CN103396886A - Compound microcapsule wall material and application thereof in essence microcapsules for cigarettes - Google Patents
Compound microcapsule wall material and application thereof in essence microcapsules for cigarettes Download PDFInfo
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- CN103396886A CN103396886A CN2013103192795A CN201310319279A CN103396886A CN 103396886 A CN103396886 A CN 103396886A CN 2013103192795 A CN2013103192795 A CN 2013103192795A CN 201310319279 A CN201310319279 A CN 201310319279A CN 103396886 A CN103396886 A CN 103396886A
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- 239000000463 material Substances 0.000 title claims abstract description 64
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- 150000001875 compounds Chemical class 0.000 title abstract 4
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229920002472 Starch Polymers 0.000 claims abstract description 11
- 235000010489 acacia gum Nutrition 0.000 claims abstract description 11
- 235000010413 sodium alginate Nutrition 0.000 claims abstract description 11
- 239000000661 sodium alginate Substances 0.000 claims abstract description 11
- 229940005550 sodium alginate Drugs 0.000 claims abstract description 11
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- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims abstract description 10
- 229930006000 Sucrose Natural products 0.000 claims abstract description 10
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- 229920001285 xanthan gum Polymers 0.000 claims abstract description 10
- 229940082509 xanthan gum Drugs 0.000 claims abstract description 10
- 241000208125 Nicotiana Species 0.000 claims description 32
- 235000002637 Nicotiana tabacum Nutrition 0.000 claims description 32
- 239000000839 emulsion Substances 0.000 claims description 25
- 230000001804 emulsifying effect Effects 0.000 claims description 11
- 244000215068 Acacia senegal Species 0.000 claims description 10
- 229920000084 Gum arabic Polymers 0.000 claims description 10
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- 239000007787 solid Substances 0.000 claims description 10
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- 229920003109 sodium starch glycolate Polymers 0.000 claims description 9
- 229940032147 starch Drugs 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 9
- 239000005720 sucrose Substances 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- 239000003921 oil Substances 0.000 claims description 8
- 235000019198 oils Nutrition 0.000 claims description 8
- NOOLISFMXDJSKH-UTLUCORTSA-N (+)-Neomenthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@@H]1O NOOLISFMXDJSKH-UTLUCORTSA-N 0.000 claims description 7
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 claims description 7
- 229940041616 menthol Drugs 0.000 claims description 7
- 241000628997 Flos Species 0.000 claims description 5
- 240000006927 Foeniculum vulgare Species 0.000 claims description 5
- 235000002782 Foeniculum vulgare var dulce Nutrition 0.000 claims description 5
- 235000019501 Lemon oil Nutrition 0.000 claims description 5
- 239000010643 fennel seed oil Substances 0.000 claims description 5
- 239000010501 lemon oil Substances 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims description 4
- 240000004760 Pimpinella anisum Species 0.000 claims description 3
- 235000012550 Pimpinella anisum Nutrition 0.000 claims description 3
- FFBHFFJDDLITSX-UHFFFAOYSA-N benzyl N-[2-hydroxy-4-(3-oxomorpholin-4-yl)phenyl]carbamate Chemical compound OC1=C(NC(=O)OCC2=CC=CC=C2)C=CC(=C1)N1CCOCC1=O FFBHFFJDDLITSX-UHFFFAOYSA-N 0.000 claims description 3
- 238000000265 homogenisation Methods 0.000 claims description 3
- 235000005976 Citrus sinensis Nutrition 0.000 claims description 2
- 240000002319 Citrus sinensis Species 0.000 claims description 2
- 239000010502 orange oil Substances 0.000 claims description 2
- 239000002245 particle Substances 0.000 abstract description 8
- 102000011632 Caseins Human genes 0.000 abstract description 7
- 108010076119 Caseins Proteins 0.000 abstract description 7
- 229940080237 sodium caseinate Drugs 0.000 abstract description 7
- GUOCOOQWZHQBJI-UHFFFAOYSA-N 4-oct-7-enoxy-4-oxobutanoic acid Chemical compound OC(=O)CCC(=O)OCCCCCCC=C GUOCOOQWZHQBJI-UHFFFAOYSA-N 0.000 abstract description 6
- 239000005913 Maltodextrin Substances 0.000 abstract description 6
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- 102000004169 proteins and genes Human genes 0.000 abstract description 2
- 239000001785 acacia senegal l. willd gum Substances 0.000 abstract 1
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- 206010011732 Cyst Diseases 0.000 description 9
- 208000031513 cyst Diseases 0.000 description 9
- 239000003205 fragrance Substances 0.000 description 7
- 230000014759 maintenance of location Effects 0.000 description 7
- 238000000034 method Methods 0.000 description 7
