo red-,
By agitaion of the oxygen in glaze, colourful transmutation stripe effect is generated, compared to traditional archaized decoration effect, layer
Secondary more horn of plenty, color is more rich in agile hopping sense, by the collective effect of screen printing glaze modelled after an antique and transmutation metal dry granular, finally
Obtain having that metal-like, color are simple and unsophisticated, noble do not lose elegant novel transmutation decorative effect but.
In the present invention, the metal cloud covers entire adobe surface, mainly there is two aspect effects：First, in billet surface
Form irregular dotted glazing effect modelled after an antique；Second is that the small rut on green body mould flower surface is filled up, to improve the soil resistance of pit
Energy.
In the present invention, the overglaze fusing point between metal cloud and pattern decorative layer is higher, in addition to highlight pattern is decorated
Outside, it also can prevent cloud from being reacted with pattern screen printing glaze or ink and form aberration.
As further technical solution, the metal dry granular can be used cooperatively with a kind of low viscosity dry granular, this is low
Viscosity dry granular group becomes SiO2 55% ~ 65%, Al2O3 0.5% ~ 2%, CaO 8% ~ 10%, MgO 2% ~ 6%, K2O 8% ~ 12%, Na2O
9% ~ 14%, ZnO 10% ~ 15%, surplus are impurity.Metal dry granular is 3 with low viscosity dry granular proportioning:2~9:1.
As further technical solution, the step 6）One or multi-channel screen printing dataller can be used in middle pattern printing
Sequence, and metal glaze printing can be introduced in wherein arbitrary one of printing process.The metal glaze be based on metal dry granular,
Appropriate suspending agent and degumming agent are introduced, water is added to grind, control glaze slip fineness is 325 mesh screen residues 0.05% hereinafter, obtained density is
The glaze slip of 1.5 ~ 1.6g/cm3.
As further technical solution, the printed patterns of metal dry granular need to be adjusted according to the Z-Correct bump mapping Z-correct that mould is spent,
Preferably, can continuous female flower be set in adobe edge and dotted female flower, printing gold is set in intermediate region
Belong to dry granular, metal dry granular is made to work in coordination with color printing glaze, realizes the ingenious combination of transmutation and archaized decoration effect.
As further technical solution, cloth flash glaze can be applied after silk-screen printing or ink jet printing, Shi Buliang is 13 ~
18g/m2.The flash glaze is the cerium oxide using the metal glaze additional 5% ~ 15%, with the precipitation of high-temperature oxydation cerium crystal grain, oxygen
Changing cerium crystal grain, there is (200) face of good properties of specular reflection to be parallel to glaze arrangement, and glaze is made to generate minute surface hair in face of incident light
It penetrates, flash effect can be increased on the basis of printed decoration, with the variation of viewing angle, vision can be realized by applying cloth flash glaze region
The effect of gloss transformation.
It, can be in step 6 as further technical solution）With 7）Between increase printing clear frit the step of, correspondingly,
Step 9）Middle increase polishing process, can obtain the Antique Imitation Tiles with certain three-dimensional sense and Modern Decorative style.The clear frit applies cloth
Amount is 35 ~ 45g/m2, and glazing thickness is 1.5 ~ 2.5mm.
Advantageous effect obtained by the present invention is：The present invention is in decorative effect innovatively by transmutation effect and Antique Imitation Tiles
Dexterously combine, provide a kind of transmutation Antique Imitation Tiles and its production method, solve Antique Imitation Tiles decoration technique it is more single,
Not abundant enough the problem of level.By in a variety of colour systems modelled after an antique such as a wide range of process yellow of ceramic tile surface, coffee color, kermesinus
Sub-shine glaze forms the distinctive simple and unsophisticated charm of Antique Imitation Tiles and style of missing old times or old friends, while in the metal of ceramic tile surface printing and mould flower cooperation
Dry granular is influenced at high temperature by glaze body itself and firing atmosphere using oxide in metal dry granular and generates complicated develop the color
There is strong corrosion of metal sense and vicissitudes to feel for effect, Antique Imitation Tiles obtained, and simple dignified style of missing old times or old friends has catered to the modern times
The phychology that people advocates nature, recovers one's original simplicity, great decorative and artistry.It is different from some traditional Antique Imitation Tiles, it is not to use
The later stages such as acidleach, autoclaving manually do old mode deliberately for it, but colour system glaze modelled after an antique and kiln are used in phase allotment before manufacture
Become metal dry granular, reaches the decorative effect that color is natural, texture is dignified using the colour developing effect of its high temperature complexity, provide one
Produce the brand-new approach of Antique Imitation Tiles.
