CN108203631A - A kind of antibacterial cleaning products and preparation method thereof - Google Patents
A kind of antibacterial cleaning products and preparation method thereof Download PDFInfo
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- CN108203631A CN108203631A CN201611166525.8A CN201611166525A CN108203631A CN 108203631 A CN108203631 A CN 108203631A CN 201611166525 A CN201611166525 A CN 201611166525A CN 108203631 A CN108203631 A CN 108203631A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/02—Compositions of detergents based essentially on soap on alkali or ammonium soaps
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/005—Antimicrobial preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/22—Organic compounds, e.g. vitamins
- C11D9/26—Organic compounds, e.g. vitamins containing oxygen
- C11D9/265—Organic compounds, e.g. vitamins containing oxygen containing glycerol
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/22—Organic compounds, e.g. vitamins
- C11D9/30—Organic compounds, e.g. vitamins containing nitrogen
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/22—Organic compounds, e.g. vitamins
- C11D9/38—Products in which the composition is not well defined
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/44—Perfumes; Colouring materials; Brightening agents ; Bleaching agents
- C11D9/442—Perfumes
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
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- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Public Health (AREA)
- Dermatology (AREA)
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- General Health & Medical Sciences (AREA)
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- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
- Cosmetics (AREA)
Abstract
The invention discloses a kind of antibacterial cleaning products and preparation method thereof, the Cannador of Optimum is added in the antibacterial cleaning products, particularly hemp leaf extract, bacteriostatic activity is high, can effectively inhibit various pathogens, clean effect is good, it is safe and non-toxic, there is not the problems such as coarse dry to no skin irritation, and using rear skin, it can be not only used for the washing of clothing etc., it can also be used to the cleaning of skin.The manufacture craft of above-mentioned antibacterial cleaning products provided by the invention is simple and safe, and production cost is relatively low, is easy to industrialize.
Description
Technical field
The present invention relates to hygienic articles technical fields, and in particular to a kind of antibacterial cleaning products and preparation method thereof, especially
It is a kind of antibacterial cleansing soap and preparation method thereof.
Background technology
There is a large amount of pathogenic bacteria and fungi, common bacteria and fungal infections in the environment that we live to happen occasionally,
Skin is the significant points of prevailing conditions pathogenic bacteria parasitism, the use of the perfumed soap for having fungistatic effect is good the arranging of prevention infection generation
One of apply.The perfumed soap sold in the market is greatly, safety antibacterial using chemical substances such as triclocarban, triclosans
Need to be probed into, and be used for a long time certain chemical substance inhibit bacteria growth can cause microorganism generate drug resistance.Some manufactures
Quotient is to make perfumed soap as primary raw material using sodium soap and other surfaces activating agent, adds quality improver and appearance improvement
Agent, the manufactured product after machine-shaping, since the pH value of these perfumed soap products is higher, skin can not be resistant to for a long time, can only
For cleaning clothing.And the natural bacteriostatic active material contained in some plant extracts, adverse reaction will not be generated to human body
And side effect, the health of user is not damaged.The natural active matter extracted in plant is added by Many researchers in recent years
Realized in perfumed soap it is antibacterial, if patent CN201310577658.4 discloses a kind of beautifying and antibacterial toilet soap, wherein antibacterial raw material components
Including：Bighead atractylodes rhizome decocting liquid, root of Dahurain angelica ultrasound alcohol extract, lucid asparagus decocting liquid, tea tree ethereal oil, antipathogenic composition is more, the antibacterial toilet soap
Preparation process is more complicated, and total preparation cost is higher.
Related document report both at home and abroad, Cannador has bacteriostatic activity, but yet there are no and apply it to daily chemical products
In report.
Invention content
In consideration of it, the present invention provides a kind of antibacterial cleaning products, material composition includes：Solvent, base agent, aliphatic acid,
Chelating agent, Cannador；The bacteriostatic activity of the antibacterial cleaning products is high, can effectively inhibit various pathogens, and clean effect is good,
And it is safe and non-toxic, to no skin irritation, there is not the problems such as coarse dry using rear skin.
