CN104544802B - A kind of jewelry and its manufacture craft with protecting film - Google Patents

A kind of jewelry and its manufacture craft with protecting film Download PDF

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Publication number
CN104544802B
CN104544802B CN201410830851.9A CN201410830851A CN104544802B CN 104544802 B CN104544802 B CN 104544802B CN 201410830851 A CN201410830851 A CN 201410830851A CN 104544802 B CN104544802 B CN 104544802B
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metal
film
jewelry
area
metal area
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CN104544802A (en
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何桥华
陈圣芙
张昱
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Zhejiang Renfeng Technology Co ltd
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Individual
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Abstract

The invention provides a kind of jewelry with protecting film and its manufacture craft, it, which includes setting on jade body, the jade body on an at least metal area, the metal area, has at least one layer of metal film.Using such scheme, the present invention uses and an at least metal area is set on jewelry, there is at least one layer of metal film on metal area, there is provided new jewelry structure, suitable for production technology, the jewelry with metal film can be manufactured, and manufacture can be produced in batches, industrialization product is formed, with very high market application value.

Description

A kind of jewelry and its manufacture craft with protecting film
Technical field
The present invention relates to jewelry, more particularly to, a kind of jewelry with protecting film.
Background technology
General custom is by the natural material outside the metals such as gold and silver(Mineral, rock, biology etc.)It is made, with a price Jewellery, handicraft or other collections of value are referred to as jewelry, therefore have the saying of " gold, silver and jewelry ", manage the jewelry row of these articles Also referred to collectively as " jewelry row ".Scientifically say, the concept of " jewelry " and " jewel " of broad sense is identical.The jewel of broad sense refers to that Suitably pondered a bit or Carving Machining is jewellery or the raw material of handicraft.
Jewelry generally comprises natural jewels and jade and artificial gem, substantially can be collectively referred to as jade, wherein, natural jewelry is beautiful Stone includes natural gemstone, natural jade, natural organic gemstone etc., and artificial gem includes synthetic cut stone, reconstruction jewel, split treasured Stone, synthetic gem etc..For example, natural gemstone include diamond, it is ruby, sapphire, golden green opal, beryl, emerald, green The color calcedony of imperial or royal seal, opal, ice, jade of the He family etc.;Natural jade includes Huanglong's jade, agate, jasper, Lingbi jade, Khotan jade, Xiuyan The color calcedony of jade, Nanyang jade, ice, emerald, Lantian jade, malachite, turquoise, Dongling jade, white marble, Zhunger Basin are beautiful, noctilucence is beautiful, silicon Malachite, green lardite, lapis lazuli, golden yellow jade, ice flower jade, diamond stone etc..Natural color stone includes agalmatolite, orpiment, stone from Qingtian county in Zhejiang Province, used to make seals, chicken Heliotrope, five flower stones, changbaiite, end stone, wash one's face stone, preserved egg stone, Yuhuatai colorful pebble, Balin Stone, Helan jade, chrysanthemum stone, purple marble, huge solid rock, Swallow stone, inhale stone, red silk stone, rocks, prosperous fossil, serpentine, upper water stone, talcum, granite, marble etc..It is natural organic Jewel includes amber, pearl, coral, ivory, jet etc..
Jewelry processing mainly includes following items.
Cutting:Mainly according to jade(Or be jewel)Difference and form massive material is divided into specific chi Very little and shape, may use blanking machine;
Pre- shape:Woollen is repaired and is referred to as preliminary moulding, finishing machine may be used;
Grinding:Primarily to being ground out the moulding of jewel.Different with grinding tool according to grinding method, equipment for grinding can divide For Wheel grinder, disc mill, band grinding machine, tumbling mill etc.;
Polishing:For jewel to be polished.It can be polished in some cases by changing the grinding tool of equipment for grinding, abrasive material, But, also there is special polishing machine;
Drilling:Some jewellery, such as suspension member, pearl need punching, and this is accomplished by using puncher.
Certainly, according to circumstances different, the working process of jewel also has cleaning, bonded or even other processing procedures, only this Sample, the jewelry that could finally create fineness comes.
But, then studied seldom for jewelry overlay film.
Chinese patent 201280013894.7 discloses the forming method of noble metal diaphragm and noble metal diaphragm, its shape A kind of excellent adhesion between diaphragm, with noble metal matrix, need not pay special attention to processing in daily life Durability with just being continually worn on, it is firmly and fine and close, and it is possible to by the excellent corrosion resistance and the effect above Diaphragm that can be lasting for a long time is conveniently formed on the surface of noble metal matrix.Noble metal diaphragm involved by the invention Be as following manner formation quartz glass film, i.e. on the surface of noble metal matrix apply be coated with polysilazane as mainly into The glass film formation composition divided, in it there is the atmosphere of vapor, is coated with the glass film formation combination The noble metal matrix of thing is placed at a temperature of less than fusing point, is consequently formed the quartz glass film that thickness is 0.2 μm~1.0 μm.
