CN103711029A - Method for manufacturing aroma-increasing moisture retention cigarette paper - Google Patents

Method for manufacturing aroma-increasing moisture retention cigarette paper Download PDF

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CN103711029A
CN103711029A CN201310714874.9A CN201310714874A CN103711029A CN 103711029 A CN103711029 A CN 103711029A CN 201310714874 A CN201310714874 A CN 201310714874A CN 103711029 A CN103711029 A CN 103711029A
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cigarette paper
caco
flavouring
filler
modification
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CN103711029B (en
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刘德桃
陈进波
陈克复
阮蒙
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South China University of Technology SCUT
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South China University of Technology SCUT
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Abstract

The invention discloses a method for manufacturing aroma-increasing moisture retention cigarette paper. The method comprises the following steps: according to mass percent, firstly drying a CaCO3 filler till the moisture content of the filler is lower than 0.5%; emulsifying and modifying the dried CaCO3 filler under the effect of a stearic acid coupling agent for 0.5-3 minutes, dispersing 0.1-20% of tobacco extractive and fruit extractive relative to the mass percentage of the CaCO3 filler in an ethanol solution, loading an aroma-increasing component on the surface of the modified CaCO3 filler, and uniformly distributing the loaded and modified CaCO3 on paper by adopting a common papermaking technology, thus obtaining the aroma-increasing moisture retention cigarette paper. The method has the characteristics of good treatment effect, low cost, easy operation and the like; the produced novel aroma-increasing moisture retention cigarette paper has mellow fragrance, strong durability and improvement of quality of cigarettes; materials used in the method conform to the admittance criterion of additives for cigarette industries; and a relatively good processing effect can be obtained through the minor improvement in a production process.

Description

A kind of method of manufacturing flavouring humectation cigarette paper
Technical field
The present invention relates to a kind of cigarette paper, particularly relate to a kind of functions of increasing aroma and keeping lubrication cigarette paper and preparation method thereof, belong to flavored type cigarette products field.
Background technology
In the last few years, both at home and abroad researcher was mainly making be used as much work as the auxiliary material of reconstituted tobacoo using tobacco waste as offal, tobacco leaf, offal etc. and extract thereof, and had obtained some important achievement.As the people such as China An Rui (pacify auspicious, Xie Yimin, Wang Lei, Wang Fenglan, Yao Yuanjun, the preparation and property research of reconstituted tobacoo type cigarette paper, China's papermaking, 2012,31(1): 45 ?48) take offal and join and copy into reconstituted tobacoo type cigarette paper with a small amount of wood pulp as waste obtains chemi-mechanical pulp, to coat on cigarette paper through the extract of water extracting offal again making tobacco sheet type cigarette paper (26g/m 2), its wooden assorted gas reduces, and excitant reduces, and quality is got a promotion, but the active ingredient of load is volatile, and protecting Xiang Gong can be poor.(the Yang Shaowen such as Yang Shaowen, Huanghai Sea group, Luo Lili, Zhu Zizhong, Shen Jingxuan, Xiao Weiyi, the research and development of brown cigarette paper and application, tobacco science and technology, 2009,5:5 ?9) select to adopt the natural extract of tobacco extract, black tea, acorn nut husk, walnut shell, cocoa shell and food coloring etc. to prepare brown cigarette paper for toner, its chroma stability and additive to the fume indication of cigarette and suction quality without negative effect.Relevant scholar divides ascusization menthol by natural natural plants as peppermint extracting active ingredient and coats on cigarette body paper, making characteristic peppermint type cigarette tissue coats and on cigarette paper or reconstituted tobacoo, prepares mint type cigarette product (Huang Fu, Liu Bin, Wang Pingjun, the exploitation of characteristic peppermint type cigarette tissue and application, Chinese papermaking, 2012,31(1): 42 ?44), the parent who is subject to market looks at.And adopt the flavouring active component that fruit is extracted to make an addition in cigarette material, use and seldom have relevant research report.
But relevant scholar finds by research, by being organic matter by the active ingredient great majority of extracting, there is volatile feature, and mode by coating is added on cigarette paper or reconstituted tobacoo and easily produces fragrance and run off serious or be difficult to lasting serious consequence, and can cause the burn rate, degree of ventilation, puff number, master's (side) stream flue gas etc. of cigarette to be difficult to control.Therefore, adopting a kind of new technology to make to add to flavouring organic matter can protect lastingly fragrant, significantly strengthen fragrance satisfaction, therefore, guaranteeing under the prerequisite of regular-size cigarette paper normal configuration, by loading in cigarette paper of the high-purity glucosides class bonding state aroma substance extracting from fruit or tobacco, will give the new function of cigarette paper, prepare novel flavoring humectation function cigarette goods.And the high-purity glucosides class of this class bonding state aroma substance etc. can obtain in a large amount of fruit products from agricultural production completely, the new function cigarette paper of preparation will give cigarette different function impression and sensory evaluation.And China's research in this respect comparatively lacks, external in this respect due to the particularity of industry, most of achievement in research there is not yet report.
Summary of the invention
The object of the invention is to overcome the deficiency that prior art exists, provide a kind of fragrance lasting, functions of increasing aroma and keeping lubrication cigarette paper that cost is low and preparation method thereof.
For improving abundant, the lasting effect of fragrance of flavored type cigarette product, the present invention proposes the flavouring component of extracting from tobacco or fruit by coupling agent modified CaCO such as stearic acid 3filler load, prepares novel flavoring functional cigarette paper and cigarette by the regular-size cigarette technology of manufacturing paper with pulp, make it strength power full, protect aromatic thickly, promote the differentiation quality of cigarette product.Novel flavoring cigarette product flue gas continuous stability and the combustion process thermodynamic property of preparation.Can overcome that surface-coated method flavouring cigarette paper fragrance easily runs off, the deficiency of combustion heat poor stability.
