CN109293397A - A kind of Antique Imitation Tiles and preparation method thereof with 3D embossment - Google Patents
A kind of Antique Imitation Tiles and preparation method thereof with 3D embossment Download PDFInfo
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- CN109293397A CN109293397A CN201811171893.0A CN201811171893A CN109293397A CN 109293397 A CN109293397 A CN 109293397A CN 201811171893 A CN201811171893 A CN 201811171893A CN 109293397 A CN109293397 A CN 109293397A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
- C03C8/04—Frit compositions, i.e. in a powdered or comminuted form containing zinc
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/20—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2204/00—Glasses, glazes or enamels with special properties
- C03C2204/04—Opaque glass, glaze or enamel
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2205/00—Compositions applicable for the manufacture of vitreous enamels or glazes
- C03C2205/02—Compositions applicable for the manufacture of vitreous enamels or glazes for opaque enamels or glazes
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Structural Engineering (AREA)
- Finishing Walls (AREA)
Abstract
The invention discloses a kind of preparation methods of Antique Imitation Tiles with 3D embossment, comprising: obtains finished product after billet surface is sequentially prepared ground coat enamel, ink jet printing, overglaze, drying, firing.The present invention seeps flower technology by ink-jet, is prepared for enriching 3D embossment true to nature in Antique Imitation Tiles brick face, preparation process is simple, without substantially saving production cost according to the different designs of Antique Imitation Tiles more mold exchange.Correspondingly, surface gloss is low, clean mark the invention also discloses a kind of Antique Imitation Tiles with 3D embossment, three-dimensional sense is strong；And anti-pollution, non-skid property are excellent.
Description
Technical field
The invention belongs to Ceramic Tiles preparation field more particularly to a kind of Antique Imitation Tiles and preparation method thereof with 3D embossment.
Background technique
Antique Imitation Tiles are a kind of bricks with antique effect glaze paint, are generally Shi porcelain or porcelain.Antique Imitation Tiles glaze paint is only
Spy is the product quite to get consumer reception often with classic flavor.With advances in technology, Antique Imitation Tiles have gradually expanded respectively
The glazing effect of kind various kinds, such as timber Antique Imitation Tiles, the pseudo-classic brick of carpet, the pseudo-classic brick of natural stone；Current main research direction is imitative
Lithotome lines.However, conventional Antique Imitation Tiles, glaze paint production technology is to be screen printed onto surface, can not embody day at all
The visual impression of right stone material concave convex texture.
A kind of improved method is to build the concave-convex sense of imitation stone in Antique Imitation Tiles billet surface using Strand Feeding Technique；As in
State patent CN104193415A discloses a kind of method that three-dimensional decorative effect ceramic tile is manufactured using secondary material distributing.However,
This technique limits huge among daily production: one product of every replacement just needs to design different mold, production process
In also need market more mold exchange, not only high production cost, production efficiency are also low.
Ink-jet seeps flower technology as a kind of new technique, is widely used in the production of Imitation Rock Porcelain Tiles at present.Its cardinal principle
It is to drench ground coat enamel in Imitation Rock Porcelain Tiles billet surface or secondary material distributing prepares green body, then ink is permeated in spray, so that pattern penetrates into bottom
It among glaze layer or green body, is polished again after firing, is formed the visual impression of stereo decoration.Patent CN105330342B is
The structure for adding transparent overglaze using ground coat enamel plus infiltration ink, has been prepared the super flat porcelain of once burning with three-dimensional decorative effect
Matter brick.However, for now, this flower technology of seeping is chiefly used in the porcelain brick product that glaze paint has very high gloss, such as glaze is thrown
Brick etc.；This also requires to be polished after firing；To promote Imitation Rock Porcelain Tiles surface gloss, enable three-dimensional decorative effect
Enough to present, process is cumbersome；On the other hand, in order to promote the glossiness of glaze paint, it is necessary to be adjusted to the formula of glaze
Section also just reduces the content of crystal in glaze paint after being burnt into, reduces the resistance to of Imitation Rock Porcelain Tiles so that it is with very high translucency
Performance is ground, Mohs' hardness only reaches 5-6；It is easily worn out.
On the one hand, since Antique Imitation Tiles are dedicated to imitating the visual effect of natural stone, timber, carpet etc., surface gloss
It is lower；How in the case where seeping flower technology using ink-jet, the effect of stereo decoration is shown, difficult point is just become；And it is another
Aspect, so that Antique Imitation Tiles have glossiness low as far as possible, has and more forces how under the premise of seeping flower technology using ink-jet
Genuine effect and a difficult point；Finally, guaranteeing the wear-resisting effect of Antique Imitation Tiles how in the case where seeping flower technology using ink-jet
Fruit, anti-fouling effect, antiskid effect are the another hang-ups for needing to overcome.
Summary of the invention
Technical problem to be solved by the present invention lies in, a kind of preparation method of Antique Imitation Tiles with 3D embossment is provided,
Method is simple, it is high-efficient, can mass production, Antique Imitation Tiles surface detail obtained is true to nature, and resistance to soiling, skid resistance be excellent, surface
Glossiness is low.
The present invention also technical problems to be solved are, provide a kind of Antique Imitation Tiles with 3D embossment, and resistance to soiling is prevented
Slip is excellent, and surface gloss is low, and texture is soft.