But, the invention is not related to jewelry overlay film.
Chinese patent 200810065146.9 discloses jewellery surface protective film and preparation method thereof, jewelry surface therein Diaphragm, is prepared from the following raw materials in parts by weight:Aminopropyl triethoxysilane 0.5~3, Al2O31~5, SiO2 15~ 25th, isopropanol 20~30, water 35~42.The preparation method of jewellery surface protective film, comprises the following steps:(1) in SiO2Micro mist After 10-15 parts of (parts by weight) isopropanols of middle first addition stir, Al is added2O3Micro mist and aminopropyl triethoxysilane, It is eventually adding remaining isopropyl alcohol and water to be mixed evenly, becomes the coating fluid of jewellery surface protective film;(2) jewelry is cleaned Surface;(3) by the coating liquid of jewelry diaphragm in jewelry surface;(4) dry, i.e., one layer of hard guarantor is formed on jewelry Cuticula.Present invention protection film hardness is high, protecting effect is good, be difficult to be damaged, and its preparation method technique is simple, cost is low.
In addition, vacuum coating technology has developed into ripe, specifically, it is begun to show in the 1930s, 40 or five ten years Generation start commercial Application occur, industrialization large-scale production start from the 1980s, electronics, aerospace, packaging, decoration, Obtain and be widely applied in the industry such as gold stamping printing.Vacuum coating refers under vacuum conditions, by certain metal or metal compound Thing deposits to material surface in the form of gas phase(Typically nonmetallic materials), belong to physical gas-phase deposition.Because coating It is often metallic film, therefore also referred to as vacuum metallization processes.The vacuum coating of broad sense is additionally included in metal or non-metal material surface vacuum The nonmetallic functional films such as polymer are deposited.It is most commonly seen with plastics in all plated materials, it is paper plated film secondly. Relative to materials such as metal, ceramics, timber, there is plastics source abundance, performance to be easy to the advantage such as regulation and control, easy to process, therefore Miscellaneous plastics or other high polymer materials are widely used in automobile, household electrical appliances, daily as engineering decorative structural material The industrial circles such as packaging, Handicraft decorative.But plastic material has that case hardness is not high, outward appearance is not magnificent enough, wearability is low mostly Etc. defect, one layer of very thin metallic film such as is deposited in frosting, you can assign plastics Cheng Liang metal appearance, suitable gold Category source can also greatly increase Surface Wear Resistance of Materials energy, and the dicoration and application of plastics have been widened significantly.
The function of vacuum coating is many, and this also determines that its application scenario is enriched very much.On the whole, Vacuum Deposition The major function of film includes assigning plating piece apparent height metallic luster and mirror effect, makes film layer have on thin-film material There is provided excellent electromagnetic shielding and conductive effect for the barrier property of color.
But, the structure that metal film is set is lacked on jewelry.
The content of the invention
The technical problems to be solved by the invention are to provide a kind of new jewelry with metal film.
Technical scheme is as follows:A kind of jewelry with protecting film, it includes jade body, the jade body There is at least one layer of metal film on a upper setting at least metal area, the metal area.
It is preferred that, the metal film is gold film.
It is preferred that, the thickness of the gold film is 10-100 nanometers.
It is preferred that, the average thickness of the gold film is 15-20 nanometers.
It is preferred that, in the jade body, each metal area is only simultaneously set.
It is preferred that, at least partly described metal area constitutes a preset shape.
It is preferred that, coating is set on the jade body, it covers the jade body surface.
It is preferred that, the coating has paper structure.
It is preferred that, each metal area of coating correspondence sets some portions of leaving a blank, for exposing each gold respectively Belong to area.
It is preferred that, the coating electrostatic adheres to the jade body surface.
It is preferred that, some connection positions are set on the jade body.
It is preferred that, some pits are set on the metal area.