The object of the invention is to be achieved through the following technical solutions:
Manufacture a method for flavouring humectation cigarette paper, it is characterized in that comprising the steps:
1) paddle dryer is processed: by percentage to the quality, and CaCO 3paddle dryer is processed to moisture content lower than 0.5%;
2) coupling modification: 3000 ?under 6000 revs/min of high-speed stirred, 40 ?at 80 ℃ of temperature, by dried CaCO 3filler is emulsification modification 0.5 ?30min under the effect of stearic acid coupling agent, is cooled to room temperature after modification; Described stearic acid addition is CaCO 3quality 0.1 ?5%;
3) extraction of tobacco extract: after tobacco sample section and pulverizing, adopt NaOH solution vibration extracting, after extracting 2 ℃ ?4 ℃ of cryogenic conditions lower seals preserve; Described tobacco sample is one or more in offal, tobacco leaf discarded object and offal;
4) fruit extract: obtain and squeeze the juice after banana, apple, strawberry, red bayberry, water chestnut, pear or coconut are squeezed the juice, resin adsorption is separated, and wash-out, obtains purified product, through 30 ℃ ?50 ℃ of low temperature dryings and 2 ℃ ?4 ℃ of low temperature preserve;
5) extract components load C aCO 3filler: will be with respect to CaCO 3packing quality percentage be 0.1 ?20% tobacco extract and fruit extract be scattered in ethanolic solution, by mulser medium speed, be 2000 ?mixed at high speed effect under 5000 revs/min of conditions, flavouring component is carried on to the CaCO of modification 3on filling surface; Described tobacco extract and fruit extract weight ratio 1 ?99%:1 ?99%;
6) manufacturing paper with pulp of flavouring cigarette paper: adopt common papermaking process by the flavouring component load C aCO of modification 3filler, softwood pulp, hemp are according to mass ratio (20 ?50%): (30 ?70%): (10 ?30%) prepare pulp suspension, the flavouring humectation cigarette paper of manufacturing paper with pulp to obtain.
For further realizing the object of the invention, preferably, described CaCO 3it is to be dried to moisture content lower than the concentration 0.2mol/L of NaOH solution described in 0.5% through 105 ℃ that paddle dryer is processed.Described vibration extracting adopt NaOH solution 50 ?with liquor ratio 10:1, carry out under 70 ℃ of conditions.Described resin adsorption separated with Amberlite XAD ?2 resin adsorption separated.Described wash-out adopts ether, pentane and carrene continuous backflow wash-out 3 times, each wash-out 60 ?360min, then through methanol-eluted fractions.Described pulp suspension is 0.1% by percentage to the quality.The time of described mixed at high speed effect be 30 ?40 minutes.The mass concentration of described ethanolic solution is 10%.
Compared with prior art, the present invention has following characteristics:
(1) method of the present invention is the CaCO making full use of in cigarette paper 3filler is modification body, and the flavouring component of extraction is loaded to CaCO by stearic acid 3on filling surface, production technology is simple, and cost is low, invests littlely, is easy to popularize.
(2) compare with traditional flavouring component rubbing method, adopt inner chemical carrying method can protect well fragrant flavouring, fragrance is lasting, improves the quality of cigarette product.
(3) to utilize tobacco or fruit be raw material in the present invention, adopts the method for low energy consumption, environmental protection to make full use of renewable plant resources, meets the requirement of national environmental protection and sustainable development.
Accompanying drawing explanation
Fig. 1 is embodiment 1 cigarette paper CaCO 3scanning electron microscope (SEM) photograph before modification;
Fig. 2 is embodiment 1 cigarette paper CaCO 3scanning electron microscope (SEM) photograph after modification;
Fig. 3 is embodiment 1 extract load C aCO 3rear scanning electron microscope (SEM) photograph.
The specific embodiment
For understanding better the present invention, below in conjunction with embodiment, the invention will be further described, but embodiments of the present invention are not limit so.
Embodiment 1
A method of manufacturing flavouring humectation cigarette paper, comprises the following steps:
1. cigarette paper CaCO 3the dry processing of filler: by percentage to the quality, CaCO 3filler is dried to moisture content lower than 0.5% through 105 ℃;
2. coupling modified technique: under 4000 revs/min of high-speed stirred conditions, by dried CaCO 3filler and stearic acid coupling agent mix, and under 50 ℃ of conditions, emulsification modification 30min, is cooled to room temperature after modification; Stearic acid coupling agent consumption is with respect to CaCO 3packing quality 4%; After tested, CaCO 3the activation grade of filler reaches 84%.Utilize hydrophobic changing features degree after calcium carbonate surface treatment to measure the coated activation degree on calcium carbonate surface.Concrete grammar is, take 2g sample, be placed in 250mL separatory funnel, add 200mL water, speed with 120 times/min comes and goes jolting 1min, then put down gently on funnel stand, standing 20min, after obvious layering, lower floor's mixture is put in advance at 105 ± 5 ℃ of crucible type filters that are dried to constant weight, suction filtration, except anhydrating, then moves into filter in insulating box, at 105 ± 5 ℃, is dried to constant weight.Activation grade is calculated as follows: X=[1 ?(m2 ?m1)/m] * 100; X ?the activation grade that represents with mass percent; M ?the quality g of calcium carbonate sample; M2 ?crucible and the quality g of coated caco3 (sinking part) not; M1 ?the quality g of crucible.