In order to solve the above-mentioned technical problems, the present invention provides a kind of preparation method of Antique Imitation Tiles with 3D embossment, packets
It includes:
(1) green body, ground coat enamel glaze slip, overglaze glaze slip, ink-jet ink and finishing impression ink are prepared respectively；
(2) ground coat enamel glaze slip is applied to form ground glaze layer in the billet surface of drying；
(3) ink-jet ink and finishing impression ink printed decoration pattern are used on the ground glaze layer；
(4) green body that step (3) obtains is placed preset time to form embossed layer so that decorative pattern permeates；
(5) overglaze glaze slip is applied to form cover coat in the billet surface；
(6) green body for obtaining step (5) is dried；
(7) green body for obtaining step (6) is burnt into, and obtains the Antique Imitation Tiles finished product with 3D embossment；
Wherein, the permeability-thickness of the embossed layer is 0.2-1mm；
The glossiness of the Antique Imitation Tiles is 6-8 degree, and stain resistance is 5 grades, coefficient of friction >=0.6.
As an improvement of the above technical solution, the finishing impression ink is made of raw material from the following weight: tackifier 25-
50 parts and penetration-assisting agent 5-20 parts；Wherein, the tackifier select one of glycerol, carboxymethyl cellulose, starch or combination
Object, the penetration-assisting agent select one of sodium carbonate, sodium hydroxide, potassium hydroxide or combination.
As an improvement of the above technical solution, the overglaze glaze slip is prepared by the raw material of following parts by weight: albite
35-48 parts, 6-10 parts of kaolin, kaolin 3-7 parts of burning, 1-3 parts of calcining zinc oxide, 3-6 parts of talcum, 7-15 parts of strontium carbonate, oxygen
Change zirconium 10-15 parts, 10-25 parts of additive；
Wherein, the chemical component of additive is SiO245-49%, Al2O315-17%, Fe2O30.2-0.7%, TiO2
0.2-0.5%, CaO 12.9-16.8%, MgO 1-3%, K2O 1.5-3.5%, Na2O 0.5-0.8%, ZnO 12.7-
15.9%, surplus is impurity.
As an improvement of the above technical solution, the chemical component of the overglaze glaze slip are as follows: SiO245.6-52.7%,
Al2O312-17%, Fe2O30.1-0.2%, TiO20.2-0.5%, CaO 5-7.5%, MgO 0.3-0.7%, K2O
2.7-5.8%, Na2O 3.6-5.3%, ZnO 3-5%, SrO7-9%, ZrO23-5%, surplus are impurity；
The fineness of the overglaze glaze slip is that 325 meshes tail over 0.4-0.7%, specific gravity 1.88-1.93g/mL, and flow velocity is
30-38 seconds.
As an improvement of the above technical solution, the ground coat enamel glaze slip is prepared by the raw material of following parts by weight: potassium feldspar
37-55 parts, 6-12 parts of kaolin, kaolin 5-7 parts of burning is 8-13 parts of barium carbonate, 4-8 parts quartzy, 1-3 parts of calcining zinc oxide, forges
Burn talcum 3-6 parts, 5-10 parts of additive.
As an improvement of the above technical solution, the chemical component of the ground coat enamel glaze slip are as follows: SiO257-59%, Al2O3
10-17%, Fe2O30.2-0.7%, TiO20.3-0.5%, CaO 1-6%, MgO 8-11%, K2O 5-8%, Na2O 1.5-
3.0%, ZnO 1.5-2.5%, BaO 8-11%, surplus are impurity；
The fineness of the ground coat enamel glaze slip is that 325 meshes tail over 0.5-0.9%, specific gravity 1.85-1.92g/mL, flow velocity 30-
38 seconds.
As an improvement of the above technical solution, in step (2), the glaze volume of the ground coat enamel glaze slip is 350-400 g/m2；
In step (5), the glaze volume of overglaze glaze slip is 180-200g/m2。
As an improvement of the above technical solution, in step (7), firing temperature is 1155-1200 DEG C, firing period 55-
65 minutes.
As an improvement of the above technical solution, the Antique Imitation Tiles wearability is 5 grades, surface Mohs' hardness >=6；Water absorption rate
≤ 0.1%；The modulus of rupture >=45MPa.
Correspondingly, using above-mentioned preparation method system the invention also discloses a kind of Antique Imitation Tiles with 3D embossment
?.
The present invention provides a kind of preparation method of Antique Imitation Tiles with 3D embossment, using apply ground coat enamel, ink-jet seep flower, finishing impression,
The Antique Imitation Tiles with 3D embossment have been prepared in the technique for applying overglaze, firing.Carry out the beneficial effect of technical solution of the present invention
It is as follows:
1, the present invention seeps flower technology by ink-jet, is prepared for enriching 3D embossment true to nature in Antique Imitation Tiles brick face, prepares work
Skill is simple, without substantially saving production cost according to the different designs of Antique Imitation Tiles more mold exchange.
2, the present invention in such a way that finishing impression ink combines, increases the thickness of infiltration using ink-jet ink, seeks on surface
Made very strong three-dimensional sense, and the later period without polishing, remain three-dimensional shape；Since Antique Imitation Tiles surface three-dimensional structure is to light
Line is scattered；Effectively reduce the glossiness of ceramic brick surface；And to produce under finishing impression ink and overglaze collective effect
The double effects for sinking and peeling off form the texture of concave-convex and light and shade variation on Antique Imitation Tiles surface, and hand sense of touch is true to nature, color
It is soft.
