RU2014111849A - Получение полимеров контролируемой радикальной полимеризацией - Google Patents
Получение полимеров контролируемой радикальной полимеризацией Download PDFInfo
- Publication number
- RU2014111849A RU2014111849A RU2014111849/04A RU2014111849A RU2014111849A RU 2014111849 A RU2014111849 A RU 2014111849A RU 2014111849/04 A RU2014111849/04 A RU 2014111849/04A RU 2014111849 A RU2014111849 A RU 2014111849A RU 2014111849 A RU2014111849 A RU 2014111849A
- Authority
- RU
- Russia
- Prior art keywords
- carbon atoms
- alkyl
- monomers
- polymers
- general formula
- Prior art date
Links
- 229920000642 polymer Polymers 0.000 title claims abstract 9
- 238000010526 radical polymerization reaction Methods 0.000 title claims abstract 5
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract 25
- 125000000217 alkyl group Chemical group 0.000 claims abstract 19
- 238000000034 method Methods 0.000 claims abstract 13
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract 12
- 239000001257 hydrogen Substances 0.000 claims abstract 10
- 239000000178 monomer Substances 0.000 claims abstract 10
- 239000010949 copper Substances 0.000 claims abstract 9
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract 7
- 239000003446 ligand Substances 0.000 claims abstract 7
- 125000003118 aryl group Chemical group 0.000 claims abstract 6
- 239000003054 catalyst Substances 0.000 claims abstract 5
- 239000003999 initiator Substances 0.000 claims abstract 5
- 239000002904 solvent Substances 0.000 claims abstract 5
- 229910052736 halogen Inorganic materials 0.000 claims abstract 4
- 150000002367 halogens Chemical class 0.000 claims abstract 4
- 125000005842 heteroatom Chemical group 0.000 claims abstract 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract 3
- 229910052802 copper Inorganic materials 0.000 claims abstract 3
- 238000006116 polymerization reaction Methods 0.000 claims abstract 3
- 125000003342 alkenyl group Chemical group 0.000 claims abstract 2
- 125000003545 alkoxy group Chemical group 0.000 claims abstract 2
- 125000000304 alkynyl group Chemical group 0.000 claims abstract 2
- 125000004104 aryloxy group Chemical group 0.000 claims abstract 2
- 125000000753 cycloalkyl group Chemical group 0.000 claims abstract 2
- 150000004820 halides Chemical class 0.000 claims abstract 2
- 125000001072 heteroaryl group Chemical group 0.000 claims abstract 2
- 125000000623 heterocyclic group Chemical group 0.000 claims abstract 2
- 150000002431 hydrogen Chemical class 0.000 claims abstract 2
- 239000000203 mixture Substances 0.000 claims abstract 2
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract 2
- 125000002577 pseudohalo group Chemical group 0.000 claims abstract 2
- 125000001424 substituent group Chemical group 0.000 claims abstract 2
- 229920001577 copolymer Polymers 0.000 claims 3
- 229910001502 inorganic halide Inorganic materials 0.000 claims 3
- 150000003839 salts Chemical class 0.000 claims 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims 2
- 150000003926 acrylamides Chemical class 0.000 claims 2
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims 2
- 229920001400 block copolymer Polymers 0.000 claims 2
- 239000003607 modifier Substances 0.000 claims 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims 1
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 claims 1
- 229920000028 Gradient copolymer Polymers 0.000 claims 1
- 239000004609 Impact Modifier Substances 0.000 claims 1