3. the extraction of tobacco extract: (1) tobacco extract: tobacco sample is offal; After above-mentioned tobacco sample is cut into slices respectively and pulverizing, dry with standby under 80 ℃ of conditions.Adopt above-mentioned tobacco leaf particle is vibrated under the 60 ℃ of conditions extracting (liquor ratio 10:1) of the NaOH solution of 0.2mol/L, after extracting, at 2 ℃ of cryogenic conditions lower seals, preserve;
4. fruit extract: obtain and squeeze the juice after banana is squeezed the juice, with Amberlite XAD ?2 resin adsorption be separated into basis, adopt ether, pentane and carrene continuous backflow wash-out 3 times (each 300min), through methanol-eluted fractions process, obtain purified product again, through low temperature drying (30 ℃) and low temperature, preserve (2 ℃).
5. extract components load C aCO 3the preparation technology of filler: will be with respect to CaCO 3packing quality percentage is that 10% tobacco extract and fruit extract (weight ratio 50%:50%) are scattered in ethanol (mass concentration is 10%), by being that under 3500 revs/min of conditions, mixed at high speed effect is carried on flavouring component the CaCO of modification at mulser medium speed 3on filling surface, temperature is room temperature condition.Figure 1 ?3 be CaCO 3(Fig. 1 is scanning electron microscope (SEM) photograph before modification to scanning electron microscope (SEM) photograph before and after modification; Fig. 2 is scanning electron microscope (SEM) photograph after modification; Fig. 3 is extract load C aCO 3rear scanning electron microscope (SEM) photograph).By the CaCO after stearic acid modified 3more coarse and some the imperceptible particle of grain surface texture adheres in its surface; And pass through after extract emulsification load, the attached full many superfine slight grains in its surface, and be regularly arranged.
Through detecting: extract is at modification CaCO 3load factor reaches 42%.The load factor on modified calcium carbonate surface is measured in utilization in the changes in weight degree before and after load through stearic acid modified calcium carbonate.Concrete grammar is to take the forward and backward modified calcium carbonate sample of 2g sample load extract and be placed at 40 ℃ of vacuumizes to constant weight, and weigh.Load factor is calculated as follows: X=[1 ?(m2 ?m1)/m] * 100; X ?the load factor that represents with mass percent; M2 ?the quality g of crucible and load extract post-modification calcium carbonate sample; M1 ?the quality g of modified calcium carbonate sample after load extract.
6. manufacturing paper with pulp of flavouring cigarette paper: adopt common papermaking process by the flavouring component load C aCO of step 4 modification 3filler, softwood pulp, hemp are according to mass ratio (30%): (50%): (20%) prepares 0.1% mass concentration pulp suspension is quantitatively 35g/cm according to manufacturing paper with pulp at sheet forming apparatus 2pattern, after dry to be detected.
After testing, by obtaining effective extract, can be carried on well CaCO 3on surface, cigarette paper sensory evaluating smoking evaluate well.Sensory evaluating smoking's method is to adopt whole round-robin method and method of comparison, just refers to while smokeing panel test that flue gas direct oral cavity sucks, throat swallows, nasal cavity is breathed out, and catches the overall process of flue gas feature.
Embodiment 2
New method and a production technology thereof of manufacturing flavouring humectation cigarette paper, it comprises the following steps:
1. cigarette paper CaCO 3the dry processing of filler, by percentage to the quality, CaCO 3through 105 ℃, be dried to moisture content lower than 0.5%.
2. coupling modified technique: by dried CaCO 3filler, will be with respect to CaCO under high-speed stirred (4000 revs/min) effect of emulsifying agent 3packing quality percentage is stearic acid emulsification modification 30min under 50 ℃ of conditions of 3%, is cooled to room temperature after modification;
3. the extraction of tobacco extract: tobacco sample is tobacco leaf; After tobacco sample is cut into slices respectively and pulverizing, adopt above-mentioned tobacco leaf particle is vibrated under the 60 ℃ of conditions extracting (liquor ratio 10:1) of 0.2mol/LNaOH solution, after extracting, at low temperature (2 ℃) condition lower seal, preserve;
4. fruit extract: obtain and squeeze the juice after apple is squeezed the juice, with Amberlite XAD ?2 resin adsorption be separated into basis, adopt ether, pentane and carrene continuous backflow wash-out 3 times (each 300min), through methanol-eluted fractions process, obtain purified product again, through low temperature drying (30 ℃) and low temperature, preserve (2 ℃).
5. extract components load C aCO 3the preparation technology of filler: will be with respect to CaCO 3packing quality percentage is that 15% tobacco extract and fruit extract are scattered in (weight ratio 1%:99%) ethanol (mass concentration is 10%), by flavouring component being carried on to the CaCO of modification in mulser high speed immixture 3on filling surface, emulsification rotating speed is 4500 revs/min, and temperature is room temperature condition.
6. manufacturing paper with pulp of flavouring cigarette paper: adopt common papermaking process by the flavouring component load C aCO of modification 3filler, softwood pulp, hemp are according to mass ratio (25%): (45%): (30%) prepares 0.1% concentration pulp suspension, according to manufacturing paper with pulp at sheet forming apparatus, be quantitatively 30 ?50g/cm 2pattern, after dry to be detected
After testing, adopt the method described in this example to obtain effective tobacco extract and fruit aroma component, and by the stearic acid modified CaCO that makes 3the activation grade of filler reaches 88%, and extraction components load factor reaches 56%, and cigarette paper sensory evaluating smoking evaluate well.
