CN108585955A - A kind of manufacturing method of the Ceramic Tiles moulded pottery not yet put in a kiln to bake with Z-Correct bump mapping Z-correct - Google Patents
A kind of manufacturing method of the Ceramic Tiles moulded pottery not yet put in a kiln to bake with Z-Correct bump mapping Z-correct Download PDFInfo
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- CN108585955A CN108585955A CN201810586783.4A CN201810586783A CN108585955A CN 108585955 A CN108585955 A CN 108585955A CN 201810586783 A CN201810586783 A CN 201810586783A CN 108585955 A CN108585955 A CN 108585955A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/457—Non-superficial impregnation or infiltration of the substrate
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
Abstract
A kind of manufacturing method of the Ceramic Tiles moulded pottery not yet put in a kiln to bake with Z-Correct bump mapping Z-correct comprising following steps：A, surface often is made with raw material using Ceramic Tiles has the moulded pottery not yet put in a kiln to bake of Z-Correct bump mapping Z-correct；B, the organic infiltration color glaze ink of charity；C, the organic penetration-assisting agent ink of charity；D, 10 60 minutes dry at a temperature of 50 200 DEG C.By the present invention in that the Ceramic Tiles prepared with above-mentioned Ceramic Tiles moulded pottery not yet put in a kiln to bake, the permeable formation of formation penetrates into precoat, so that decorative pattern is wear-resistant, solve the problems, such as to print the printed decor to be formed intolerant to abrasion by conventional colorant ink jet in existing full throwing glaze technology；Simultaneously as suppressing the adobe surface come carries Z-Correct bump mapping Z-correct, keep its combined decoration better, more three-dimensional.
Description
Technical field
The present invention relates to architectural pottery product manufacturing technology field more particularly to a kind of Ceramic Tiles mud with Z-Correct bump mapping Z-correct
The manufacturing method of base.
Background technology
Ceramic ink jet printing technology is to be widely used in a kind of technology of ceramic tile production in recent years, will be black by nozzle
Water is printed upon the decorative means such as adobe face instead conventional screen stamp, roller printing, can since it is a kind of non-contact printing
" printing " male and fomale(M＆F) product, does not need plate-making in kind, turns version simply rapidly, it can be achieved that personalized produce, and production is reproducible, because
And use scope is more and more wider.But its disadvantage is that the decorative layer printed is excessively shallow, meanwhile, ink fire after wearability compared with
Difference can make decorative effect have a greatly reduced quality with the extension of usage time, thus have and applied in the decorative layer after inkjet printing
Bright glaze or cloth clear frit, to protect the technique of decorative layer decorative pattern.However, being clear frit or clear frit, in order to make ink-jet
Better decorative effect is presented in decorative layer, must just enhance the transparency, but while transparency raising, wearability can also decline
(contain the cosolvents such as lead and zinc in order to increase transparency, in glaze also makes glaze become more while increasing glaze transparency
It is soft, not wear-resisting), thus still cannot fundamentally solve the problems, such as to keep long-term decorative effect.
Application number CN201210331440.6 discloses one kind and oozing colored Imitation Rock Porcelain Tiles and its production method, is oozed water-soluble
Flower ink is printed upon leaching on the starch adhesive on adobe surface by way of inkjet printing, although after infiltration, can generate certain
The decorative pattern of depth, but because starch adhesive moisture content is higher, cause the infiltration difficulty of aqueous infiltration color glaze ink to increase, and due to brick
Base moisture evaporation also be easy to cause faulty nozzle to nozzle.In addition, being easily formed using the glaze slip that bell jar is drenched in adobe surface
The defect of edge protrusion, the color difference control being unfavorable for after polishing.In addition, worldwide aqueous infiltrating glaze ink is until current
Until and it is immature, be also applicable to far away on practical ink jet printer and produce.
Thus when firing due to inconsistent with bottom base shrinking percentage and then will produce deformation, raw green strength reduces, easy
Split brick.
Application number CN201110187245.6 discloses a kind of aqueous infiltrating glaze suitable for inkjet printing and its for making pottery
The method of ceramic tile production, is directly to be printed upon aqueous infiltrating glaze in adobe by inkjet printing, then spray water to help and ooze.But actually
Aqueous infiltrating glaze ink is up to the present and immature, is also applicable to far away on practical ink jet printer and produces.
