CN103173304A - Perfumed soap for showering and washing clothes and preparation method thereof - Google Patents
Perfumed soap for showering and washing clothes and preparation method thereof Download PDFInfo
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- CN103173304A CN103173304A CN2012104656792A CN201210465679A CN103173304A CN 103173304 A CN103173304 A CN 103173304A CN 2012104656792 A CN2012104656792 A CN 2012104656792A CN 201210465679 A CN201210465679 A CN 201210465679A CN 103173304 A CN103173304 A CN 103173304A
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Abstract
The invention discloses perfumed soap for showering and washing clothes with strong detersive power and safety and reliability, belonging to the field of daily chemical washing appliances. The perfumed soap comprises grease prescription and soap forming components. The grease prescription comprises the following ingredients in percentage by weight: 60 percent of palm oil, 20 percent of coconut oil, 10 percent of olive oil, and 10 percent of almond oil; and the soap forming components comprise the following ingredients in percentage by weight: 73 percent of sodium fatty acid, 6 percent of glycerol, 1 percent of fatty alcohol-polyoxyethylene ether (AEO9), 0.5 percent of mite removing bactericide (R-301), and the balance of others. The invention relates to a preparation method. The method comprises the following steps of: uniformly mixing coconut oil, palm oil, olive oil and almond oil, serving as raw materials, in a preparation tank after the raw materials are weighed; preparing fatty acid with color within 200# from the mixed oil through high-pressure hydrolysis and distillation; and preparing soap granules from the fatty acid through continuous neutralization and vacuum drying; and producing a finished product soap through soap forming equipment. The perfumed soap has the beneficial effects of strong detersive power, safety to human body, showering and clothes washing functions, disinfection and bacteriostasis, bleaching and the like, and is easy to biodegrade.
Description
Technical field
The present invention relates to a kind of detergents and cosmetic articles for washing, more particularly, the present invention relates to a kind of strong detergency, the safe and reliable shower dual-purpose perfumed soap of laundry and preparation method.
Background technology
Washing soap and perfumed soap are the requisite daily necessities of people, and its main component is sodium soap, are take grease as main raw material, and grease is mainly Tallow Inedible Grade, plam oil, Oleum Cocois (palm-kernel oil), lard etc.national standard (QB/T 2486) according to washing soap, washing soap is summarized as two kinds, I type and II type, the I type is done soda soap content more than or equal to 54%, the II type do soda soap content more than or equal to 43% less than 54%, in senior washing soap, fatty acid content can reach more than 68%, except sodium soap, in order to improve the performance of washing soap, improve the laundry soil removability, adjust the content of lipid acid in washing soap, reduce the cost of washing soap, make the fabric lasting, when preparing, washing soap also needs to add the components such as certain filler and essence, but washing soap is alkalescence, it can destroy the ph balancing of skin, use in the winter time and xerosis cutis easily occurs, itch, play the symptoms such as scurf, according to the national standard (QB/T 2485) of perfumed soap, perfumed soap also is summarized as two kinds, I type and II type, and the I type is done soda soap content more than or equal to 83%, the total working substance content of II type is more than or equal to 53%, in senior perfumed soap, fatty acid content can reach more than 78%, perfumed soap is the human body clean articles for use of commonly using, also can wash some not too dirty clothes, the requirement of its quality is higher than washing soap, always have following some fundamental property: it is low that (1) contains free alkali, not skin irritation.(2) appearance profile is clearly demarcated, does not shrink after storage, does not ftracture.(3) dissolving power appropriateness in water, insoluble disintegration in warm water.(4) can produce fine and closely woven and stable foam.(5) clearing power is suitable, uses rear skin feel good, stays delicate fragrance etc. after washing.
Summary of the invention
The objective of the invention is to overcome the deficiencies in the prior art, a kind of strong detergency, the dual-purpose perfumed soap of safe and reliable shower laundry are provided.
The objective of the invention is to be achieved through the following technical solutions:
The dual-purpose perfumed soap of a kind of shower laundry comprises the grease formula and becomes the soap component that the grease formula is plam oil 60%; Oleum Cocois 20%; Sweet oil 10%; Prunus amygdalus oil 10%, becoming the soap component is sodium soap 73%; Glycerine 6 %; Fatty alcohol-polyoxyethylene ether (AEO9) 1%; Except acarus and bacteria agent (R-301) 0.5%; Other is surplus.
