CN103865700B - A kind of montanin wax fancy soap and preparation method thereof - Google Patents
A kind of montanin wax fancy soap and preparation method thereof Download PDFInfo
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- CN103865700B CN103865700B CN201410085798.4A CN201410085798A CN103865700B CN 103865700 B CN103865700 B CN 103865700B CN 201410085798 A CN201410085798 A CN 201410085798A CN 103865700 B CN103865700 B CN 103865700B
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Abstract
Open a kind of montanin wax fancy soap of the present invention and preparation method thereof, belongs to daily cleaning product and production technical field thereof.This montanin wax fancy soap is formulated by montanin wax, sodium hydroxide, complexed surfactant, antibacterial acaricide agent, skin toning agent, other auxiliary agents and deionized water science.The present invention uses the montanin wax of saponification to replace traditional soap base, have developed one and there is the Multifucntional fancy soaps such as U.S. face moisturizing, antibacterial anti-acne, submissive skin smoothing, it goes stain ability strong, resistance to hard water is strong, feel is splendid, easily biological-degradable, preparation technology simple, wide market, is suitable for industrialized production.
Description
Technical field
The present invention relates to a kind of montanin wax fancy soap and preparation method thereof, belong to daily cleaning product and production technology neck thereof
Territory.
Background technology
Fancy soap has become as the necessary article of people's daily life, along with improving constantly of people's living standard, product category
It is on the increase, and the direction progressively towards environmental protection, functionalization, specialization and seriation is developed.Modern product is for difference
Consumer demand has incorporated some additional functions, such as antibacterial, submissive, moisturizing, anti-acne, skin smoothing, U.S. on the basis of tradition fancy soap
White and lasting lastings etc., consumer obtains clean skin, the multiple experience such as comfortable, salubrious in use, meets the life joint of modern
Play.Therefore, this series products is constantly made earnest efforts by consumer, becomes family's fancy soap class and washes the first-selection protecting product.
The soap base of fancy soap is essentially identical with soap, and soap broadly refers to oils and fats, wax, Colophonium or fatty acid etc. and alkali
Class plays saponification or neutralizes the soap of reaction gained, during tradition soapmaking, uses the senior of the animality such as cattle, Adeps Caprae seu ovis more
Stearic acid or oils and fats, and the vegetal senior stearic acid such as Oleum Cocois, Petiolus Trachycarpi oil or oils and fats.Montanin wax, also known as lignite wax, be
Finger extinct plants and animal (mainly plant) remains are under microorganism and geophysics, chemical action, through a series of decomposition and conversion
The class macromole organic monoacid mixture formed.Montanin wax is mainly made up of higher fatty acids and fatty acid ester, includes in addition
A small amount of alcohol and hydrocarbons.It contains a number of C10 ~ C18, the particularly many index of oxide purification montanin wax and meets
Or close to the soapmaking requirement to oils and fats, additionally in thick montanin wax, resinous principle has some similarity in nature with Colophonium, can
Increase dissolubility and strengthen detergency.Owing to montanin wax and humic acids belong to Symbiont, the most also there is similarity,
As containing surfactant materials, there is the effects such as good emulsifying, moistening, solubilising, moisturizing, lubrication, softness, antistatic, because of
This, utilize montanin wax to prepare novel soap base and have feasibility.
At present montanin wax is made soap base and being further processed into and has stain, antibacterial, submissive, anti-acne, skin smoothing, whitening concurrently
Have not been reported with multi-functional fancy soaps such as lasting lastings, it is therefore necessary to invent this type of new product and develop market.
Summary of the invention
It is an object of the invention to provide a kind of montanin wax fancy soap, prepare this montanin wax fancy soap and include prepared by following raw material,
Each raw material and percentage by weight be: montanin wax 55-65%, sodium hydroxide 6 ~ 10%, complexed surfactant 10 ~ 20%, antibacterial
Acaricide agent 1 ~ 3%, skin toning agent 1 ~ 3%, other auxiliary agents 9 ~ 24%, described percentage by weight is all with the gross weight of each raw material as base
Standard, the percentage by weight sum of all raw materials is 100%.
Needed for being divided into preparation solution due to deionized water and needed for reaction directly, therefore above-mentioned raw materials does not comprise deionization
Water, in preparation process, the most required deionized water of reaction is each raw material gross weight 5 ~ 10%.