3, the present invention forms embossment structure on Antique Imitation Tiles surface by reasonable ink set；Enhance Antique Imitation Tiles
Antiskid effect；Simultaneously because embossment sink, the aperture in hole is big, and hole depth is controllable, therefore its anti-pollution is excellent.
4. the present invention, which passes through, designs reasonable finishing impression ink set system, so that it is strong in pattern penetration, and penetrating
It is not easy to disperse in journey, does not form dizzy dye, guarantee clear patterns, undistorted, and no color differnece.
5. the present invention is by reasonable overglaze formula system, so that overglaze also has in the case where guaranteeing higher clarity
There is higher hardness, effectively enhances the abrasion resistant effect of Antique Imitation Tiles；Its Mohs' hardness can reach 6 or more.
Specific embodiment
In order to make the objectives, technical solutions, and advantages of the present invention clearer, with reference to embodiments, to this hair
It is bright to be further elaborated.It should be appreciated that specific embodiment described herein is used only for explaining the present invention, not
For limiting the present invention.
The present invention provides a kind of preparation method of Antique Imitation Tiles with 3D embossment, comprising:
(1) green body, ground coat enamel glaze slip, overglaze glaze slip, ink-jet ink and finishing impression ink are prepared respectively；
Wherein, there is no special limitation for the raw material of the specific formula of green body and use, those skilled in the art can
It is selected according to the corresponding condition of production；Preferably, using Imitation Rock Porcelain Tiles body recipe, and green body thermal expansion coefficient and glaze of the present invention
Material is adapted, and the defect that glaze is split does not occur with guarantee.
Preferably, the ground coat enamel glaze slip in the present invention is prepared by the raw material of following parts by weight: 37-55 parts of potassium feldspar, high
Soil 6-12 parts of ridge, kaolin 5-7 parts of burning is 8-13 parts of barium carbonate, 4-8 parts quartzy, and 1-3 parts of calcining zinc oxide, calcination of talc 3-6
Part, 5-10 parts of additive；Barium carbonate and zinc oxide can play the role of extraordinary milkiness, can preferably cover green body table
The defect in face, while being also beneficial to the color development of later period ink；Prepare the Antique Imitation Tiles of anaglyph.Meanwhile using burning kaolinite
Soil, calcining zinc oxide, calcination of talc can effectively remove kaolin, zinc oxide, the impurity in talcum powder, and it is excellent that property is prepared
Good glaze.Wherein, the additive chemistry ingredient are as follows: SiO245-49%, Al2O315-17%, Fe2O30.2-0.7%,
TiO20.2-0.5%, CaO 12.9-16.8%, MgO 1-3%, K2O 1.5-3.5%, Na2O 0.5-0.8%, ZnO
12.7-15.9%, surplus are impurity.Additive is frit, and the addition of frit reduces firing temperature, expands firing range,
The stability of glaze is also improved simultaneously.
Preferably, ground coat enamel glaze slip chemical component are as follows: SiO257-59%, Al2O310-17%, Fe2O30.2-0.7%,
TiO20.3-0.5%, CaO 1-6%, MgO 8-11%, K2O 5-8%, Na2O 1.5-3.0%, ZnO 1.5-2.5%, BaO
8-11%, surplus are impurity；Ground coat enamel in the present invention uses BaO-ZnO-K2O-SiO2-Al2O3System opaque glaze, and matching
Containing the MgO of higher amount in side, ground coat enamel can not only be promoted to melt at a lower temperature, at the same MgO can be used as it is good
Mineralizer promotes the precipitation of crystal in ground coat enamel, promotes opaque effect.Preferably, the fineness of the ground coat enamel glaze slip is 325 meshes
Tail over 0.5-0.9%, specific gravity 1.85-1.92g/mL, flow velocity 30-38 seconds；Glaze slip within the scope of this fineness has relatively good
Mobility can be dispersed in Antique Imitation Tiles billet surface during glazing；The glaze paint with superperformance is prepared.
Preferably, the overglaze is prepared by the raw material of following parts by weight: 35-48 parts of albite, kaolin 6-10
Part, kaolin 3-7 parts of burning, 1-3 parts of calcining zinc oxide, 3-6 parts of talcum, 7-15 parts of strontium carbonate, 10-15 parts of zirconium oxide, additive
10-25 parts.The present invention is used using albite, talcum as the glaze formula system of main fluxing, can be melted at a lower temperature
Change, good glaze paint is prepared；And the glaze paint in the present invention is transparent glaze paint, can preferably show the effect of embossment.
Wherein, the chemical component of additive is SiO245-49%, Al2O315-17%, Fe2O30.2-0.7%, TiO2
0.2-0.5%, CaO 12.9-16.8%, MgO 1-3%, K2O 1.5-3.5%, Na2O 0.5-0.8%, ZnO 12.7-
15.9%, surplus is impurity.