【Description of the drawings】
Fig. 1 is the process flow chart of transmutation Antique Imitation Tiles production method of the present invention（It is optional step in dotted line frame）.
【Specific implementation mode】
Embodiment 1
1）Prepare adobe：Porcelain Antique Imitation Tiles green body powder is prepared according to a conventional method, and mold compression moulding prepares adobe, standby
With；
2）Prepare metal dry granular：Glass frit preparation process routinely, selection are former containing lithium minerals, quartz and chemical industry
Material, be melted by dispensing, 1250 DEG C, water quenching, drying, broken, sieving, the processes such as classification, acquisitions composition range be SiO2 25%,
Al2O3 6%, Fe2O3 7%, Li2O 1%, B2O3 4%, ZnO 35%, PbO 15%, surplus be fining agent and impurity, moisture≤
0.5% grain size is the frit of 100 ~ 200 mesh, spare；
3）Prepare metal cloud：With step 2）Based on the metal dry granular of preparation, appropriate suspending agent and degumming agent are introduced, is added
Water is ground, and control glaze slip fineness is 325 mesh screen residues 0.05% hereinafter, obtaining the metal cloud that density is 1.3g/cm3；
4）Apply cloth cloud：In step 1）Cloth metal cloud is applied with glaze spraying mode in the adobe of preparation, it is 4g/ that cloud, which applies cloth amount,
m2；
5）Print overglaze：Overglaze density is 1.5g/cm3, Shi Buliang 17g/m2；
6）Printed patterns：Spanish furnish is carried out using 4 silk-screen printings, is followed successively by red, yellow, brown, grey；
7）Apply cloth metal dry granular：Using screen printing step 2）The metal dry granular of preparation, Shi Buliang 40g/m2；
8）Dry firing：After adobe is well-dried, in 1220 DEG C of firings, firing period 60min；
9）Edging is made in transmutation Antique Imitation Tiles finished product.
Embodiment 2
1）Prepare adobe：Porcelain Antique Imitation Tiles green body powder is prepared according to a conventional method, and mold compression moulding prepares adobe, standby
With；
2）Prepare metal dry granular：Glass frit preparation process routinely, selection are former containing lithium minerals, quartz and chemical industry
Material, be melted by dispensing, 1200 DEG C, water quenching, drying, broken, sieving, the processes such as classification, acquisitions composition range be SiO2 30%,
Al2O3 3%, Fe2O3 5%, Li2O 2%, B2O3 5%, ZnO 28%, PbO 18%, surplus be fining agent and impurity, moisture≤
0.5% grain size is the frit of 100 ~ 200 mesh, spare；
3）Prepare metal cloud：With step 2）Based on the metal dry granular of preparation, appropriate suspending agent and degumming agent are introduced, is added
Water is ground, and control glaze slip fineness is 325 mesh screen residues 0.05% hereinafter, obtaining the metal cloud that density is 1.4g/cm3；
4）Apply cloth cloud：In step 1）Cloth metal cloud is applied with glaze spraying mode in the adobe of preparation, it is 3g/ that cloud, which applies cloth amount,
m2；
5）Print overglaze：Overglaze density is 1.54g/cm3, Shi Buliang 14g/m2；
6）Printed patterns：Spanish furnish is carried out using ink jet printing；
7）Print clear frit：Shi Buliang is 38g/m2, and glazing thickness is 2mm.
8）Type metal dry granular：Using screen printing step 2）The metal dry granular of preparation, Shi Buliang 43g/m2；
9）Dry firing：After adobe is well-dried, in 1180 DEG C of firings, firing period 70min；
10）Edging, polishing mainly use soft throwing, and transmutation Antique Imitation Tiles finished product is made.