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- 239000000205 acacia gum Substances 0.000 description 6
- 238000001694 spray drying Methods 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 5
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- 238000005516 engineering process Methods 0.000 description 3
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- 125000003118 aryl group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 235000013871 bee wax Nutrition 0.000 description 1
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Abstract
The invention provides a compound microcapsule wall material and an application thereof in essence microcapsules for cigarettes. The compound microcapsule wall material is mixed by the following components in percentage by weight: 30.0-50.0% of starch octenylsuccinate, 15.0-30.0% of maltodextrin, 10.0-30.0% of sodium carboxymethyl starch, 10.0-30.0% of soy isolate protein, 1.0-5.0% of Arabic gum, 1.0-5.0% of sodium caseinate, 1.0-5.0% of saccharose, 0.1-0.5% of sodium alginate, 0.1-0.5% of xanthan gum and 0.1-0.5% of pullulan. The compound microcapsule wall material provided by the invention is good in solubleness, good in emulsibility, good in film-forming property, low in solution viscosity, and economical and practical benefits. Higher embedding rate can be obtained by using the wall material to prepare the essence microcapsules for cigarettes, and the product is good in sensory performance, smooth and uniform in particle, compact in capsule wall, lower in moisture content, good in dispersibility and stronger in practicality.
Description
Technical field
The invention belongs to technical field of cigarette flavors, specifically refer to a kind of Compositional type microcapsule wall material and the application in the flavouring essence for tobacco microcapsule thereof.
Background technology
The flavouring essence for tobacco majority is volatile aromatic liquid class material, and its fragrance or fragrance can be considered as " soul " of Chinese-style cigarette.Because the most of composition in flavouring essence for tobacco has very strong volatility, to light, heat, oxygen sensitivity, easy and other component generation chemical reactions, be easy to cause odor type distortion or fragrance to weaken.These drawbacks limit its application in cigarette composition, simultaneously the volatilization because of essence escapes the life-span that can shorten cigarette between the shelf lives.Therefore people urgently wish to search out a kind of method that can well protect flavouring essence for tobacco, improve its stability and processibility.
Microcapsulary is to utilize macromolecular material (wall material), with solid or liquid (core) through the formed a kind of technology with minigel of semipermeability or sealing cyst membrane of packing.With flavouring essence for tobacco after micro encapsulation is processed, the sealing function of cyst wall can effectively suppress the volatilization loss of essence, reduce contacting of susceptibility material and external environment, greatly improve oxytolerant, fast light and heat-resisting ability, thereby increase the stability of essence storage and use; Can change simultaneously the physical aspect of essence under normal temperature, make liquid or semi-solid essence change free-pouring powder into, improve its dispersion stabilization.In addition, micro encapsulation can make flavouring essence for tobacco have slow-release function, very sufficient and the phenomenon that after for some time, fragrance obviously weakens of fragrance in the time of can avoiding occurring just starting.
Spray-drying process prepares wall material commonly used in the essence microcapsule technology vegetable jelly class (gum arabic, sodium alginate, carrageenin etc.), carbohydrate (dextrin, oligose, derivatived cellulose class, modified starch etc.), protein-based (gelatin, sodium-caseinate, soybean protein, whey-protein etc.), lipid (paraffin, beeswax, Yelkin TTS etc.).A kind of desirable essence microcapsule wall material should possess following character: 1) stable, nontoxic, tasteless, the nonirritant of material property; 2) good solubility, emulsifying stability, moulding property; 3) can be compatible with essence but chemical reaction does not occur; 4) possesses good rheological property (low viscosity) under high density; 5) source is sufficient, and is cheap.But, almost do not have a kind of wall material can meet simultaneously above all character; Use certain single wall material not only expensive, and be difficult to reach the embedding effect of expection.Therefore, in production application, can be in conjunction with the relative merits of various single wall materials,, according to certain proportioning, select two or more wall material to unite and make to prepare the essence microcapsule product, to reaching desirable embedding effect.