Invention content
It is not wear-resisting it is an object of the invention to solve to print the printed decor to be formed by typical inkjet in the prior art
Damage, the problems such as three-dimensional sense is poor, propose a kind of manufacturing method of the Ceramic Tiles moulded pottery not yet put in a kiln to bake with Z-Correct bump mapping Z-correct.
For this purpose, the present invention uses following technical scheme：
A kind of manufacturing method of the Ceramic Tiles moulded pottery not yet put in a kiln to bake with Z-Correct bump mapping Z-correct comprising following steps：
A, surface often is made with raw material using Ceramic Tiles has the moulded pottery not yet put in a kiln to bake of Z-Correct bump mapping Z-correct；
B, the organic infiltration color glaze ink of charity；
C, the organic penetration-assisting agent ink of charity；
D, 10-60 minutes dry at a temperature of 50-200 DEG C.
In the prior art, klining can be directly entered after ink-jet printed at this is to be directed to aqueous infiltrating agent.But it is used in this programme
Be organic penetration glaze ink, if directly entering kiln high temperature firing, the organic component in ink can volatilize, and can influence color development in this way,
If organic component remain in it is more in green body, firing when be susceptible to stomata the defects of.In order to solve the above problem, at this
In scheme, the step of increasing by a step redrying, organic material can be made slowly to volatilize, be formed and steady seepage gradient and contained
The less precoat for thering is machine aided to ooze material.So processing can also save ink consumption simultaneously.
Preferably, in the above-mentioned methods, a placement moulded pottery not yet put in a kiln to bake is also wrapped between step C and step D to help to ooze to form permeable formation
The step of, it helps and oozes the time and be no less than 10 minutes.Ink needs are formed in green body after certain penetration depth subsequently to be dried again
Preferably, because the organic component in drying process in ink can volatilize, this can promote the chromophoe constituent in ink to spread to step, but
If the permeable formation for not forming certain depth is just dried, it is easy to occur because volatilize it is too fast caused by penetration depth is shallower asks
Topic.For this purpose, it is preferred that before being dried, first green body is placed 10 minutes or more and help oozing, forms the permeable formation of certain depth
It is dried again afterwards.
Preferably, the adobe in step be fabric and bottom material using precoat it is upper just beat secondary material distributing after
Compacting forms adobe and drying, and fabric layer thickness is 0.5-2.0mm.
Preferably, include the steps that decoration protective layer is formed on moulded pottery not yet put in a kiln to bake after step D in above method；It is described
Decoration protective layer is at least one of glaze, clear frit particle or translucent dry granular.
Had using the mode of bottom material and fabric progress cloth and just break cloth and instead break two kinds of cloth, distinguishing the mode of the two is
For precoat in top or lower part, anti-the texture formed by distributing technique in precoat can preferably be kept by breaking cloth, and just be beaten
Cloth is then easy to control adobe thickness and flatness.In view of this, the moulded pottery not yet put in a kiln to bake provided in the present invention also have using penetration glaze ink into
Luggage is adornd and penetration-assisting agent ink forms deeper infiltration decorative layer together, in this regard, it is preferred that by the way of just breaking cloth, because
It can preferably control the thickness of precoat and its flatness in adobe, moreover, precoat is upper, follow-up process of osmosis without
Green body need to be overturn.
It is further preferred that the thickness of the precoat is 0.8-1.2mm.
Preferably, in stepb organic infiltration color glaze ink main component be acylate and ester mixture,
Middle acylate be carboxyl acid group, sulfonate radical, sulfinate, at least one of thionothiolic acid root with the nothings such as iron, cobalt, chromium, copper
The salt that at least one of machine color development ion is constituted；The ester is long chain alkane, isooctyl acid methyl esters, in pungent methyl caprate extremely
Few one kind.The color development of infiltration color glaze ink relies primarily on inorganic color development ion therein, and different ions and different kinds of ions are not
Different colours are will produce with combination, such as individual cobalt will produce bright-coloured blue, the combination of iron, cobalt and chromium can generate black
Color can form abundant full-color effect by combination of the above.Such as use red, yellow, blue, black four chromatic inks.
It is further preferred that the acylate be the inorganic color development ion such as carboxyl acid group and iron, cobalt, chromium, copper in extremely
A kind of few salt of composition.Carboxylic acid has better osmotic effect, and it is easy compared to other organic acids in green body
Volatilization remains in green body and avoids generating the increased number of stomata because of its volatilization generation in follow-up firing less, improves product quality.