Preferably, the Cannador, the extract part of hemp plant include：One in stalk core, flower, leaf and root
The combination of kind or two or more arbitrary proportions；
Preferably, the Cannador can be that different plant parts are extracted the extract of formation respectively or are carried
The combination of object is taken, such as hemp stalk core extract, hemp flower extract, hemp leaf extract, hemp root extract or, hemp stalk
The combination of core extract, hemp flower extract, hemp leaf extract and two or more arbitrary proportions in hemp root extract；
Preferably, the Cannador can extract different plant parts or combinations simultaneously, and what is obtained carries
Take the group of the combination of object or extract, i.e. the extract extract of the combination of one or more of stalk core, flower, leaf, root
It closes.Such as extract, the hemp stalk core of the extract of cannabis and leaf, hemp stalk core and flower, the extract of leaf, hemp stalk core and flower
Extract of extract, cannabis and root with leaf etc.；
Plant extraction process conventional in the prior art can be used to prepare in the Cannador, such as solvent extraction
Method, steam distillation, sublimed method, supercritical fluid extraction, film extraction and separation technology etc.；Preferably, solvent can be used to carry
It follows the example of, Extraction solvent can be：Low mass molecule alcohol (such as methanol, ethyl alcohol, butanol either propyl alcohol), acetic acid esters (such as methyl acetate or second
Acetoacetic ester), ketone (such as acetone), ether (such as methyl ether either ether), low-boiling aliphatic hydrocarbon or aromatic hydrocarbon or chlorinated hydrocabon；It carries
The technique taken can be to be heated to reflux, and may also be combined with other extraction separate modes as in extraction, distillation, crystallization, chromatographic isolation etc.
One or more combinations carries out further purification ＆ isolation to extract.
Preferably, the Cannador in the antibacterial cleaning products is hemp leaf extract；
Preferably, the mass percent of Cannador is 0.1-30% in the antibacterial cleaning products；Preferably 0.1-
20%, more preferably 0.1-10%；
Preferably, the mass percent of solvent is 15-55%, more preferably 25-45% in the antibacterial cleaning products；
Preferably, the mass percent of base agent is 1-10%, more preferably 5-10% in the antibacterial cleaning products；
Preferably, the mass percent of aliphatic acid is 30-60%, more preferably 40-50% in the antibacterial cleaning products；
Preferably, the mass percent of chelating agent is 0.01-5%, more preferably 0.01- in the antibacterial cleaning products
1%；
Preferably, the solvent is water, more preferably deionized water；
Preferably, the base agent is selected from：Sodium hydroxide, potassium hydroxide, triethanolamine it is one or more；
Preferably, the aliphatic acid is linear saturated fatty acids, more preferably certainly：Palmitic acid, stearic acid, lauric acid, meat
Myristic acid it is one or more；
Preferably, the chelating agent is selected from：Disodium ethylene diamine tetraacetate (EDTA-2Na), tetrasodium ethylenediamine tetraacetate
(EDTA-4Na), it is one or more in 1-hydroxy ethylidene-1,1-diphosphonic acid (EHDP), sodium citrate；More preferably EDTA-2Na；
Preferably, the raw material components of the antibacterial cleaning products further include：One kind in emollient, moisturizer, deodorant tune
It is or a variety of；
In a preferred embodiment of the invention, the raw material components of the antibacterial cleaning products include：Solvent, alkali help
Agent, aliphatic acid, chelating agent, Cannador, emollient, moisturizer, deodorant tune.
