CN102209736B - 具有宽分布的b嵌段的aba三嵌段共聚物的制备方法 - Google Patents
具有宽分布的b嵌段的aba三嵌段共聚物的制备方法 Download PDFInfo
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- CN102209736B CN102209736B CN200980144196.9A CN200980144196A CN102209736B CN 102209736 B CN102209736 B CN 102209736B CN 200980144196 A CN200980144196 A CN 200980144196A CN 102209736 B CN102209736 B CN 102209736B
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/001—Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/04—Polymerisation in solution
- C08F2/06—Organic solvent
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
- C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F6/00—Post-polymerisation treatments
- C08F6/02—Neutralisation of the polymerisation mass, e.g. killing the catalyst also removal of catalyst residues
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/26—Removing halogen atoms or halogen-containing groups from the molecule
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/34—Introducing sulfur atoms or sulfur-containing groups
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D153/00—Coating compositions based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2438/00—Living radical polymerisation
- C08F2438/01—Atom Transfer Radical Polymerization [ATRP] or reverse ATRP
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Graft Or Block Polymers (AREA)
- Paints Or Removers (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Sealing Material Composition (AREA)
- Polymerization Catalysts (AREA)
Abstract
Description
对比实施例1 | 实施例1 | 实施例2 | 实施例3 | |
单体1 | 1a)n-BA | 1b)n-BA | 1c)n-BA | 1d)n-BA |
用量 | 200.6g | 200.6g | 201.6g | 200.7g |
氧化铜(I) | 1.3g | 1.3g | 1.3g | 1.3g |
PMDETA | 3.4g | 3.3g | 3.4g | 3.3g |
引发剂1 | 0.85g | 0.85g | 0.81g | 0.81g |
引发剂2 | 2.52g | 2.53g | 2.44g | 2.44g |
t1 | 45min | 120min | 180min | 180min |
t2 | 165min | 60min | 150min | 150min |
单体2 | 2a)n-BA | 2b)n-BA | 2d)n-BA | 2e)n-BA |
用量 | 50.2g | 50.4g | 50.3g | 51.1g |
单体3 | 3a)MEMO | 3b)MEMO | 3c)AMA | 3d)HEMA |
用量 | 10.4g | 10.4g | 6.8g | 5.7g |
Mn(第1阶段) | 30000 | 27300 | 26800 | 27300 |
D | 1.60 | 1.88 | 2.14 | 2.11 |
Mn(终产物) | 31900 | 31000 | 28800 | 29400 |
D | 1.81 | 1.91 | 2.09 | 2.08 |
对比实施例2 | 对比实施例3 | 对比实施例4 | |
单体1 | 1e)MMA | 1f)n-BA | 1g)n-BA |
用量 | 81.0g | 79.6g | 79.6g |
单体2 | 2e)MMA | 2f)MMA | 2g)n-BA |
用量 | 19.9g | 19.9g | 20.0g |
单体3 | 3e)MEMO | 3f)MEMO | 3g)MEMO |
用量 | 4.8g | 4.8g | 4.8g |
引发剂的用量 | 1.25g | 1.25g | 1.25g |
Mn(第1阶段) | 21600 | 17800 | 18100 |
D | 1.21 | 1.22 | 1.28 |
Mn(终产物) | 26800 | 20300 | 22500 |
D | 1.31 | 1.36 | 1.38 |
Claims (22)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102008043669A DE102008043669A1 (de) | 2008-11-12 | 2008-11-12 | Verfahren zur Herstellung von ABA-Triblockcopolymeren mit einem breit verteilten B-Block |
DE102008043669.0 | 2008-11-12 | ||
PCT/EP2009/062927 WO2010054893A1 (de) | 2008-11-12 | 2009-10-06 | Verfahren zur herstellung von aba-triblockcopolymeren mit einem breit verteilten b-block. |
Publications (2)
Publication Number | Publication Date |
---|---|
CN102209736A CN102209736A (zh) | 2011-10-05 |
CN102209736B true CN102209736B (zh) | 2014-10-29 |
Family
ID=41288584