Preferably, the chemical component of the overglaze glaze slip are as follows: SiO245.6-52.7%, Al2O312-17%, Fe2O3
0.1-0.2%, TiO20.2-0.5%, CaO 5-7.5%, MgO 0.3-0.7%, K2O 2.7-5.8%, Na2O 3.6-
5.3%, ZnO 3-5%, SrO 7-9%, ZrO23-5%, surplus are impurity.It can from the chemical component of overglaze glaze slip
Out, Na in the present invention2O, the alkali metal oxide contents such as ZnO, SrO are higher, therefore it can be melted at a lower temperature.Together
When glaze of the invention in also contain a small amount of MgO, the melting temperature of glaze paint, but the MgO of too high amount can be significantly reduced
Or as the zirconium precipitation that mineralizer is, opacifying effect is formed, therefore the additional amount of talcum is controlled in the present invention.Preferably, described
The fineness of overglaze glaze slip is that 325 meshes tail over 0.4-0.7%, specific gravity 1.88-1.93g/mL, and flow velocity is 30-38 seconds.This is thin
There is glaze slip in degree range relatively good mobility can be dispersed in Antique Imitation Tiles billet surface during glazing；
The glaze paint with superperformance is prepared.
It should be understood that in order to promote the 3D effect of embossment in the present invention, it is necessary to so that glaze paint is at a lower temperature
Melting, so that overglaze can form 3D effect with finishing impression ink collective effect；Meanwhile also to make overglaze as far as possible and have and is higher
The transparency.In order to ensure the above effect, a kind of method is using the method polished after firing, but technique is more troublesome, production
Low efficiency；Another method is to change glaze formula, reduces wherein Al2O3Content, to reduce the content of crystal in glaze, i.e.,
The content for reducing emulsifier in glaze, so that glaze is sufficiently transparent；But the wearability of this glaze paint is particularly poor, therefore causes
The overall wear resistance in brick face reduces.The present invention overcomes above two defect by the improvement of glaze formula and technique: first
First, the present invention integrally reduces the melting temperature of glaze paint by reducing the content of Al, but in order to promote hardness of glaze surface, is being formulated
Middle introducing zirconium oxide can effectively promote the wear-resisting property of glaze paint；But introducing zirconium oxide can make glaze fusion point increase；Cause
This, secondly, the present invention by introducing a small amount of talcum and using the albite of low-temperature melting point, guarantee introduce zirconium oxide with
Afterwards, the melting temperature of glaze paint is not promoted；Finally, the present invention also accurately controls the content of magnesia, so that overglaze is introducing oxygen
Change after zirconium the not mineralising in sintering process, does not form opacifying effect；It ensure that there is overglaze enough transparencies can present
3D effect, but also guarantee that glaze has dumb light effect simultaneously, so that the glossiness in brick face further decreases, the texture of 3D embossment
It is more life-like, it is more suitable for the production of imitation stone, woven design, carpet brick.To sum up, by the rational design of overglaze formula,
The 3D effect for effectively improving Antique Imitation Tiles reduces glossiness, and improves the hardness in brick face, so that Antique Imitation Tiles are more wear-resisting,
Antique Imitation Tiles surface Mohs' hardness >=6 in the present invention, it is further preferred that surface Mohs' hardness >=7.
Wherein, the ink-jet ink is using ink common in the market, if Caro is than the TSG-40001 that sub- company produces
The ink-jet ink etc. of model, those skilled in the art can select adaptable ink according to the color effect of brick mask body.
Wherein, the finishing impression ink is made of raw material from the following weight: 25-50 parts and penetration-assisting agent 5-20 parts of tackifier；
Tackifier can guarantee that ink rapidly permeates into ground glaze layer without scattering, dizzy dye；Penetration-assisting agent then enables to the color in ink-jet ink
Material penetrates into certain depth, forms embossing pattern.Preferably, the tackifier select glycerol, carboxymethyl cellulose, in starch
A kind of or composition, the further preferably composition of glycerol and carboxymethyl cellulose, its ratio be glycerol: carboxymethyl cellulose
Element=1:3；The tackifier of this matched proportion density can effectively promote the viscosity of ink-jet ink, so that colorant does not scatter.It is preferred that
, the penetration-assisting agent is one of sodium carbonate, sodium hydroxide, potassium hydroxide, hydrofluoric acid or combinations thereof, is further selected as
The combination of sodium carbonate and sodium hydroxide, and sodium carbonate: sodium hydroxide=1:1；Sodium carbonate and sodium hydroxide can be with coloring metals
Ion is effectively complexed, so that the penetrating power of infiltration colorant is obviously reinforced.
(2) ground coat enamel glaze slip is applied to form ground glaze layer in the billet surface of drying；
Wherein, the technique for applying ground coat enamel to billet surface is not particularly limited, can be used and the side such as drenches glaze, glaze spraying, gets rid of glaze
Formula carries out.Preferably, using the glazing mode of leaching glaze, leaching glaze is specifically carried out using bell jar.Bell jar leaching glaze can effectively ensure glaze
Material is uniformly distributed, and can recycle extra glaze slip, saves cost.
Preferably, the glaze volume of ground coat enamel is 350-400g/m2, further preferably 380-400g/m2, suitable glaze volume
It can be formed during finishing impression ink bleed rich in relief pattern.