Preferably, the emollient is selected from：Wheat-germ oil, Sweet Almond Oil, jojoba oil, methoxy cinnamic acid ethyl
It is one or more in own ester, wheat-germ oil glyceride type, Avocado Oil, castor oil, sunflower oil, soybean oil；
Preferably, the moisturizer is selected from：1,3 butylene glycol, lactic acid, sorbierite, glycerin polyether -26, polyethylene glycol -
401st, beta glucan, sodium lactate, ethoxy urea, Sodium Hyaluronate, 1,2- propylene glycol, glycerine, fucoidan, seaweed
It is one or more in sugar, allantoin, hydrolytic collagen, honey；
Deodorant tune of the present invention can be conventional daily chemical essence of the prior art, and those skilled in the art can basis
Manufacturing process and production and sales need to select suitable essence, to recall special odor type and effect, it is possible to use a variety of essence groups
It closes, the present invention is not specifically limited this；
In another preferred embodiment of the invention, the raw material components of above-mentioned antibacterial cleaning products and its quality percentage
Than being respectively：Solvent 15-55%, base agent 1-10%, aliphatic acid 30-60%, chelating agent 0.01-5%, Cannador 0.1-
30%th, emollient 0.01-10%, moisturizer 0.01-20%, deodorant tune 0.01-1.0%.
Preferably, mass percent of the above-mentioned emollient in above-mentioned antibacterial cleaning products is 0.01-10%, preferably
0.1-5%；
Preferably, mass percent of the above-mentioned moisturizer in above-mentioned antibacterial cleaning products is 0.01-20%, preferably
0.1-10%；
Preferably, mass percent of the above-mentioned deodorant tune in above-mentioned antibacterial cleaning products is 0.01-1.0%, preferably
0.1-0.5%.
Those skilled in the art can also add according to actual needs into above-mentioned antibacterial cleaning products：Colorant, preservative,
Antioxidant, emulsifier, foaming agent, curing agent, thickener, solubilizer, nourishing additive agent, interfacial agent, pH adjusting agent, day
One or more in the additives such as right flowers and plants, the antibacterial cleaning products of gained are also included in protection scope of the present invention.
Preferably, the antibacterial cleaning products can be liquid form such as liquid soap, solid form such as perfumed soap, facial soap
Deng preferably solid form, particularly antibacterial toilet soap, facial soap.
Another aspect of the present invention also provides the preparation method of above-mentioned antibacterial cleaning products, and the method includes following step
Suddenly：
(1) solvent, chelating agent, alkali are mixed, heating；Heat aliphatic acid；
(2) alkali and the solution of chelating agent obtained step (1) is mixed with aliphatic acid, carries out saponification；
(3) system for obtaining step (2) cools down, and adds in Cannador, mixing；
Optionally, the system that (4) obtain step (3) is dried.
Preferably, the temperature that is heated to described in step (1) is 70-90 DEG C；
Preferably, step (2) mixed system is kept stirring, until reaction terminates；
Preferably, the temperature that is cooled to described in step (3) is 30-50 DEG C；
In one embodiment of the invention, the step (4) includes：The system that step (3) obtains is poured into mold
Afterwards, it covers, keeps the temperature；It is demoulded after solidification, natural drying is got product.
Preferably, further included in the antibacterial cleaning products it is one or more in emollient, moisturizer, deodorant tune,
Mixing is added in after step (2).
The present invention also provides a kind of application of above-mentioned antibacterial cleaning products in cosmetics, bath article is prepared.
The present invention also provides a kind of application of above-mentioned antibacterial cleaning products in the cleaning of skin and clothing is antibacterial.
Preferably, above application cleans antibacterial for skin.
The Cannador of Optimum, particularly marihuana is added in antibacterial cleaning products provided by the invention to extract
Object, bacteriostatic activity is high, can effectively inhibit various pathogens, clean effect is good, and safe and non-toxic, to no skin irritation, and makes
There is not the problems such as coarse dry with rear skin, can be not only used for the washing of clothing etc., it can also be used to the cleaning of skin.The present invention
The manufacture craft of the above-mentioned antibacterial cleaning products provided is simple and safe, and production cost is relatively low, is easy to industrialize.
Specific embodiment
The technical solution in the embodiment of the present invention will be clearly and completely described below, it is clear that described implementation
Example is only part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, the common skill in this field
Art personnel all other embodiments obtained without creative efforts belong to the model that the present invention protects
It encloses.
