CN103877957A - 蒽醌法制备过氧化氢用再生剂及其制备方法 - Google Patents
蒽醌法制备过氧化氢用再生剂及其制备方法 Download PDFInfo
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- CN103877957A CN103877957A CN201410089107.8A CN201410089107A CN103877957A CN 103877957 A CN103877957 A CN 103877957A CN 201410089107 A CN201410089107 A CN 201410089107A CN 103877957 A CN103877957 A CN 103877957A
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- powder
- hydrogen peroxide
- alumina
- anthraquinone
- alumina powder
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- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 title claims abstract description 35
- 150000004056 anthraquinones Chemical class 0.000 title claims abstract description 31
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 title claims abstract description 30
- 238000000034 method Methods 0.000 title claims abstract description 18
- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- 230000008569 process Effects 0.000 title claims abstract description 10
- 239000000843 powder Substances 0.000 claims abstract description 111
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 52
- 241000219782 Sesbania Species 0.000 claims abstract description 27
- 239000002994 raw material Substances 0.000 claims abstract description 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 124
- 239000003795 chemical substances by application Substances 0.000 claims description 70
- 230000001172 regenerating effect Effects 0.000 claims description 70
- 239000000243 solution Substances 0.000 claims description 43
- 239000012224 working solution Substances 0.000 claims description 33
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 18
- 239000012467 final product Substances 0.000 claims description 18
- 235000011121 sodium hydroxide Nutrition 0.000 claims description 17
- WUOFAZKBVWWYER-UHFFFAOYSA-N anthracene-9,10-dione;hydrogen peroxide Chemical compound OO.C1=CC=C2C(=O)C3=CC=CC=C3C(=O)C2=C1 WUOFAZKBVWWYER-UHFFFAOYSA-N 0.000 claims description 16
- 230000002779 inactivation Effects 0.000 claims description 13
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 12
- 238000002386 leaching Methods 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 7
- 229960000583 acetic acid Drugs 0.000 claims description 6
- 239000012362 glacial acetic acid Substances 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 239000007787 solid Substances 0.000 claims description 3
- 238000001035 drying Methods 0.000 abstract description 10
- 238000002156 mixing Methods 0.000 abstract description 3
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 1
- 239000011148 porous material Substances 0.000 description 17
- 230000000694 effects Effects 0.000 description 11
- 238000004458 analytical method Methods 0.000 description 10
- 238000004519 manufacturing process Methods 0.000 description 9
- 230000008929 regeneration Effects 0.000 description 9
- 238000011069 regeneration method Methods 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 230000000704 physical effect Effects 0.000 description 7
- 239000007864 aqueous solution Substances 0.000 description 6
- 239000007857 degradation product Substances 0.000 description 6
- 230000035772 mutation Effects 0.000 description 5
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 4
- 230000007423 decrease Effects 0.000 description 4
- 239000000428 dust Substances 0.000 description 4
- 229910017604 nitric acid Inorganic materials 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 230000012010 growth Effects 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000003513 alkali Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 238000005984 hydrogenation reaction Methods 0.000 description 2
- 238000011031 large-scale manufacturing process Methods 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 229940126680 traditional chinese medicines Drugs 0.000 description 2
- 238000012795 verification Methods 0.000 description 2
