CN103764688A - 借助受控自由基聚合生产聚合物 - Google Patents

借助受控自由基聚合生产聚合物 Download PDF

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Publication number
CN103764688A
CN103764688A CN201280042447.4A CN201280042447A CN103764688A CN 103764688 A CN103764688 A CN 103764688A CN 201280042447 A CN201280042447 A CN 201280042447A CN 103764688 A CN103764688 A CN 103764688A
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China
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alkyl
methyl
monomers
general formula
optionally
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Pending
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CN201280042447.4A
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English (en)
Chinese (zh)
Inventor
P·海斯
S·弗雷施曼
F·贝克尔
K·米尔巴赫
K-D·洪根博格
M·布里姆
M·克莱纳
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BASF SE
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BASF SE
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Publication of CN103764688A publication Critical patent/CN103764688A/zh
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/01—Processes of polymerisation characterised by special features of the polymerisation apparatus used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/40—Redox systems
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00—Living radical polymerisation
    • C08F2438/01—Atom Transfer Radical Polymerization [ATRP] or reverse ATRP
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00—Living radical polymerisation
    • C08F2438/02—Stable Free Radical Polymerisation [SFRP]; Nitroxide Mediated Polymerisation [NMP] for, e.g. using 2,2,6,6-tetramethylpiperidine-1-oxyl [TEMPO]

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  • Chemical & Material Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polymerisation Methods In General (AREA)
  • Polymerization Catalysts (AREA)
  • Graft Or Block Polymers (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CN201280042447.4A 2011-08-30 2012-08-30 借助受控自由基聚合生产聚合物 Pending CN103764688A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP11179291.7 2011-08-30
EP11179291 2011-08-30
PCT/EP2012/066838 WO2013030261A1 (de) 2011-08-30 2012-08-30 Herstellung von polymeren durch kontrollierte radikalische polymerisation

Publications (1)

Publication Number Publication Date
CN103764688A true CN103764688A (zh) 2014-04-30

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CN201280042447.4A Pending CN103764688A (zh) 2011-08-30 2012-08-30 借助受控自由基聚合生产聚合物

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EP (1) EP2751143A1 (https=)
JP (1) JP2014525486A (https=)
KR (1) KR20140069032A (https=)
CN (1) CN103764688A (https=)
BR (1) BR112014003922A2 (https=)
IN (1) IN2014CN02321A (https=)
MX (1) MX2014002011A (https=)
RU (1) RU2014111849A (https=)
SG (1) SG2014014492A (https=)
WO (1) WO2013030261A1 (https=)
ZA (1) ZA201402272B (https=)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106471022A (zh) * 2014-07-09 2017-03-01 巴斯夫欧洲公司 作为生产聚合物的共聚单体的反应性单体

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8883941B2 (en) * 2013-03-18 2014-11-11 Henkel Corporation Methods and apparatus for controlled single electron transfer living radical polymerization
EP2899215A1 (de) 2014-01-24 2015-07-29 Basf Se Verfahren zur Aufarbeitung eines Gemischs (G), das eine organische Komponente (A), die mindestens eine Halogen-Kohlenstoffbindung aufweist, und eine Übergangsmetallkomponente (B) enthält
WO2025079624A1 (ja) * 2023-10-10 2025-04-17 株式会社ダイセル ポリマーの製造方法
TW202534087A (zh) * 2023-10-10 2025-09-01 日商大賽璐股份有限公司 聚合物的製造方法

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1183107A (zh) * 1995-03-31 1998-05-27 K·马蒂加茨吾斯基 新的(共)聚合物和新的基于原子(或基团)转移自由基聚合的聚合方法
CN101959912A (zh) * 2008-02-29 2011-01-26 株式会社钟化 固化性组合物

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5807937A (en) 1995-11-15 1998-09-15 Carnegie Mellon University Processes based on atom (or group) transfer radical polymerization and novel (co) polymers having useful structures and properties
FR2757865B1 (fr) 1996-12-26 1999-04-02 Atochem Elf Sa Procede de polymerisation ou copolymerisation radicalaire controlee de monomeres (meth)acryliques, vinyliques, vinylideniques et dieniques et (co)polymeres obtenus
TW593347B (en) 1997-03-11 2004-06-21 Univ Carnegie Mellon Improvements in atom or group transfer radical polymerization
AU3919500A (en) 1999-03-23 2000-10-09 Carnegie Wave Energy Limited Catalytic processes for the controlled polymerization of free radically (co)polymerizable monomers and functional polymeric systems prepared thereby
US6639029B1 (en) 2000-11-13 2003-10-28 Rohmax Additives Gmbh Process for continuous synthesis of polymer compositions as well as use of same
JP4237483B2 (ja) * 2002-12-27 2009-03-11 株式会社カネカ ビニル系重合体の製造方法
CN101522726B (zh) 2006-08-04 2014-02-12 宾夕法尼亚大学理事会 含吸电子侧基的活化和非活化单体的活性自由基聚合
EP2291412B1 (en) 2008-06-18 2013-07-24 Henkel Corporation Apparatus and methods for controlled radical polymerization
JP2010241907A (ja) * 2009-04-02 2010-10-28 Kaneka Corp （メタ）アクリル系ブロック共重合体の製造方法

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1183107A (zh) * 1995-03-31 1998-05-27 K·马蒂加茨吾斯基 新的(共)聚合物和新的基于原子(或基团)转移自由基聚合的聚合方法
CN101959912A (zh) * 2008-02-29 2011-01-26 株式会社钟化 固化性组合物

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106471022A (zh) * 2014-07-09 2017-03-01 巴斯夫欧洲公司 作为生产聚合物的共聚单体的反应性单体

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Publication number Publication date
EP2751143A1 (de) 2014-07-09
ZA201402272B (en) 2015-12-23
IN2014CN02321A (https=) 2015-06-19
KR20140069032A (ko) 2014-06-09
RU2014111849A (ru) 2015-10-10
JP2014525486A (ja) 2014-09-29
MX2014002011A (es) 2014-03-27
SG2014014492A (en) 2014-05-29
WO2013030261A1 (de) 2013-03-07
BR112014003922A2 (pt) 2017-03-28

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Application publication date: 20140430