The preparation of 1 Cannador of embodiment
Technique：
1st, raw material hemp stalk core, cannabis, marihuana and/or cannabis root are cleaned air-dried；
2nd, the raw material after above-mentioned air-dry are crushed to 10-40 mesh；
3rd, it by gained powder, is measured with 4-8 times, the ethyl alcohol cold soaking of 30%-60% extracts 1-3 times, it is 0.5-2 hours each；
4th, merge extracting solution, decolourize through 0.1-1wt% activated carbon adsorptions；
5th, under 70 DEG C of temperature conditions, it is concentrated under reduced pressure into relative density 1.01-1.03；
Up to Cannador medicinal extract, such as hemp stalk core extract, hemp flower extract, hemp leaf extract, cannabis root
The combination of extract or two of which, three kinds or four kinds extracts.
Cannador used in following embodiments can be that 1 method of embodiment be made or public in the prior art
Other extracting methods opened are made.
The preparation of 2 product of the present invention of embodiment
Technique：
1st, A heat phases to 80 DEG C are uniformly mixed, B heat phases is added to 80 DEG C in A phases, are stirred complete to saponification.
2 then add in C phase raw materials be uniformly mixed.
3rd, D phases are added in after 40 DEG C of cooling to stir evenly to get soap lye.
4th, it dips a small amount of olive oil with brush and applies die inside, after mixing soap lye then is poured into mold, use plastic film
Mold is covered, 35 DEG C of incubators place 24-48h；Demoulding is air-dried after its solidification, normal temperature environment ventilation is then placed within and allows
It spontaneously dries 4 weeks to obtain the final product.
Wherein the ingredient of A, B, C, D phase and quality proportioning are as shown in table 1.
The ingredient and composition of 1 A, B, C, D phase of table
The preparation of 3 product of the present invention of embodiment
Technique：
1st, A heat phases to 70 DEG C are uniformly mixed, B heat phases is added to 70 DEG C in A phases, are stirred complete to saponification.
2 then add in C phase raw materials be uniformly mixed.
3rd, D phases are added in after 30 DEG C of cooling to stir evenly to get soap lye.
4th, it dips a small amount of olive oil with brush and applies die inside, after mixing soap lye then is poured into mold, use plastic film
Mold is covered, 35 DEG C of incubators place 24-48h；Demoulding is air-dried after its solidification, normal temperature environment ventilation is then placed within and allows
It spontaneously dries 4 weeks to obtain the final product.
Wherein the ingredient of A, B, C, D phase and composition are as shown in table 2.
The ingredient and composition of 2 A, B, C, D phase of table
The preparation of 4 product of the present invention of embodiment
Technique：
1st, A heat phases to 90 DEG C are uniformly mixed, B heat phases is added to 90 DEG C in A phases, are stirred complete to saponification.
2 then add in C phase raw materials be uniformly mixed.
3rd, D phases are added in after 50 DEG C of cooling to stir evenly to get soap lye.
4th, it dips a small amount of olive oil with brush and applies die inside, after mixing soap lye then is poured into mold, use plastic film
Mold is covered, 35 DEG C of incubators place 24-48h；Demoulding is air-dried after its solidification, normal temperature environment ventilation is then placed within and allows
It spontaneously dries 4 weeks to obtain the final product.
Wherein the ingredient of A, B, C, D phase and composition are as shown in table 3.
The ingredient and composition of 3 A, B, C, D phase of table
The preparation of 5 product of the present invention of embodiment
Technique：
1st, A heat phases to 90 DEG C are uniformly mixed, B heat phases is added to 90 DEG C in A phases, are stirred complete to saponification.
2nd, D phases are added in after 50 DEG C of cooling to stir evenly to get soap lye.
3rd, it dips a small amount of olive oil with brush and applies die inside, after mixing soap lye then is poured into mold, use plastic film
Mold is covered, 35 DEG C of incubators place 24-48h；Demoulding is air-dried after its solidification, normal temperature environment ventilation is then placed within and allows
It spontaneously dries 4 weeks to obtain the final product.
Wherein the ingredient of A, B, D phase and composition are as shown in table 4.