Described montanin wax be thick montanin wax, defat montanin wax, oxide purification montanin wax therein any one.
Described complexed surfactant is polyoxyethylenated alcohol sodium sulfate, dodecylbenzene sodium sulfonate, poly alkyl alcohol
Oxygen vinyl Ether, alkyl polyglucoside two or more therein mix gained in any proportion.
Described antibacterial acaricide agent be tea saponin, sodium fulvate one or both and plant therein press down demodicid mite element all by arbitrarily than
Example mixing gained.
Described skin toning agent be laminarin, Herba Dendrobii extract, Folium Menthae extract therein one or more in any proportion
Mixing gained.
Other auxiliary agents described are sodium silicate 2 ~ 5%, sodium carbonate 0.05 ~ 1%, Borax 1 ~ 3%, glycerol 2.6 ~ 8%, LBD-
1 dispersant 0.04 ~ 0.5%, citric acid 3 ~ 6%, natural essence 0.3 ~ 0.45%, fluorescent whitening agent 0.01 ~ 0.05% are described heavy
On the basis of amount percentage ratio all prepares the gross weight of this each raw material of montanin wax fancy soap beyond deionizing water.
Described thick montanin wax reference literature (Zhang Huifen etc. Yunnan lignite extracts the new technology [J] of lignite wax. spectrum experiment
Room, 2013,30(3): in 1272-1276.), method prepares, and described defat montanin wax is with reference to patent CN 201310047688.4
In " escape method of resin object in lignite wax ", method prepares, and described oxide purification montanin wax is with reference to patent CN 2008102335
In 81.8 " oxidization fine purification albefaction methods of lignite wax ", method prepares, and commercial each montanin wax kind is the most qualified
After, it is possible to use.
With reference to patent CN 200810233669.X, " oxidation and degradation of brown coal produces humic acids and salt thereof to described sodium fulvate
Method " in method prepare, after commercial refined sodium fulvate is the most qualified, it is possible to use.
Another object of the present invention is to provide the preparation method of described montanin wax fancy soap, specifically include following steps:
(1) be first divided into mass ratio to be 1:3:2 sodium hydroxide three parts, and to be configured to mass fraction respectively be 5 ~ 10%
The high alkali liquid III of alkali liquor II, 25 ~ 30% of sig water I, 15 ~ 20%, standby；
(2) add montanin wax with backward reactor and make its heating for dissolving, then add while stirring under the conditions of 85 ~ 95 DEG C
Sig water I reacts 3 ~ 5 minutes, adds alkali liquor II the most rapidly and reacts 5 ~ 10 minutes, be eventually adding high alkali liquid III react 60 ~
90 minutes, stir after being then sequentially added into sodium silicate, sodium carbonate, and with 1 ~ 3% citric acid (herein mass percent with
On the basis of preparing the gross weight of this each raw material of montanin wax fancy soap beyond deionizing water) regulation pH value, it is allowed to be 7 ~ 9, the most defeated
Deliver to drying equipment be dried, obtain montanin wax soda soap；
(3) by step (2) gained montanin wax soda soap add stirred tank, be sequentially added under 65 ~ 75 DEG C of controlled temperature conditions: go from
Sub-water, glycerol, Borax, complexed surfactant, LBD-1 dispersant, residue citric acid, antibacterial acaricide agent, skin toning agent, natural
Essence, fluorescent whitening agent, carry out being dried of follow-up routine, grindings, shaping, printing etc. are grasped after stirring and standing 5 ~ 10 minutes
Making, finally packaging gets final product the montanin wax fancy soap of finished product.
Beneficial effects of the present invention is as follows:
(1) properties of product of the present invention are gentle minimum to skin irritation, be suitable for having a bath, wash one's face and removing ornaments and formal dress when
Clean skin；
(2) product life-time service of the present invention has Continuous sterilization and presses down effect of demodicid mite, and degree of depth clean skin suppresses to a certain extent
The growth of pox；
(3) when product of the present invention uses, feel is submissive, can produce comfort after using, and after shower, energy hypnotic is stable；
(4) lipid that product of the present invention needs rich in skin, lubrication moistening effect is good, makes skin moisten gloss；The suitableeest
Use together in dry skin and winter, there is certain skin Caring effect；
(5) in product of the present invention, sodium fulvate has chelation, may replace the diamidogen tetrem of traditional difficult for biological degradation
Acid etc. are as chelating agen；
(6) product of the present invention is without additionally adding preservative, easily biological-degradable, and environment does not results in pollution, technique letter
Single, it is suitable for industrialized production.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is described in further detail, but scope is not limited to described interior
Hold.