- 239000000853 adhesive Substances 0.000 claims 1
- 230000001070 adhesive effect Effects 0.000 claims 1
- 150000001412 amines Chemical class 0.000 claims 1
- 229910001431 copper ion Inorganic materials 0.000 claims 1
- 239000002270 dispersing agent Substances 0.000 claims 1
- 238000002848 electrochemical method Methods 0.000 claims 1
- 238000001914 filtration Methods 0.000 claims 1
- 229920001519 homopolymer Polymers 0.000 claims 1
- 238000005342 ion exchange Methods 0.000 claims 1
- 229910052757 nitrogen Inorganic materials 0.000 claims 1
- 239000004014 plasticizer Substances 0.000 claims 1
- -1 polybutylene terephthalate Polymers 0.000 claims 1
- 229920001707 polybutylene terephthalate Polymers 0.000 claims 1
- 239000004800 polyvinyl chloride Substances 0.000 claims 1
- 229920000915 polyvinyl chloride Polymers 0.000 claims 1
- 238000001556 precipitation Methods 0.000 claims 1
- 238000000746 purification Methods 0.000 claims 1
- 229920005604 random copolymer Polymers 0.000 claims 1
- 239000000565 sealant Substances 0.000 claims 1
- 239000000126 substance Substances 0.000 claims 1
- 229920006250 telechelic polymer Polymers 0.000 claims 1
- 229920002725 thermoplastic elastomer Polymers 0.000 claims 1
- 230000007704 transition Effects 0.000 claims 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- 125000004429 atom Chemical group 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/01—Processes of polymerisation characterised by special features of the polymerisation apparatus used
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
- C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/40—Redox systems
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2438/00—Living radical polymerisation
- C08F2438/01—Atom Transfer Radical Polymerization [ATRP] or reverse ATRP
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2438/00—Living radical polymerisation
- C08F2438/02—Stable Free Radical Polymerisation [SFRP]; Nitroxide Mediated Polymerisation [NMP] for, e.g. using 2,2,6,6-tetramethylpiperidine-1-oxyl [TEMPO]
Landscapes
- Chemical & Material Sciences (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polymerisation Methods In General (AREA)
- Polymerization Catalysts (AREA)
- Graft Or Block Polymers (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP11179291.7 | 2011-08-30 | ||
| EP11179291 | 2011-08-30 | ||
| PCT/EP2012/066838 WO2013030261A1 (de) | 2011-08-30 | 2012-08-30 | Herstellung von polymeren durch kontrollierte radikalische polymerisation |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| RU2014111849A true RU2014111849A (ru) | 2015-10-10 |
Family
ID=46796583
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2014111849/04A RU2014111849A (ru) | 2011-08-30 | 2012-08-30 | Получение полимеров контролируемой радикальной полимеризацией |
Country Status (11)
| Country | Link |
|---|---|
| EP (1) | EP2751143A1 (https=) |
| JP (1) | JP2014525486A (https=) |
| KR (1) | KR20140069032A (https=) |
| CN (1) | CN103764688A (https=) |
| BR (1) | BR112014003922A2 (https=) |
| IN (1) | IN2014CN02321A (https=) |
| MX (1) | MX2014002011A (https=) |
| RU (1) | RU2014111849A (https=) |
| SG (1) | SG2014014492A (https=) |
| WO (1) | WO2013030261A1 (https=) |
| ZA (1) | ZA201402272B (https=) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8883941B2 (en) * | 2013-03-18 | 2014-11-11 | Henkel Corporation | Methods and apparatus for controlled single electron transfer living radical polymerization |