Embodiment 3
New method and a production technology thereof of manufacturing flavouring humectation cigarette paper, it comprises the following steps:
1. cigarette paper CaCO 3the dry processing of filler, by percentage to the quality, CaCO 3through 105 ℃, be dried to moisture content lower than 0.5%.
2. coupling modified technique: coupling modified technique: by dried CaCO 3filler, will be with respect to CaCO under high-speed stirred (4000 revs/min) effect of emulsifying agent 3packing quality percentage is stearic acid emulsification modification 30min under 50 ℃ of conditions of 5%, is cooled to room temperature after modification;
3. the extraction of tobacco extract: tobacco sample is offal; After above-mentioned tobacco sample is cut into slices respectively and pulverizing, adopt above-mentioned tobacco leaf particle is vibrated under the 60 ℃ of conditions extracting (liquor ratio 10:1) of 0.2mol/L NaOH solution, after extracting, at low temperature (2 ℃) condition lower seal, preserve;
4. fruit extract: obtain and squeeze the juice after strawberry is squeezed the juice, with Amberlite XAD ?2 resin adsorption be separated into basis, adopt ether, pentane and carrene continuous backflow wash-out 3 times (each 300min), through methanol-eluted fractions process, obtain purified product again, through low temperature drying (30 ℃) and low temperature, preserve (2 ℃).
5. extract components load C aCO 3the preparation technology of filler: will be with respect to CaCO 3packing quality percentage is that 20% tobacco extract and fruit extract (weight ratio 30%:70%) are scattered in ethanol (mass concentration is 10%), by flavouring component being carried on to the CaCO of modification in mulser high speed immixture 3on filling surface, emulsification rotating speed is 5000 revs/min, and temperature is room temperature condition.
5. manufacturing paper with pulp of flavouring cigarette paper: adopt common papermaking process by the flavouring component load C aCO of modification 3filler, softwood pulp, hemp are according to mass ratio (45%): (35%): (20%) prepares 0.1% concentration pulp suspension is quantitatively 35g/cm according to manufacturing paper with pulp at sheet forming apparatus 2pattern, after dry to be detected.
After testing, adopt the method described in this example to obtain effective tobacco extract and fruit aroma component, and by the stearic acid modified CaCO that makes 3the activation grade of filler reaches 94%, and flavouring active principle load factor reaches 48%, and cigarette paper sensory evaluating smoking evaluate well.
Embodiment 4
New method and a production technology thereof of manufacturing flavouring humectation cigarette paper, it comprises the following steps:
1. cigarette paper CaCO 3the dry processing of filler, by percentage to the quality, CaCO 3through 105 ℃, be dried to moisture content lower than 0.5%.
2. coupling modified technique: by dried CaCO 3filler, will be with respect to CaCO under high-speed stirred (6000 revs/min) effect of emulsifying agent 3packing quality percentage is stearic acid emulsification modification 30min under 80 ℃ of conditions of 5%, is cooled to room temperature after modification;
3. the extraction of tobacco extract: tobacco sample is offal and discarded object thereof; After above-mentioned tobacco sample is cut into slices respectively and pulverizing, adopt above-mentioned tobacco leaf particle is vibrated under the 60 ℃ of conditions extracting (liquor ratio 10:1) of 0.2mol/L NaOH solution, after extracting, at low temperature (2 ℃) condition lower seal, preserve;
4. fruit extract: obtain and squeeze the juice after red bayberry is squeezed the juice, with Amberlite XAD ?2 resin adsorption be separated into basis, adopt ether, pentane and carrene continuous backflow wash-out 3 times (each 300min), through methanol-eluted fractions process, obtain purified product again, through low temperature drying (30 ℃) and low temperature, preserve (2 ℃).
5. extract components load C aCO 3the preparation technology of filler: will be with respect to CaCO 3packing quality percentage is that 13% tobacco extract and fruit extract (weight ratio 99%:1%) are scattered in ethanol (mass concentration is 10%), by flavouring component being carried on to the CaCO of modification in mulser high speed immixture 3on filling surface, emulsification rotating speed is 3600 revs/min, and temperature is room temperature condition.
6. manufacturing paper with pulp of flavouring cigarette paper: adopt common papermaking process by the flavouring component load C aCO of modification 3filler, softwood pulp, hemp are according to mass ratio (35%): (35%): (30%) prepares 0.1% concentration pulp suspension is quantitatively 35g/cm according to manufacturing paper with pulp at sheet forming apparatus 2pattern, after dry to be detected.
After testing, adopt the method described in this example to obtain effective tobacco extract and fruit aroma component, and by the stearic acid modified CaCO that makes 3the activation grade of filler reaches 82%, and flavouring active principle load factor reaches 66%, and cigarette paper sensory evaluating smoking evaluate well.
Embodiment 5
New method and a production technology thereof of manufacturing flavouring humectation cigarette paper, it comprises the following steps:
1. cigarette paper CaCO 3the dry processing of filler, by percentage to the quality, CaCO 3through 105 ℃, be dried to moisture content lower than 0.5%.