A kind of manufacture craft of the jewelry with protecting film, the manufacture method of described jewelry, it comprises the following steps:
The first step, antenatal data processing, compensates line width, on jewelry idiosome convex surface unit and working plate according to equipment situation The rectangular bars of test thickness are done, the test-strips of convex surface one time need to be connected with 0.22 millimeter to 0.33 millimeter of line and edges of boards Connect;Convex surface second test bar length will shorten half or so;
Second step, with 2 to 45 millimeters of one side copper thickness, with 56 to 266 millimeters of jewelry idiosome sawing sheets of another side copper thickness, base material Thickness is determined according to the requirement of client;
3rd step, bakes 7 to 15 hours, for eliminating jewelry embryo between the jewelry idiosome after sawing sheet is spent 100 to 150 The warpage when internal stress of body is to prevent finished product;
4th step, the jewelry idiosome after overbaking is drilled according to drawing, it is necessary to distinguish convex surface up still Convex surface is face-up, it is impossible to bore anti-;Then heavy copper is carried out, be every empty bay or by 48 degree of angle oblique cutting framves of plate, really during heavy copper Protect Kong Wutong generation;
5th step, as requested using low current for a long time, the jewelry idiosome whole plate copper facing after heavy copper;
Convex design is done on 6th step, the jewelry idiosome after overall copper facing, there is gold on convex surface when exposing jewelry idiosome finished product The part of category;
7th step, carries out normal treatment before plating, then for the first time directly the jewelry idiosome after the circuit of convex surface one time is carried out Tin plating 21-33 minutes;Then carry out moving back film, for the first time etching for the first time, move back tin for the first time;
8th step, the jewelry idiosome after first time moves back tin, makes convex surface processing, bossing is exposed;It is raised The part that part is higher by when being jewelry finished product;
9th step, second is carried out directly tin plating 22-45 minutes the jewelry idiosome after the secondary line of convex surface is carried out;So After moved back film, second etching for the second time, move back tin for the second time;This time etching is mostly important, it is to be ensured that the drop of bossing In allowed band, etching machine speed is first tried with debugging board, it is ensured that the temperature and concentration of etching solution are in normal range (NR), then Etching disposably or is repeatedly completed according to the performance of etching machine;
Tenth step, carry out it is smooth after jewelry idiosome carry out that third time is tin plating, film moved back for the third time, third time etching, the Move back tin three times;
11st step, will move back the jewelry idiosome after tin and carries out chemical nickel and gold processing, after this process, every paper or bay with Pre- anti-scratch jewelry idiosome face;
Jewelry idiosome after turmeric is handled, is carried out forming processes by the 12nd step;
13rd step, detects the jewelry idiosome after forming processes, has detected whether out hollow out phenomenon;
14th step, ultrasonic wave immerses cleaning, and the jewelry idiosome by detection, which is carried out ultrasonic wave, immerses cleaning:Using water Based cleaning agent, temperature is 77-99 DEG C;2)Pressure-air dropping liquid:Pressure is 0.2~0.5Mpa;Spray rinsing:Using rinsing liquid, Temperature is 76~95 DEG C, and pressure is 0.2~0.3Mpa, using stainless steel Fan Spray Nozzle;
15th step, hot blast air-dries knife blowing drying:Electrical heating, temperature is 90~100 DEG C, configures the finned sky of stainless steel Pneumoelectric heating tube and overtemperature sensor, using high-pressure vortex air pump, by the heated drying of pure air after filtering;
Jewelry idiosome after air-drying, is carried out electron microscopic detection by the 16th step, electron microscopic detection, detects product Meet product requirement into next link, if detection finds substandard product, next flow can not be entered;
Jewelry idiosome by detection is carried out vacuum coating by the 17th step, vacuum coating;
Using vacuum type coating machine, the vacuum of vacuum type coating machine is set to be selected for 5 × 10-1Pa~10 × 10-7Pa Diaphragm mixture is target, and two diaphragm mixtures are bombarded by the electron gun of vacuum type coating machine, vacuum type coating machine The electric current of electron gun is 2~28A;Vacuum coating is carried out to the jewelry idiosome in vacuum type coating machine, on the surface of jewelry idiosome Plate layer protecting film;In coating process, the protection film thickness of jewelry surface is deposited on using film thickness gauge measurement;In diaphragm Thickness reaches shuts down after setting value, controls to be deposited on jewellery surface protective film for 80-255nm;Diaphragm mixture.18th Jewelry idiosome of the inspection eventually after qualified, is packed shipment by step.
The composition of diaphragm mixture is:Proportioning is as follows:PC10-30 parts;6-10 parts of bifluoride magnesium;5-9 parts of makrolon; 7-10 parts of polyethylene terephthalate;8-8.5 parts of polytetrafluoroethylene (PTFE);2-2.5 parts of titanium dioxide;Double (3, the 5- tert-butyl group -4- Hydroxy phenyl) 5.5-5.8 parts of thioether;4.5~6 parts of polytrimethylene ether;1.8-3.6 parts of anti-impact agent;0.9-2.9 parts of organic solvent;It is compatible 1.5-1.8 parts of agent;1.6-1.8 parts of antistatic additive;1-2 parts of 3- ethyls -3- oxazolines;3- ethylhexyl diphenyl phosphates 0.5-1 Part;1-2 parts of polypropylene glycol;0.5-1 parts of polyglyceryl fatty acid ester;2-4 parts of diphenyl sulfone;1-2 parts of ultra-violet absorber;Peroxidating 1-3 parts of the 2 ethyl hexanoic acid tert-butyl ester;PA6 is 2-4 parts;1-1.2 parts of antioxidant;Nano oxidized samarium 5-15 parts, nano barium sulfate 1-5 Part, 1-5 parts of cellulose, 1-3 parts of nano bismuth oxide, 2-8 parts of polycarbonate resin, 2-6 parts of styrene resin, polyoxamide tree 2-5 parts of 3-9 parts of fat, 1-2 parts of anti-yellowing agent, 2-3 parts of initiator and adipic acid ester plasticizer.