- BJOAMCSNLUKBSK-UHFFFAOYSA-N 2h-dibenzo-p-dioxin-1-one Chemical compound O1C2=CC=CC=C2OC2=C1C(=O)CC=C2 BJOAMCSNLUKBSK-UHFFFAOYSA-N 0.000 description 1
- 238000006424 Flood reaction Methods 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- -1 alkyl hydrogen anthraquinone Chemical class 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 235000019994 cava Nutrition 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000005340 laminated glass Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000011017 operating method Methods 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000004704 ultra performance liquid chromatography Methods 0.000 description 1
Images
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
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- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105152137A (zh) * | 2015-09-28 | 2015-12-16 | 湘潭大学 | 一种蒽醌法制备双氧水工艺中的双氧水工作液再生剂及其制备方法 |
CN107298454A (zh) * | 2017-08-01 | 2017-10-27 | 广西壮族自治区化工研究院 | 一种利用废弃蒽醌再生剂制备活性氧化铝的方法 |
CN107572567A (zh) * | 2016-07-05 | 2018-01-12 | 江苏中科睿赛污染控制工程有限公司 | 一种工业废弃Al2O3小球微孔活化系统及其处理方法 |
CN108187663A (zh) * | 2017-12-04 | 2018-06-22 | 浙江巴陵恒逸己内酰胺有限责任公司 | 催化剂及其制备方法和在催化将蒽醌降解物再生为有效蒽醌中的用途 |
CN109806875A (zh) * | 2019-02-26 | 2019-05-28 | 浙江巴陵恒逸己内酰胺有限责任公司 | 催化蒽醌降解物再生的催化剂及其制备方法和循环工作液的再生方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5435985A (en) * | 1993-02-10 | 1995-07-25 | Kemira Oy | Hydrogenation catalyst for use in a hydrogen peroxide process, and method for the preparation thereof |
CN1810645A (zh) * | 2006-02-16 | 2006-08-02 | 福州大学 | 稀硝酸浸渍和煅烧法再生废活性氧化铝的方法 |
CN101259420A (zh) * | 2008-04-25 | 2008-09-10 | 江苏佳誉信实业有限公司 | 一种加氢催化剂及其制法和用途 |
CN101293662A (zh) * | 2007-04-28 | 2008-10-29 | 中国石油化工股份有限公司 | 一种γ-氧化铝的制备方法 |
-
2014
- 2014-03-12 CN CN201410089107.8A patent/CN103877957B/zh active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5435985A (en) * | 1993-02-10 | 1995-07-25 | Kemira Oy | Hydrogenation catalyst for use in a hydrogen peroxide process, and method for the preparation thereof |
CN1810645A (zh) * | 2006-02-16 | 2006-08-02 | 福州大学 | 稀硝酸浸渍和煅烧法再生废活性氧化铝的方法 |
CN101293662A (zh) * | 2007-04-28 | 2008-10-29 | 中国石油化工股份有限公司 | 一种γ-氧化铝的制备方法 |
CN101259420A (zh) * | 2008-04-25 | 2008-09-10 | 江苏佳誉信实业有限公司 | 一种加氢催化剂及其制法和用途 |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105152137A (zh) * | 2015-09-28 | 2015-12-16 | 湘潭大学 | 一种蒽醌法制备双氧水工艺中的双氧水工作液再生剂及其制备方法 |
CN105152137B (zh) * | 2015-09-28 | 2018-03-09 | 湘潭大学 | 一种蒽醌法制备双氧水工艺中的双氧水工作液再生剂及其制备方法 |
CN107572567A (zh) * | 2016-07-05 | 2018-01-12 | 江苏中科睿赛污染控制工程有限公司 | 一种工业废弃Al2O3小球微孔活化系统及其处理方法 |
CN107572567B (zh) * | 2016-07-05 | 2019-10-01 | 江苏中科睿赛污染控制工程有限公司 | 一种工业废弃Al2O3小球微孔活化系统及其处理方法 |
CN107298454A (zh) * | 2017-08-01 | 2017-10-27 | 广西壮族自治区化工研究院 | 一种利用废弃蒽醌再生剂制备活性氧化铝的方法 |
CN107298454B (zh) * | 2017-08-01 | 2019-02-22 | 广西壮族自治区化工研究院 | 一种利用废弃蒽醌再生剂制备活性氧化铝的方法 |
CN108187663A (zh) * | 2017-12-04 | 2018-06-22 | 浙江巴陵恒逸己内酰胺有限责任公司 | 催化剂及其制备方法和在催化将蒽醌降解物再生为有效蒽醌中的用途 |
CN109806875A (zh) * | 2019-02-26 | 2019-05-28 | 浙江巴陵恒逸己内酰胺有限责任公司 | 催化蒽醌降解物再生的催化剂及其制备方法和循环工作液的再生方法 |
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Address after: 530000 No. 7, beierli, Wangzhou Road, XiXiangTang District, Nanning City, Guangxi Zhuang Autonomous Region Patentee after: GUANGXI RESEARCH INSTITUTE OF CHEMICAL INDUSTRY Co.,Ltd. Address before: 530000 No. 7, beierli, Wangzhou Road, XiXiangTang District, Nanning City, Guangxi Zhuang Autonomous Region Patentee before: Guangxi Research Institute of Chemical Industry |
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Application publication date: 20140625 Assignee: GUANGXI NANNING LVJING FUNCTIONAL POLYMER MATERIALS Co.,Ltd. Assignor: GUANGXI RESEARCH INSTITUTE OF CHEMICAL INDUSTRY Co.,Ltd. Contract record no.: X2023980046311 Denomination of invention: Regenerant and preparation method for preparing hydrogen peroxide using anthraquinone method Granted publication date: 20160518 License type: Common License Record date: 20231108 |
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