| EP2899215A1 (de) | 2014-01-24 | 2015-07-29 | Basf Se | Verfahren zur Aufarbeitung eines Gemischs (G), das eine organische Komponente (A), die mindestens eine Halogen-Kohlenstoffbindung aufweist, und eine Übergangsmetallkomponente (B) enthält |
| KR20170030538A (ko) * | 2014-07-09 | 2017-03-17 | 바스프 에스이 | 중합체의 제조를 위한 공단량체로서의 반응성 단량체 |
| WO2025079624A1 (ja) * | 2023-10-10 | 2025-04-17 | 株式会社ダイセル | ポリマーの製造方法 |
| TW202534087A (zh) * | 2023-10-10 | 2025-09-01 | 日商大賽璐股份有限公司 | 聚合物的製造方法 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5763548A (en) * | 1995-03-31 | 1998-06-09 | Carnegie-Mellon University | (Co)polymers and a novel polymerization process based on atom (or group) transfer radical polymerization |
| US5807937A (en) | 1995-11-15 | 1998-09-15 | Carnegie Mellon University | Processes based on atom (or group) transfer radical polymerization and novel (co) polymers having useful structures and properties |
| FR2757865B1 (fr) | 1996-12-26 | 1999-04-02 | Atochem Elf Sa | Procede de polymerisation ou copolymerisation radicalaire controlee de monomeres (meth)acryliques, vinyliques, vinylideniques et dieniques et (co)polymeres obtenus |
| TW593347B (en) | 1997-03-11 | 2004-06-21 | Univ Carnegie Mellon | Improvements in atom or group transfer radical polymerization |
| AU3919500A (en) | 1999-03-23 | 2000-10-09 | Carnegie Wave Energy Limited | Catalytic processes for the controlled polymerization of free radically (co)polymerizable monomers and functional polymeric systems prepared thereby |
| US6639029B1 (en) | 2000-11-13 | 2003-10-28 | Rohmax Additives Gmbh | Process for continuous synthesis of polymer compositions as well as use of same |
| JP4237483B2 (ja) * | 2002-12-27 | 2009-03-11 | 株式会社カネカ | ビニル系重合体の製造方法 |
| CN101522726B (zh) | 2006-08-04 | 2014-02-12 | 宾夕法尼亚大学理事会 | 含吸电子侧基的活化和非活化单体的活性自由基聚合 |
| US20110009517A1 (en) * | 2008-02-29 | 2011-01-13 | Kaneka Corporation | Curable composition |
| EP2291412B1 (en) | 2008-06-18 | 2013-07-24 | Henkel Corporation | Apparatus and methods for controlled radical polymerization |
| JP2010241907A (ja) * | 2009-04-02 | 2010-10-28 | Kaneka Corp | （メタ）アクリル系ブロック共重合体の製造方法 |
-
2012
- 2012-08-30 IN IN2321CHN2014 patent/IN2014CN02321A/en unknown
- 2012-08-30 KR KR1020147007911A patent/KR20140069032A/ko not_active Withdrawn
- 2012-08-30 RU RU2014111849/04A patent/RU2014111849A/ru not_active Application Discontinuation
- 2012-08-30 SG SG2014014492A patent/SG2014014492A/en unknown
- 2012-08-30 MX MX2014002011A patent/MX2014002011A/es unknown
- 2012-08-30 EP EP12753968.2A patent/EP2751143A1/de not_active Withdrawn
- 2012-08-30 JP JP2014527650A patent/JP2014525486A/ja active Pending
- 2012-08-30 CN CN201280042447.4A patent/CN103764688A/zh active Pending
- 2012-08-30 WO PCT/EP2012/066838 patent/WO2013030261A1/de not_active Ceased
- 2012-08-30 BR BR112014003922A patent/BR112014003922A2/pt not_active IP Right Cessation
-
2014
- 2014-03-27 ZA ZA2014/02272A patent/ZA201402272B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| EP2751143A1 (de) | 2014-07-09 |
| ZA201402272B (en) | 2015-12-23 |
| IN2014CN02321A (https=) | 2015-06-19 |
| KR20140069032A (ko) | 2014-06-09 |
| JP2014525486A (ja) | 2014-09-29 |
| MX2014002011A (es) | 2014-03-27 |
| SG2014014492A (en) | 2014-05-29 |
| WO2013030261A1 (de) | 2013-03-07 |
| CN103764688A (zh) | 2014-04-30 |
| BR112014003922A2 (pt) | 2017-03-28 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FA93 | Acknowledgement of application withdrawn (no request for examination) |
Effective date: 20150831 |