Using such scheme, the present invention, which uses to set on jewelry, has at least one layer on an at least metal area, metal area There is provided new jewelry structure for metal film, it is adaptable in production technology, can manufacture the jewelry with metal film, and can be with Batch production manufacture, forms industrialization product, with very high market application value.
Brief description of the drawings
Fig. 1 is the schematic diagram of embodiments of the invention 1;
Fig. 2 is the schematic diagram of embodiments of the invention 2;
Fig. 3 is the schematic diagram of embodiments of the invention 3;
Fig. 4 is the schematic diagram of embodiments of the invention 4;
Fig. 5 is the schematic diagram of embodiments of the invention 5;
Fig. 6 is the schematic diagram of embodiments of the invention 6;
Fig. 7 is the schematic diagram of embodiments of the invention 7.
Embodiment
For the ease of understanding the present invention, below in conjunction with the accompanying drawings and specific embodiment, the present invention will be described in more detail. The preferred embodiment of the present invention is given in this specification and its accompanying drawing, still, the present invention can be in many different forms To realize, however it is not limited to the embodiment described by this specification.On the contrary, the purpose for providing these embodiments is made to the present invention Disclosure understanding more it is thorough comprehensively.
It should be noted that when a certain element is fixed on another element, including that the element is directly fixed on into this is another Individual element, or the element by least one other element placed in the middle is fixed on another element.When an element connects Another element is connect, including the element is directly connected to another element, or the element is placed in the middle by least one Other elements be connected to another element.
The present invention solves the technical problem of setting metal film on jewelry there is provided the jewelry with metal film, suitable for work Industryization is produced in batches, and this is that prior art is never provided.One embodiment of the present of invention is, a kind of pearl with protecting film Treasured, it, which includes setting on jade body, the jade body on an at least metal area, the metal area, has at least one layer of metal Film;For example, having one layer, two layers or metal multilayer film on the metal area;It is preferred that, the material of each layer metal film it is identical or It is different to set;For example, each layer is gold film;And for example, superficial layer is gold film;And for example, bottom is alloy film, for example copper alloy Or aluminium alloy, such as ormolu, so, the consumption of gold can be reduced to a certain extent;And for example, the metal area On layer of metal film is only set.As shown in figure 1, jewelry includes jade body 100, the jade body is heart, is set thereon One star-shaped metal area 200;And for example, as shown in Fig. 2 a kind of jewelry with protecting film, it includes the jade body of heart 100, metal area 200 two heart-shaped is set on the jade body;It is preferred that, as shown in Fig. 2 the shape of each metal area 200 Congruence is set;And for example, each metal area is symmetrical arranged.And for example, as shown in figure 3, a kind of jewelry with protecting film, it includes heart Jade body, two star-shaped metal areas are set on the jade body;And for example, as shown in figure 4, a kind of with protecting film Jewelry, it includes two heart-shaped metal areas, and a crescent moon is arranged side by side on the jade body of heart, the jade body The metal area of shape;And for example, as shown in figure 5, a kind of jewelry with protecting film, it includes the jade body of heart, the jade Be arranged side by side two star-shaped metal areas on body, and a crescent metal area;And for example, as shown in fig. 6, one kind has The jewelry of protecting film, it includes setting star-shaped metal area, the metal of crescent on the jade body of circle, the jade body Area and criss-cross metal area.Various embodiments of the present invention do not make specifically limited to the jade body, only need it to have jade Stone material matter and it can be used as jewelry, jade therein, which can be equal, be interpreted as jewel.
Wherein, there is at least one layer of metal film on the metal area.It is preferred that, vacuum is used at least described in one on metal area Plated film mode sets at least one layer of metal film;And for example, one layer of gold is set using vacuum coating mode on metal area at least described in one Belong to film;For example, the metal film at least partly covers the metal area where it;It is preferred that, the metal film portion or complete Cover the metal area where it.And for example, one or more layers metal film is set using vacuum coating mode on each metal area. For example, be coated with metal film on the metal area of jade body using magnetic control multi-arc ion plating film mode, including titanium nitride and titanium, Metal films such as nickel, chromium, copper, gold etc., the metal film is including alloy film etc., so as to increase product its aesthetic appearance, improves product specification, Suitable for batch production;And for example, same ornaments contain two kinds and above color coated surface treatment technology, are then passed through again by surface Cross after polishing, polishing, then by treatment before plating and plating, form electrodeposited coating so that jewelry more seems bright incomparable, beautiful dynamic People.
It is preferred that, the metal film is gold film.Gold film has popular characteristic, and quality compactness is high, wearability By force, it is difficult for drop-off.For example, the thickness of the gold film is 10-100 nanometers.And for example, it is preferred that the average thickness of the gold film Spend for 15-20 nanometers;For example, the thickness of the gold film is 18 nanometers.So, gold has on the one hand been saved, product is reduced Cost;Another aspect gold film is elegant in appearance, is greatly favored by consumers, and metal reflective and the use of refraction can be brought to imitate for product Really.