2. coupling modified technique: by dried CaCO 3filler, will be with respect to CaCO under high-speed stirred (5500 revs/min) effect of emulsifying agent 3packing quality percentage is stearic acid emulsification modification 25min under 65 ℃ of conditions of 4.5%, is cooled to room temperature after modification;
3. the extraction of tobacco extract: tobacco sample is tobacco leaf and discarded object thereof; After above-mentioned tobacco sample is cut into slices respectively and pulverizing, adopt above-mentioned tobacco leaf particle is vibrated under the 65 ℃ of conditions extracting (liquor ratio 10:1) of 0.2mol/L NaOH solution, after extracting, at low temperature (2 ℃) condition lower seal, preserve;
4. fruit extract: obtain and squeeze the juice after water chestnut is squeezed the juice, with Amberlite XAD ?2 resin adsorption be separated into basis, adopt ether, pentane and carrene continuous backflow wash-out 3 times (each 320min), through methanol-eluted fractions process, obtain purified product again, through low temperature drying (30 ℃) and low temperature, preserve (2 ℃).
5. extract components load C aCO 3the preparation technology of filler: will be with respect to CaCO 3packing quality percentage is that 0.6% tobacco extract and fruit extract (weight ratio 20%:80%) are scattered in ethanol (mass concentration is 10%), by flavouring component being carried on to the CaCO of modification in mulser high speed immixture 3on filling surface, emulsification rotating speed is 3000 revs/min, and temperature is room temperature condition.
5. manufacturing paper with pulp of flavouring cigarette paper: adopt common papermaking process by the flavouring component load C aCO of modification 3filler, softwood pulp, hemp are according to mass ratio (25%): (65%): (10%) prepares 0.1% concentration pulp suspension is quantitatively 35g/cm according to manufacturing paper with pulp at sheet forming apparatus 2pattern, after dry to be detected.
After testing, adopt the method described in this example to obtain effective tobacco extract and fruit aroma component, and by the stearic acid modified CaCO that makes 3the activation grade of filler reaches 79%, and flavouring active principle load factor reaches 38%, and cigarette paper sensory evaluating smoking evaluates not good enough.
Embodiment 6
New method and a production technology thereof of manufacturing flavouring humectation cigarette paper, it comprises the following steps:
1. cigarette paper CaCO 3the dry processing of filler, by percentage to the quality, CaCO 3through 105 ℃, be dried to moisture content lower than 0.5%.
2. coupling modified technique: by dried CaCO 3filler, will be with respect to CaCO under high-speed stirred (5000 revs/min) effect of emulsifying agent 3packing quality percentage is stearic acid emulsification modification 26min under 80 ℃ of conditions of 2.5%, is cooled to room temperature after modification;
3. the extraction of tobacco extract: tobacco sample is offal and discarded object thereof; After above-mentioned tobacco sample is cut into slices respectively and pulverizing, adopt above-mentioned tobacco leaf particle is vibrated under the 80 ℃ of conditions extracting (liquor ratio 10:1) of 0.2mol/L NaOH solution, after extracting, at low temperature (2 ℃) condition lower seal, preserve;
4. fruit extract: obtain and squeeze the juice after pear is squeezed the juice, with Amberlite XAD ?2 resin adsorption be separated into basis, adopt ether, pentane and carrene continuous backflow wash-out 3 times (each 300min), through methanol-eluted fractions process, obtain purified product again, through low temperature drying (30 ℃) and low temperature, preserve (2 ℃).
5. extract components load C aCO 3the preparation technology of filler: will be with respect to CaCO 3packing quality percentage is that 5% tobacco extract and fruit extract (weight ratio 70%:30%) are scattered in ethanol (mass concentration is 10%), by flavouring component being carried on to the CaCO of modification in mulser high speed immixture 3on filling surface, emulsification rotating speed is 4000 revs/min, and temperature is room temperature condition.
6. manufacturing paper with pulp of flavouring cigarette paper: adopt common papermaking process by the flavouring component load C aCO of modification 3filler, softwood pulp, hemp are according to mass ratio (45%): (45%): (10%) prepares 0.1% concentration pulp suspension, according to manufacturing paper with pulp at sheet forming apparatus, be quantitatively 30 ?50g/cm 2pattern, after dry to be detected.
After testing, adopt the method described in this example to obtain effective tobacco extract and fruit aroma component, and by the stearic acid modified CaCO that makes 3the activation grade of filler reaches 81%, and flavouring active principle load factor reaches 69%, and cigarette paper sensory evaluating smoking evaluates good.
Embodiment 7
New method and a production technology thereof of manufacturing flavouring humectation cigarette paper, it comprises the following steps:
1. cigarette paper CaCO 3the dry processing of filler, by percentage to the quality, CaCO 3through 105 ℃, be dried to moisture content lower than 0.5%.
2. coupling modified technique: by dried CaCO 3filler, will be with respect to CaCO under high-speed stirred (3000 revs/min) effect of emulsifying agent 3packing quality percentage is stearic acid emulsification modification 30min under 80 ℃ of conditions of 5%, is cooled to room temperature after modification;
3. the extraction of tobacco extract: tobacco sample is offal; After tobacco sample is cut into slices respectively and pulverizing, adopt above-mentioned tobacco leaf particle is vibrated under the 60 ℃ of conditions extracting (liquor ratio 10:1) of 0.2mol/LNaOH solution, after extracting, at low temperature (2 ℃) condition lower seal, preserve;
4. fruit extract: obtain and squeeze the juice after coconut is squeezed the juice, with Amberlite XAD ?2 resin adsorption be separated into basis, adopt ether, pentane and carrene continuous backflow wash-out 3 times (each 60min), through methanol-eluted fractions process, obtain purified product again, through low temperature drying (30 ℃) and low temperature, preserve (2 ℃).
5. extract components load C aCO 3the preparation technology of filler: will be with respect to CaCO 3packing quality percentage is that 8% tobacco extract and fruit extract (weight ratio 40%:60%) are scattered in ethanol (mass concentration is 10%), by flavouring component being carried on to the CaCO of modification in mulser high speed immixture 3on filling surface, emulsification rotating speed be 2000 ?5000 revs/min, temperature is room temperature condition.