Product physical and chemical index of the present invention detection performs People's Republic of China (PRC) light industry industry standard fancy soap QB/T
2485-2008。
It is antibacterial that product fungistatic effect of the present invention inspection performs People's Republic of China's light industry industry standard daily chemical products
The evaluation methodology QB/T 2738-2012(of fungistatic effect is antibacterial around-France), selected strain is: staphylococcus aureus, large intestine
Bacillus, Candida albicans, bacillus pyocyaneus, wherein in table 1.2, table 2.2, table 3.2, "-" represents that inhibition zone diameter is less than 7mm, examination
Test sample without bacteriostasis, specifically comprise the following steps that
(1) preparation of bacteria inhibition tablet: 0.5g fancy soap sample Sterile standard hard water is dissolved and be diluted to normal concentration (1:
100), take aseptic dry filter paper sheet, every dropping test sample solution 20 l, then filter paper is lain against aseptic plane ware
In, uncap to put in calorstat 37 DEG C and dry, standby；
(2) preparation of control sample: taking aseptic dry filter paper sheet, every drips sterile distilled water 20 l, the most standby；
(3) inoculation of test organisms: dipping concentration with sterile cotton swab is 5 × 104Cfu/ml test organisms suspension, at nutrition fine jade
Fat culture medium flat plate surface uniform application three times, often smears flat board and rotates 60 °, finally with cotton swab around flat board one week, covers
Good plate, puts drying at room temperature 5 minutes；
(4) bacteriostatic test print is placed with: test is placed with a microbiological contamination flat board every time, and each flat board is placed with four test samples
Sheet, a piece of comparison print, it is placed with in planar surface with aseptic nipper coupongs, at a distance of more than 25mm between each print center, with
Flat board periphery, at a distance of more than 15mm, is placed with afterwards with aseptic nipper light pressure-like sheet so that it is be close to planar surface, build plate, put
Observed result after 37 DEG C of calorstats are cultivated 16 hours, with diameter (including paster) the record of the antibacterial ring of vernier caliper measurement,
In triplicate, final result is averaged in test.
Product of the present invention is used for improving skin test, each experimenter totally 4 people, women 2 people, male 2 people, age
15-25 year, adhere to using product of the present invention every day, continue two months observe face and hand skin change.
Embodiment 1
This enforcement described montanin wax fancy soap, includes the component of following percentage by weight beyond deionizing water, and summation is
100%:
Thick montanin wax 55%；Sodium hydroxide (AR) 8%；
Complexed surfactant 10%: polyoxyethylenated alcohol sodium sulfate 5%, alkyl polyglucoside 5%；
Antibacterial acaricide agent 1%: tea saponin 0.5%, plant press down demodicid mite element 0.5%；
Skin toning agent 2%: laminarin 0.5%, Herba Dendrobii extract 0.5%, Folium Menthae extract 1%；
Other auxiliary agents 24%: sodium silicate 5%, sodium carbonate 1%, Borax 3%, glycerol 8%, LBD-1 dispersant 0.5%,
Citric acid 6%, jasmin essence 0.45%, fluorescent whitening agent 0.05%.
The most required deionized water of reaction is each raw material gross weight 8%.
Described in the present embodiment, the preparation method of montanin wax fancy soap, specifically comprises the following steps that
(1) be first divided into mass ratio to be 1:3:2 the sodium hydroxide of 800g three parts, and be configured to mass fraction respectively and be
The high alkali liquid III of the alkali liquor II, 25% of the sig water I, 15% of 5%, standby；The thick montanin wax of 5500g is added with backward reactor
Making its heating for dissolving, then under the conditions of 95 DEG C of temperature control stirrings, speed adds sig water I moderately and reacts 4 minutes, the most slightly
Add alkali liquor II rapidly and react 8 minutes, be eventually adding high alkali liquid III and react 60 minutes, being then sequentially added into the bubble of 500g
Stir after spending the sodium carbonate of alkali, 100g, and with 300g Fructus Citri Limoniae acid for adjusting pH value, be allowed to be 7.0；It is delivered to afterwards be dried set
Standby dry, obtain montanin wax soda soap.