Further to save the consumption of gold, it is preferred that in the jade body, only simultaneously set each metal area; For example, only viewing and admiring face sets each metal area.For example, the jade body is flat pattern, it has two sides, its In, each metal area is set sideways only described in one.
It is preferred that, at least partly described metal area constitutes a preset shape;For example, preset shape is triangle, sector, bow Shape or its combination, so, can derive a variety of shapes or pattern in theory, using flexibly extensive;And for example, preset It is shaped as specific red-letter day pattern, including Santa Claus, teacher, lantern or Zongzi etc..For example, as shown in fig. 7, five triangles The metal area of shape constitutes a similar pentalpha, so as to form the metal film area of a similar pentalpha.
It is preferred that, coating is set on the jade body, it covers the jade body surface;Wherein, the covering Layer at least partly covers the jade body surface;For example, the coating all covers the jade body surface;And for example, The covering layer segment covers the jade body surface.It is preferred that, each metal area of coating correspondence sets some Leave a blank portion, for exposing each metal area respectively, such structure design is easy to the work flow in later stage;For example, described stay Empty portion is room behind room, or machine-cut etc..So, when carrying out vacuum coating, metal area covering metal film, coating Metal film is covered, coating is removed afterwards the jewelry with metal film can be achieved.To improve production efficiency, it is easy to remove covering Layer, it is preferred that the coating electrostatic adheres to the jade body surface, so, after vacuum coating operation is carried out, easily In removing the coating.It is preferred that, the coating has paper structure, so, after vacuum coating operation is carried out, easily In reclaiming unnecessary gold, with fabulous practical function.For example, the coating removed after vacuum coating operation is burnt, I.e. recyclable unnecessary gold, it is easy to use, it is adaptable to large-scale production.
It is preferred that, some connection positions are set on the jade body, and the connection position is fixedly connected with a movable part, the work Some metal subregions are set in dynamic portion, wherein, at least one layer of gold is set using vacuum coating mode on each metal subregion Belong to film.It is preferred that, some bonding pads are also set up on the movable part, each metal subregion at least described in one by connecting Area, is connected to other metal subregions.It is preferred that, the movable part is a jade split, an or jade stone.It is preferred that, it is described Jade stone has different material with the jade body.It is preferred that, each metal subregion is arranged in series, each metal point Area passes through metal subregion, the shape such as being designed to the Big Dipper described in bonding pad connection one described in one.And for example, the movable part On, in the position being connected with the connection position, thicken metal subregion around setting one, it is preferred that on the thickening metal subregion Metal film, its thickness be more than other metal subregions on metal film thickness;For example, both thickness ratios are 1.5 to 2:1; So, be conducive to strengthening the durability of the position of connection to a certain extent;And for example, the thickening metal subregion is annulus shape, Similar to the cloth ring of a relaxation;It is preferred that, the most narrow width of the thickening metal subregion is 2 millimeters.So, enhancing is conducive to connect Position physical strength, metal film is difficult for drop-off.It is preferred that, movable part is fixedly attached to pair by chain portion at least described in one In the connection position answered, so, the longer jewelry product of achievable entirety;And for example, movable part described in one is only set.
It is preferred that, some pits are set on the metal area, so, are conducive to strengthening the overall adhesiveness of metal film, tool There is higher use intensity.For example, each pit is uniformly distributed;And for example, the pit be hemispherical, it is preferred that its radius be 3 to 8 nanometers;One preferable example is that annular sets each pit, also, the pit is hemispherical, and its radius is 4 to 6 Nanometer.It is preferred that, three lug bosses are also set up beside each pit, three lug bosses are arranged as a triangle;It is preferred that, it is described Pit is arranged at the barycenter oftriangle or geometric center.It is preferred that, the triangle is equilateral triangle.It is preferred that, The lug boss is hemispherical;For example, the shape of the lug boss is identical with the pit with size.So, enhancing is conducive to The bulk strength of metal film, effectively increases the service life.
And for example, a kind of jewelry with protecting film, it includes setting some metals on jade body, the jade body At least one layer of metal film is set using vacuum coating mode on area, each metal area.It is preferred that, metal area at least described in two It is interconnected and sets.For example, setting five endless metal areas of Olympic Five Ring shape, each endless metal area is at least with other two Endless metal area, which is interconnected, to be set.It is preferred that, the metal area be shaped as triangle, arch, sector or its combination, this Sample, can form various patterns or shape.It is preferred that, at least with a circular metal area, so, there can be necessarily anti- Penetrate effect.It is preferred that, metal area has segment structure at least described in one, and an as spherosome is divided into two parts by a plane, cut Except part remaining after a part;So, set after at least one layer of metal film, the reflecting effect of optically focused can be obtained;This is All jewelry are not all disclosed known to applicant;Used with reference to the embodiment with LED chip, effect is even more to dazzle the eyes credit Eye, attracts the attention of millions of people.