The ingredient and composition of 4 A, B, D phase of table
The preparation of 6 product of the present invention of embodiment
Technique according to embodiment 3 prepares cleansing soap, and the wherein ingredient of A, B, C, D phase and composition is as shown in table 5.
The ingredient and composition of 5 A, B, C, D phase of table
The preparation of 7 product of the present invention of embodiment
Technique：
1st, A heat phases to 90 DEG C are uniformly mixed, B heat phases is added to 90 DEG C in A phases, are stirred complete to saponification.
2nd, D phases are added in after 50 DEG C of cooling to stir evenly to get soap lye.
3rd, it dips a small amount of olive oil with brush and applies die inside, after mixing soap lye then is poured into mold, use plastic film
Mold is covered, 35 DEG C of incubators place 24-48h；Demoulding is air-dried after its solidification, normal temperature environment ventilation is then placed within and allows
It spontaneously dries 4 weeks to obtain the final product.
Wherein the ingredient of A, B, D phase and composition are as shown in table 6.
The ingredient and composition of 6 A, B, D phase of table
The preparation of 8 product of the present invention of embodiment
Technique according to embodiment 2 prepares cleansing soap, and the wherein ingredient of A, B, C, D phase and composition is as shown in table 7.
The ingredient and composition of 7 A, B, C, D phase of table
The preparation of 9 product of the present invention of embodiment
Technique according to embodiment 2 prepares cleansing soap, and the wherein ingredient of A, B, C, D phase and composition is as shown in table 8.
The ingredient and composition of 8 A, B, C, D phase of table
The preparation of 10 product of the present invention of embodiment
Technique according to embodiment 3 prepares cleansing soap, and the wherein ingredient of A, B, C, D phase and composition is as shown in table 9.
The ingredient and composition of 9 A, B, C, D phase of table
The preparation of 11 product of the present invention of embodiment
Technique according to embodiment 2 prepares cleansing soap, and the wherein ingredient of A, B, C, D phase and composition is as shown in table 10.
The ingredient and composition of 10 A, B, C, D phase of table
The preparation of 12 product of the present invention of embodiment
Technique according to embodiment 2 prepares cleansing soap, and the wherein ingredient of A, B, C, D phase and composition is as shown in table 11.
The ingredient and composition of 11 A, B, C, D phase of table
The preparation of 13 product of the present invention of embodiment
Technique according to embodiment 2 prepares cleansing soap, and the wherein ingredient of A, B, C, D phase and composition is as shown in table 12.
The ingredient and composition of 12 A, B, C, D phase of table
The preparation of 14 product of the present invention of embodiment
Technique according to embodiment 3 prepares cleansing soap, and the wherein ingredient of A, B, C, D phase and composition is as shown in table 13.
The ingredient and composition of 13 A, B, C, D phase of table
The preparation of 15 product of the present invention of embodiment
Technique：
1st, by A heat phases to 80 DEG C be uniformly mixed, B heat phases are added to 80 DEG C in A phases, stir it is complete to saponification,
Heat preservation is placed at dry and ventilated after 2 weeks spare as soap base.
2nd, melt soap base, add in C phases, D phases, stir evenly, obtain liquid soap, bottle.
Wherein the ingredient of A, B, C, D phase and composition are as shown in table 14.
The ingredient and composition of 14 A, B, C, D phase of table
The preparation of 16 product of the present invention of embodiment
Technique according to embodiment 15 prepares cleansing soap, and the wherein ingredient of A, B, C, D phase and composition is as shown in Table 15.
The ingredient and composition of 15 A, B, C, D phase of table
17 cleansing soap bacteriostatic test of embodiment
First, experiment material
1st, bacterial strain：Staphylococcus aureus, Escherichia coli, Pseudomonas aeruginosa, Candida albicans；
2nd, test specimen：Cleansing soap prepared by embodiment 2-16.
2nd, experimental method
1st, experiment is by GB15979-2002《Disposable Sanitary Accessory sanitary standard》" stripping property resists (suppression) appendix C 4
Bacterium product bacteriostasis property test method " carries out.