(2) step (1) gained soda soap is added temperature control stirring still, be sequentially added under 65 DEG C of controlled temperature conditions: 800g goes
Ionized water, the glycerol of 800g, the Borax of 300g, the polyoxyethylenated alcohol sodium sulfate of 500g, the poly-glucose of alkyl of 500g
Glycosides, the LBD-1 dispersant of 50g, the citric acid of 300g, the tea saponin of 50g, the plant of 50g press down demodicid mite element, the laminarin of 50g,
The Herba Dendrobii extract of 50g, the Folium Menthae extract of 100g, the jasmin essence of 45g, the fluorescent whitening agent of 5g, stir and stand 8
Carry out being dried of follow-up routine, grindings, shaping, the operation such as printing after minute, finally pack and get final product finished product.
The performance of the montanin wax fancy soap reason that the present embodiment prepares and using effect are as shown in table 1.1 ~ 1.3:
Table 1.1 physical and chemical index testing result
Table 1.2 bacteriostatic test result
Table 1.3 skin effect
Embodiment 2
This enforcement described montanin wax fancy soap, includes the component of following percentage by weight beyond deionizing water, and summation is
100%:
Defat montanin wax 65%；Sodium hydroxide (AR) 10%；
Complexed surfactant 12%: dodecylbenzene sodium sulfonate 6%, fatty alcohol-polyoxyethylene ether 6%；
Antibacterial acaricide agent 3%: tea saponin 1%, sodium fulvate 1%, plant press down demodicid mite element 1%；
Skin toning agent 1%: laminarin 0.3%, Herba Dendrobii extract 0.2%, Folium Menthae extract 0.5%；
Other auxiliary agents 9%: sodium silicate 2%, sodium carbonate 0.05%, Borax 1%, glycerol 2.6%, LBD-1 dispersant
0.04%, citric acid 3%, flavoring banana essence 0.3%, fluorescent whitening agent 0.01%.
The most required deionized water of reaction is each raw material gross weight 10%.
Described in the present embodiment, the preparation method of montanin wax fancy soap, specifically comprises the following steps that
(1) be first divided into mass ratio to be 1:3:2 the sodium hydroxide of 1000g three parts, and it is configured to mass fraction respectively
It is the high alkali liquid III of the alkali liquor II, 28% of the sig water I, 18% of 8%, standby；The defat adding 6500g with backward reactor is covered
Denier wax makes its heating for dissolving, and then under the conditions of 90 DEG C of temperature control stirrings, speed adds sig water I moderately and reacts 5 minutes, connects
And add alkali liquor II the most rapidly and react 10 minutes, be eventually adding high alkali liquid III and react 75 minutes, being then sequentially added into
The sodium silicate of 200g, 5g sodium carbonate after stir, and with the Fructus Citri Limoniae acid for adjusting pH value of 100g, be allowed to be 9.0；Carry afterwards
It is dried to drying equipment, obtains montanin wax soda soap.
(2) step (1) gained soda soap is added temperature control stirring still, be sequentially added under 70 DEG C of controlled temperature conditions: 1000g goes
Ionized water, the glycerol of 260g, the Borax of 100g, the dodecylbenzene sodium sulfonate of 600g, the fatty alcohol-polyoxyethylene ether of 600g,
The LBD-1 dispersant of 4g, the citric acid of 200g, the tea saponin of 100g, the sodium fulvate of 100g, the plant of 100g press down demodicid mite element, 30g
Laminarin, the Herba Dendrobii extract of 20g, the Folium Menthae extract of 50g, the flavoring banana essence of 30g, the fluorescent whitening agent of 1g, stirring
Uniformly and carry out the operations such as being dried of follow-up routine, grindings, shaping, printing after standing 10 minutes, finally pack and get final product finished product.