6. manufacturing paper with pulp of flavouring cigarette paper: adopt common papermaking process by the flavouring component load C aCO of modification 3filler, softwood pulp, hemp are according to mass ratio (35%): (50%): (15%) prepares 0.1% concentration pulp suspension is quantitatively 35g/cm according to manufacturing paper with pulp at sheet forming apparatus 2pattern, after dry to be detected.
After testing, adopt the method described in this example to obtain effective tobacco extract and fruit aroma component, and by the stearic acid modified CaCO that makes 3the activation grade of filler reaches 99%, and flavouring active principle load factor reaches 75%, and cigarette paper sensory evaluating smoking evaluates good.
Embodiment 8
New method and a production technology thereof of manufacturing flavouring humectation cigarette paper, it comprises the following steps:
1. cigarette paper CaCO 3the dry processing of filler, by percentage to the quality, CaCO 3through 105 ℃, be dried to moisture content lower than 0.5%.
2. coupling modified technique: by dried CaCO 3filler, will be with respect to CaCO under high-speed stirred (5000 revs/min) effect of emulsifying agent 3packing quality percentage is stearic acid emulsification modification 20min under 70 ℃ of conditions of 3.5%, is cooled to room temperature after modification;
3. the extraction of tobacco extract: tobacco sample is tobacco leaf; After tobacco sample is cut into slices respectively and pulverizing, adopt above-mentioned tobacco leaf particle is vibrated under the 55 ℃ of conditions extracting (liquor ratio 10:1) of 0.2mol/LNaOH solution, after extracting, at low temperature (2 ℃) condition lower seal, preserve;
4. fruit extract: obtain and squeeze the juice after banana and apple (mass ratio is 1:1) are squeezed the juice respectively, with Amberlite XAD ?2 resin adsorption be separated into basis, adopt ether, pentane and carrene continuous backflow wash-out 3 times (each 220min), through methanol-eluted fractions process, obtain purified product again, through low temperature drying (30 ℃) and low temperature, preserve (2 ℃).
5. extract components load C aCO 3the preparation technology of filler: will be with respect to CaCO 3packing quality percentage is that 10% tobacco extract and fruit extract (weight ratio 10%:90%) are scattered in ethanol (mass concentration is 10%), by flavouring component being carried on to the CaCO of modification in mulser high speed immixture 3on filling surface, emulsification rotating speed is 3500 revs/min, and temperature is room temperature condition.
6. manufacturing paper with pulp of flavouring cigarette paper: adopt common papermaking process by the flavouring component load C aCO of modification 3filler, softwood pulp, hemp are according to mass ratio (40%): (40%): (20%) prepares 0.1% concentration pulp suspension is quantitatively 35g/cm according to manufacturing paper with pulp at sheet forming apparatus 2pattern, after dry to be detected.
After testing, adopt the method described in this example to obtain effective tobacco extract and fruit aroma component, and by the stearic acid modified CaCO that makes 3the activation grade of filler reaches 91%, and flavouring active principle load factor reaches 68%, and cigarette paper sensory evaluating smoking evaluates good.
Embodiment 9
New method and a production technology thereof of manufacturing flavouring humectation cigarette paper, it comprises the following steps:
1. cigarette paper CaCO 3the dry processing of filler, by percentage to the quality, CaCO 3through 105 ℃, be dried to moisture content lower than 0.5%.
2. coupling modified technique: by dried CaCO 3filler, will be with respect to CaCO under high-speed stirred (5600 revs/min) effect of emulsifying agent 3packing quality percentage is stearic acid emulsification modification 25min under 75 ℃ of conditions of 4.5%, is cooled to room temperature after modification;
3. the extraction of tobacco extract: tobacco sample is offal; After above-mentioned tobacco sample is cut into slices respectively and pulverizing, adopt above-mentioned tobacco leaf particle is vibrated under the 60 ℃ of conditions extracting (liquor ratio 10:1) of 0.2mol/L NaOH solution, after extracting, at low temperature (2 ℃) condition lower seal, preserve;
4. fruit extract: obtain and squeeze the juice after banana, apple and strawberry (mass ratio 1:1:1) are squeezed the juice respectively, with Amberlite XAD ?2 resin adsorption be separated into basis, adopt ether, pentane and carrene continuous backflow wash-out 3 times (each 250min), through methanol-eluted fractions process, obtain purified product again, through low temperature drying (30 ℃) and low temperature, preserve (2 ℃).
5. extract components load C aCO 3the preparation technology of filler: will be with respect to CaCO 3packing quality percentage is that 20% tobacco extract and fruit extract (weight ratio 90%:10%) are scattered in ethanol (mass concentration is 10%), by flavouring component being carried on to the CaCO of modification in mulser high speed immixture 3on filling surface, emulsification rotating speed is 5000 revs/min, and temperature is room temperature condition.
6. manufacturing paper with pulp of flavouring cigarette paper: adopt common papermaking process by the flavouring component load C aCO of modification 3filler, softwood pulp, hemp are according to mass ratio (30%): (50%): (20%) prepares 0.1% concentration pulp suspension is quantitatively 35g/cm according to manufacturing paper with pulp at sheet forming apparatus 2pattern, after dry to be detected.
After testing, adopt the method described in this example to obtain effective tobacco extract and fruit aroma component, and by the stearic acid modified CaCO that makes 3the activation grade of filler reaches 96%, and flavouring active principle load factor reaches 77%, and cigarette paper sensory evaluating smoking evaluates good.