(3) ink-jet ink and finishing impression ink printed decoration pattern are used on the ground glaze layer；
Preferably, ink jet printing is carried out between 40-60 DEG C；It is further preferred that carrying out ink-jet print at 50-60 DEG C
Brush, the temperature for controlling ink jet printing can accelerate the infiltration rate that brick faces ink-jet ink and finishing impression ink, reduce ink
Dizzy dye effect, so that infiltration lines are more life-like.
(4) green body that step (3) obtains is placed preset time to form embossed layer so that decorative pattern permeates；
Preferably, green body is placed 3-10 minutes, so that finishing impression ink sufficiently acts on, forms embossed layer；It is further excellent
Choosing, green body is placed 3-5 minutes, too long standing time will affect production efficiency.
(5) overglaze glaze slip is applied to form cover coat in the billet surface；
Wherein, the technique for applying overglaze to billet surface is not particularly limited, can be used and the side such as drenches glaze, glaze spraying, gets rid of glaze
Formula carries out.Preferably, using the glazing mode of glaze spraying, glaze spraying is specifically carried out using water knife glaze spraying machine.Due to by finishing impression it
Brick face afterwards has more micro- 3D structure, can ensure that glaze is evenly dispersed using glaze spraying, and formation is relatively thin, adapts to micro- 3D
The glaze paint of structure, it is ensured that 3D effect.
Preferably, the glaze volume of overglaze glaze slip is 180-200g/m2, excessive glaze volume can block 3D pattern, and waste
Raw material.Very few overglaze cannot then play the effect of enhancing surface abrasion resistance.
(6) green body that step (5) obtains is dried；
Preferably, after drying, moisture content≤1% of the green body, it is further preferred that moisture content≤0.8%；Due to
The glaze paint of Antique Imitation Tiles in the present invention is thicker, therefore before entering kiln firing, needs sufficiently to dry it, to prevent brick
The defects of face is cracked.
(7) green body that step (6) obtains is burnt into, obtains the Antique Imitation Tiles finished product with 3D embossment；
Preferably, firing temperature is 1155-1200 DEG C, and firing period is 55-65 minutes.It is burnt at this temperature, it can
So that green body, glaze paint are sufficiently sintered, the stable Imitation Rock Porcelain Tiles of performance are obtained.
The infiltration of the embossed layer is with a thickness of 0.2-1mm；Preferably 0.5-1mm, further preferably 0.8-1mm.Using
Deeper infiltration thickness effectively can highlight 3D effect under conditions of low-luster.The present invention seeps flower skill by ink-jet
Art is prepared for enriching 3D embossment true to nature in Antique Imitation Tiles brick face, and preparation process is simple, does not have to replacement production mould, substantially saves
Production cost is saved.
It should be noted that flower technology is seeped in existing ink-jet, it is all to be polished after the sintering, to promote surface light
Damp degree, so that 3D effect is more life-like.In order to ensure glaze paint glossiness and reduce the loss of bistrique in polishing process, Chang Cai
With the lower overglaze formula containing aluminium, this reduces the hardness of glaze paint, reduce the wear-resisting property of ceramic tile；On the other hand, it polishes
Glaze paint is further gone to be roughened, so that the non-skid property of ceramic tile is greatly reduced；Polishing, which also exposes, is hidden in the small of glaze paint
Stomata (10-100 μm of diameter), this hole are very not easy to clean after entering spot.
The present invention overcomes the above problem by entirely different technique and formula.Firstly, the present invention is by deepening essence
The depth of penetration for carving layer, has ensured its visual effect.Present invention eliminates polishing processes, remain the true stereochemical structure in brick face,
This structure forms matte effect by the scattering for light, effectively reduces the glossiness of ceramic brick surface；And essence
The double effects for sinking and peeling off are produced under carving ink and overglaze collective effect, are formd on Antique Imitation Tiles surface concave-convex and bright
The texture secretly changed, hand sense of touch is true to nature, and color is soft.Further, Antique Imitation Tiles are formed by micro- 3D anaglyph in the present invention
So that brick surface roughness is promoted, the antiskid effect of Antique Imitation Tiles is effectively enhanced；Simultaneously because embossment sink, the aperture in hole is big, and
Hole depth is controllable, even if there is dirty infiltration, is also easy cleaning, therefore its anti-pollution is excellent.
Correspondingly, using the above method to be prepared the invention also discloses a kind of Antique Imitation Tiles with 3D embossment；
Preferably, the Antique Imitation Tiles glossiness is 6-8 degree, and stain resistance is 5 grades, and coefficient of friction >=0.6, wearability is 5 grades, surface
Mohs' hardness >=6；Water absorption rate≤0.1%；The modulus of rupture >=45MPa.
With specific embodiment, the present invention is further explained below
Embodiment 1
(1) green body, ground coat enamel glaze slip, overglaze glaze slip, ink-jet ink and finishing impression ink are prepared respectively；
Wherein, ground coat enamel glaze slurry formula: 37 parts of potassium feldspar；6 parts of kaolin, 5 parts of kaolin of burning, 13 parts of barium carbonate, quartz 4
Part, 1 part of calcining zinc oxide, 3 parts of calcination of talc, 5 parts of additive；
Additive chemistry ingredient are as follows: SiO245.87%, Al2O315.22%, Fe2O30.24%, TiO20.26%,
CaO 13.48%, MgO 1.48%, K2O 2.5%, Na2O 0.66%, ZnO 13.45%, surplus are impurity；Ground coat enamel chemistry
Ingredient are as follows: SiO257.23%, Al2O312.33%, Fe2O30.33%, TiO20.32%, CaO 1.32%, MgO
8.11%, K2O 5%, Na2O1.5%, ZnO2.05%, BaO9.24%, surplus are impurity.325 mesh of ground coat enamel tail over for
0.55%, specific gravity 1.90g/mL, flow velocity are 35 seconds.