Embodiment 3
1）Prepare adobe：Porcelain Antique Imitation Tiles green body powder is prepared according to a conventional method, and mold compression moulding prepares adobe, standby
With；
2）Prepare metal dry granular：Glass frit preparation process routinely, selection are former containing lithium minerals, quartz and chemical industry
Material, be melted by dispensing, 1300 DEG C, water quenching, drying, broken, sieving, the processes such as classification, acquisitions composition range be SiO2 30%,
Al2O3 6%, Fe2O3 9%, Li2O 1.5%, B2O3 2.5%, ZnO 26%, PbO 14%, surplus be fining agent and impurity, water
It is the frit of 100 ~ 200 mesh to divide the grain size of < 0.5%, spare；
3）Prepare metal cloud：With step 2）Based on the metal dry granular of preparation, appropriate suspending agent and degumming agent are introduced, is added
Water is ground, and control glaze slip fineness is 325 mesh screen residues 0.05% hereinafter, obtaining the metal cloud that density is 1.1g/cm3；
4）Apply cloth cloud：In step 1）Cloth metal cloud is applied with getting rid of glaze mode in the adobe of preparation, and cloud applies cloth amount and is
2.5g/m2；
5）Print overglaze：Overglaze density is 1.48g/cm3, Shi Buliang 16g/m2；
6）Printed patterns：Spanish furnish is carried out using 3 silk-screen printings, then using ink jet printing；
7）Type metal dry granular：Using screen printing step 2）The metal dry granular of preparation, Shi Buliang 36g/m2；
8）Dry firing：After adobe is well-dried, in 1230 DEG C of firings, firing period 50min；
9）Transmutation Antique Imitation Tiles finished product is made in edging.
Embodiment 4
1）Prepare adobe：Porcelain Antique Imitation Tiles green body powder is prepared according to a conventional method, and mold compression moulding prepares adobe, standby
With；
2）Prepare metal dry granular：Glass frit preparation process routinely, selection are former containing lithium minerals, quartz and chemical industry
Material, be melted by dispensing, 1270 DEG C, water quenching, drying, broken, sieving, the processes such as classification, acquisitions composition range be SiO2 28%,
Al2O3 4%, Fe2O3 6%, Li2O 1.7%, B2O3 3.5%, ZnO 32%, PbO 16%, surplus be fining agent and impurity, water
It is the frit of 100 ~ 200 mesh to divide the grain size of < 0.5%, spare；
3）Prepare metal cloud：With step 2）Based on the metal dry granular of preparation, appropriate suspending agent and degumming agent are introduced, is added
Water is ground, and control glaze slip fineness is 325 mesh screen residues 0.05% hereinafter, obtaining the metal cloud that density is 1.2g/cm3；
4）Apply cloth cloud：In step 1）Cloth metal cloud is applied with glaze spraying mode in the adobe of preparation, cloud applies cloth amount and is
4.5g/m2；
5）Print overglaze：Overglaze density is 1.53g/cm3, Shi Buliang 15g/m2；
6）Printed patterns：Spanish furnish is carried out using 5 silk-screen printings, is followed successively by yellow, red, grey, brown, finally
It is flash glaze together；
7）Type metal dry granular：Using screen printing step 2）The metal dry granular of preparation, Shi Buliang 41g/m2；
8）Dry firing：After adobe is well-dried, in 1210 DEG C of firings, firing period 65min；
9）Transmutation Antique Imitation Tiles finished product is made in edging.
Claims (7)
1. a kind of production method of transmutation Antique Imitation Tiles, which is characterized in that include the following steps：
1）Prepare adobe：Porcelain Antique Imitation Tiles green body powder is prepared according to a conventional method, and adobe is prepared using the tool compression moulding of mould embossing die,
It is spare；
2）Prepare metal dry granular：Glass frit preparation process routinely, selection contain lithium minerals, quartz and industrial chemicals, lead to
Cross dispensing, 1200 ~ 1300 DEG C be melted, water quenching, drying, broken, sieving, classification process, acquisitions composition range is SiO2 22%~
30%、Al2O3 1%~6%、Fe2O3 3%~10%、Li2O 0.5%~2%、B2O30.5% ~ 5%, ZnO 25% ~ 35%, PbO 10% ~ 20%,
Surplus is fining agent and impurity, and the grain size of moisture≤0.5% is the frit of 100 ~ 200 mesh, spare；
3）Prepare metal cloud：With step 2）Based on the metal dry granular of preparation, appropriate suspending agent and degumming agent are introduced, water is added to grind
Mill, control glaze slip fineness are 325 mesh screen residues 0.05% hereinafter, it is 1.1 ~ 1.4g/cm to obtain density3Metal cloud；
4）Apply cloth cloud：In step 1）It with glaze spraying or gets rid of glaze mode in the adobe of preparation and applies cloth metal cloud, cloud applies cloth amount control
System is in 2.5 ~ 5.5g/m2；
5）Print overglaze：Overglaze density is 1.48 ~ 1.54g/cm3, Shi Buliang is 13 ~ 18g/m2；
6）Printed patterns：Pattern decorative is carried out using silk-screen printing or ink jet printing；
7）Apply cloth metal dry granular：Using screen printing step 2）The metal dry granular of preparation, Shi Buliang are 35 ~ 45g/m2；
8）Dry firing：After adobe is well-dried, in 1180 ~ 1230 DEG C of firings, firing period is 50 ~ 80min；
9）Transmutation Antique Imitation Tiles finished product is made in edging.
