CN106235378A - The preparation method of a kind of filler flavouring auxiliary agent and the application in Medicated cigarette thereof - Google Patents

The preparation method of a kind of filler flavouring auxiliary agent and the application in Medicated cigarette thereof Download PDF

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Publication number
CN106235378A
CN106235378A CN201610915735.6A CN201610915735A CN106235378A CN 106235378 A CN106235378 A CN 106235378A CN 201610915735 A CN201610915735 A CN 201610915735A CN 106235378 A CN106235378 A CN 106235378A
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China
Prior art keywords
auxiliary agent
flavouring auxiliary
filler
flavouring
paper
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CN201610915735.6A
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Chinese (zh)
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CN106235378B (en
Inventor
吴景强
刘维娟
沈靖轩
肖维毅
尧珍玉
黄海群
徐兰兰
沈妍
刘琳
刘哲
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Yunnan Reascend Tobacco Technology Group Co Ltd
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Yunnan Reascend Tobacco Technology Group Co Ltd
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Priority to CN201610915735.6A priority Critical patent/CN106235378B/en
Publication of CN106235378A publication Critical patent/CN106235378A/en
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Classifications

    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24BMANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
    • A24B3/00Preparing tobacco in the factory
    • A24B3/14Forming reconstituted tobacco products, e.g. wrapper materials, sheets, imitation leaves, rods, cakes; Forms of such products
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24BMANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
    • A24B3/00Preparing tobacco in the factory
    • A24B3/12Steaming, curing, or flavouring tobacco

Abstract

The preparation method of a kind of filler flavouring auxiliary agent and the application in Medicated cigarette thereof, add heated and stirred in distilled water by the wall material of 0.1%~30% by mass percentage, obtain wall material solution;The flavoring substances that will be equivalent to wall material mass percent 1%~50% is slowly added in wall material solution, and stirs 4h under conditions of 50 DEG C, 500~2000r/min, by flavoring substances inclusion to the cavity of wall material, obtains inclusion solution;By spray-dried for inclusion solution prepared flavouring auxiliary agent.Flavoring substances is prepared flavouring auxiliary agent by embedding by the present invention, and production technology is simple, it is easy to promote.Flavouring auxiliary agent is applied in Medicated cigarette by the present invention with the form of filler, can reduce the volatility of flavoring substances, and when making flue gas aspirate, front and back end concentration is more uniform unanimously, improves the suction quality of Medicated cigarette.