Summary of the invention
The objective of the invention is the deficiency according to existing single wall material, provide that a kind of solvability is good, emulsifying property is good, moulding property is good, low viscosity, economical and practical Compositional type microcapsule wall material.
For achieving the above object, Compositional type microcapsule wall material provided by the invention is characterized in that: it is to be mixed by mass percentage by following component: 30.0 ~ 50.0% starch octenylsuccinates, 15.0 ~ 30.0% maltodextrins, 10.0 ~ 30.0% sodium starch glycolatees, 10.0 ~ 30.0% soybean protein isolates, 1.0 ~ 5.0% gum arabics, 1.0 ~ 5.0% sodium-caseinates, 1.0 ~ 5.0% sucrose, 0.1 ~ 0.5% sodium alginate, 0.1 ~ 0.5% xanthan gum, 0.1 ~ 0.5% pullulan.
As preferred version, described Compositional type microcapsule wall material, it is to be mixed by mass percentage by following component: 30.0 ~ 45.0% starch octenylsuccinates, 20.0 ~ 30.0% maltodextrins, 15.0 ~ 20.0% sodium starch glycolatees, 12.0 ~ 15.0% soybean protein isolates, 1.0 ~ 2.0% gum arabics, 2.0 ~ 3.0% sodium-caseinates, 1.0 ~ 2.0% sucrose, 0.2 ~ 0.4% sodium alginate, 0.3 ~ 0.5% xanthan gum, 0.1 ~ 0.5% pullulan.
The present invention also provides a kind of as the application of above-mentioned Compositional type microcapsule wall material in the flavouring essence for tobacco microcapsule, it is characterized in that: above-mentioned Compositional type microcapsule wall material is scattered in water to form solid content be 15 ~ 35% wall material solution by mass percentage, after solid substance fully dissolves again in essence: wall material mass ratio is that the ratio of 1:4 ~ 1:10 adds flavouring essence for tobacco, is prepared into emulsion after stirring; Finally with the spray-dried flavouring essence for tobacco microcapsule that prepare of above-mentioned emulsion.
The present invention also provides another kind of as the application of above-mentioned Compositional type microcapsule wall material in the flavouring essence for tobacco microcapsule, it is characterized in that: above-mentioned Compositional type microcapsule wall material is dissolved in the water, and to form solid content be 20 ~ 25% wall material solution, after solid substance fully dissolves again in flavouring essence for tobacco: wall material mass ratio is that the ratio of 1:5 ~ 1:8 adds essence, makes emulsion after stirring; Finally with the spray-dried flavouring essence for tobacco microcapsule that prepare of above-mentioned emulsion.
As preferred version, the described emulsion for preparing is first to use the high-speed emulsifying homogeneous machine at 10000 ~ 15000rpm condition down cut, 1 ~ 3min, prepares thick emulsion; Be 25 ~ 35MPa under to process 1 ~ 2 time obtain emulsion to thick emulsion at homogenization pressure with the super-voltage micro jet clarifixator again.
Further, described spray-dired inlet temperature is 160 ~ 180 ℃, and air outlet temperature is 70 ~ 80 ℃, and input speed is 5 ~ 10mL/min.
Further, described flavouring essence for tobacco is the easy volatile flavouring essence for tobacco.
Further, described flavouring essence for tobacco is California lemon oil, Flos Caryophylli oil, Sweet fennel oil, star aniseed oil, menthol or sweet orange oil.
The invention has the advantages that: the Compositional type microcapsule wall material of the present invention's preparation has the advantages such as solvability is good, emulsifying property is good, moulding property is good, soltion viscosity is low, economical and practical.Use this wall material to prepare the flavouring essence for tobacco microcapsule and have higher embedding rate, and the organoleptic properties of product is good, have fine and smooth even, the advantages such as cyst wall is fine and close, moisture content is lower, good dispersity of particle, the stability that can improve the essence storage simultaneously and use, extend the retention time of fragrance, have stronger practicality.
Embodiment
The present invention is described in further detail below in conjunction with specific embodiment.