Preferably, the inkjet printing penetration glaze ink is to pass sequentially through different spray nozzles to print polychrome infiltration in stepb
Glaze ink；By the mixing of different colours ink, abundant decorative effect can be obtained, such as common is blue, red, yellow, black 4
Color is not limited above in practical applications certainly, can be arranged in pairs or groups according to demand to ink color.It can also be according to need
Want certain infiltration color glaze of duplicate printing multiple, to obtain saturation form and aspect.
Certainly, the inkjet printing in step B can also use the mode of screen printing or roller printing to substitute, but as ink
Water more properly uses the mode charity of inkjet printing.
Preferably, organic penetration-assisting agent ink main component described in step C is the mixture of organic acid and ester, described to have
Machine acid is at least one of carboxylic acid, sulfonic acid, sulfinic acid, thionothiolic acid；The ester is long chain alkane, isooctyl acid methyl esters, the pungent last of the ten Heavenly stems
At least one of sour methyl esters is organic liquid material.Organic type penetration-assisting agent ink good can permeate color glaze with organic type
Ink combines, and has the function of that it is promoted to permeate into green body, and penetration-assisting agent ink can be preferably saved by inkjet printing mode
The dosage of water, and the thickness of permeable formation can be controlled.It, can be by changing penetration-assisting agent ink and according to the needs of penetration depth
Water printing times come realize different depth permeate (penetration depth is adjustable within the scope of 0.2-1.5mm), naturally it is also possible to later
Increase the more simple methods such as spraying, roll printing, silk-screen printing to reach same effect.Preferably by multiple ink-jet
Method of printing.
Preferably, drying temperature is 60-120 DEG C in step D, and the time is 30-50 minutes.
Preferably, when cloth is just being beaten using bottom material and fabric or it is counter play cloth molding when, quality hundred is contained in fabric
Score helps at least one in red dose for 0.1-2% titanium dioxide, 0.1-0.5% zinc oxide, 0.1-5% zirconium silicates or 0.5-5%
Kind.It can promote color development by adding the above component, achieve the purpose that save ink.Help red dose as other several components,
All it is assistant toner, is conducive to ink color development, main component is nano silicon dioxide, and there are sale, example in glaze materials company
As there are such product in Mei Gao companies.
Preferably, in step F, in the following way in one or more combinations mode charity decorate protective layer：
Apply clear frit, the translucent dry granular of paving cloth or paving cloth clear frit.
The present invention also provides a kind of using Ceramic Tiles moulded pottery not yet put in a kiln to bake made from the above method, includes from bottom to top:Initial bed,
Precoat decorates protective layer.On the precoat have concave convex texture and include thickness be 0.3~0.6mm organic liquid materials
The permeable formation of formation.The moulded pottery not yet put in a kiln to bake of the above structure, after sintering because permeable formation has certain thickness, along with 0.2-0.5mm is thick
The decoration protective layer of degree, can successfully carry out rubbing down processing, and to be formed by decorative pattern also especially wear-resisting for permeable formation.
Concave convex texture on precoat is formed by using the punch-forming mold with concave convex texture.
The present invention also provides a kind of methods manufacturing Ceramic Tiles using above-mentioned Ceramic Tiles moulded pottery not yet put in a kiln to bake, and above-mentioned Ceramic Tiles moulded pottery not yet put in a kiln to bake is entered
Klining obtains having and is provided simultaneously with organic ink-jet penetration glaze decoration texture and translucent dry granular at, then polished edging processing
Or the Ceramic Tiles of concave convex texture combined decoration effect together that clear frit filling mold is formed.
Compared with prior art, the present invention is by penetration glaze ink printed on fabric after secondary material distributing, and uses ink-jet
Penetration-assisting agent is printed, because inkjet printing penetration-assisting agent is identical as infiltration color glaze ink property, occupation mode is identical, it is thus possible to ensure more
Good penetration depth so that the Wear Resistance after firing is good, and decorative pattern keeps lasting, and since decorative layer has certain thickness
Degree, can carry out the processing such as chamfering.