2nd, with sample 1：1 solution acts on 2min to test organisms, tests and is repeated 3 times under the conditions of 20 ± 1 DEG C, is averaged.
3rd, evaluation criterion
Bacteriostasis rate >=50% -90%, product have bacteriostasis；Bacteriostasis rate >=90%, product have stronger bacteriostasis.
Experimental result
Experimental result is as shown in table 16.By result in table 16 it is found that various cleansing soaps provided by the present invention are to golden yellow
Staphylococcus, Escherichia coli, Pseudomonas aeruginosa, Candida albicans are respectively provided with stronger inhibiting effect.
The bacteriostatic experiment result of 16 cleansing soap of table
18 cleansing soap sterilization test of embodiment
First, experiment material
1st, bacterial strain：Staphylococcus aureus, Escherichia coli, Pseudomonas aeruginosa, Candida albicans；
2nd, test specimen：Cleansing soap prepared by embodiment 2-16.
2nd, experimental method
1st, experiment is by QB/T2738《The evaluation method of daily chemical products antibacterial bacteriostatic effect》In 7.2 antimicrobial form daily chemical products
The bactericidal effect method of inspection (suspension quantitative method) carries out.
2nd, with sample 1：1 (v/v) solution acts on 2min to test organisms, tests and is repeated 3 times under the conditions of 20 ± 1 DEG C, is made even
Mean value.
3rd, effect assessment
Sterilizing rate >=90% of product shows that product has stronger antibacterial action, reaches A1 grades of levels.
4th, experimental result
Experimental result is as shown in table 17.
The sterilization experiment result of 17 cleansing soap of table
As shown in Table 17, various cleansing soaps provided by the present invention are to staphylococcus aureus, Escherichia coli, green pus bar
Bacterium, Candida albicans are respectively provided with stronger bactericidal effect.
19 cleansing soap skin irritation test of embodiment
First, experimental method
According to the Ministry of Public Health《Disinfection technology standard》2002 editions, toxicology is carried out to sample prepared by 2-16 of the embodiment of the present invention
Experiment, an intact skin irritant test and multiple intact skin irritation test including cavy.
1st, an intact skin irritant test
(1) before the test for 24 hours, the hair of guinea pig back backbone both sides is removed with depilatory agent, skin must not be damaged.Unhairing model
It encloses, left and right each about 3cm × 3cm.
(2) next day is by tested material (cleansing soap a concentration of 1：5 water diluents) 0.5g directly drip in area for 2.5cm ×
On the side unhairing intact skin of 2.5cm or drop on an equal amount of 2 layers~4 layers gauze and apply in side skin of unhairing
Then surface is covered with one layer of non-stimulated plastic foil or oilpaper, then with non-stimulated immobilization with adhesive tape.Opposite side skin of unhairing is as empty
White control (or solvent control).The application time is 4h.After the test, it is tested with warm water or nonirritant solvent removing residual
Object.
(3) after tested material is removed 1h, for 24 hours with 48h observation local skin reaction, and by table 18 carry out stimulate the reaction
Scoring.
2nd, multiple intact skin irritant test
(1) before the test for 24 hours, the hair of guinea pig back backbone both sides is removed with depilatory agent, skin must not be damaged.Unhairing model
It encloses, left and right each about 3cm × 3cm.
(2) next day is by tested material (cleansing soap a concentration of 1：5 water diluents) 0.5g is coated on the skin of side, and opposite side applies molten
As control, the 4h after smearing is cleaned with water or non-stimulated suitable solvent for agent, removes residue.It smears daily once, continuously
Smear 14d.Observation for 24 hours by table 18 as a result, score after each smear.It is seen for the ease of the smearing and result of tested material
It examines, answers cropping when necessary.The same trial zone of processing method of check plot.