Embodiment one:
Compositional type microcapsule wall material 1 of the present invention is mixed by mass percentage by following component: 45.0% starch octenylsuccinate, 20.0% maltodextrin, 15.0% sodium starch glycolate, 12.0% soybean protein isolate, 2.0% gum arabic, 3.0% sodium-caseinate, 2.0% sucrose, 0.2% sodium alginate, 0.3% xanthan gum, 0.5% pullulan.
Get 60g Compositional type wall material 1 and be dissolved in formation wall material solution in 340mL water, add 12g California lemon oil after fully stirring.First use the high-speed emulsifying homogeneous machine at 15000rpm condition down cut 2min; Re-using the super-voltage micro jet clarifixator processes 1 time under pressure 35MPa condition.The emulsion of gained is carried out spray drying treatment, and inlet temperature is 180 ℃, 80 ℃ of air outlet temperatures, input speed 5mL/min.Collect California lemon oil microcapsule product and sealing preservation.
The California lemon oil microcapsule product of above-mentioned gained has good organoleptic properties, and particle is fine and smooth, even, and cyst wall is fine and close, and drier, without caking phenomenon, mobility is better, and its embedding rate reaches 94.5%; After storing six months under 25 ℃ of conditions, the essence retention rate is 92.1%.
Embodiment two:
Compositional type microcapsule wall material 2 of the present invention is mixed by mass percentage by following component: 30.0% starch octenylsuccinate, 30.0% maltodextrin, 20.0% sodium starch glycolate, 15.0% soybean protein isolate, 1.0% gum arabic, 2.0% sodium-caseinate, 1.0% sucrose, 0.4% sodium alginate, 0.5% xanthan gum, 0.1% pullulan.
Get 80g Compositional type wall material 2 and be dissolved in formation wall material solution in 320mL water, add the 12g Flos Caryophylli oil after fully stirring.First use the high-speed emulsifying homogeneous machine at 10000rpm condition down cut 3min; Re-using the super-voltage micro jet clarifixator processes 2 times under pressure 25MPa condition.The emulsion of gained is carried out spray drying treatment, and inlet temperature is 175 ℃, 70 ℃ of air outlet temperatures, input speed 7mL/min.Collect Flos Caryophylli oil microcapsule product and sealing preservation.
The Flos Caryophylli oil microcapsule product of above-mentioned gained has good organoleptic properties, and particle is fine and smooth, even, and cyst wall is fine and close, and drier, without caking phenomenon, mobility is better, and its embedding rate reaches 96.1%; After storing six months under 25 ℃ of conditions, the essence retention rate is 93.5%.
Embodiment three:
Compositional type microcapsule wall material 3 of the present invention is mixed by mass percentage by following component: 30.0% starch octenylsuccinate, 15.0% maltodextrin, 30.0% sodium starch glycolate, 10.0% soybean protein isolate, 5.0% gum arabic, 5.0% sodium-caseinate, 3.9% sucrose, 0.1% sodium alginate, 0.5% xanthan gum, 0.5% pullulan.
Get 70g Compositional type wall material 3 and be dissolved in formation wall material solution in 230mL water, add 10g Sweet fennel oil after fully stirring.First use the high-speed emulsifying homogeneous machine at 12000rpm condition down cut 2min; Re-using the super-voltage micro jet clarifixator processes 2 times under pressure 25MPa condition.The emulsion of gained is carried out spray drying treatment, and inlet temperature is 165 ℃, 75 ℃ of air outlet temperatures, input speed 9mL/min.Collect Sweet fennel oil microcapsule product and sealing preservation.
The Sweet fennel oil microcapsule product of above-mentioned gained has good organoleptic properties, and particle is fine and smooth, even, and cyst wall is fine and close, and drier, without caking phenomenon, mobility is better, and its embedding rate reaches 94.6%; After storing six months under 25 ℃ of conditions, the essence retention rate is 92.8%.
Embodiment four:
Compositional type microcapsule wall material 4 of the present invention is mixed by mass percentage by following component: 50.0% starch octenylsuccinate, 25.0% maltodextrin, 10.0% sodium starch glycolate, 10.0% soybean protein isolate, 1.0% gum arabic, 1.0% sodium-caseinate, 2.0% sucrose, 0.4% sodium alginate, 0.2% xanthan gum, 0.4% pullulan.