Simultaneously as the design of the change and inkjet printing pattern of cloth system can be passed through so that the cloth of precoat
Grain effect, mold grain effect, the decorative effect of penetration glaze and the decorative effect of dry granular or frit are combined, thus than existing
Have technology CN201210331440.6 printed on starch adhesive penetration glaze have decorative effect is more rich, be easier to operate to and effectively
Ground solves the defects of infiltration of starch adhesive moisture disaster and edge protrusion；Due in fabric be added titanium dioxide, zinc oxide, help it is red
The assistant toners such as agent, zirconium silicate, can obtain comprehensive color development and texture after high-temperature firing, and level transition sense is strong and stereoscopic depth
Sense is strong, can generate more rich color and deeper osmotic effect；It is polished using the module of well known different meshes and hardness
It also can get the tandem product of various luster degree afterwards.
By the present invention in that obtaining Ceramic Tiles prepared by Ceramic Tiles moulded pottery not yet put in a kiln to bake in aforementioned manners, the permeable formation of formation penetrates into fabric
In layer so that decorative pattern is wear-resistant, solves existing complete throw in glaze technology and prints by conventional colorant ink jet to be formed
The problem of printed decor is intolerant to abrasion；Simultaneously as suppressing the adobe surface come carries Z-Correct bump mapping Z-correct, in preferred embodiment,
The decorative effect for increasing one layer of translucent dry granular or clear frit after spending in mold groove is oozed to completion, so its synthesis dress
It adorns better, more three-dimensional.
Specific implementation mode
The technical solution further illustrated the present invention below by specific implementation mode.
Embodiment 1
The Ceramic Tiles manufactured the present embodiment provides a kind of Ceramic Tiles moulded pottery not yet put in a kiln to bake and using it.
A kind of manufacturing method of the Ceramic Tiles moulded pottery not yet put in a kiln to bake with Z-Correct bump mapping Z-correct comprising following steps：
A, ceramic adobe bottom material and fabric well known to selection form adobe through just breaking cloth, and fabric layer thickness is in green body
Adobe is dried in 1.2mm；Used mold has Z-Correct bump mapping Z-correct, makes after molding that the bed of material has asperities above adobe
Reason；
B, by the organic infiltration color glaze ink of adobe inkjet printing after drying；Adobe temperature is 45-55 DEG C when inkjet printing；
C, the organic penetration-assisting agent ink of inkjet printing；
D, place adobe 10 minutes or more, so that organic penetration-assisting agent ink is played one's part to the full, form certain depth helps infiltration layer
(generally 0.3mm or more)；
E, redrying obtains the Ceramic Tiles moulded pottery not yet put in a kiln to bake with permeable formation for 60 minutes at a temperature of 50 DEG C；
F, one layer of translucent dry granular of charity on precoat.
Here process above is illustrated, in step D the standing time of adobe can according to production need be adjusted,
But not lower than 10 minutes, otherwise it is difficult to ensure that the effect of infiltration；In step E carry out redrying be have with the prior art it is larger
Difference place, adobe ooze in the prior art can enter klining after flower decoration at but this mode is built upon water at once
Property bleeding agent on the basis of, for organic infiltration ink, organic component therein can be made to volatilize using redrying, in addition to can
To make osmotic effect more fully outer, organic component residual can also be reduced, is avoided acute in the rapid heating condition that kiln is burnt into
Strong volatilization forms increased number of stomata, is impacted to the decorative effect and antifouling property in brick face.Therefore, drying temperature is not generally
More than 200 DEG C, and the too low influence drying efficiency of temperature, therefore, it is 50-200 DEG C to be normally set up drying temperature, and drying time is
10-60 minutes.It balances and considers from drying effect and efficiency, it is 70-120 DEG C to be preferably set as drying temperature, drying time
It is 15-30 minutes.
The ink used in step B and step C is organic inks, has similar component, what wherein step B was used has
Machine permeate color glaze ink be acylate and ester mixture, wherein acylate be carboxyl acid group, sulfonate radical, sulfinate,
At least one of thionothiolic acid root and the salt constituted at least one of the inorganic color development ion such as iron, cobalt, chromium, copper；Ester is
At least one of long chain alkane, isooctyl acid methyl esters, pungent methyl caprate.And the organic penetration-assisting agent ink used in step C is to have
The mixture of machine acid and ester, organic acid are at least one of carboxylic acid, sulfonic acid, sulfinic acid, thionothiolic acid；The ester is long alkane
At least one of hydrocarbon, isooctyl acid methyl esters, pungent methyl caprate are organic liquid material.The two has similar component, mixed
Can also have the effect of when closing use similar.