Overglaze formula are as follows: 35 parts of albite, 10 parts of kaolin, 7 parts of kaolin of burning, 3 parts of calcining zinc oxide, 6 parts of talcum,
9 parts of strontium carbonate, 15 parts of zirconium oxide, 15 parts of additive；
Overglaze chemical component are as follows: SiO250.14%, Al2O315.55%, Fe2O30.11%, TiO20.32%, CaO
5.8%, MgO 0.4%, K2O3.5%, Na2O 5%, ZnO 3.44%, SrO7.68%, ZrO24.65%, surplus is miscellaneous
Matter.It is 0.65% that 325 mesh of overglaze, which tails over, specific gravity 1.92g/mL, and flow velocity is 30 seconds.
Wherein, the finishing impression ink is made of raw material from the following weight: 5-10 parts and penetration-assisting agent 50-80 parts of tackifier；
Tackifier can guarantee that ink rapidly permeates into ground glaze layer without scattering, dizzy dye；Penetration-assisting agent then enables to the color in ink-jet ink
Material penetrates into certain depth, forms embossing pattern.Preferably, the tackifier select glycerol, carboxymethyl cellulose, in starch
A kind of or composition, the further preferably composition of glycerol and carboxymethyl cellulose, its ratio be glycerol: carboxymethyl cellulose
Element=1:3；The tackifier of this matched proportion density can effectively promote the viscosity of ink-jet ink, so that colorant does not scatter.It is preferred that
, the penetration-assisting agent is one of sodium carbonate, sodium hydroxide, potassium hydroxide, hydrofluoric acid or combinations thereof, is further selected as
The combination of sodium carbonate and sodium hydroxide, and sodium carbonate: sodium hydroxide=1:1；Sodium carbonate and sodium hydroxide can be with coloring metals
Ion is effectively complexed, so that the penetrating power of infiltration colorant is obviously reinforced.
Finishing impression ink set is 50 parts of tackifier, 5 parts of penetration-assisting agents；Wherein, tackifier are carboxymethyl cellulose, penetration-assisting agent
For sodium carbonate.
(2) use bell jar leaching ground coat enamel glaze slip to form ground glaze layer in the billet surface of drying；
(3) ink-jet ink and finishing impression ink printed decoration pattern are used on the ground glaze layer；
(4) green body for obtaining step (3) places 5 minutes so that decorative pattern, which permeates, to form embossed layer；
(5) overglaze glaze slip is applied to form cover coat in the billet surface；
(6) green body that step (5) obtains is dried, green body moisture≤0.8% after drying；
(7) Antique Imitation Tiles with 3D embossment are obtained after being burnt into the green body that step (6) obtains at 1200 DEG C；Firing week
Phase is 55 minutes；The embossed layer permeability-thickness is 0.8mm.
Embodiment 2
(1) green body, ground coat enamel glaze slip, overglaze glaze slip, ink-jet ink and finishing impression ink are prepared respectively；
Wherein, ground coat enamel glaze slurry formula: 48 parts of potassium feldspar；12 parts of kaolin, 6 parts of kaolin of burning, 10 parts of barium carbonate, quartz 6
Part, 3 parts of calcining zinc oxide, 6 parts of calcination of talc, 9 parts of additive；
Additive chemistry ingredient are as follows: SiO248.32%, Al2O316.25%, Fe2O30.22%, TiO20.48%, CaO
12.99%, MgO2.5%, K2O 2.68%, Na2O 0.55%, ZnO 12.8%, surplus are impurity；Ground coat enamel chemical component are as follows:
SiO258.65%, Al2O313.44%, Fe2O30.26%, TiO20.32%, CaO1.22%, MgO 8.05%, K2O
5.4%, Na2O 1.55%, ZnO1.25%, BaO8.55%, surplus are impurity.It is 0.53% that 325 mesh of ground coat enamel, which tails over, than
Weight is 1.90g/mL, and flow velocity is 32 seconds.
Overglaze formula are as follows: 41 parts of albite, 8 parts of kaolin, 7 parts of kaolin of burning, 2.5 parts of calcining zinc oxide, talcum 3.5
Part, 8 parts of strontium carbonate, 12 parts of zirconium oxide, 18 parts of additive；
Overglaze chemical component are as follows: SiO251.33%, Al2O315.45%, Fe2O30.15%, TiO20.25%,
CaO6.5%, MgO 0.6%, K2O 5.35%, Na2O 3.7%, ZnO 3.45%, SrO8.05%, ZrO23.25%, surplus
For impurity.It is 0.45% that 325 mesh of overglaze, which tails over, specific gravity 1.88g/mL, and flow velocity is 30 seconds.
