CN103774285B - 一种纤维素活性纳米碳纤维吸附材料的制备方法 - Google Patents
一种纤维素活性纳米碳纤维吸附材料的制备方法 Download PDFInfo
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- CN103774285B CN103774285B CN201310748150.6A CN201310748150A CN103774285B CN 103774285 B CN103774285 B CN 103774285B CN 201310748150 A CN201310748150 A CN 201310748150A CN 103774285 B CN103774285 B CN 103774285B
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- 239000001913 cellulose Substances 0.000 title claims abstract description 45
- 239000000463 material Substances 0.000 title claims abstract description 33
- 238000002360 preparation method Methods 0.000 title claims abstract description 33
- 239000002121 nanofiber Substances 0.000 title claims abstract description 26
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title abstract description 6
- 229910052799 carbon Inorganic materials 0.000 title abstract description 6
- 238000009987 spinning Methods 0.000 claims abstract description 77
- 238000000034 method Methods 0.000 claims abstract description 39
- 238000003763 carbonization Methods 0.000 claims abstract description 25
- 238000010041 electrostatic spinning Methods 0.000 claims abstract description 18
- 239000003960 organic solvent Substances 0.000 claims abstract description 8
- 239000000835 fiber Substances 0.000 claims description 44
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 42
- 239000012530 fluid Substances 0.000 claims description 28
- 239000002134 carbon nanofiber Substances 0.000 claims description 25
- 230000004913 activation Effects 0.000 claims description 21
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 17
- 239000004917 carbon fiber Substances 0.000 claims description 17
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 14
- 238000001816 cooling Methods 0.000 claims description 14
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- 238000010438 heat treatment Methods 0.000 claims description 14
- 238000010792 warming Methods 0.000 claims description 14
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 12
- YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical compound CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 claims description 12
- 230000001461 cytolytic effect Effects 0.000 claims description 12
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 9
- 238000009413 insulation Methods 0.000 claims description 9
- 229910052757 nitrogen Inorganic materials 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 7
- 241000196324 Embryophyta Species 0.000 claims description 6
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims description 6
- 229910052786 argon Inorganic materials 0.000 claims description 6
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims description 4
- 235000017491 Bambusa tulda Nutrition 0.000 claims description 4
- 241001330002 Bambuseae Species 0.000 claims description 4
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 4
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims description 4
- 239000011425 bamboo Substances 0.000 claims description 4
- 239000001307 helium Substances 0.000 claims description 4
- 229910052734 helium Inorganic materials 0.000 claims description 4
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 claims description 4
- 239000010902 straw Substances 0.000 claims description 4
- 235000014676 Phragmites communis Nutrition 0.000 claims description 3
- 235000008331 Pinus X rigitaeda Nutrition 0.000 claims description 3
- 235000011613 Pinus brutia Nutrition 0.000 claims description 3
- 241000018646 Pinus brutia Species 0.000 claims description 3
- 241000219000 Populus Species 0.000 claims description 3
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 3
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 claims description 3
- 238000000926 separation method Methods 0.000 claims description 3
- 241000609240 Ambelania acida Species 0.000 claims description 2
- 229920000742 Cotton Polymers 0.000 claims description 2
- GSNUFIFRDBKVIE-UHFFFAOYSA-N DMF Natural products CC1=CC=C(C)O1 GSNUFIFRDBKVIE-UHFFFAOYSA-N 0.000 claims description 2
- 241000209140 Triticum Species 0.000 claims description 2