Get 100g Compositional type microcapsule wall material 4 and be dissolved in formation wall material solution in 300mL water, add the 10g menthol after fully stirring.First use the high-speed emulsifying homogeneous machine at 15000rpm condition down cut 1min; Re-using the super-voltage micro jet clarifixator processes 1 time under pressure 30MPa condition.The emulsion of gained is carried out spray drying treatment, and inlet temperature is 160 ℃, 80 ℃ of air outlet temperatures, input speed 10mL/min.Collect menthol microcapsules product and sealing preservation.
The star aniseed oil microcapsule product of above-mentioned gained has good organoleptic properties, and particle is fine and smooth, even, and cyst wall is fine and close, and drier, without caking phenomenon, mobility is better, and its embedding rate reaches 93.7%; After storing six months under 25 ℃ of conditions, the essence retention rate is 92.2%.
Embodiment five:
Compositional type microcapsule wall material 5 of the present invention is mixed by mass percentage by following component: 30.0% starch octenylsuccinate, 25.0% maltodextrin, 10.0% sodium starch glycolate, 30.0% soybean protein isolate, 1.0% gum arabic, 1.0% sodium-caseinate, 2.0% sucrose, 0.5% sodium alginate, 0.1% xanthan gum, 0.4% pullulan.
Get 120g Compositional type microcapsule wall material 5 and be dissolved in formation wall material solution in 600mL water, add the 15g menthol after fully stirring.First use the high-speed emulsifying homogeneous machine at 15000rpm condition down cut 1min; Re-using the super-voltage micro jet clarifixator processes 1 time under pressure 30MPa condition.The emulsion of gained is carried out spray drying treatment, and inlet temperature is 160 ℃, 80 ℃ of air outlet temperatures, input speed 10mL/min.Collect menthol microcapsules product and sealing preservation.
The menthol microcapsules product of above-mentioned gained has good organoleptic properties, and particle is fine and smooth, even, and cyst wall is fine and close, and drier, without caking phenomenon, mobility is better, and its embedding rate reaches 94.3%; After storing six months under 25 ℃ of conditions, the essence retention rate is 92.1%.
As can be seen from the above-described embodiment, the preparation method of Compositional type microcapsule wall material of the present invention is simple, and is easy to operate, economical and practical.Use this wall material to prepare the flavouring essence for tobacco microcapsule and have higher embedding rate, and the organoleptic properties of product is good, have fine and smooth even, the advantages such as cyst wall is fine and close, moisture content is lower, good dispersity of particle, the stability that can improve the essence storage simultaneously and use, extend the retention time of fragrance, have stronger practicality.
Claims (9)
1. Compositional type microcapsule wall material, it is characterized in that: it is to be mixed by mass percentage by following component: 30.0 ~ 50.0% starch octenylsuccinates, 15.0 ~ 30.0% maltodextrins, 10.0 ~ 30.0% sodium starch glycolatees, 10.0 ~ 30.0% soybean protein isolates, 1.0 ~ 5.0% gum arabics, 1.0 ~ 5.0% sodium-caseinates, 1.0 ~ 5.0% sucrose, 0.1 ~ 0.5% sodium alginate, 0.1 ~ 0.5% xanthan gum, 0.1 ~ 0.5% pullulan.
2. Compositional type microcapsule wall material according to claim 1, it is characterized in that: it is to be mixed by mass percentage by following component: 30.0 ~ 45.0% starch octenylsuccinates, 20.0 ~ 30.0% maltodextrins, 15.0 ~ 20.0% sodium starch glycolatees, 12.0 ~ 15.0% soybean protein isolates, 1.0 ~ 2.0% gum arabics, 2.0 ~ 3.0% sodium-caseinates, 1.0 ~ 2.0% sucrose, 0.2 ~ 0.4% sodium alginate, 0.3 ~ 0.5% xanthan gum, 0.1 ~ 0.5% pullulan.