Finishing impression ink set is 35 parts of tackifier, 7 parts of penetration-assisting agent；Wherein, the tackifier are carboxymethyl cellulose and form sediment
The composition of powder, and carboxymethyl cellulose: starch=2:1；Injection is the composition of sodium carbonate and potassium hydroxide, and carbonic acid
Sodium: potassium hydroxide=1:1.
(2) use bell jar leaching ground coat enamel glaze slip to form ground glaze layer in the billet surface of drying；
(3) ink-jet ink and finishing impression ink printed decoration pattern are used on the ground glaze layer；
(4) green body for obtaining step (3) places 4 minutes so that decorative pattern, which permeates, to form embossed layer；
(5) overglaze glaze slip is applied to form cover coat in the billet surface；
(6) green body that step (5) obtains is dried, green body moisture≤0.8% after drying；
(7) Antique Imitation Tiles with 3D embossment are obtained after being burnt into the green body that step (6) obtains at 1185 DEG C；Firing week
Phase is 50 minutes；The embossed layer permeability-thickness is 0.5mm.
Embodiment 3
(1) green body, ground coat enamel glaze slip, overglaze glaze slip, ink-jet ink and finishing impression ink are prepared respectively；
Wherein, ground coat enamel glaze slurry formula: 50 parts of potassium feldspar；12 parts of kaolin, 7 parts of kaolin of burning, 9 parts of barium carbonate, quartz 4
Part, 3 parts of calcining zinc oxide, 6 parts of calcination of talc, 9 parts of additive；
Additive chemistry ingredient are as follows: SiO248.32%, Al2O316.25%, Fe2O30.22%, TiO20.48%,
CaO 12.99%, MgO 2.5%, K2O 2.68%, Na2O 0.55%, ZnO 12.8%, surplus are impurity；Ground coat enamel chemistry at
It is divided into: SiO257.68%, Al2O312.11%, Fe2O30.35%, TiO20.35%, CaO 1.25%, MgO
8.05%, K2O 5.35%, Na2O 1.55%, ZnO8.5%, BaO3.46%, surplus are impurity.325 mesh of ground coat enamel tail over for
0.52%, specific gravity 1.91g/mL, flow velocity are 32 seconds.
Overglaze formula are as follows: 43 parts of albite, 10 parts of kaolin, 5 parts of kaolin of burning, 2 parts of calcining zinc oxide, talcum 3.5
Part, 8.5 parts of strontium carbonate, 12 parts of zirconium oxide, 16 parts of additive；
Overglaze chemical component are as follows: SiO250.45%, Al2O314.87%, Fe2O30.12%, TiO20.38%,
CaO6.55%, MgO 0.6%, K2O 3.65%, Na2O 5.2%, ZnO4%, SrO 8%, ZrO24.2%, surplus is miscellaneous
Matter.It is 0.45% that 325 mesh of overglaze, which tails over, specific gravity 1.9g/mL, and flow velocity is 30 seconds.
Finishing impression ink set are as follows: 45 parts of tackifier, 7 parts of penetration-assisting agent；Wherein tackifier are glycerol and carboxymethyl cellulose
Composition, and glycerol: carboxymethyl cellulose=1:3；Penetration-assisting agent is the mixture of sodium carbonate and sodium hydroxide, sodium carbonate: hydrogen-oxygen
Change sodium=1:1.
(2) use bell jar leaching ground coat enamel glaze slip to form ground glaze layer in the billet surface of drying；
(3) ink-jet ink and finishing impression ink printed decoration pattern are used on the ground glaze layer；
(4) green body for obtaining step (3) places 4 minutes so that decorative pattern, which permeates, to form embossed layer；
(5) overglaze glaze slip is applied to form cover coat in the billet surface；
(6) green body that step (5) obtains is dried, green body moisture≤0.8% after drying；
(7) green body that step (6) obtains is carried out obtaining the Antique Imitation Tiles with 3D embossment after being burnt at 1150 DEG C；It burns
It is 55 minutes at the period；
The embossed layer permeability-thickness is 0.5mm.
The Antique Imitation Tiles with 3D embossment in embodiment 1-3 are detected, wherein using in GB/T 3810.3-2006
Method tests its water absorption rate；Its modulus of rupture is tested using the method in GB/T 3810.4-2006, using GB/T3810.6-
Method in 2006 tests its surface abrasion resistance；Its resistance to soiling is tested using the test method in GB/T 3810.14-2006
Energy；Its water absorption rate is tested using the method in GB/T 4100-2015；Examination its result of its glossiness is measured using surface gloss
It is as follows:
| Resistance to soiling | Wearability | Mohs' hardness | Water absorption rate | The modulus of rupture | Coefficient of friction | Glossiness | |
| Embodiment 1 | 5 grades | 5 grades | 6 | 0.1% | 45MPa | 0.6 | 8 |
| Embodiment 2 | 5 grades | 5 grades | 6.5 | 0.09% | 48MPa | 0.65 | 6.5 |
| Embodiment 3 | 5 grades | 5 grades | 7 | 0.03% | 55MPa | 0.8 | 6 |
To sum up, water absorption rate≤0.1% of the Antique Imitation Tiles prepared by the present invention with 3D embossment, the modulus of rupture >=45MPa,
Glossiness≤6, coefficient of friction >=0.6, stain resistance are 5 grades, and wearability is 5 grades, surface Mohs' hardness >=7；In the present invention
Antique Imitation Tiles have good stain resistance, wearability and non-skid property.