Specifically, the organic infiltration chromatic ink used in step B is divided into blue, red, yellow black four color according to its hair color effect, so
It is 200PL blue, red, yellow, the black 4 color organic solvents of inkjet printing successively to use the resolution ratio 400dpi of printer, nozzle bore afterwards
Type permeates color glaze ink.The ink ejection amount of mono ink is in 0-50g/m2, to obtain the hair color effect of enough saturations,.It needs exist for
Illustrate, in practical applications, the color of ink can there are many selection, such as it is blue, red, yellow in the present embodiment can synthesize it is more
The infiltration color glaze ink of kind color, and then full-color effect is obtained, and black can adjust the gray scale of color, specific used ink
Type and dosage can carry out selection collocation according to practical print pattern effect.
Step C is to reuse ink-jet printer in adobe surface inkjet printing 1-3 all over penetration-assisting agent ink, and penetration-assisting agent ink is total
For ink ejection amount in 30 ± 10 grams/m2, penetration depth meets the soft requirement for throwing technology controlling and process in 0.3-0.6mm.
By dry granular machine in moulded pottery not yet put in a kiln to bake whole face one layer of translucent dry granular of uniform spreading, granularity is in 20-60 mesh ranges, to obtain thickness
Spend the having transparent decoration layer of 0.3mm or so.
The Ceramic Tiles moulded pottery not yet put in a kiln to bake that above method is obtained enters klining at then (the throwing amount of cutting is in 0.3- through high-strength flexible polishing
Within the scope of 0.5mm) and chamfer machining after, you can obtain have infiltration decorative layer Ceramic Tiles, the infiltration decorative layer on brick body surface
With certain thickness, and it is that there is particularly preferred abrasion resistant effect inside embedded adobe.
In this embodiment, used kiln is roller kilns, and firing problem is 1210~1250 DEG C, firing period 50-
90 minutes.In practical applications, calcining system is adjusted according to kiln conditions and body recipe system, this belongs to this field
Technician can judge according to knowhow or be obtained by limited trials, just no longer do and additionally repeat.
In addition, by test, when penetration-assisting agent ink is in 30 ± 10 grams/m2, penetration depth is in 0.3-0.6mm；It is oozed when helping
For agent ink in 50 ± 10 grams/m2, penetration depth is in 0.5-0.8mm；When penetration-assisting agent ink is in 80 ± 20 grams/m2, infiltration is deep
Degree is in 0.7-1.0mm.When in use, penetration depth that can be as needed carries out the dosage of setting penetration-assisting agent ink, such as
Ink ejection amount can be increased or by the way of repeating inkjet printing.It, can be with when penetration glaze ink and more penetration-assisting agent ink consumption
Deeper permeable formation is formed, the defect revealed the exact details caused by crossing throwing can be reduced.
Embodiment 2
A kind of manufacturing method of the Ceramic Tiles moulded pottery not yet put in a kiln to bake with Z-Correct bump mapping Z-correct comprising following steps：
A, ceramic adobe bottom material and fabric well known to selection, after just breaking cloth punch forming form adobe, fabric in green body
Layer thickness is 2mm, and adobe is dried；The mold that punch forming uses has Z-Correct bump mapping Z-correct, and adobe precoat has after molding
There is Z-Correct bump mapping Z-correct；
B, by the organic infiltration color glaze ink of adobe inkjet printing after drying；Adobe temperature is 45-55 DEG C when inkjet printing；
C, silk screen and roller combine the printing organic penetration-assisting agent ink of charity；The dosage of organic penetration-assisting agent ink is 80 ± 20 grams/m2；
D, adobe is placed 30 minutes, so that organic penetration-assisting agent ink is played one's part to the full, form certain depth helps infiltration layer；
E, the Ceramic Tiles moulded pottery not yet put in a kiln to bake that it is about 0.9mm with infiltration layer depth that redrying obtains for 20 minutes at a temperature of 120 DEG C；
F, one layer of translucent dry granular of charity on precoat.
Used ink is identical as 1 system of embodiment.
In step, contain assistant toner in used fabric, for titanium dioxide, zinc oxide, help red dose, zirconium silicate
At least one of.Additive amount is 0.1-2% titanium dioxide, 0.1-0.5% zinc oxide, the 0.1-5% of fabric quality percentage
Zirconium silicate or 0.5-5% help red dose.It is used herein above to help red dose to be shown for red component in a kind of promotions ink known in the industry
The additive of color, key component is nano silicon dioxide, such as just there is Related product in U.S. high company, reality in the present invention
Apply be previously mentioned in example help red dose, be purchased from Mei Gao companies.