Description

The preparation method of a kind of filler flavouring auxiliary agent and the application in Medicated cigarette thereof
Technical field
The invention belongs to Medicated cigarette packing technique field, be specifically related to the preparation of filler flavouring auxiliary agent and in Medicated cigarette Application.
Background technology
Flavouring humectation is an up the key technology of cigarette quality, is also one of nine key special subjects determining of industry.Medicated cigarette Type of aroma and style decide class and the grade of Medicated cigarette product, Medicated cigarette " flavouring " class essence and flavoring agent thing to a certain extent Matter, can make cigarette flavor amount get a promotion, Medicated cigarette note is increased or abundant, and the quality of Medicated cigarette is produced directly impact. But spices and essence material has volatility mostly, exist high volatility, the holdup time is short, the shelf-life is short, essence release inequality The problem such as even, the drawback that before and after making cigarette smoke release concentration exist, section is inconsistent, thus affect the raising of cigarette smoking quality And the range of application in Medicated cigarette.
Use microcapsule embedded technology to be embedded in the cavity of wall material by essence spice for cigarette, protect the same of this material Time also can improve its stability, reduce volatility, and make it slowly release fragrance under Medicated cigarette burns and sucks state or External Force Acting Composition, flavouring is effective, protect perfume persistently, discharge uniform effect to make essence and flavoring agent material reach, and gives Medicated cigarette and preferably aspirates Sensory experience.Filler can improve cigarette paper, the breathability of reconstituted tobacco chip base, opacity, whiteness, tensile property and even The indexs such as degree.By can also impart to its certain functional character to filler modified.The China of Publication No. CN103711029A Patent describes a kind of loaded modified CaCO3 filler, uses common papermaking process to prepare flavouring humectation cigarette paper, makes fragrance alcohol Thick, lasting, improve the quality of Medicated cigarette.Its filler modified method of described CaCO3 is to be carried on by mulser by flavor components Modified CaCO3Filling surface, but flavoring substances is not played protection and slow releasing function.In Publication No. CN103362033A State's patent discloses a kind of cigarette paper, and its described cigarette paper is will to cause the microcapsule that fragrant extract is prepared as having slow-release function, Then add during two pressures of Medicated cigarette copy paper and obtain.Wherein in microcapsule, flavor matter accounts for the 5% of beta-schardinger dextrin-quality, and 0.1% micro encapsulation causes fragrant mixed liquor interpolation quality and only accounts for the 0.1% of cigarette paper quality.Its described cause perfume (or spice) extract is at Medicated cigarette Interpolation in paper is range-restricted relatively big, and the allotment that may affect flavouring formula uses.
Existing Medicated cigarette filler aromatizing technology application effect is undesirable, and microcapsule perfuming technology is at cigarette paper, reconstituted tobacco In research less.
Summary of the invention
It is an object of the invention to make up the deficiencies in the prior art, improve the use limitation of flavoring substances, it is provided that Yi Zhongjuan The cigarette preparation method of flavouring filler and the application in Medicated cigarette.
For achieving the above object, the present invention adopts the following technical scheme that
The preparation method of a kind of filler flavouring auxiliary agent, comprises the steps:
(1) by mass percentage the wall material of 0.1%~30% is added heated and stirred in distilled water, obtain wall material solution;
(2) flavoring substances that will be equivalent to wall material mass percent 1%~50% is slowly added in wall material solution, and Stir 4h under conditions of 50 DEG C, 500~2000r/min, by flavoring substances inclusion to the cavity of wall material, obtain inclusion solution;
(3) by spray-dried for inclusion solution prepared flavouring auxiliary agent.
Wall material described in above-mentioned steps (1) is alpha-cyclodextrin, beta-schardinger dextrin-, gamma-cyclodextrin, HP-β-CD, sulphur One or more in fourth group-beta-cyclodextrin, resin and silica gel.Flavoring substances described in step (2) includes but not limited to Nicotiana tabacum L. Class absolute oil, senior this perfume of Nicotiana tabacum L., tree moss absolute, Flos Rosae Rugosae quintessence oil, oleum Citri sinensis, Oleum menthae, Fructus Citri Limoniae oil, Oleum Menthae Rotundifoliae, cognac are green Oil, dorinone, alpha, beta-lonone, Megastigmatrienone, linalool, isoamyl butyrate, lactone, β-caryophyllene, folic alcohol, Xin Kui One or more in acid glyceride.Described flavouring auxiliary agent is water-fast solid powdery material.
The filler flavouring auxiliary agent that the present invention prepares application in Medicated cigarette, is in the preparation process of cigarette paper Or in papermaking-method reconstituted tobaccos preparation process, flavouring auxiliary agent is added as filler.Described cigarette paper includes Medicated cigarette Paper, filter stick formation paper, cigarette tipping paper.
Flavouring auxiliary agent feed postition in cigarette paper preparation process can be use papermaking process by flavouring auxiliary agent, CaCO3, wood pulp cellulose, hemp according to quality than flavouring auxiliary agent: CaCO3: wood pulp cellulose: hemp is (10~35%): (5~40%): (40~75%): (0~45%) ratio mixes, and is prepared as pulp suspension, and then manufacturing paper with pulp obtains cigarette paper.Increase Fragrant auxiliary agent feed postition in papermaking-method reconstituted tobaccos preparation process can also reproduce cigarette for adding to manufacture paper with pulp by flavouring auxiliary agent In the tobacco slurry of blade base and mix homogeneously, papermaking-method reconstituted tobaccos of manufacturing paper with pulp to obtain;Flavouring auxiliary agent accounts for the matter of chip base oven dry weight Amount percentage ratio is 5~20%.
Compared with prior art, the invention have the advantages that
(1) by embedding, flavoring substances being prepared flavouring auxiliary agent, production technology is simple, it is easy to promote;
(2) comparing with traditional perfuming mode, flavouring auxiliary agent is applied in Medicated cigarette by the present invention with the form of filler, permissible Reducing the volatility of flavoring substances, when making flue gas aspirate, front and back end concentration is more uniform unanimously, improves the suction quality of Medicated cigarette;