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN200980144196.9A Expired - Fee Related CN102209736B (zh) | 2008-11-12 | 2009-10-06 | 具有宽分布的b嵌段的aba三嵌段共聚物的制备方法 |
Country Status (8)
Country | Link |
---|---|
US (1) | US8829117B2 (zh) |
EP (1) | EP2344558B1 (zh) |
JP (1) | JP5717641B2 (zh) |
CN (1) | CN102209736B (zh) |
AU (1) | AU2009315872A1 (zh) |
BR (1) | BRPI0922044A2 (zh) |
DE (1) | DE102008043669A1 (zh) |
WO (1) | WO2010054893A1 (zh) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20130137142A (ko) * | 2010-08-03 | 2013-12-16 | 쉘 인터내셔날 리써취 마트샤피지 비.브이. | 중합체 폴리올의 제조 방법 |
US20150005466A1 (en) * | 2013-07-01 | 2015-01-01 | E I Du Pont De Nemours And Company | Ab block copolymer dispersants having an ink vehicle soluble block |
FI126972B (en) | 2014-04-11 | 2017-08-31 | Kemira Oyj | Water soluble crosslinked block copolymers |
US9587062B2 (en) | 2014-12-15 | 2017-03-07 | Henkel IP & Holding GmbH and Henkel AG & Co. KGaA | Photocrosslinkable block copolymers for hot-melt adhesives |
CN108417836B (zh) * | 2018-01-31 | 2021-05-04 | 闽南师范大学 | 一种锂离子电池的电极粘结剂及其制备方法 |
CN111971342A (zh) * | 2018-04-27 | 2020-11-20 | 东亚合成株式会社 | 固化性树脂组合物、以及嵌段共聚物及其制造方法 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7825199B1 (en) * | 1999-03-23 | 2010-11-02 | Carnegie Mellon University | Catalytic processes for the controlled polymerization of free radically (co)polymerizable monomers and functional polymeric systems prepared thereby |
Family Cites Families (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5807937A (en) | 1995-11-15 | 1998-09-15 | Carnegie Mellon University | Processes based on atom (or group) transfer radical polymerization and novel (co) polymers having useful structures and properties |
ATE207082T1 (de) | 1996-06-12 | 2001-11-15 | Univ Warwick | Polymerisation-katalysator und -verfahren |
TW593347B (en) | 1997-03-11 | 2004-06-21 | Univ Carnegie Mellon | Improvements in atom or group transfer radical polymerization |
WO1999015567A1 (fr) | 1997-09-22 | 1999-04-01 | Kaneka Corporation | Polymere, procede de production dudit polymere et composition durcissable contenant ledit polymere |
US6143848A (en) | 1997-10-23 | 2000-11-07 | The B.F.Goodrich Company | End-functionalized polymers by controlled free-radical polymerization process and polymers made therefrom |
DE69921651T2 (de) | 1998-03-27 | 2005-11-03 | Kaneka Corp. | Polymer und verfahren zur polymerherstellung |
DE69939959D1 (de) | 1998-09-02 | 2009-01-02 | Kaneka Corp | Polymer, Verfahren zu seiner Herstellung und Zusammensetzung |
EP1637550B1 (en) | 1999-03-23 | 2017-09-20 | Carnegie Mellon University | Catalytic processes for the controlled polymerization of free radically (co) polymerizable monomers and functional polymeric systems prepared thereby |
JP4447753B2 (ja) * | 2000-08-11 | 2010-04-07 | 株式会社カネカ | ブロック共重合体を含有する硬化性組成物 |
JP2002338625A (ja) * | 2001-05-14 | 2002-11-27 | Kanegafuchi Chem Ind Co Ltd | ブロック共重合体 |
TWI314934B (en) | 2002-02-13 | 2009-09-21 | Kaneka Corporatio | Polymer composition |
WO2003102077A1 (fr) | 2002-05-31 | 2003-12-11 | Asahi Denka Co., Ltd. | Composition de sol acrylique |
EP1433799A3 (en) * | 2002-12-23 | 2004-07-14 | Ucb, S.A. | Star shaped acrylic block copolymer |
JP2004203917A (ja) * | 2002-12-24 | 2004-07-22 | Mitsubishi Chemicals Corp | ミクロ相分離構造を形成するブロックポリマーおよびそれを用いた化粧料 |