Specifically, the titanium dioxide for being 1% and 3% zirconium silicate are used in this embodiment.
By using the above assistant toner, organic penetration glaze ink color development can be made more abundant, while saving valuable raw material,
Also more preferably decorative effect can be obtained.
It by adobe achieved above, in roller kilns, is burnt into through 1200-1250 DEG C, polished, edging processing is had
There is the ceramic brick product for oozing colored decorative effect.This product it is more conventional to ooze flower prod decorative layer solid wear-resisting, and resistance to soiling
More preferably.
Embodiment 3
A kind of manufacturing method of the Ceramic Tiles moulded pottery not yet put in a kiln to bake with Z-Correct bump mapping Z-correct comprising following steps：
A, ceramic adobe bottom material and fabric well known to selection form adobe, precoat in green body through just playing cloth punch forming
Thickness is 0.8mm, and adobe is dried；There is Z-Correct bump mapping Z-correct on used punch-forming mold, make adobe after molding
Precoat on also have Z-Correct bump mapping Z-correct；
B, by the organic infiltration color glaze ink of adobe inkjet printing after drying；Adobe temperature is 45-55 DEG C when inkjet printing；
C, silk screen and roller combine the printing organic penetration-assisting agent ink of charity；The dosage of organic penetration-assisting agent ink is 50 ± 10 grams/m2；
D, adobe is placed 15 minutes, so that organic penetration-assisting agent ink is played one's part to the full, form certain depth helps infiltration layer；
E, the Ceramic Tiles moulded pottery not yet put in a kiln to bake that it is about 0.8mm with infiltration layer depth that redrying obtains for 35 minutes at a temperature of 80 DEG C；Infiltration
Layer thickness and fabric layer thickness are essentially identical；
F, the charity layer of transparent frit on precoat.
Used ink is identical as 1 system of embodiment.
In step, contain assistant toner in used fabric, for titanium dioxide, zinc oxide, help red dose, zirconium silicate
At least one of.Additive amount is 0.1-2% titanium dioxide, 0.1-0.5% zinc oxide, the 0.1-5% of fabric quality percentage
Zirconium silicate or 0.5-5% help red dose.Use in this embodiment the titanium dioxide for being 1%, 0.3% zinc oxide, 2% zirconium silicate and
3% helps red dose.
By using the above assistant toner, organic penetration glaze ink color development can be made more abundant, while saving valuable raw material,
Also more preferably decorative effect can be obtained.
It by adobe achieved above, in roller kilns, is burnt into through 1200-1250 DEG C, polished, edging processing is had
There is the ceramic brick product for oozing colored decorative effect.This product it is more conventional to ooze flower prod decorative layer solid wear-resisting, and resistance to soiling
More preferably.
In the present embodiment, polishing uses well known block combiner after burning, obtains the matt effect that glossiness is 5-30 °.
The technical principle of the present invention is described above in association with specific embodiment.These descriptions are intended merely to explain the present invention's
Principle, and it cannot be construed to limiting the scope of the invention in any way.Based on the explanation herein, the technology of this field
Personnel would not require any inventive effort the other specific implementation modes that can associate the present invention, these modes are fallen within
Within protection scope of the present invention.
Claims (10)
1. a kind of manufacturing method of the Ceramic Tiles moulded pottery not yet put in a kiln to bake with Z-Correct bump mapping Z-correct, it is characterised in that：It includes the following steps：
A, surface often is made with raw material using Ceramic Tiles has the moulded pottery not yet put in a kiln to bake of Z-Correct bump mapping Z-correct；
B, the organic infiltration color glaze ink of charity；
C, the organic penetration-assisting agent ink of charity；
D, 10-60 minutes dry at a temperature of 50-200 DEG C.
2. the manufacturing method of Ceramic Tiles moulded pottery not yet put in a kiln to bake according to claim 1, which is characterized in that between step C and step D also
Include the steps that one to place moulded pottery not yet put in a kiln to bake and help and ooze to form permeable formation, helps and ooze the time and be no less than 10 minutes.