(3) by preparing the flavouring auxiliary agent of filler, flavouring auxiliary agent can be expanded in cigarette paper, reconstituted tobacco Range of application, the filler for cigarette paper, reconstituted tobacco provides new form and new developing direction.
Detailed description of the invention
For being more fully understood that the present invention, below in conjunction with embodiment, the invention will be further described, but the reality of the present invention The mode of executing is not limited to this.
Implement row 1
By mass percentage the beta-schardinger dextrin-of 2% is added heated and stirred in distilled water, obtain beta-schardinger dextrin-solution, by phase In the Oleum menthae in beta-schardinger dextrin-mass percent 1% is slowly added into beta-schardinger dextrin-solution, and at 50 DEG C, 800r/min Under the conditions of stir 4h, by flavoring substances Oleum menthae inclusion to the cavity of beta-schardinger dextrin-, obtain inclusion solution;By inclusion solution warp It is spray-dried and prepares water-fast powder flavouring auxiliary agent.
The flavouring auxiliary agent of preparation uses regular-size cigarette paper papermaking process, by flavouring auxiliary agent, CaCO3, wood pulp cellulose, Fructus Cannabis fine Tie up according to quality than flavouring auxiliary agent: CaCO3: wood pulp cellulose: hemp=15%:10%:40%:45% is prepared as paper pulp and hangs Supernatant liquid, prepared cigarette paper of then manufacturing paper with pulp.
Implement row 2
By gamma-cyclodextrin heated and stirred in distilled water that mass percent is 3%, obtain gamma-cyclodextrin solution;By phase When in the oleum Citri sinensis of gamma-cyclodextrin mass percent 25%, isoamyl butyrate (quality is than oleum Citri sinensis: isoamyl butyrate=80%: 20%) be slowly added in gamma-cyclodextrin solution, and 50 DEG C, stir 4h under conditions of 1000r/min, by oleum Citri sinensis and fourth Isoamyl valerate inclusion, in the cavity of gamma-cyclodextrin, obtains inclusion solution;By spray-dried for inclusion solution prepared water insoluble Flavouring auxiliary agent.
The flavouring auxiliary agent of preparation uses regular-size cigarette paper papermaking process, by flavouring auxiliary agent, CaCO3, wood pulp cellulose, Fructus Cannabis fine Dimension is prepared as pulp suspension according to mass ratio 10%:5%:75%:10%, and then manufacturing paper with pulp obtains cigarette paper.
Implement row 3
By HP-β-CD heated and stirred in distilled water that mass percent is 30%, obtain hydroxy propyl-Beta-ring Dextrin solution;(Nicotiana tabacum L. is senior to will be equivalent to senior perfume (or spice) of Nicotiana tabacum L. of HP-β-CD mass percent 20% and Fructus Citri Limoniae oil This perfume: the mass ratio of Fructus Citri Limoniae oil is 80%:20%) it is slowly added in HP-β-CD solution, and at 50 DEG C, 500r/ Stirring 4h under conditions of min, obtain inclusion solution, reaction prepares flavouring auxiliary agent through spray drying after terminating.
By the flavouring auxiliary agent of preparation, by the 5% of the chip base oven dry weight tobacco slurry adding reconstituted tobacco chip base of manufacturing paper with pulp to In, mix homogeneously, papermaking-method reconstituted tobaccos of manufacturing paper with pulp to obtain.
Implement row 4
By resin heated and stirred in distilled water that mass percent is 0.1%, obtain resin solution;Will be equivalent to resin Senior this perfume of Nicotiana tabacum L. of mass percent 8%, tree moss absolute, Flos Rosae Rugosae quintessence oil, pungent certain herbaceous plants with big flowers acid glyceride 20%:10% in mass ratio: 10%:60% is slowly added in resin solution, and 50 DEG C, stir 4h under conditions of 2000r/min, obtain inclusion solution, Reaction prepares flavouring auxiliary agent through spray drying after terminating.
The flavouring auxiliary agent of preparation uses regular-size cigarette paper papermaking process, by flavouring auxiliary agent, CaCO3, wood pulp cellulose, Fructus Cannabis fine Dimension is prepared as pulp suspension according to mass ratio 35%:10%:45%:10%, manufactures paper with pulp and obtains cigarette tipping paper.
Implement row 5
By Sulfobutyl ether β _ cyclodextrin heated and stirred in distilled water that mass percent is 20%, obtain sulphur butyl-β-ring Dextrin solution;Will be equivalent to the cognac green oil of Sulfobutyl ether β _ cyclodextrin mass percent 50%, folic alcohol, pungent certain herbaceous plants with big flowers acid glyceride It is slowly added in Sulfobutyl ether β _ cyclodextrin solution after the mixing of 40%:10%:50% in mass ratio, and at 50 DEG C, 1000r/ Stir 4h under conditions of min, obtain inclusion solution;Reaction prepares flavouring auxiliary agent through spray drying after terminating.
By the flavouring auxiliary agent of preparation, by the 20% of the chip base oven dry weight tobacco slurry adding reconstituted tobacco chip base of manufacturing paper with pulp to In, mix homogeneously, papermaking-method reconstituted tobaccos of manufacturing paper with pulp to obtain.
Implement row 6
By alpha-cyclodextrin that mass percent is 5%, silica gel heated and stirred in distilled water of 10%, obtain alpha-cyclodextrin With the mixed solution of silica gel, will be equivalent to alpha-cyclodextrin and the dorinone of silica gel gross mass percentage ratio 20%, β-caryophyllene by Be slowly added in silica gel solution after mass ratio 50%:50% mixing, and 50 DEG C, stir 4h under conditions of 1500r/min, To inclusion solution;Reaction prepares flavouring auxiliary agent through spray drying after terminating.
The flavouring auxiliary agent of preparation uses regular-size cigarette paper papermaking process, by flavouring auxiliary agent, CaCO3, wood pulp cellulose is according to matter Amount is prepared as pulp suspension than 10%:40%:50%, manufactures paper with pulp and obtains filter stick formation paper.
Implement row 7
By mass percentage the beta-schardinger dextrin-of 10% is added heated and stirred in distilled water, obtain beta-schardinger dextrin-solution, will Gross mass is equivalent to the tobacco absolute oil of beta-schardinger dextrin-mass percent 5% and Oleum Menthae Rotundifoliae is slowly added into beta-schardinger dextrin-solution In, and 50 DEG C, stir 4h under conditions of 1200r/min, by the sky of tobacco absolute oil and Oleum Menthae Rotundifoliae inclusion to beta-schardinger dextrin- In chamber, obtain inclusion solution;By spray-dried for inclusion solution prepared flavouring auxiliary agent.
By the flavouring auxiliary agent of preparation, by the 10% of the chip base oven dry weight tobacco slurry adding reconstituted tobacco chip base of manufacturing paper with pulp to In, mix homogeneously, papermaking-method reconstituted tobaccos of manufacturing paper with pulp to obtain.
Flavoring substances used by the present invention can also is that alpha, beta-lonone, Megastigmatrienone, linalool, lactone material Deng.