Purpose of the present invention can also be achieved through the following technical solutions:
A kind of preparation method of the dual-purpose perfumed soap of laundry of taking a shower, described method comprises the following steps:
The first step is determined formula take Oleum Cocois, plam oil, sweet oil, Prunus amygdalus oil as glyceride stock, calculate the consumption of the every kind of grease of throwing according to formula and turnout, mixes in material-compound tank by measuring afterwards;
Second step, mixing oil obtains the lipid acid of color and luster in 200# by highly pressured hydrolysis, distillation;
1) hydrolysis of grease: generate glycerine and lipid acid after fat hydrolysis, to be that grease is reverse in hydrolysis tower be hydrolyzed fat hydrolysis technique continuously; Grease enters at the bottom of tower, water enters from tower top, make water-dispersion become fine droplets by sparger, 6.0MPa high pressure steam three passes into hydrolysis tower from upper, middle and lower respectively, keep the temperature of reaction of interior 250 ℃ of tower, oil and water countercurrent flow and step reaction in tower, glycerol liquor is drawn at the bottom of tower, and the lipid acid that generates after fat hydrolysis is drawn from tower top;
2) fatty acid distillation: the hydrolysis gained croude fatty acids in moisture content less than 0.1%, free fatty acids 97%～98%, grease 2%～3%, because of shade deviation, must through the distillation, make it the decolouring, deodorization, obtain refined fat acid, for the manufacture of high-quality soap; Fatty acid distillation adopts high vacuum continuous still battery mode to carry out, croude fatty acids enters degassing tower after preheating slough moisture and air in lipid acid, lipid acid after degassed enters the distillation tower top again, lipid acid distributes along column plate under the high temperature high vacuum condition, and being heated is evaporated to steam, and after vaporization, raffinate flows into lower floor's column plate by downtake, again the vaporization of being heated, so repeat, until lower floor's column plate finally makes lipid acid separate with residue and the volatile odoriferous substance of difficulty volatilization;
In the 3rd step, lipid acid prepares neat soap by continuous neutralization, vacuum-drying;
1) in lipid acid and the preparation soap base: neutralization reaction is carried out in reactor continuously, in tower, temperature is 85-95 ℃, lipid acid and concentration are that 32% ionic membrane caustic soda generates soap base through powerful mixing pump instantaneous reaction, reactant is at the still internal recycle, recycle ratio is controlled at 20: 1 left and right, borrow the pressure in tower, it is aging that the soap base after neutralization directly enters the soap base pot;
2) soap base vacuum-drying prepares neat soap: soap base and other interpolation component are transferring cylinder to be in harmonious proportion evenly, and temperature is controlled at 80～90 ℃; The soap base slip that mixes up is squeezed into vacuum drying chamber with the soap base pump, the soap base slip sprays cooling curing on the vacuum drying chamber barrel from nozzle, under the scraper shovel that is rotated, soap flakes under shovel fall into the twin-screw plodder below tapered bottom, be squeezed into continuous soap bar, be cut into neat soap by scraper again, neat soap is neutrality or slightly acidic;
In the 4th step, neat soap is produced the finished product soap with components such as removing acarus and bacteria agent, glycerine, fatty alcohol-polyoxyethylene ether AEO9 by soapmaking equipment.
The various raw materials of making soap are evenly mixed by formula, mix in the stirrer of helical-ribbon type, make it evenly mixed with stirring before and after material; Mix later raw material and carry out again the homogenizing processing, namely grind or extrusion machine with refiner and three-roller, with soap flakes mix with other components more even, the crystal formation of soap is changed, make it major part and change the β phase into, namely improve the application performance of perfumed soap: quality is hard, foam is abundant etc.; The press strip moulding is that the neat soap through homogenizing is pressed into the bar shaped of certain sectional area through vacuum plodder, plodder is with vacuum chamber, and soap flakes enter the bubble of taking out after vacuum chamber in soap bar, then extrusion molding, the sectional area of soap bar can be regulated, in order to control the weight of soap blank; Printing is that the soap blank after cutting is pressed into the shape of regulation in die, and extrudes decorative pattern or brand mark, prints to require trace clear, plentiful, and soap blank can not sticking to mould, adopts freezing die, and the temperature of die reduces, and effectively prevents mold sticking.
Compared with prior art, the present invention has following beneficial effect:
1. abundant, the good hand touch of strong detergency, foam;
2. to human-body safety, readily biodegradable is safe from harm to environment;
3. can easily underwear pants be cleaned dual-use material when taking a shower;
4. the function that has the deep layer cleanings such as sterilization is antibacterial, bleaching.