It is preferred that, the marginal position of each metal area sets a limiting section;For example, limiting section is surrounding for a closure Structure, for example, the limiting section is annular or moulding shape etc..It is preferred that, the limiting section projection is set, such as described spacing 20 to 40 nanometers of portion's projection;Or, the limiting section is recessed to be set, such as described recessed 40 to 80 nanometers of limiting section.So, exist It is easily achieved in production, and the effect of vacuum coating can be ensured to a certain extent.It is preferred that, the limiting section combines each bag The related embodiment of the coating is included, is used in conjunction with, after vacuum coating operation is carried out, it is easy to remove the coating, It is very easy to use, and stereoeffect is good.
It is preferred that, each metal area has a preset height difference with the jade body, for example, preset height difference For 1 millimeter, or, preset height difference is 20 nanometers, 30 nanometers, 50 nanometers or 100 nanometers etc..So, each metal area There is difference in height with the jade body, after at least one layer of metal film is set, each metal area and the jade body Concordantly;Or, it is preferred that each metal area projection is set, such as each 20 to 40 nanometers of metal area projection;It is preferred that , the height that each metal area projection is set is equal with the thickness of the metal film thereon;Third dimension can so be made Extremely strong jewelry product.Or, each metal area is recessed to be set, such as each recessed 40 to 80 nanometers of metal area.It is excellent Choosing, the depth of each recessed setting of metal area is equal with the thickness of the metal film thereon.
It is preferred that, at least described in one on metal area, solar cell film, i.e. film solar cell, the jade sheet are set A mounting groove is also set up on body, the mounting groove sets a control system, minicell and some installations point groove, each described Install and a LED chip be set on point groove, solar cell film connects the minicell by the control system, for for its Charging, the minicell connects each LED chip by the control system respectively, for being powered for it.For example, the jade Body is flat pattern, and it has two sides, wherein, each metal area is set sideways described in one, and the same side is set Put the mounting groove.It is preferred that, the set-up of control system touch sensible switch, the confession for connecting or cutting off each LED chip Circuit.So, at daytime or enough brightness, solar cell film charges for minicell, in night or dark ring Under border, user is switched by touching the touch sensible so that each LED chip is luminous or flashes or closes, so that jewelry Integral luminous or flicker or closing, make it that jewelry is more brilliant dazzling on Consumer's Experience, stretch out one's hand market welcome.Need explanation , solar cell film, minicell, control system, touch sensible switch, each LED chip and its connection, are existing skill Art, such as LED chip are luminous or flash or close, and belong to the control technology of existing LED flashlight, the tool of these prior arts The body time limit is not belonging to scope of the present invention, and the inventive point of each related embodiment of the invention is to dodge these The technologies such as light, charging, touch control, applied to jewelry art, the especially jewelry with metal film, the luminous of LED is shined upon On jade body and/or metal film, occur refraction and reflection, under certain structure, occur repeatedly refraction and reflection so that pearl Treasured glittering blazes, and this is that existing jewelry is never accomplished.Another example, each described install of the mounting groove is divided Groove, is respectively communicated with metal area described in one, also, the light emission direction for installing the LED chip in point groove is against institute Metal area, i.e. LED illumination is stated to the metal area;It is preferred that, point groove of installing is set with the metal area noncontact.This Sample, realizes the micro lighting of jewelry so that jewelry also can be high-visible in dark surrounds;Also, it is effectively utilized metal Reflective, the refraction action of film so that LED light is fully utilized, with fabulous market value.
Further, embodiments of the invention also include, each technical characteristic of the various embodiments described above, are mutually combined what is formed Jewelry with metal film.
