CN103380135B - 用于内酯类开环聚合的基于n-杂环卡宾的锆络合物 - Google Patents

用于内酯类开环聚合的基于n-杂环卡宾的锆络合物 Download PDF

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Publication number
CN103380135B
CN103380135B CN201180059470.XA CN201180059470A CN103380135B CN 103380135 B CN103380135 B CN 103380135B CN 201180059470 A CN201180059470 A CN 201180059470A CN 103380135 B CN103380135 B CN 103380135B
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thf
bis
quat
tert
butylphenyl
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English (en)
Chinese (zh)
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CN103380135A (zh
Inventor
P·斯特法纳特
C·罗曼
S·达格尼
S·拜勒敏-拉珀纳兹
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Clariant Finance BVI Ltd
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Clariant Finance BVI Ltd
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/85—Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/28—Titanium compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F261/00—Macromolecular compounds obtained by polymerising monomers on to polymers of oxygen-containing monomers as defined in group C08F16/00
    • C08F261/12—Macromolecular compounds obtained by polymerising monomers on to polymers of oxygen-containing monomers as defined in group C08F16/00 on to polymers of unsaturated acetals or ketals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/72—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44
    • C08F4/74—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from refractory metals
    • C08F4/76—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from refractory metals selected from titanium, zirconium, hafnium, vanadium, niobium or tantalum
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/823—Preparation processes characterised by the catalyst used for the preparation of polylactones or polylactides

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polyesters Or Polycarbonates (AREA)
CN201180059470.XA 2010-12-10 2011-12-05 用于内酯类开环聚合的基于n-杂环卡宾的锆络合物 Expired - Fee Related CN103380135B (zh)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
EP100155449 2010-12-10
EP10015544 2010-12-10
EP10015544.9 2010-12-10
PCT/EP2011/006076 WO2012076140A1 (en) 2010-12-10 2011-12-05 N-heterocyclic carbene based zirconium complexes for use in lactones ring opening polymerization

Publications (2)

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CN103380135A CN103380135A (zh) 2013-10-30
CN103380135B true CN103380135B (zh) 2016-08-31

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Country Status (6)

Country Link
US (1) US20130281653A1 (https=)
EP (1) EP2649083A1 (https=)
JP (1) JP2014505027A (https=)
KR (1) KR20140029373A (https=)
CN (1) CN103380135B (https=)
WO (1) WO2012076140A1 (https=)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2799462A1 (en) 2013-05-02 2014-11-05 PURAC Biochem BV Method to manufacture PLA using a new polymerization catalyst
CN105541893A (zh) * 2016-01-05 2016-05-04 内蒙古工业大学 对称四齿丙胺吗啉双酚类配体锆金属络合物的合成及应用
GB201714264D0 (en) * 2017-09-05 2017-10-18 Scg Chemicals Co Ltd Catalysts suitable for the ring-opening polymerisation of cyclic esters and cyclic amides
WO2021094525A1 (en) * 2019-11-15 2021-05-20 Total Corbion Pla Bv Process for polymerising lactide using a liquid catalyst formulation
CN113403056B (zh) * 2021-05-27 2022-08-16 长江大学 一种催化剂组合物及其制备方法和应用
CN113292980B (zh) * 2021-05-27 2022-08-16 长江大学 一种水溶性稠油降黏剂及其制备方法和应用
CN116813898A (zh) * 2023-07-07 2023-09-29 中化泉州能源科技有限责任公司 一种环状内酯开环聚合催化剂及其制备方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2986509B2 (ja) 1989-05-26 1999-12-06 三井化学株式会社 変性ポリエステル樹脂組成物、その製造方法、およびその用途
US5258488A (en) 1992-01-24 1993-11-02 Cargill, Incorporated Continuous process for manufacture of lactide polymers with controlled optical purity
JP4099432B2 (ja) * 2003-06-20 2008-06-11 日本ポリプロ株式会社 オレフィン重合用触媒成分及び触媒
CN1277859C (zh) * 2005-04-15 2006-10-04 浙江大学 一种脂肪族聚酯的制备方法
FR2909679A1 (fr) * 2006-12-06 2008-06-13 Rhodia Recherches & Tech Composition comprenant un carbene et une matrice organique, son procede d'obtention et son utilisation
CN101665565B (zh) * 2008-09-01 2012-01-04 南京工业大学 一种用卡宾衍生物催化制备聚乳酸的方法

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WO2012076140A1 (en) 2012-06-14
US20130281653A1 (en) 2013-10-24
JP2014505027A (ja) 2014-02-27
KR20140029373A (ko) 2014-03-10
EP2649083A1 (en) 2013-10-16
CN103380135A (zh) 2013-10-30

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