The foregoing is merely preferred embodiments of the invention, are not intended to limit the invention, all in spirit of the invention
With any modification affected within principle, equivalent replacement and improvement etc. be should all be included in the protection scope of the present invention.
Claims (10)
1. a kind of preparation method of the Antique Imitation Tiles with 3D embossment characterized by comprising
(1) green body, ground coat enamel glaze slip, overglaze glaze slip, ink-jet ink and finishing impression ink are prepared respectively；
(2) ground coat enamel glaze slip is applied to form ground glaze layer in the billet surface of drying；
(3) ink-jet ink and finishing impression ink printed decoration pattern are used on the ground glaze layer；
(4) green body that step (3) obtains is placed preset time to form embossed layer so that decorative pattern permeates；
(5) overglaze glaze slip is applied to form cover coat in the billet surface；
(6) green body for obtaining step (5) is dried；
(7) green body for obtaining step (6) is burnt into, and obtains the Antique Imitation Tiles finished product with 3D embossment；
Wherein, the permeability-thickness of the embossed layer is 0.2-1mm；
The glossiness of the Antique Imitation Tiles is 6-8 degree, and stain resistance is 5 grades, coefficient of friction >=0.6.
2. as described in claim 1 with 3D embossment Antique Imitation Tiles preparation method, which is characterized in that the finishing impression ink by
The raw material of following parts by weight is made: 25-50 parts and penetration-assisting agent 5-20 parts of tackifier；Wherein, the tackifier select glycerol, carboxylic first
One of base cellulose, starch or composition, the penetration-assisting agent select one of sodium carbonate, sodium hydroxide, potassium hydroxide
Or combination.
3. as described in claim 1 with 3D embossment Antique Imitation Tiles preparation method, which is characterized in that the overglaze glaze slip by
The raw material of following parts by weight is prepared: 35-48 parts of albite, 6-10 parts of kaolin, burning kaolin 3-7 parts, calcining zinc oxide
1-3 parts, 3-6 parts of talcum, 7-15 parts of strontium carbonate, 10-15 parts of zirconium oxide, 10-25 parts of additive；
Wherein, the chemical component of additive: SiO245-49%, Al2O315-17%, Fe2O30.2-0.7%, TiO2 0.2-
0.5%, CaO 12.9-16.8%, MgO 1-3%, K2O 1.5-3.5%, Na2O 0.5-0.8%, ZnO 12.7-15.9%,
Surplus is impurity.
4. the preparation method of the Antique Imitation Tiles with 3D embossment as claimed in claim 3, which is characterized in that the overglaze glaze slip
Chemical component are as follows: SiO245.6-52.7%, Al2O312-17%, Fe2O30.1-0.2%, TiO20.2-0.5%, CaO 5-
7.5%, MgO 0.3-0.7%, K2O 2.7-5.8%, Na2O 3.6-5.3%, ZnO 3-5%, SrO7-9%, ZrO2 3-
5%, surplus is impurity；
The fineness of the overglaze glaze slip is that 325 meshes tail over 0.4-0.7%, specific gravity 1.88-1.93g/mL, flow velocity 30-38
Second.
5. as described in claim 1 with 3D embossment Antique Imitation Tiles preparation method, which is characterized in that the ground coat enamel glaze slip by
The raw material of following parts by weight is prepared: 37-55 parts of potassium feldspar, 6-12 parts of kaolin, burning kaolin 5-7 parts, barium carbonate 8-13
Part, it is 4-8 parts quartzy, 1-3 parts of calcining zinc oxide, 3-6 parts of calcination of talc, 5-10 parts of additive.
6. the preparation method of the Antique Imitation Tiles with 3D embossment as described in claim 2 or 5, which is characterized in that the ground coat enamel glaze
The chemical component of slurry are as follows: SiO257-59%, Al2O310-17%, Fe2O30.2-0.7%, TiO20.3-0.5%, CaO1-
6%, MgO 8-11%, K2O 5-8%, Na2O 1.5-3.0%, ZnO 1.5-2.5%, BaO 8-11%, surplus are impurity；
The fineness of the ground coat enamel glaze slip is that 325 meshes tail over 0.5-0.9%, specific gravity 1.85-1.92g/mL, flow velocity 30-38 seconds.
7. the preparation method of the Antique Imitation Tiles with 3D embossment as described in claim 1,2 or 5, which is characterized in that step (2)
In, the glaze volume of the ground coat enamel glaze slip is 350-400g/m2；In step (5), the glaze volume of overglaze glaze slip is 180-200g/m2。
8. the preparation method of the Antique Imitation Tiles with 3D embossment as described in claim 1, which is characterized in that in step (7), firing
Temperature is 1155-1200 DEG C, and firing period is 55-65 minutes.
9. the preparation method of the Antique Imitation Tiles with 3D embossment as described in claim 1, which is characterized in that the Antique Imitation Tiles are wear-resisting
Property be 5 grades, surface Mohs' hardness >=6；Water absorption rate≤0.1%, the modulus of rupture >=45MPa.
10. a kind of Antique Imitation Tiles with 3D embossment, which is characterized in that it is used such as the described in any item preparations of claim 1-9
Method is made.
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Application publication date: 20190201 |