A kind of manufacture craft of the jewelry with protecting film, the manufacture method of described jewelry, it comprises the following steps:
The first step, antenatal data processing, compensates line width, on jewelry idiosome convex surface unit and working plate according to equipment situation The rectangular bars of test thickness are done, the test-strips of convex surface one time need to be connected with 0.22 millimeter to 0.33 millimeter of line and edges of boards Connect;Convex surface second test bar length will shorten half or so;
Second step, with 2 to 45 millimeters of one side copper thickness, with 56 to 266 millimeters of jewelry idiosome sawing sheets of another side copper thickness, base material Thickness is determined according to the requirement of client;
3rd step, bakes 7 to 15 hours, for eliminating jewelry embryo between the jewelry idiosome after sawing sheet is spent 100 to 150 The warpage when internal stress of body is to prevent finished product;
4th step, the jewelry idiosome after overbaking is drilled according to drawing, it is necessary to distinguish convex surface up still Convex surface is face-up, it is impossible to bore anti-;Then heavy copper is carried out, be every empty bay or by 48 degree of angle oblique cutting framves of plate, really during heavy copper Protect Kong Wutong generation;
5th step, as requested using low current for a long time, the jewelry idiosome whole plate copper facing after heavy copper;
Convex design is done on 6th step, the jewelry idiosome after overall copper facing, there is gold on convex surface when exposing jewelry idiosome finished product The part of category;
7th step, carries out normal treatment before plating, then for the first time directly the jewelry idiosome after the circuit of convex surface one time is carried out Tin plating 21-33 minutes;Then carry out moving back film, for the first time etching for the first time, move back tin for the first time;
8th step, the jewelry idiosome after first time moves back tin, makes convex surface processing, bossing is exposed;It is raised The part that part is higher by when being jewelry finished product;
9th step, second is carried out directly tin plating 22-45 minutes the jewelry idiosome after the secondary line of convex surface is carried out;So After moved back film, second etching for the second time, move back tin for the second time;This time etching is mostly important, it is to be ensured that the drop of bossing In allowed band, etching machine speed is first tried with debugging board, it is ensured that the temperature and concentration of etching solution are in normal range (NR), then Etching disposably or is repeatedly completed according to the performance of etching machine;
Tenth step, carry out it is smooth after jewelry idiosome carry out that third time is tin plating, film moved back for the third time, third time etching, the Move back tin three times;
11st step, will move back the jewelry idiosome after tin and carries out chemical nickel and gold processing, after this process, every paper or bay with Pre- anti-scratch jewelry idiosome face;
Jewelry idiosome after turmeric is handled, is carried out forming processes by the 12nd step;
13rd step, detects the jewelry idiosome after forming processes, has detected whether out hollow out phenomenon;
14th step, ultrasonic wave immerses cleaning, and the jewelry idiosome by detection, which is carried out ultrasonic wave, immerses cleaning:Using water Based cleaning agent, temperature is 77-99 DEG C;2)Pressure-air dropping liquid:Pressure is 0.2~0.5Mpa;Spray rinsing:Using rinsing liquid, Temperature is 76~95 DEG C, and pressure is 0.2~0.3Mpa, using stainless steel Fan Spray Nozzle;
15th step, hot blast air-dries knife blowing drying:Electrical heating, temperature is 90~100 DEG C, configures the finned sky of stainless steel Pneumoelectric heating tube and overtemperature sensor, using high-pressure vortex air pump, by the heated drying of pure air after filtering;
Jewelry idiosome after air-drying, is carried out electron microscopic detection by the 16th step, electron microscopic detection, detects product Meet product requirement into next link, if detection finds substandard product, next flow can not be entered;
Jewelry idiosome by detection is carried out vacuum coating by the 17th step, vacuum coating;
Using vacuum type coating machine, the vacuum of vacuum type coating machine is set to be selected for 5 × 10-1Pa~10 × 10-7Pa Diaphragm mixture is target, and two diaphragm mixtures are bombarded by the electron gun of vacuum type coating machine, vacuum type coating machine The electric current of electron gun is 2~28A;Vacuum coating is carried out to the jewelry idiosome in vacuum type coating machine, on the surface of jewelry idiosome Plate layer protecting film;In coating process, the protection film thickness of jewelry surface is deposited on using film thickness gauge measurement;In diaphragm Thickness reaches shuts down after setting value, controls to be deposited on jewellery surface protective film for 80-255nm;Diaphragm mixture is titanium dioxide Silicon and magnesium fluoride film mixture.Jewelry idiosome of the inspection eventually after qualified, is packed shipment by the 18th step.
The composition of diaphragm mixture is:Proportioning is as follows:PC10-30 parts;6-10 parts of bifluoride magnesium;5-9 parts of makrolon; 7-10 parts of polyethylene terephthalate;8-8.5 parts of polytetrafluoroethylene (PTFE);2-2.5 parts of titanium dioxide;Double (3, the 5- tert-butyl group -4- Hydroxy phenyl) 5.5-5.8 parts of thioether;4.5~6 parts of polytrimethylene ether;1.8-3.6 parts of anti-impact agent;0.9-2.9 parts of organic solvent;It is compatible 1.5-1.8 parts of agent;1.6-1.8 parts of antistatic additive;1-2 parts of 3- ethyls -3- oxazolines;3- ethylhexyl diphenyl phosphates 0.5-1 Part;1-2 parts of polypropylene glycol;0.5-1 parts of polyglyceryl fatty acid ester;2-4 parts of diphenyl sulfone;1-2 parts of ultra-violet absorber;Peroxidating 1-3 parts of the 2 ethyl hexanoic acid tert-butyl ester;PA6 is 2-4 parts;1-1.2 parts of antioxidant;Nano oxidized samarium 5-15 parts, nano barium sulfate 1-5 Part, 1-5 parts of cellulose, 1-3 parts of nano bismuth oxide, 2-8 parts of polycarbonate resin, 2-6 parts of styrene resin, polyoxamide tree 2-5 parts of 3-9 parts of fat, 1-2 parts of anti-yellowing agent, 2-3 parts of initiator and adipic acid ester plasticizer.