The standards of grading of 18 skin wound repair of table
2nd, evaluation regulation
1st, a Skin Irritation Test
In each observing time point, scored with oedema formational situation the erythema of animal according to table 18, and point
Temporally o'clock the scoring of 3 animals is not added divided by number of animals, obtains the skin wound repair integral mean value of different time points
(stimulus index).Wherein highest skin irritation index is taken, rank of the tested material to animal skin stimulus intensity is evaluated by table 19.
2nd, multiple Skin Irritation Test
Every animal average integral (stimulus index) daily is calculated, and judge that skin irritatin is strong with table 19 by following equation
Degree.
19 skin irritatin strength grading of table
3rd, evaluation result
According to above-mentioned experimental method, for given the test agent in skin irritation test, the integration of assessment result is 0-0.5 areas
Between, show that cleansing soap of the present invention without skin irritation, is suitably applied personal cleanliness and article cleaning.
20 cleansing soap detergency of embodiment detects
First, experiment material
Test soiled cotton：Carbon black greasy dirt cloth, albumen soiled cotton, sebum soiled cotton；
Given the test agent：Cleansing soap prepared by embodiment 2-16.
2nd, experimental method
Test basis GB/T13174《Dress material detergent detergency and the measure for recycling scourability》And QB/T1224
《Dress material washes agent by liquid》Relevant regulations carry out.
Experimental condition：Standard liquid detergent and given the test agent solution concentration are all 0.2%, i.e. 2g cleansing soaps grinds are dissolved in 1L
Dissolving is entirely sample solution in hard water, and experiment is repeated 3 times.
The decontamination ratio of three kinds of soiled cotton tests is all higher than 1 and meets QB/T1224《Dress material washes agent by liquid》Regulation.
3rd, experimental result
The detergency testing result of 20 cleansing soap of table
Result of the test shows that cleansing soap of the present invention is better than standard liquid detergent to three kinds of soiled cotton detergencies.
The dry and astringent degree evaluation of pachylosis of 21 cleansing soap of embodiment
First, experiment material
Given the test agent：Cleansing soap prepared by embodiment 2-16.
2nd, experimental method
Experiment is divided into 15 groups, 10 personnel's (male to female ratios 1 of every group of random selection：1) it is soaped with embodiment 2-16 cleanings
An equal amount of towel 3min is washed, is rinsed 1 minute, wash hands are dried, evaluation.
5 are denoted as with the dry and astringent degree of pachylosis, with 0-5 points of system evaluations, score value is higher to show that degree of drying is higher.
3rd, experimental result
The dry and astringent degree evaluation result of pachylosis of 21 cleansing soap of table
According to above-mentioned experimental method, given the test agent is in the dry and astringent degree evaluation experiment of pachylosis, the integration of assessment result
Essentially 0, partly it is 1, shows that cleansing soap of the present invention will not cause skin the problems such as coarse dry and astringent, there are moisture-keeping functions.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all essences in the present invention
Within god and principle, any modification for being made, equivalent replacement etc. should all be included in the protection scope of the present invention.
Claims (12)
1. a kind of antibacterial cleaning products, the antibacterial cleaning products material composition includes：Solvent, base agent, aliphatic acid, chelating
Agent, Cannador；The Cannador, the extract part of hemp plant include：One in stalk core, flower, leaf and root
The combination of kind or two or more arbitrary proportions.
2. antibacterial cleaning products as described in claim 1, which is characterized in that hemp in the antibacterial cleaning products material composition
The mass percent of extract is 0.1-30%, and the mass percent of solvent is 15-55%, and the mass percent of base agent is 1-
10%, the mass percent of aliphatic acid is 30-60%, and the mass percent of chelating agent is 0.01-5%.
3. antibacterial cleaning products as claimed in claim 2, which is characterized in that hemp in the antibacterial cleaning products material composition
The mass percent of extract is 0.1-20%, and the mass percent of the solvent is 25-45%, the quality hundred of the base agent
Divide than being 40-50% for the mass percent of 5-10%, the aliphatic acid, the mass percent of the chelating agent is 0.01-
1%.