3. the application of Compositional type microcapsule wall material in the flavouring essence for tobacco microcapsule as claimed in claim 1 or 2, it is characterized in that: above-mentioned Compositional type microcapsule wall material is scattered in water to form solid content be 15 ~ 35% wall material solution by mass percentage, after solid substance fully dissolves again in essence: wall material mass ratio is that the ratio of 1:4 ~ 1:10 adds flavouring essence for tobacco, is prepared into emulsion after stirring; Finally with the spray-dried flavouring essence for tobacco microcapsule that prepare of above-mentioned emulsion.
4. the application of Compositional type microcapsule wall material in the flavouring essence for tobacco microcapsule as claimed in claim 1 or 2, it is characterized in that: above-mentioned Compositional type microcapsule wall material is dissolved in the water, and to form solid content be 20 ~ 25% wall material solution, after solid substance fully dissolves again in flavouring essence for tobacco: wall material mass ratio is that the ratio of 1:5 ~ 1:8 adds essence, makes emulsion after stirring; Finally with the spray-dried flavouring essence for tobacco microcapsule that prepare of above-mentioned emulsion.
5. the application of Compositional type microcapsule wall material in the flavouring essence for tobacco microcapsule according to claim 3 is characterized in that: the described emulsion for preparing is first to use the high-speed emulsifying homogeneous machine at 10000 ~ 15000rpm condition down cut, 1 ~ 3min, prepares thick emulsion; Be 25 ~ 35MPa under to process 1 ~ 2 time obtain emulsion to thick emulsion at homogenization pressure with the super-voltage micro jet clarifixator again.
6. the application of Compositional type microcapsule wall material in the flavouring essence for tobacco microcapsule according to claim 4 is characterized in that: the described emulsion for preparing is first to use the high-speed emulsifying homogeneous machine at 10000 ~ 15000rpm condition down cut, 1 ~ 3min, prepares thick emulsion; Be 25 ~ 35MPa under to process 1 ~ 2 time obtain emulsion to thick emulsion at homogenization pressure with the super-voltage micro jet clarifixator again.
7. the application of Compositional type microcapsule wall material in the flavouring essence for tobacco microcapsule according to claim 6 is characterized in that: described spray-dired inlet temperature is 160 ~ 180 ℃, and air outlet temperature is 70 ~ 80 ℃, and input speed is 5 ~ 10mL/min.
8. the application of Compositional type microcapsule wall material in the flavouring essence for tobacco microcapsule according to claim 7 is characterized in that: described flavouring essence for tobacco is the easy volatile flavouring essence for tobacco.
9. the application of Compositional type microcapsule wall material in the flavouring essence for tobacco microcapsule according to claim 8 is characterized in that: described flavouring essence for tobacco is California lemon oil, Flos Caryophylli oil, Sweet fennel oil, star aniseed oil, menthol or sweet orange oil.
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| CN2013103192795A CN103396886A (en) | 2013-07-26 | 2013-07-26 | Compound microcapsule wall material and application thereof in essence microcapsules for cigarettes |
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| CN2013103192795A CN103396886A (en) | 2013-07-26 | 2013-07-26 | Compound microcapsule wall material and application thereof in essence microcapsules for cigarettes |
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Cited By (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103865650A (en) * | 2014-03-20 | 2014-06-18 | 中国热带农业科学院农产品加工研究所 | Temperature sensibility liquor-fragrance essence microcapsule for cigarette and preparation method thereof |