- 235000021307 Triticum Nutrition 0.000 claims description 2
- 239000010905 bagasse Substances 0.000 claims description 2
- 238000009835 boiling Methods 0.000 claims description 2
- 239000002699 waste material Substances 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 2
- 239000002023 wood Substances 0.000 claims description 2
- 230000003213 activating effect Effects 0.000 abstract 2
- 229920000875 Dissolving pulp Polymers 0.000 abstract 1
- 229920005610 lignin Polymers 0.000 description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- 238000001523 electrospinning Methods 0.000 description 5
- 238000007789 sealing Methods 0.000 description 5
- 229910021392 nanocarbon Inorganic materials 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000012978 lignocellulosic material Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 239000002028 Biomass Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 238000002074 melt spinning Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
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- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
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- Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
- Nonwoven Fabrics (AREA)
- Inorganic Fibers (AREA)
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CN201310748150.6A CN103774285B (zh) | 2013-12-31 | 2013-12-31 | 一种纤维素活性纳米碳纤维吸附材料的制备方法 |
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Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
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CN104131364B (zh) * | 2014-07-15 | 2016-01-20 | 李文军 | 农作物秸秆碳纤维生产方法 |
CN104307470B (zh) * | 2014-09-30 | 2016-06-29 | 天津理工大学 | 一种高吸附量的纤维素纤维基活性炭纤维的制备方法及其产品和应用 |
CN106378091A (zh) * | 2016-09-12 | 2017-02-08 | 东华大学 | 二氧化碳吸附分离用氮掺杂的碳纳米纤维吸附材料的制备 |
CN106757536A (zh) * | 2016-12-12 | 2017-05-31 | 大连工业大学 | 一种碱活化的木质素基活性碳纤维及其制备方法 |
CN108950737A (zh) * | 2017-05-18 | 2018-12-07 | 中国石油化工股份有限公司 | 一种碳纤维储氢材料及其制备方法 |
CN109894077A (zh) * | 2018-12-28 | 2019-06-18 | 安徽天富环保科技材料有限公司 | 一种粘胶基活性碳纤维高温活化设备及方法 |
CN109876772B (zh) * | 2019-04-22 | 2022-01-04 | 北京石油化工学院 | 纳米碳纤维与活性炭复合材料及其制备方法 |
CN111118883B (zh) * | 2019-12-31 | 2022-03-01 | 东华大学 | 一种纤维素基碳纳米纤维复合材料及其制备和应用 |
CN115106057A (zh) * | 2022-05-12 | 2022-09-27 | 山西新华防化装备研究院有限公司 | 一种高温煤气吸附材料的制备方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1113978A (zh) * | 1994-06-06 | 1995-12-27 | 杜海峰 | 活性碳纤维的制造方法 |
CN102634870A (zh) * | 2012-04-18 | 2012-08-15 | 江南大学 | 一种碳纳米管增强纤维素基纳米碳纤维及其制备方法 |
CN102719935A (zh) * | 2012-06-07 | 2012-10-10 | 北京林业大学 | 一种活性木质碳纤维的制备方法 |
CN103320904A (zh) * | 2013-06-20 | 2013-09-25 | 中国科学院理化技术研究所 | 微孔活性炭纤维的水蒸汽活化制备方法及制备装置 |
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2013
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Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1113978A (zh) * | 1994-06-06 | 1995-12-27 | 杜海峰 | 活性碳纤维的制造方法 |
CN102634870A (zh) * | 2012-04-18 | 2012-08-15 | 江南大学 | 一种碳纳米管增强纤维素基纳米碳纤维及其制备方法 |
CN102719935A (zh) * | 2012-06-07 | 2012-10-10 | 北京林业大学 | 一种活性木质碳纤维的制备方法 |
CN103320904A (zh) * | 2013-06-20 | 2013-09-25 | 中国科学院理化技术研究所 | 微孔活性炭纤维的水蒸汽活化制备方法及制备装置 |
Non-Patent Citations (2)
Title |
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粘胶基活性碳纤维新工艺研究;曾凡龙等;《材料科学与工程学报》;20031020;第21卷(第05期);651-655 * |
静电纺丝法制备木质素基纳米纤维;冯玉等;《造纸科学与技术》;20091015;第28卷(第05期);29-32 * |
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Denomination of invention: Preparation method for cellulose active carbon nanofibre adsorbing material Effective date of registration: 20150716 Granted publication date: 20150520 Pledgee: Wu Tongsheng Pledgor: Menghuyutong Bamboo Fiber Research & Development Center, Beijing Registration number: 2015990000568 |
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Effective date of registration: 20160317 Address after: 102611, No. 6, building 3, 20, Paradise Road, 301 Huangcun Town, Beijing, Daxing District Patentee after: Wu Tongsheng Address before: 102629, No. 32, Tianhe West Road, B District, Daxing industry zone, Beijing, Daxing District Patentee before: Menghuyutong Bamboo Fiber Research & Development Center, Beijing |