Claims (8)

1. the filler preparation method of flavouring auxiliary agent, it is characterised in that comprise the steps:
(1) by mass percentage the wall material of 0.1%~30% is added heated and stirred in distilled water, obtain wall material solution;
(2) flavoring substances that will be equivalent to wall material mass percent 1%~50% is slowly added in wall material solution, and 50 DEG C, 500~2000r/min under conditions of stir 4h, by flavoring substances inclusion to the cavity of wall material, obtain inclusion solution;
(3) by spray-dried for inclusion solution prepared flavouring auxiliary agent.
The preparation method of a kind of filler flavouring auxiliary agent the most according to claim 1, it is characterised in that above-mentioned steps (1) Described wall material is alpha-cyclodextrin, beta-schardinger dextrin-, gamma-cyclodextrin, HP-β-CD, Sulfobutyl ether β _ cyclodextrin, resin With one or more in silica gel.
The preparation method of a kind of filler flavouring auxiliary agent the most according to claim 1, it is characterised in that above-mentioned steps (2) Described flavoring substances includes but not limited to tobacco absolute oil, senior this perfume of Nicotiana tabacum L., tree moss absolute, Flos Rosae Rugosae quintessence oil, oleum Citri sinensis, thin Lotus oil, Fructus Citri Limoniae oil, Oleum Menthae Rotundifoliae, cognac green oil, dorinone, alpha, beta-lonone, Megastigmatrienone, linalool, butanoic acid are different One or more in pentyl ester, lactone, β-caryophyllene, folic alcohol, pungent certain herbaceous plants with big flowers acid glyceride.
The preparation method of a kind of filler flavouring auxiliary agent the most according to claim 1, it is characterised in that described flavouring auxiliary agent For water-fast solid powdery material.
5. the filler flavouring auxiliary agent prepared such as any one of Claims 1 to 4 application in Medicated cigarette, its feature exists In, in the preparation process of cigarette paper or in papermaking-method reconstituted tobaccos preparation process, flavouring auxiliary agent is added as filler Add.
The filler flavouring auxiliary agent the most according to claim 5 application in Medicated cigarette, it is characterised in that described Medicated cigarette is used Paper includes cigarette paper, filter stick formation paper, cigarette tipping paper.
7. according to the flavouring auxiliary agent application in Medicated cigarette of the filler described in claim 5 or 6, it is characterised in that flavouring auxiliary agent Feed postition in cigarette paper preparation process is, uses papermaking process by flavouring auxiliary agent, CaCO3, wood pulp cellulose, Fructus Cannabis fine Tie up according to quality than flavouring auxiliary agent: CaCO3: wood pulp cellulose: hemp is (10~35%): (5~40%): (40~ 75%): (0~45%) ratio mixes, and is prepared as pulp suspension, and then manufacturing paper with pulp obtains cigarette paper.
The filler flavouring auxiliary agent the most according to claim 7 application in Medicated cigarette, it is characterised in that flavouring auxiliary agent is being made Feed postition in paper method reconstituted tobacco preparation process is that flavouring auxiliary agent adds to the tobacco slurry of reconstituted tobacco chip base of manufacturing paper with pulp In and mix homogeneously, papermaking-method reconstituted tobaccos of manufacturing paper with pulp to obtain;Flavouring auxiliary agent account for the mass percent of chip base oven dry weight be 5~ 20%.
CN201610915735.6A 2016-10-20 2016-10-20 A kind of application of filler flavouring additives in cigarette Active CN106235378B (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108929776A (en) * 2018-07-09 2018-12-04 浙江大学 A kind of long-acting incense-releasing nanoparticle and preparation method thereof
CN109797443A (en) * 2019-01-30 2019-05-24 湖北中烟工业有限责任公司 For heating the preparation method and application of the mint aroma fibrofelt in not burning tobacco
CN110710707A (en) * 2018-07-11 2020-01-21 湖南中烟工业有限责任公司 Method for preparing composite low-temperature cigarette with stable nicotine release
CN111838740A (en) * 2020-09-09 2020-10-30 吉林烟草工业有限责任公司 Method for improving aroma quality of paper-making reconstituted tobacco applied to papermaking forming section