The performance of the montanin wax fancy soap reason that the present embodiment prepares and using effect are as shown in table 2.1 ~ 2.3:
Table 2.1 physical and chemical index testing result
Table 2.2 bacteriostatic test result
Table 2.3 skin effect
Embodiment 3
This enforcement described montanin wax fancy soap, includes the component of following percentage by weight beyond deionizing water, and summation is
100%:
Oxide purification montanin wax 57%；Sodium hydroxide (AR) 6%；
Complexed surfactant 20%: polyoxyethylenated alcohol sodium sulfate 10%, fatty alcohol-polyoxyethylene ether 10%；
Antibacterial acaricide agent 2%: tea saponin 1%, sodium fulvate 0.5%, plant press down demodicid mite element 0.5%；
Skin toning agent 3%: laminarin 1%, Herba Dendrobii extract 1%, Folium Menthae extract 1%；
Other auxiliary agents 12%: sodium silicate 3.2%, sodium carbonate 0.1%, Borax 2.35%, glycerol 2.8%, LBD-1 disperse
Agent 0.07%, citric acid 3.1%, Fructus Citri Limoniae essence 0.35%, fluorescent whitening agent 0.03%.
The most required deionized water of reaction is each raw material gross weight 5%.
Described in the present embodiment, the preparation method of montanin wax fancy soap, specifically comprises the following steps that
(1) be first divided into mass ratio to be 1:3:2 the sodium hydroxide of 600g three parts, and be configured to mass fraction respectively and be
The high alkali liquid III of the alkali liquor II, 30% of the sig water I, 20% of 10%, standby；With backward reactor add 5700g slightly cover denier
Wax makes its heating for dissolving, and then under the conditions of 85 DEG C of temperature control stirrings, speed adds sig water I moderately and reacts 3 minutes, then
Add alkali liquor II the most rapidly and react 5 minutes, be eventually adding high alkali liquid III and react 90 minutes, being then sequentially added into 400g's
Sodium silicate, 30g sodium carbonate after stir, and with the Fructus Citri Limoniae acid for adjusting pH value of 200g, be allowed to be 8.0；It is delivered to afterwards do
Dry equipment is dried, and obtains montanin wax soda soap.
(2) step (1) gained soda soap is added temperature control stirring still, be sequentially added under 75 DEG C of controlled temperature conditions: 500g goes
Ionized water, the glycerol of 280g, the Borax of 235g, the polyoxyethylenated alcohol sodium sulfate of 1000g, the poly alkyl alcohol of 1000g
Oxygen vinyl Ether, the LBD-1 dispersant of 7g, the citric acid of 110g, the tea saponin of 100g, the sodium fulvate of 50g, the plant of 50g press down
Demodicid mite element, the laminarin of 100g, the Herba Dendrobii extract of 100g, the Folium Menthae extract of 100g, the Fructus Citri Limoniae essence of 35g, the fluorescence of 3g
Brightening agent, carries out being dried of follow-up routine, grindings, shaping, printing etc. operate after stirring and standing 5 minutes, finally pack
Get final product finished product.
The performance of the montanin wax fancy soap reason that the present embodiment prepares and using effect are as shown in table 3.1 ~ 3.3:
Table 3.1 physical and chemical index testing result
Table 3.2 bacteriostatic test result
Table 3.3 skin effect
Claims (1)
1. a montanin wax fancy soap, it is characterised in that: prepare this montanin wax fancy soap and include prepared by following raw material, each raw material and weight
Percentage ratio is: montanin wax 55-65%, sodium hydroxide 6 ~ 10%, complexed surfactant 10 ~ 20%, antibacterial acaricide agent 1 ~ 3%,
Skin toning agent 1 ~ 3%, other auxiliary agents 9 ~ 24%, described percentage by weight all on the basis of the gross weight of each raw material, all raw materials
Percentage by weight sum is 100%；
Described montanin wax is any one in thick montanin wax, defat montanin wax, oxide purification montanin wax；
Described complexed surfactant is polyoxyethylenated alcohol sodium sulfate, dodecylbenzene sodium sulfonate, fatty alcohol polyoxy second
Two or more in alkene ether, alkyl polyglucoside mix gained in any proportion；