Description of drawings
Fig. 1 is the fatty acid distillation schema;
Fig. 2 is in lipid acid and preparation soap base schema;
Fig. 3 is that soap base vacuum-drying prepares the neat soap schema;
Fig. 4 is the neat soap soap schema that manufactures a finished product.
Embodiment
Below in conjunction with accompanying drawing, essentiality content of the present invention is described in further detail:
The dual-purpose perfumed soap of a kind of shower laundry comprises the grease formula and becomes the soap component.The grease formula is plam oil 60%; Oleum Cocois 20%; Sweet oil 10%; Prunus amygdalus oil 10%, vegetables oil have has again characteristics of cleaning ability to the skin gentleness, and becoming the soap component is sodium soap 73%; Glycerine 6 %; Fatty alcohol-polyoxyethylene ether (AEO9) 1%; Remove acarus and bacteria agent (R-301) 0.5%: other is surplus.Become in the soap component to add except acarus and bacteria agent (R-301), have broad-spectrum antibacterial and drive the mite effect; Tensio-active agent (being fatty alcohol-polyoxyethylene ether AEO9) has good dispersion of calcium soap and performance is gentle; Glycerine etc. have good wetting ability and moisturizing power.Natural plant grease is as raw material sources, and cost is relatively higher, but the protection of human body and environment is had good effect, and has better cleaning ability.Add the tensio-active agent (fatty alcohol-polyoxyethylene ether AEO9) of good dispersion of calcium soap and performance gentleness, overcome perfumed soap and only can wash the defective of less spot clothes, product has also added except components such as acarus and bacteria agent R-301, glycerine in addition, further the improving product performance.
A kind of preparation method of the dual-purpose perfumed soap of laundry of taking a shower comprises the following steps:
The first step is determined formula take Oleum Cocois, plam oil, sweet oil, Prunus amygdalus oil as glyceride stock, calculate the consumption of the every kind of grease of throwing according to formula and turnout, mixes in material-compound tank by measuring afterwards;
Second step, mixing oil obtains the lipid acid of color and luster in 200# by highly pressured hydrolysis, distillation;
1) hydrolysis of grease: generate glycerine and lipid acid after fat hydrolysis, to be that grease is reverse in hydrolysis tower be hydrolyzed fat hydrolysis technique continuously; Grease enters at the bottom of tower, water enters from tower top, make water-dispersion become fine droplets by sparger, 6.0MPa high pressure steam three passes into hydrolysis tower from upper, middle and lower respectively, keep the temperature of reaction of interior 250 ℃ of tower, oil and water countercurrent flow and step reaction in tower, glycerol liquor is drawn at the bottom of tower, and the lipid acid that generates after fat hydrolysis is drawn from tower top;
2) fatty acid distillation (referring to Fig. 1): the hydrolysis gained croude fatty acids in moisture content less than 0.1%, free fatty acids 97%～98%, grease 2%～3%, because of shade deviation, must through distillation, make it decolouring, deodorization, obtain refined fat acid, for the manufacture of high-quality soap; Fatty acid distillation adopts high vacuum continuous still battery mode to carry out, croude fatty acids enters degassing tower after preheating slough moisture and air in lipid acid, lipid acid after degassed enters the distillation tower top again, lipid acid distributes along column plate under the high temperature high vacuum condition, and being heated is evaporated to steam, and after vaporization, raffinate flows into lower floor's column plate by downtake, again the vaporization of being heated, so repeat, until lower floor's column plate finally makes lipid acid separate with residue and the volatile odoriferous substance of difficulty volatilization;
In the 3rd step, lipid acid prepares neat soap by continuous neutralization, vacuum-drying;
1) in lipid acid and the preparation soap base (referring to Fig. 2): neutralization reaction is carried out in reactor continuously, in tower, temperature is 85-95 ℃, lipid acid and concentration are that 32% ionic membrane caustic soda generates soap base through powerful mixing pump instantaneous reaction, reactant is at the still internal recycle, recycle ratio is controlled at 20: 1 left and right, borrow the pressure in tower, it is aging that the soap base after neutralization directly enters the soap base pot;