3. the manufacturing method of the Ceramic Tiles moulded pottery not yet put in a kiln to bake according to claim 1 with Z-Correct bump mapping Z-correct, it is characterised in that：The step
Further include the steps that decoration protective layer is formed on moulded pottery not yet put in a kiln to bake after rapid D；The decoration protective layer be glaze, clear frit particle or
At least one of translucent dry granular.
4. the manufacturing method of the Ceramic Tiles moulded pottery not yet put in a kiln to bake according to claim 1 with Z-Correct bump mapping Z-correct, it is characterised in that：In step
The mixture that color glaze ink is acylate and ester is permeated described in B, wherein acylate is carboxyl acid group, sulfonate radical, sub- sulphur
At least one of acid group, thionothiolic acid root and the salt constituted at least one of the inorganic color development ion such as iron, cobalt, chromium, copper；
The ester is at least one of long chain alkane, isooctyl acid methyl esters, pungent methyl caprate.
5. the manufacturing method of the Ceramic Tiles moulded pottery not yet put in a kiln to bake according to claim 4 with Z-Correct bump mapping Z-correct, it is characterised in that：It is described to have
Machine hydrochlorate is the salt that at least one of inorganic color development ion such as carboxyl acid group and iron, cobalt, chromium, copper is constituted.
6. the manufacturing method of the Ceramic Tiles moulded pottery not yet put in a kiln to bake according to claim 1 with Z-Correct bump mapping Z-correct, it is characterised in that：In step
Organic penetration-assisting agent ink main component described in C is the mixture of organic acid and ester, and the organic acid is carboxylic acid, sulfonic acid, Asia
At least one of sulfonic acid, thionothiolic acid；The ester is at least one of long chain alkane, isooctyl acid methyl esters, pungent methyl caprate.
7. the manufacturing method of the Ceramic Tiles moulded pottery not yet put in a kiln to bake according to claim 2 with Z-Correct bump mapping Z-correct, it is characterised in that：In step
Standing time is 15-30min in D.
8. the manufacturing method of the Ceramic Tiles moulded pottery not yet put in a kiln to bake according to claim 1 with Z-Correct bump mapping Z-correct, it is characterised in that：In step
Drying temperature is 60-120 DEG C in D, and the time is 30-50 minutes.
9. the manufacturing method of the Ceramic Tiles moulded pottery not yet put in a kiln to bake according to claim 1 with Z-Correct bump mapping Z-correct, it is characterised in that：Step A
Raw material be divided into bottom material and fabric, in fabric containing mass percent be 0.1-2% titanium dioxide, 0.1-0.5% zinc oxide,
0.1-5% zirconium silicates or 0.5-5% help at least one of red dose.
10. a kind of the side that the Ceramic Tiles moulded pottery not yet put in a kiln to bake with Z-Correct bump mapping Z-correct manufactures Ceramic Tiles being made using claim 1-9 the methods
Ceramic Tiles moulded pottery not yet put in a kiln to bake made from claim 1-9 the methods is entered klining at then polished edging processing, is had by method
It is provided simultaneously with the ceramics of organic ink-jet penetration glaze decoration texture and glass state material filling mold groove combined decoration effect together
Brick.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810586783.4A CN108585955A (en) | 2018-06-08 | 2018-06-08 | A kind of manufacturing method of the Ceramic Tiles moulded pottery not yet put in a kiln to bake with Z-Correct bump mapping Z-correct |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810586783.4A CN108585955A (en) | 2018-06-08 | 2018-06-08 | A kind of manufacturing method of the Ceramic Tiles moulded pottery not yet put in a kiln to bake with Z-Correct bump mapping Z-correct |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108585955A true CN108585955A (en) | 2018-09-28 |
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| CN201810586783.4A Pending CN108585955A (en) | 2018-06-08 | 2018-06-08 | A kind of manufacturing method of the Ceramic Tiles moulded pottery not yet put in a kiln to bake with Z-Correct bump mapping Z-correct |
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| CN (1) | CN108585955A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109293397A (en) * | 2018-10-09 | 2019-02-01 | 肇庆乐华陶瓷洁具有限公司 | A kind of Antique Imitation Tiles and preparation method thereof with 3D embossment |
-
2018
- 2018-06-08 CN CN201810586783.4A patent/CN108585955A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109293397A (en) * | 2018-10-09 | 2019-02-01 | 肇庆乐华陶瓷洁具有限公司 | A kind of Antique Imitation Tiles and preparation method thereof with 3D embossment |
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