JP2014505027A5 - - Google Patents
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- JP2014505027A5 JP2014505027A5 JP2013542401A JP2013542401A JP2014505027A5 JP 2014505027 A5 JP2014505027 A5 JP 2014505027A5 JP 2013542401 A JP2013542401 A JP 2013542401A JP 2013542401 A JP2013542401 A JP 2013542401A JP 2014505027 A5 JP2014505027 A5 JP 2014505027A5
- Authority
- JP
- Japan
- Prior art keywords
- thf
- aryl
- independently
- group
- aryloxy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 229910052726 zirconium Inorganic materials 0.000 claims description 5
- 229920006395 saturated elastomer Polymers 0.000 claims description 3
- 239000002994 raw material Substances 0.000 claims description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 3
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 claims 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims 2
- 125000004104 aryloxy group Chemical group 0.000 claims 2
- 229910052739 hydrogen Inorganic materials 0.000 claims 2
- 239000001257 hydrogen Substances 0.000 claims 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 2
- ADLVDYMTBOSDFE-UHFFFAOYSA-N 5-chloro-6-nitroisoindole-1,3-dione Chemical compound C1=C(Cl)C([N+](=O)[O-])=CC2=C1C(=O)NC2=O ADLVDYMTBOSDFE-UHFFFAOYSA-N 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 claims 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims 1
- 125000000051 benzyloxy group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])O* 0.000 claims 1
- 125000000753 cycloalkyl group Chemical group 0.000 claims 1
- 239000002904 solvent Substances 0.000 claims 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims 1
- 239000003446 ligand Substances 0.000 description 6
- PUAQLLVFLMYYJJ-UHFFFAOYSA-N 2-aminopropiophenone Chemical compound CC(N)C(=O)C1=CC=CC=C1 PUAQLLVFLMYYJJ-UHFFFAOYSA-N 0.000 description 5
- 125000003118 aryl group Chemical group 0.000 description 5
- 238000005481 NMR spectroscopy Methods 0.000 description 3
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 3
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910052735 hafnium Inorganic materials 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- JDIIGWSSTNUWGK-UHFFFAOYSA-N 1h-imidazol-3-ium;chloride Chemical compound [Cl-].[NH2+]1C=CN=C1 JDIIGWSSTNUWGK-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 150000002362 hafnium Chemical class 0.000 description 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- JJTUDXZGHPGLLC-UHFFFAOYSA-N lactide Chemical compound CC1OC(=O)C(C)OC1=O JJTUDXZGHPGLLC-UHFFFAOYSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000005649 metathesis reaction Methods 0.000 description 1
- HZVOZRGWRWCICA-UHFFFAOYSA-N methanediyl Chemical compound [CH2] HZVOZRGWRWCICA-UHFFFAOYSA-N 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000037361 pathway Effects 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP10015544 | 2010-12-10 | ||
| EP10015544.9 | 2010-12-10 | ||
| PCT/EP2011/006076 WO2012076140A1 (en) | 2010-12-10 | 2011-12-05 | N-heterocyclic carbene based zirconium complexes for use in lactones ring opening polymerization |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2014505027A JP2014505027A (ja) | 2014-02-27 |
| JP2014505027A5 true JP2014505027A5 (https=) | 2015-03-12 |
Family
ID=43618343
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2013542401A Pending JP2014505027A (ja) | 2010-12-10 | 2011-12-05 | ラクトン類の開環重合において使用するための、ｎ−複素環式カルベンをベースとするジルコニウム錯体 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US20130281653A1 (https=) |
| EP (1) | EP2649083A1 (https=) |
| JP (1) | JP2014505027A (https=) |
| KR (1) | KR20140029373A (https=) |
| CN (1) | CN103380135B (https=) |
| WO (1) | WO2012076140A1 (https=) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2799462A1 (en) | 2013-05-02 | 2014-11-05 | PURAC Biochem BV | Method to manufacture PLA using a new polymerization catalyst |
| CN105541893A (zh) * | 2016-01-05 | 2016-05-04 | 内蒙古工业大学 | 对称四齿丙胺吗啉双酚类配体锆金属络合物的合成及应用 |
| GB201714264D0 (en) * | 2017-09-05 | 2017-10-18 | Scg Chemicals Co Ltd | Catalysts suitable for the ring-opening polymerisation of cyclic esters and cyclic amides |
| WO2021094525A1 (en) * | 2019-11-15 | 2021-05-20 | Total Corbion Pla Bv | Process for polymerising lactide using a liquid catalyst formulation |
| CN113403056B (zh) * | 2021-05-27 | 2022-08-16 | 长江大学 | 一种催化剂组合物及其制备方法和应用 |
| CN113292980B (zh) * | 2021-05-27 | 2022-08-16 | 长江大学 | 一种水溶性稠油降黏剂及其制备方法和应用 |
| CN116813898A (zh) * | 2023-07-07 | 2023-09-29 | 中化泉州能源科技有限责任公司 | 一种环状内酯开环聚合催化剂及其制备方法 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2986509B2 (ja) | 1989-05-26 | 1999-12-06 | 三井化学株式会社 | 変性ポリエステル樹脂組成物、その製造方法、およびその用途 |
| US5258488A (en) | 1992-01-24 | 1993-11-02 | Cargill, Incorporated | Continuous process for manufacture of lactide polymers with controlled optical purity |
| JP4099432B2 (ja) * | 2003-06-20 | 2008-06-11 | 日本ポリプロ株式会社 | オレフィン重合用触媒成分及び触媒 |
| CN1277859C (zh) * | 2005-04-15 | 2006-10-04 | 浙江大学 | 一种脂肪族聚酯的制备方法 |
| FR2909679A1 (fr) * | 2006-12-06 | 2008-06-13 | Rhodia Recherches & Tech | Composition comprenant un carbene et une matrice organique, son procede d'obtention et son utilisation |
| CN101665565B (zh) * | 2008-09-01 | 2012-01-04 | 南京工业大学 | 一种用卡宾衍生物催化制备聚乳酸的方法 |
-
2011
- 2011-12-05 CN CN201180059470.XA patent/CN103380135B/zh not_active Expired - Fee Related
- 2011-12-05 EP EP11794041.1A patent/EP2649083A1/en not_active Withdrawn
- 2011-12-05 KR KR1020137017984A patent/KR20140029373A/ko not_active Withdrawn
- 2011-12-05 WO PCT/EP2011/006076 patent/WO2012076140A1/en not_active Ceased
- 2011-12-05 JP JP2013542401A patent/JP2014505027A/ja active Pending
- 2011-12-05 US US13/992,616 patent/US20130281653A1/en not_active Abandoned
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