The optimization scheme of diaphragm mixture is:
Proportioning is as follows:PC15-25 parts;7-9 parts of bifluoride magnesium;6-7 parts of makrolon;Polyethylene terephthalate 8- 9 parts;8-8.5 parts of polytetrafluoroethylene (PTFE);2-2.5 parts of titanium dioxide;Double 5.5-5.8 parts of (3,5- tert-butyl-hydroxy phenyl) thioethers; 4.5~6 parts of polytrimethylene ether;1.8-3.6 parts of anti-impact agent;1.5-2.5 parts of organic solvent;1.5-1.8 parts of compatilizer;Antistatic additive 1.6- 1.8 part;1-2 parts of 3- ethyls -3- oxazolines;0.5-1 parts of 3- ethylhexyl diphenyl phosphates;1-2 parts of polypropylene glycol;Polyglycerol ester 0.5-1 parts of fat acid esters;2-4 parts of diphenyl sulfone;1-2 parts of ultra-violet absorber;1-3 parts of the peroxidating 2 ethyl hexanoic acid tert-butyl ester;PA6 For 2-4 parts;1-1.2 parts of antioxidant;Nano oxidized samarium 8-11 parts, 1-5 parts of nano barium sulfate, 2-4 parts of cellulose, nano bismuth oxide 1-3 parts, 2-8 parts of polycarbonate resin, 4-5 parts of styrene resin, 4-7 parts of polyoxamide resin, 1-2 parts of anti-yellowing agent is drawn Send out 3-4 parts of 2-3 parts of agent and adipic acid ester plasticizer.
Dissolving resulting mixture is formed at a temperature of said protection film mixture is blended in 100-320 degree.
Using such scheme, the present invention, which uses to set on jewelry, has at least one layer on an at least metal area, metal area There is provided new jewelry structure for metal film, it is adaptable in production technology, can manufacture the jewelry with metal film, and can be with Batch production manufacture, forms industrialization product, with very high market application value.
It should be noted that above-mentioned each technical characteristic continues to be mutually combined, the various embodiments not being enumerated above are formed, It is accordingly to be regarded as the scope of description of the invention record;Also, for those of ordinary skills, it can add according to the above description To improve or convert, and all these modifications and variations should all belong to the protection domain of appended claims of the present invention.

Claims (6)

1. an at least gold medal is set on a kind of jewelry with protecting film, it is characterised in that including jade body, the jade body Belonging on area, the metal area has at least one layer of metal film;Metal area has segment structure, the segment structure at least described in one It is divided into part remaining after two parts, an excision part by a plane for a spherosome;Set some on the jade body Connection position, the connection position, which is fixedly connected on a movable part, the movable part, sets some metal subregions, wherein, it is each described Layer of metal film is set using vacuum coating mode on metal subregion;Some bonding pads, Mei Yisuo are also set up on the movable part Metal subregion is stated by bonding pad at least described in one, other metal subregions are connected to;On the movable part, with the connection position The position being connected, around the metal film set on a thickening metal subregion, the thickening metal subregion, its thickness is more than other gold Belong to the thickness of the metal film on subregion;Thicken the thickness ratio of the metal film and the metal film on other metal subregions on metal subregion For 1.5 to 2:1;The thickening metal subregion is annulus shape, and the most narrow width of the thickening metal subregion is 2 millimeters;
Some pits are set on the metal area, and the pit is hemispherical, and its radius is 3 to 8 nanometers;By each pit While also setting up three lug bosses, three lug bosses are arranged as a triangle;The pit is arranged at the geometric center of the triangle;
The marginal position of each metal area sets a limiting section;The limiting section is a closure around structure, the limit Position portion is recessed to be set;
Each metal area has a preset height difference with the jade body, and each metal area is recessed to be set, each described The depth of the recessed setting of metal area is equal with the thickness of the metal film on the metal area;
At least described in one on metal area, set and also set up a mounting groove, the installation on solar cell film, the jade body Groove sets a control system, minicell and some installations point groove, and each described install sets a LED chip on point groove, too Positive energy battery membranes connect the minicell by the control system, and for being charged for it, the minicell passes through respectively The control system connects each LED chip, for being powered for it, the set-up of control system touch sensible switch, for connecting Or the power supply circuit of each LED chip of cut-out;Each described install of the mounting groove divides a groove, is respectively communicated with to metal area described in one Place, also, the light emission direction for installing the LED chip in point groove is against the metal area.
2. jewelry according to claim 1, it is characterised in that the metal film is gold film.
3. jewelry according to claim 2, it is characterised in that the thickness of the gold film is 10-100 nanometers.
4. jewelry according to claim 3, it is characterised in that the average thickness of the gold film is 15-20 nanometers.
5. jewelry according to claim 2, it is characterised in that in the jade body, only simultaneously sets each metal Area.
6. jewelry according to claim 3, it is characterised in that at least partly described metal area constitutes a preset shape.
CN201410830851.9A 2014-12-27 2014-12-27 A kind of jewelry and its manufacture craft with protecting film Active CN104544802B (en)

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