| CN104194931A (en) * | 2014-07-16 | 2014-12-10 | 广西中烟工业有限责任公司 | Menthol-loaded porous polymer microsphere tobacco spice slow-release material and preparation method thereof |
| CN104830532A (en) * | 2015-05-12 | 2015-08-12 | 天津春发生物科技集团有限公司 | Preparation method of slow release microcapsule ginger oil essence |
| CN104921047A (en) * | 2015-05-20 | 2015-09-23 | 增城华栋调味品有限公司 | Microcapsule mustard essence and preparation method thereof |
| CN105029667A (en) * | 2015-07-31 | 2015-11-11 | 湖北中烟工业有限责任公司 | Water-soluble anise oil microemulsion for cigarettes and preparation method and application thereof |
| CN105813486A (en) * | 2013-12-31 | 2016-07-27 | 菲利普莫里斯生产公司 | Smoking article with liquid release component |
| CN106235378A (en) * | 2016-10-20 | 2016-12-21 | 云南瑞升烟草技术（集团）有限公司 | The preparation method of a kind of filler flavouring auxiliary agent and the application in Medicated cigarette thereof |
| CN107212459A (en) * | 2017-05-31 | 2017-09-29 | 东南大学 | A kind of preparation method for being sustained tobacco aromaticss microcapsules |
| CN107568700A (en) * | 2017-09-01 | 2018-01-12 | 南通香佳纺织科技有限公司 | A kind of bergamot essential oil microcapsules baking bread flavouring agent and preparation method thereof |
| CN108546384A (en) * | 2018-04-27 | 2018-09-18 | 武汉工程大学 | A kind of quick-fried pearl material of modified soy-bean protein and preparation method thereof |
| CN108669641A (en) * | 2018-08-28 | 2018-10-19 | 中国烟草总公司郑州烟草研究院 | A kind of cigarette capsule and preparation method thereof of package water |
| CN110062769A (en) * | 2016-12-01 | 2019-07-26 | 卡莉西亚公司 | The method for preparing the particle and microcapsules of controlled dimensions |
| CN111074674A (en) * | 2020-01-08 | 2020-04-28 | 云南恩典科技产业发展有限公司 | Slow-release essence forming paper |
| CN111118958A (en) * | 2020-01-08 | 2020-05-08 | 云南恩典科技产业发展有限公司 | Preparation method of water-soluble essence slow-release cigarette paper |
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| CN111992153A (en) * | 2020-08-10 | 2020-11-27 | 江南大学 | High-loading-capacity high-thermal-stability menthol microcapsule and preparation method thereof |
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| CN113170873A (en) * | 2021-05-31 | 2021-07-27 | 四川省雅士科技有限公司 | Preparation method of microcapsule spicy seasoning |
| CN113502190A (en) * | 2021-07-13 | 2021-10-15 | 广州芬豪香精有限公司 | Manufacturing method of slow-volatilization fragrance-retaining essence |
| CN115886226A (en) * | 2022-11-02 | 2023-04-04 | 江西省华宝孔雀食品科技发展有限公司 | Microcapsule paste essence and preparation method thereof |
| WO2023232432A1 (en) * | 2022-05-31 | 2023-12-07 | Unilever Ip Holdings B.V. | Microcapsule and method |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101023763A (en) * | 2006-02-21 | 2007-08-29 | 北京市农林科学院 | Method for making high-embedding-ratio powder walnut oil |
| CN101125133A (en) * | 2007-09-27 | 2008-02-20 | 武汉麦可得生物技术有限公司 | Unsaturated fatty acid microcapsule preparing technology and application |
| CN101199319A (en) * | 2007-11-08 | 2008-06-18 | 江南大学 | Enzyme composite bactericide with broad-spectrum high-efficient bactericidal action and its preparation method |
| CN101519624A (en) * | 2009-01-20 | 2009-09-02 | 华南农业大学 | Cinnamon essential oil microcapsule and preparation method thereof |
| CN101649254A (en) * | 2009-09-14 | 2010-02-17 | 太仓文华实业有限公司 | Micro-capsule essence with two-layer capsule wall and preparation method and application thereof |
| CN101972038A (en) * | 2010-10-28 | 2011-02-16 | 上海理工大学 | Slowly-released filter stick essence microcapsule and preparation method thereof |
| CN102008108A (en) * | 2010-10-27 | 2011-04-13 | 江苏省农业科学院 | Xanthophyll-reinforced sweet corn beverage and preparation method thereof |
| CN102140387A (en) * | 2011-01-20 | 2011-08-03 | 深圳市如烟生物科技有限公司 | Method for preparing microcapsule essence for cigarette |