Embodiment 10
New method and a production technology thereof of manufacturing flavouring humectation cigarette paper, it comprises the following steps:
1. cigarette paper CaCO 3the dry processing of filler, by percentage to the quality, CaCO 3through 105 ℃, be dried to moisture content lower than 0.5%.
2. coupling modified technique: by dried CaCO 3filler, will be with respect to CaCO under high-speed stirred (5200 revs/min) effect of emulsifying agent 3packing quality percentage is stearic acid emulsification modification 10min under 65 ℃ of conditions of 3.5%, is cooled to room temperature after modification;
3. the extraction of tobacco extract: tobacco sample is offal, tobacco leaf or offal and discarded object thereof; After above-mentioned tobacco sample is cut into slices respectively and pulverizing, adopt above-mentioned tobacco leaf particle is vibrated under the 55 ℃ of conditions extracting (liquor ratio 10:1) of 0.2mol/L NaOH solution, after extracting, at low temperature (2 ℃) condition lower seal, preserve;
4. fruit extract: banana, apple, strawberry, red bayberry, water chestnut, pear, coconut (mass ratio is 1:1:1:1:1:1:1) are obtained and squeezed the juice after squeezing the juice respectively, with Amberlite XAD ?2 resin adsorption be separated into basis, adopt ether, pentane and carrene continuous backflow wash-out 3 times (each 220min), through methanol-eluted fractions process, obtain purified product again, through low temperature drying (30 ℃) and low temperature, preserve (2 ℃).
5. extract components load C aCO 3the preparation technology of filler: will be with respect to CaCO 3packing quality percentage is that 15% tobacco extract and fruit extract (weight ratio 50%:50%) are scattered in ethanol (mass concentration is 10%), by flavouring component being carried on to the CaCO of modification in mulser high speed immixture 3on filling surface, emulsification rotating speed is 4000 revs/min, and temperature is room temperature condition.
5. manufacturing paper with pulp of flavouring cigarette paper: adopt common papermaking process by the flavouring component load C aCO of modification 3filler, softwood pulp, hemp are according to mass ratio (40%): (50%): (10%) prepares 0.1% concentration pulp suspension is quantitatively 35g/cm according to manufacturing paper with pulp at sheet forming apparatus 2pattern, after dry to be detected.
After testing, adopt the method described in this example to obtain effective tobacco extract and fruit aroma component, and by the stearic acid modified CaCO that makes 3the activation grade of filler reaches 88%, and flavouring active principle load factor reaches 79%, and cigarette paper sensory evaluating smoking evaluates good.

Claims (9)

1. manufacture a method for flavouring humectation cigarette paper, it is characterized in that comprising the steps:
1) paddle dryer is processed: by percentage to the quality, and CaCO 3paddle dryer is processed to moisture content lower than 0.5%;
2) coupling modification: 3000 ?under 6000 revs/min of high-speed stirred, 40 ?at 80 ℃ of temperature, by dried CaCO 3filler is emulsification modification 0.5 ?30min under the effect of stearic acid coupling agent, is cooled to room temperature after modification; Described stearic acid addition is CaCO 3quality 0.1 ?5%;
3) extraction of tobacco extract: after tobacco sample section and pulverizing, adopt NaOH solution vibration extracting, after extracting 2 ℃ ?4 ℃ of cryogenic conditions lower seals preserve; Described tobacco sample is one or more in offal, tobacco leaf discarded object and offal;
4) fruit extract: obtain and squeeze the juice after banana, apple, strawberry, red bayberry, water chestnut, pear or coconut are squeezed the juice, resin adsorption is separated, and wash-out, obtains purified product, through 30 ℃ ?50 ℃ of low temperature dryings and 2 ℃ ?4 ℃ of low temperature preserve;
5) extract components load C aCO 3filler: will be with respect to CaCO 3packing quality percentage be 0.1 ?20% tobacco extract and fruit extract be scattered in ethanolic solution, by mulser medium speed, be 2000 ?mixed at high speed effect under 5000 revs/min of conditions, flavouring component is carried on to the CaCO of modification 3on filling surface; Described tobacco extract and fruit extract weight ratio 1 ?99%:1 ?99%;
6) manufacturing paper with pulp of flavouring cigarette paper: adopt common papermaking process by the flavouring component load C aCO of modification 3filler, softwood pulp, hemp are according to mass ratio (20 ?50%): (30 ?70%): (10 ?30%) prepare pulp suspension, the flavouring humectation cigarette paper of manufacturing paper with pulp to obtain.
2. the method for manufacture flavouring humectation cigarette paper according to claim 1, is characterized in that: described CaCO 3it is to be dried to moisture content lower than 0.5% through 105 ℃ that paddle dryer is processed.
3. the method for manufacture flavouring humectation cigarette paper according to claim 1, is characterized in that: the concentration 0.2mol/L of described NaOH solution.
4. the method for manufacture flavouring humectation cigarette paper according to claim 1, is characterized in that: described vibration extracting adopt NaOH solution 50 ?with liquor ratio 10:1, carry out under 70 ℃ of conditions.
5. the method for manufacture flavouring humectation cigarette paper according to claim 1, is characterized in that: described resin adsorption separated with Amberlite XAD ?2 resin adsorption separated.
6. the method for manufacture flavouring humectation cigarette paper according to claim 1, is characterized in that: described wash-out adopts ether, pentane and carrene continuous backflow wash-out 3 times, each wash-out 60 ?360min, then through methanol-eluted fractions.
7. the method for manufacture flavouring humectation cigarette paper according to claim 1, is characterized in that: described pulp suspension is 0.1% by percentage to the quality.