2. the production method of transmutation Antique Imitation Tiles according to claim 1, which is characterized in that step 3）,7）The metal
Dry granular is used cooperatively with a kind of low viscosity dry granular, which becomes SiO2 55%~65%、Al2O3 0.5%~2%、CaO
8%~10%、MgO 2%~6%、K2O 8%~12%、Na2O 9% ~ 14%, ZnO 10% ~ 15%, surplus are impurity；The metal dry granular with
Low viscosity dry granular proportioning is 3:2~9:1.
3. the production method of transmutation Antique Imitation Tiles according to claim 1, which is characterized in that step 6）Middle pattern printing uses
One or multi-channel silkscreen process, and metal glaze printing is introduced in wherein arbitrary one of printing process；The metal glaze
It is to introduce appropriate suspending agent and degumming agent based on metal dry granular, water is added to grind, control glaze slip fineness is 325 mesh screen residues
0.05% hereinafter, obtained density is 1.5 ~ 1.6g/cm3Glaze slip.
4. the production method of transmutation Antique Imitation Tiles according to claim 1, which is characterized in that step 1）Adobe edge is set
It sets continuous female flower and dotted female flower is set in intermediate region；Step 7）The printed patterns of middle metal dry granular are according to brick
The Z-Correct bump mapping Z-correct of mold flower is adjusted so that metal dry granular is printed on the female and takes.
5. the production method of transmutation Antique Imitation Tiles according to claim 3, which is characterized in that step 6）It is applied again after printed patterns
Cloth flash glaze, Shi Buliang are 13 ~ 18g/m2；The flash glaze is the cerium oxide using the metal glaze additional 5% ~ 15%.
6. the production method of transmutation Antique Imitation Tiles according to claim 1, which is characterized in that in step 6）With 7）Between increase
The step of printing clear frit, correspondingly, in step 9）Middle increase polishing process；It is 35 ~ 45g/m that the clear frit, which applies cloth amount,2, apply
Glaze thickness is 1.5mm ~ 2.5mm.
7. transmutation Antique Imitation Tiles prepared by the production method of the transmutation Antique Imitation Tiles according to claim 1 ~ 6 any claim.
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| CN102557756A (en) * | 2012-01-10 | 2012-07-11 | 广东道氏技术股份有限公司 | Preparation method of stone-pattern-simulating glazed brick |
| CN102794950A (en) * | 2012-07-21 | 2012-11-28 | 佛山瑭虹釉料科技有限公司 | Once-fired color microcrystal brick and production process thereof |
| CN102826872A (en) * | 2012-08-17 | 2012-12-19 | 广东宏陶陶瓷有限公司 | Formula and preparation method of national flag bright red glazed brick |
| CN103435369A (en) * | 2013-08-12 | 2013-12-11 | 广东家美陶瓷有限公司 | Method for manufacturing wear-resistant antiskid dry-particle ceramic tile |
| CN103626523A (en) * | 2013-11-26 | 2014-03-12 | 广东金意陶陶瓷有限公司 | Ceramic tile with dry particle glaze-decorated surface and manufacturing method thereof |
| CN103833423A (en) * | 2014-01-14 | 2014-06-04 | 佛山市东鹏陶瓷有限公司 | Ceramic tile preparation method and product thereof |
| CN104016726A (en) * | 2014-05-26 | 2014-09-03 | 东莞市唯美陶瓷工业园有限公司 | Manufacturing process of ceramic accessory tile and ceramic accessory tile manufactured by the process |
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