2) soap base vacuum-drying prepares neat soap (referring to Fig. 3): soap base and other interpolation component are transferring cylinder to be in harmonious proportion evenly, and temperature is controlled at 80～90 ℃; The soap base slip that mixes up is squeezed into vacuum drying chamber with the soap base pump, the soap base slip sprays cooling curing on the vacuum drying chamber barrel from nozzle, under the scraper shovel that is rotated, soap flakes under shovel fall into the twin-screw plodder below tapered bottom, be squeezed into continuous soap bar, be cut into neat soap by scraper again, neat soap is neutrality or slightly acidic;
In the 4th step, neat soap is produced finished product soap (referring to Fig. 4) with components such as removing acarus and bacteria agent, glycerine, fatty alcohol-polyoxyethylene ether (AEO9) by soapmaking equipment:
The various raw materials of making soap are evenly mixed by formula, mix in the stirrer of helical-ribbon type, make it evenly mixed with stirring before and after material; Mix later raw material and carry out again the homogenizing processing, namely grind or extrusion machine with refiner and three-roller, with soap flakes mix with other components more even, the crystal formation of soap is changed, make it major part and change the β phase into, namely improve the application performance of perfumed soap: quality is hard, foam is abundant etc.; The press strip moulding is that the neat soap through homogenizing is pressed into the bar shaped of certain sectional area through vacuum plodder, plodder is with vacuum chamber, and soap flakes enter the bubble of taking out after vacuum chamber in soap bar, then extrusion molding, the sectional area of soap bar can be regulated, in order to control the weight of soap blank; Printing is that the soap blank after cutting is pressed into the shape of regulation in die, and extrudes decorative pattern or brand mark, prints to require trace clear, plentiful, and soap blank can not sticking to mould, adopts freezing die, and the temperature of die reduces, and effectively prevents mold sticking.
Claims (2)
1. dual-purpose perfumed soap of laundry of taking a shower is characterized in that: described perfumed soap comprises the grease formula and becomes the soap component, and the grease formula is plam oil 60%; Oleum Cocois 20%; Sweet oil 10%; Prunus amygdalus oil 10%.Becoming the soap component is sodium soap 73%; Glycerine 6 %; Fatty alcohol-polyoxyethylene ether (AEO9) 1%; Remove acarus and bacteria agent (R-301) 0.5%: other is surplus.
2. the preparation method of a kind of dual-purpose perfumed soap of laundry of taking a shower according to claim 1, is characterized in that, described preparation method comprises the following steps:
The first step is determined formula take Oleum Cocois, plam oil, sweet oil, Prunus amygdalus oil as glyceride stock, calculate the consumption of the every kind of grease of throwing according to formula and turnout, mixes in material-compound tank by measuring afterwards;
Second step, mixing oil obtains the lipid acid of color and luster in 200# by highly pressured hydrolysis, distillation;
1) hydrolysis of grease: generate glycerine and lipid acid after fat hydrolysis, to be that grease is reverse in hydrolysis tower be hydrolyzed fat hydrolysis technique continuously; Grease enters at the bottom of tower, water enters from tower top, make water-dispersion become fine droplets by sparger, 6.0MPa high pressure steam three passes into hydrolysis tower from upper, middle and lower respectively, keep the temperature of reaction of interior 250 ℃ of tower, oil and water countercurrent flow and step reaction in tower, glycerol liquor is drawn at the bottom of tower, and the lipid acid that generates after fat hydrolysis is drawn from tower top;
2) fatty acid distillation: the hydrolysis gained croude fatty acids in moisture content less than 0.1%, free fatty acids 97%～98%, grease 2%～3%, because of shade deviation, must through the distillation, make it the decolouring, deodorization, obtain refined fat acid, for the manufacture of high-quality soap; Fatty acid distillation adopts high vacuum continuous still battery mode to carry out, croude fatty acids enters degassing tower after preheating slough moisture and air in lipid acid, lipid acid after degassed enters the distillation tower top again, lipid acid distributes along column plate under the high temperature high vacuum condition, and being heated is evaporated to steam, and after vaporization, raffinate flows into lower floor's column plate by downtake, again the vaporization of being heated, so repeat, until lower floor's column plate finally makes lipid acid separate with residue and the volatile odoriferous substance of difficulty volatilization;
In the 3rd step, lipid acid prepares neat soap by continuous neutralization, vacuum-drying;