DE10350786A1 (de) | 2003-10-29 | 2005-06-02 | Röhm GmbH & Co. KG | Mischungen zur Herstellung von Reaktivschmelzklebstoffen sowie daraus erhältliche Reaktivschmelzklebstoffe |
DE102005045458A1 (de) | 2005-09-22 | 2007-03-29 | Röhm Gmbh | Verfahren zur Herstellung von ABA-Triblockcopolymeren auf (Meth)acrylatbasis |
DE102006015846A1 (de) | 2006-04-03 | 2007-10-04 | Röhm Gmbh | Kupferentfernung aus ATRP-Produkten mittels Zugabe von Schwefelverbindungen |
DE102006035726A1 (de) | 2006-07-28 | 2008-01-31 | Evonik Röhm Gmbh | Verfahren zur Herstellung von ABA-Triblockcopolymeren auf (Meth)acrylatbasis |
DE102006037350A1 (de) | 2006-08-09 | 2008-02-14 | Evonik Röhm Gmbh | Verfahren zur Herstellung von halogenfreien ATRP-Produkten |
DE102006037352A1 (de) | 2006-08-09 | 2008-02-14 | Evonik Röhm Gmbh | Verfahren zur Herstellung von säureterminierten ATRP-Produkten |
DE102006037351A1 (de) | 2006-08-09 | 2008-02-14 | Evonik Röhm Gmbh | Verfahren zur Herstellung von hydroxytelecheler ATRP-Produkten |
DE102006048154A1 (de) | 2006-10-10 | 2008-04-17 | Evonik Röhm Gmbh | Verfahren zur Herstellung von silyltelechelen Polymeren |
DE102008002016A1 (de) | 2008-05-28 | 2009-12-03 | Evonik Röhm Gmbh | Verfahren zur Herstellung von silyl-funktionalisierten ABA-Triblockcopolymeren auf (Meth)acrylatbasis |
DE102008043668A1 (de) * | 2008-11-12 | 2010-05-20 | Evonik Röhm Gmbh | Verfahren zur Herstellung von ABA-Triblockcopolymeren mit einem bimodalen B-Block |
DE102008043674A1 (de) * | 2008-11-12 | 2010-05-20 | Evonik Röhm Gmbh | Verfahren zur Herstellung von Telechelen mit einer bimodalen Molekulkargewichtsverteilung |
DE102008043662A1 (de) * | 2008-11-12 | 2010-05-20 | Evonik Röhm Gmbh | Verfahren zur Herstellung von Telechelen mit breiter Molekulargewichtsverteilung |
-
2008
- 2008-11-12 DE DE102008043669A patent/DE102008043669A1/de not_active Withdrawn
-
2009
- 2009-10-06 AU AU2009315872A patent/AU2009315872A1/en not_active Abandoned
- 2009-10-06 CN CN200980144196.9A patent/CN102209736B/zh not_active Expired - Fee Related
- 2009-10-06 EP EP09783761.1A patent/EP2344558B1/de not_active Not-in-force
- 2009-10-06 WO PCT/EP2009/062927 patent/WO2010054893A1/de active Application Filing
- 2009-10-06 JP JP2011535942A patent/JP5717641B2/ja not_active Expired - Fee Related
- 2009-10-06 US US13/128,777 patent/US8829117B2/en not_active Expired - Fee Related
- 2009-10-06 BR BRPI0922044A patent/BRPI0922044A2/pt not_active Application Discontinuation
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7825199B1 (en) * | 1999-03-23 | 2010-11-02 | Carnegie Mellon University | Catalytic processes for the controlled polymerization of free radically (co)polymerizable monomers and functional polymeric systems prepared thereby |
Also Published As
Publication number | Publication date |
---|---|
WO2010054893A1 (de) | 2010-05-20 |
EP2344558A1 (de) | 2011-07-20 |
JP5717641B2 (ja) | 2015-05-13 |
JP2012508308A (ja) | 2012-04-05 |
EP2344558B1 (de) | 2013-07-03 |
US8829117B2 (en) | 2014-09-09 |
BRPI0922044A2 (pt) | 2015-12-22 |
CN102209736A (zh) | 2011-10-05 |
AU2009315872A1 (en) | 2010-05-20 |
DE102008043669A1 (de) | 2010-05-20 |
US20110282007A1 (en) | 2011-11-17 |
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