Described antibacterial acaricide agent is that one or both and plant in tea saponin, sodium fulvate press down demodicid mite element and mix the most in any proportion
Gained；
Described skin toning agent be laminarin, Herba Dendrobii extract, Folium Menthae extract therein one or more mix in any proportion
Gained；
Other auxiliary agents described are that sodium silicate 2 ~ 5%, sodium carbonate 0.05 ~ 1%, Borax 1 ~ 3%, glycerol 2.6 ~ 8%, LBD-1 divide
Powder 0.04 ~ 0.5%, citric acid 3 ~ 6%, natural essence 0.3 ~ 0.45%, fluorescent whitening agent 0.01 ~ 0.05%；
The preparation method of described montanin wax fancy soap comprises the steps:
(1) be first divided into mass ratio to be 1:3:2 sodium hydroxide three parts, and be configured to respectively mass fraction be 5 ~ 10% dilute
The high alkali liquid III of the alkali liquor II, 25 ~ 30% of alkali liquor I, 15 ~ 20%, standby；
(2) add montanin wax with backward reactor and make its heating for dissolving, under the conditions of 85 ~ 95 DEG C, then add diluted alkaline while stirring
Liquid I reacts 3 ~ 5 minutes, adds alkali liquor II the most rapidly and reacts 5 ~ 10 minutes, is eventually adding high alkali liquid III and reacts 60 ~ 90 points
Clock, stirs after being then sequentially added into sodium silicate, sodium carbonate, and with the Fructus Citri Limoniae acid for adjusting pH value of 1 ~ 3%, is allowed to be 7 ~ 9, it
After be delivered to drying equipment and be dried, obtain montanin wax soda soap；
(3) step (2) gained soda soap is added stirred tank, be sequentially added under 65 ~ 75 DEG C of controlled temperature conditions: deionized water, the third three
Alcohol, Borax, complexed surfactant, LBD-1 dispersant, residue citric acid, antibacterial acaricide agent, skin toning agent, natural essence, fluorescence
Brightening agent, carry out after stirring and standing 5 ~ 10 minutes follow-up routine be dried, grinding, shaping, printing, finally pack
Get final product finished product.
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| CN201410085798.4A CN103865700B (en) | 2014-03-11 | 2014-03-11 | A kind of montanin wax fancy soap and preparation method thereof |
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| CN103865700B true CN103865700B (en) | 2016-12-07 |
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Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106497713B (en) * | 2016-09-14 | 2019-01-29 | 深圳海悦生物科技有限公司 | The anti-acne soap and preparation method thereof of adjustable sebum secretion |
| CN106833990A (en) * | 2016-12-25 | 2017-06-13 | 池州市建东生物科技有限公司 | A kind of antibacterial special soap of skin care |
| CN107822931B (en) * | 2017-10-24 | 2020-12-15 | 昆明理工大学 | Montan wax resin whitening mask and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1878940A (en) * | 1928-01-14 | 1932-09-20 | Ig Farbenindustrie Ag | Decomposition of waxes |
| CN1238386A (en) * | 1998-06-08 | 1999-12-15 | 陈文乾 | Formula and process for preparing sodium xanthonate by fermentation method |
| CN101020870A (en) * | 2007-03-09 | 2007-08-22 | 陈良超 | Natural cleaning powder and preparation method thereof |
| CN102274138A (en) * | 2010-06-11 | 2011-12-14 | 上海家化联合股份有限公司 | Dendrobe extract and preparation method and application thereof |
| CN103173304A (en) * | 2012-11-19 | 2013-06-26 | 上海制皂(集团)如皋有限公司 | Perfumed soap for showering and washing clothes and preparation method thereof |
-
2014
- 2014-03-11 CN CN201410085798.4A patent/CN103865700B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1878940A (en) * | 1928-01-14 | 1932-09-20 | Ig Farbenindustrie Ag | Decomposition of waxes |
| CN1238386A (en) * | 1998-06-08 | 1999-12-15 | 陈文乾 | Formula and process for preparing sodium xanthonate by fermentation method |
| CN101020870A (en) * | 2007-03-09 | 2007-08-22 | 陈良超 | Natural cleaning powder and preparation method thereof |
| CN102274138A (en) * | 2010-06-11 | 2011-12-14 | 上海家化联合股份有限公司 | Dendrobe extract and preparation method and application thereof |
| CN103173304A (en) * | 2012-11-19 | 2013-06-26 | 上海制皂(集团)如皋有限公司 | Perfumed soap for showering and washing clothes and preparation method thereof |
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