1) in lipid acid and the preparation soap base: neutralization reaction is carried out in reactor continuously, in tower, temperature is 85-95 ℃, lipid acid and concentration are that 32% ionic membrane caustic soda generates soap base through powerful mixing pump instantaneous reaction, reactant is at the still internal recycle, recycle ratio is controlled at 20: 1 left and right, borrow the pressure in tower, it is aging that the soap base after neutralization directly enters the soap base pot;
2) soap base vacuum-drying prepares neat soap: soap base and other interpolation component are transferring cylinder to be in harmonious proportion evenly, and temperature is controlled at 80～90 ℃; The soap base slip that mixes up is squeezed into vacuum drying chamber with the soap base pump, the soap base slip sprays cooling curing on the vacuum drying chamber barrel from nozzle, under the scraper shovel that is rotated, soap flakes under shovel fall into the twin-screw plodder below tapered bottom, be squeezed into continuous soap bar, be cut into neat soap by scraper again, neat soap is neutrality or slightly acidic;
In the 4th step, neat soap is produced the finished product soap with components such as removing acarus and bacteria agent (R-301), glycerine, fatty alcohol-polyoxyethylene ether (AEO9) by soapmaking equipment:
The various raw materials of making soap are evenly mixed by formula, mix in the stirrer of helical-ribbon type, make it evenly mixed with stirring before and after material; Mix later raw material and carry out again the homogenizing processing, namely grind or extrusion machine with refiner and three-roller, with soap flakes mix with other components more even, the crystal formation of soap is changed, make it major part and change the β phase into, namely improve the application performance of perfumed soap: quality is hard, foam is abundant etc.; The press strip moulding is that the neat soap through homogenizing is pressed into the bar shaped of certain sectional area through vacuum plodder, plodder is with vacuum chamber, and soap flakes enter the bubble of taking out after vacuum chamber in soap bar, then extrusion molding, the sectional area of soap bar can be regulated, in order to control the weight of soap blank; Printing is that the soap blank after cutting is pressed into the shape of regulation in die, and extrudes decorative pattern or brand mark, prints to require trace clear, plentiful, and soap blank can not sticking to mould, adopts freezing die, and the temperature of die reduces, and effectively prevents mold sticking.
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| CN2012104656792A CN103173304A (en) | 2012-11-19 | 2012-11-19 | Perfumed soap for showering and washing clothes and preparation method thereof |
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| CN2012104656792A CN103173304A (en) | 2012-11-19 | 2012-11-19 | Perfumed soap for showering and washing clothes and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103834512A (en) * | 2014-03-11 | 2014-06-04 | 昆明理工大学 | Montan wax washing soap and preparation method thereof |
| CN103865700A (en) * | 2014-03-11 | 2014-06-18 | 昆明理工大学 | Montan wax toilet soap and preparation method thereof |
| CN104928081A (en) * | 2015-05-26 | 2015-09-23 | 田七集团（香港）国际有限公司 | Horse oil and plant composition for inhibiting and removing mites and use of horse oil and plant composition in soap making |
| CN105385505A (en) * | 2015-10-15 | 2016-03-09 | 深圳市正大福报文化传播有限公司 | Technology for molding block raw materials used for oil lamps |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1362505A (en) * | 2000-12-25 | 2002-08-07 | 资生堂贺妮健工业株式会社 | Transparent bar-type soap composition |
-
2012
- 2012-11-19 CN CN2012104656792A patent/CN103173304A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1362505A (en) * | 2000-12-25 | 2002-08-07 | 资生堂贺妮健工业株式会社 | Transparent bar-type soap composition |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103834512A (en) * | 2014-03-11 | 2014-06-04 | 昆明理工大学 | Montan wax washing soap and preparation method thereof |
| CN103865700A (en) * | 2014-03-11 | 2014-06-18 | 昆明理工大学 | Montan wax toilet soap and preparation method thereof |
| CN103834512B (en) * | 2014-03-11 | 2016-10-26 | 昆明理工大学 | A kind of montanin wax laundry soap and preparation method thereof |
| CN103865700B (en) * | 2014-03-11 | 2016-12-07 | 昆明理工大学 | A kind of montanin wax fancy soap and preparation method thereof |
| CN104928081A (en) * | 2015-05-26 | 2015-09-23 | 田七集团（香港）国际有限公司 | Horse oil and plant composition for inhibiting and removing mites and use of horse oil and plant composition in soap making |
| CN104928081B (en) * | 2015-05-26 | 2018-01-16 | 广州瑞嘉精细化工有限公司 | A kind of house oil and plant composition and its purposes in soapmaking for pressing down mite except mite |
| CN105385505A (en) * | 2015-10-15 | 2016-03-09 | 深圳市正大福报文化传播有限公司 | Technology for molding block raw materials used for oil lamps |
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Application publication date: 20130626 |