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CN103362033A (en) * 2013-07-31 2013-10-23 广州市澳键丰泽生物科技有限公司 Cigarette paper
CN103396886A (en) * 2013-07-26 2013-11-20 湖北中烟工业有限责任公司 Compound microcapsule wall material and application thereof in essence microcapsules for cigarettes
CN103451999A (en) * 2013-09-06 2013-12-18 湖北中烟工业有限责任公司 Method for preparing colorful recombined tobacco leaf paper by microencapsulation of coating liquid
CN103451019A (en) * 2013-09-04 2013-12-18 湖北中烟工业有限责任公司 Microcapsule essence perfume for cigarettes as well as preparation method of microcapsule essence perfume
CN103711029A (en) * 2013-12-20 2014-04-09 华南理工大学 Method for manufacturing aroma-increasing moisture retention cigarette paper
CN105661626A (en) * 2016-03-25 2016-06-15 河南中烟工业有限责任公司 Composite biological agent microcapsule capable of improving sensory quality of tobacco
CN105925375A (en) * 2016-06-23 2016-09-07 云南中烟工业有限责任公司 Compound essence for cigarette as well as preparation method and purpose thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3550598A (en) * 1967-08-15 1970-12-29 James H Mcglumphy Reconstituted tobacco containing adherent encapsulated flavors and other matter
CN103396886A (en) * 2013-07-26 2013-11-20 湖北中烟工业有限责任公司 Compound microcapsule wall material and application thereof in essence microcapsules for cigarettes
CN103362033A (en) * 2013-07-31 2013-10-23 广州市澳键丰泽生物科技有限公司 Cigarette paper
CN103451019A (en) * 2013-09-04 2013-12-18 湖北中烟工业有限责任公司 Microcapsule essence perfume for cigarettes as well as preparation method of microcapsule essence perfume
CN103451999A (en) * 2013-09-06 2013-12-18 湖北中烟工业有限责任公司 Method for preparing colorful recombined tobacco leaf paper by microencapsulation of coating liquid
CN103711029A (en) * 2013-12-20 2014-04-09 华南理工大学 Method for manufacturing aroma-increasing moisture retention cigarette paper
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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108929776A (en) * 2018-07-09 2018-12-04 浙江大学 A kind of long-acting incense-releasing nanoparticle and preparation method thereof
CN108929776B (en) * 2018-07-09 2021-04-30 浙江大学 Long-acting fragrance-releasing nano particle and preparation method thereof
CN110710707A (en) * 2018-07-11 2020-01-21 湖南中烟工业有限责任公司 Method for preparing composite low-temperature cigarette with stable nicotine release
CN109797443A (en) * 2019-01-30 2019-05-24 湖北中烟工业有限责任公司 For heating the preparation method and application of the mint aroma fibrofelt in not burning tobacco
CN111838740A (en) * 2020-09-09 2020-10-30 吉林烟草工业有限责任公司 Method for improving aroma quality of paper-making reconstituted tobacco applied to papermaking forming section
CN111838740B (en) * 2020-09-09 2022-05-13 吉林烟草工业有限责任公司 Method for improving aroma quality of paper-making reconstituted tobacco applied to papermaking forming section

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