4. the antibacterial cleaning products as described in claim 1-3 any one, which is characterized in that the solvent is deionization
Water；The alkali is sodium hydroxide, one or more in potassium hydroxide, triethanolamine；The aliphatic acid is straight chain saturation
It is one or more in aliphatic acid, preferably palmitic acid, stearic acid, lauric acid, myristic acid；The chelating agent is ethylenediamine
It is one or more in tetraacethyl disodium, tetrasodium ethylenediamine tetraacetate, 1-hydroxy ethylidene-1,1-diphosphonic acid, sodium citrate, preferably second two
Amine tetraacethyl disodium.
5. antibacterial cleaning products as described in claim 1, which is characterized in that the material composition of the antibacterial cleaning products also wraps
It includes：It is one or more in emollient, moisturizer, deodorant tune.
6. antibacterial cleaning products as claimed in claim 5, which is characterized in that the emollient is selected from：Wheat-germ oil, sweet tea
Apricot kernel oil, jojoba oil, ethylhexyl methoxy cinnamate, wheat-germ oil glyceride type, Avocado Oil, castor oil, sunflower seeds
It is one or more in oil, soybean oil；The moisturizer is selected from：1,3 butylene glycol, lactic acid, sorbierite, glycerin polyether -26,
Polyethylene glycol -401, beta glucan, sodium lactate, ethoxy urea, Sodium Hyaluronate, 1,2- propylene glycol, glycerine, fucosan sulphur
It is one or more in acid esters, trehalose, allantoin, hydrolytic collagen, honey.
7. antibacterial cleaning products as claimed in claim 6, which is characterized in that the emollient antibacterial cleaning products raw material into
Mass percent in point is 0.01-10%, preferably 0.1-5%；Quality hundred of the moisturizer in antibacterial cleaning products
Score is 0.01-20%, preferably 0.1-10%；Mass percent of the deodorant tune in antibacterial cleaning products is 0.01-
1.0%, preferably 0.1-0.5%.
8. antibacterial cleaning products as claimed in claim 5, which is characterized in that the material composition packet of the antibacterial cleaning products
It includes：Solvent, base agent, aliphatic acid, chelating agent, Cannador, emollient, moisturizer, deodorant tune；The antibacterial cleaning products
Material composition and its mass percent be respectively：Solvent 15-55%, base agent 1-10%, aliphatic acid 30-60%, chelating agent
0.01-5%, Cannador 0.1-30%, emollient 0.01-10%, moisturizer 0.01-20%, deodorant tune 0.01-1%.
9. antibacterial cleaning products as described in claim 1, which is characterized in that the antibacterial cleaning products are liquid or solid.
10. a kind of preparation method of the antibacterial cleaning products of claim 1-9 any one of them, the method includes following step
Suddenly：
(1) solvent, chelating agent, alkali are mixed, heating；Heat aliphatic acid；
(2) alkali and the solution of chelating agent obtained step (1) is mixed with aliphatic acid, carries out saponification；
(3) system for obtaining step (2) cools down, and adds in Cannador, mixing；
Optionally, the system that (4) obtain step (3) is dried.
11. the preparation method of antibacterial cleaning products according to any one of claims 10, the step is heated to temperature 70-90 in (1)
℃；30-50 DEG C of temperature is cooled in the step (3).
12. a kind of application of antibacterial cleaning products of claim 1-9 any one of them in the cleaning of skin and clothing is antibacterial.
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| CN111184650A (en) * | 2018-12-05 | 2020-05-22 | 张红 | Herbal bacteriostatic skin-moisturizing liquid washing and caring product and preparation method thereof |
| CN111187683A (en) * | 2018-12-05 | 2020-05-22 | 张红 | Cannabis antibacterial skin-moistening health-care perfumed soap and preparation method thereof |
| CN111297721A (en) * | 2019-11-16 | 2020-06-19 | 广东科誉新材料有限公司 | Application of hydroxyethyl diphosphate in soap-based shower gel |
| CN112940880A (en) * | 2021-02-04 | 2021-06-11 | 云南根之然生物科技有限公司 | Multifunctional handmade soap containing industrial hemp root extract and preparation method thereof |
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