8. the method for manufacture flavouring humectation cigarette paper according to claim 1, is characterized in that: the time of described mixed at high speed effect be 30 ?40 minutes.
9. the method for manufacture flavouring humectation cigarette paper according to claim 1, is characterized in that: the mass concentration of described ethanolic solution is 10%.
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CN104126861A (en) * 2014-07-16 2014-11-05 湖南中烟工业有限责任公司 Application of coconut juice concentrate
CN105369692A (en) * 2015-11-20 2016-03-02 郭宏 Aloe vera cigarette paper and preparation method thereof
CN106235378A (en) * 2016-10-20 2016-12-21 云南瑞升烟草技术（集团）有限公司 The preparation method of a kind of filler flavouring auxiliary agent and the application in Medicated cigarette thereof
CN107419593A (en) * 2017-10-11 2017-12-01 云南中烟工业有限责任公司 A kind of sweet odor type cigarette paper and preparation method thereof
CN107476136A (en) * 2017-07-28 2017-12-15 河南中烟工业有限责任公司 A kind of milk fragrance cigarette paper and its preparation technology for having humectation and harm reduction function concurrently
CN107513891A (en) * 2017-07-28 2017-12-26 河南中烟工业有限责任公司 A kind of dried orange peel cigarette paper for having humectation function concurrently and preparation method thereof
CN107558303A (en) * 2017-07-28 2018-01-09 河南中烟工业有限责任公司 A kind of fruit perfume (or spice) cigarette paper for having humectation function concurrently and preparation method thereof
CN107604748A (en) * 2017-07-28 2018-01-19 河南中烟工业有限责任公司 A kind of roasting fragrant and sweet cigarette paper for having humectation function concurrently and preparation method thereof
CN107604762A (en) * 2017-07-28 2018-01-19 河南中烟工业有限责任公司 A kind of pungent fragrant cigarette paper for having humectation function concurrently and preparation method thereof
CN107653742A (en) * 2017-07-28 2018-02-02 河南中烟工业有限责任公司 A kind of fresh and sweet fragrant cigarette paper for having humectation function concurrently and preparation method thereof
CN107938435A (en) * 2017-11-21 2018-04-20 常州市鼎升环保科技有限公司 A kind of preparation method of odor type reducing tar cigarette paper
CN110130147A (en) * 2019-05-27 2019-08-16 安徽集友新材料股份有限公司 Cigarette tipping paper and preparation method thereof
CN110839936A (en) * 2019-11-28 2020-02-28 江苏中烟工业有限责任公司 Tobacco sheet coating liquid and application thereof in heating cigarette core material
CN113057369A (en) * 2021-04-28 2021-07-02 河南中烟工业有限责任公司 Paper filter stick and preparation method thereof

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CN104126861A (en) * 2014-07-16 2014-11-05 湖南中烟工业有限责任公司 Application of coconut juice concentrate
CN104126861B (en) * 2014-07-16 2016-03-23 湖南中烟工业有限责任公司 The application of coconut Normal juice concentrate
CN105369692A (en) * 2015-11-20 2016-03-02 郭宏 Aloe vera cigarette paper and preparation method thereof
CN105369692B (en) * 2015-11-20 2018-07-13 郭宏 A kind of aloe cigarette paper and preparation method thereof
CN106235378A (en) * 2016-10-20 2016-12-21 云南瑞升烟草技术（集团）有限公司 The preparation method of a kind of filler flavouring auxiliary agent and the application in Medicated cigarette thereof
CN106235378B (en) * 2016-10-20 2018-06-01 云南瑞升烟草技术（集团）有限公司 A kind of application of filler flavouring additives in cigarette
CN107604748A (en) * 2017-07-28 2018-01-19 河南中烟工业有限责任公司 A kind of roasting fragrant and sweet cigarette paper for having humectation function concurrently and preparation method thereof
CN107558303A (en) * 2017-07-28 2018-01-09 河南中烟工业有限责任公司 A kind of fruit perfume (or spice) cigarette paper for having humectation function concurrently and preparation method thereof
CN107513891A (en) * 2017-07-28 2017-12-26 河南中烟工业有限责任公司 A kind of dried orange peel cigarette paper for having humectation function concurrently and preparation method thereof
CN107604762A (en) * 2017-07-28 2018-01-19 河南中烟工业有限责任公司 A kind of pungent fragrant cigarette paper for having humectation function concurrently and preparation method thereof
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CN107476136A (en) * 2017-07-28 2017-12-15 河南中烟工业有限责任公司 A kind of milk fragrance cigarette paper and its preparation technology for having humectation and harm reduction function concurrently
CN107419593A (en) * 2017-10-11 2017-12-01 云南中烟工业有限责任公司 A kind of sweet odor type cigarette paper and preparation method thereof
CN107938435A (en) * 2017-11-21 2018-04-20 常州市鼎升环保科技有限公司 A kind of preparation method of odor type reducing tar cigarette paper
CN110130147A (en) * 2019-05-27 2019-08-16 安徽集友新材料股份有限公司 Cigarette tipping paper and preparation method thereof
CN110839936A (en) * 2019-11-28 2020-02-28 江苏中烟工业有限责任公司 Tobacco sheet coating liquid and application thereof in heating cigarette core material
CN110839936B (en) * 2019-11-28 2022-05-03 江苏中烟工业有限责任公司 Tobacco sheet coating liquid and application thereof in heating cigarette core material
CN113057369A (en) * 2021-04-28 2021-07-02 河南中烟工业有限责任公司 Paper filter stick and preparation method thereof

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