| CN103146480A (en) * | 2013-03-05 | 2013-06-12 | 湖北中烟工业有限责任公司 | Essence microcapsule wall material for cigarettes and essence microcapsule |
-
2013
- 2013-07-26 CN CN2013103192795A patent/CN103396886A/en active Pending
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101023763A (en) * | 2006-02-21 | 2007-08-29 | 北京市农林科学院 | Method for making high-embedding-ratio powder walnut oil |
| CN101125133A (en) * | 2007-09-27 | 2008-02-20 | 武汉麦可得生物技术有限公司 | Unsaturated fatty acid microcapsule preparing technology and application |
| CN101199319A (en) * | 2007-11-08 | 2008-06-18 | 江南大学 | Enzyme composite bactericide with broad-spectrum high-efficient bactericidal action and its preparation method |
| CN101519624A (en) * | 2009-01-20 | 2009-09-02 | 华南农业大学 | Cinnamon essential oil microcapsule and preparation method thereof |
| CN101649254A (en) * | 2009-09-14 | 2010-02-17 | 太仓文华实业有限公司 | Micro-capsule essence with two-layer capsule wall and preparation method and application thereof |
| CN102008108A (en) * | 2010-10-27 | 2011-04-13 | 江苏省农业科学院 | Xanthophyll-reinforced sweet corn beverage and preparation method thereof |
| CN101972038A (en) * | 2010-10-28 | 2011-02-16 | 上海理工大学 | Slowly-released filter stick essence microcapsule and preparation method thereof |
| CN102140387A (en) * | 2011-01-20 | 2011-08-03 | 深圳市如烟生物科技有限公司 | Method for preparing microcapsule essence for cigarette |
| CN103146480A (en) * | 2013-03-05 | 2013-06-12 | 湖北中烟工业有限责任公司 | Essence microcapsule wall material for cigarettes and essence microcapsule |
Non-Patent Citations (1)
| Title |
|---|
| 吴酉芝等: "微胶囊化香精在香烟滤嘴中添加的应用与分析", 《农产品加工(学刊)》 * |
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| CN105813486A (en) * | 2013-12-31 | 2016-07-27 | 菲利普莫里斯生产公司 | Smoking article with liquid release component |
| CN103865650A (en) * | 2014-03-20 | 2014-06-18 | 中国热带农业科学院农产品加工研究所 | Temperature sensibility liquor-fragrance essence microcapsule for cigarette and preparation method thereof |
| CN103865650B (en) * | 2014-03-20 | 2015-10-21 | 中国热带农业科学院农产品加工研究所 | A kind of cigarette temperature sensitivity aroma essence microcapsule and preparation method thereof |
| CN104194931A (en) * | 2014-07-16 | 2014-12-10 | 广西中烟工业有限责任公司 | Menthol-loaded porous polymer microsphere tobacco spice slow-release material and preparation method thereof |
| CN104830532A (en) * | 2015-05-12 | 2015-08-12 | 天津春发生物科技集团有限公司 | Preparation method of slow release microcapsule ginger oil essence |
| CN104921047A (en) * | 2015-05-20 | 2015-09-23 | 增城华栋调味品有限公司 | Microcapsule mustard essence and preparation method thereof |
| CN105029667A (en) * | 2015-07-31 | 2015-11-11 | 湖北中烟工业有限责任公司 | Water-soluble anise oil microemulsion for cigarettes and preparation method and application thereof |
| CN106235378A (en) * | 2016-10-20 | 2016-12-21 | 云南瑞升烟草技术（集团）有限公司 | The preparation method of a kind of filler flavouring auxiliary agent and the application in Medicated cigarette thereof |
| CN106235378B (en) * | 2016-10-20 | 2018-06-01 | 云南瑞升烟草技术（集团）有限公司 | A kind of application of filler flavouring additives in cigarette |
| CN110062769B (en) * | 2016-12-01 | 2021-07-23 | 卡莉西亚公司 | Process for preparing microparticles and microcapsules of controlled size |
| CN110062769A (en) * | 2016-12-01 | 2019-07-26 | 卡莉西亚公司 | The method for preparing the particle and microcapsules of controlled dimensions |
| CN107212459A (en) * | 2017-05-31 | 2017-09-29 | 东南大学 | A kind of preparation method for being sustained tobacco aromaticss microcapsules |
| CN107568700A (en) * | 2017-09-01 | 2018-01-12 | 南通香佳纺织科技有限公司 | A kind of bergamot essential oil microcapsules baking bread flavouring agent and preparation method thereof |
| CN108546384A (en) * | 2018-04-27 | 2018-09-18 | 武汉工程大学 | A kind of quick-fried pearl material of modified soy-bean protein and preparation method thereof |
| CN108669641A (en) * | 2018-08-28 | 2018-10-19 | 中国烟草总公司郑州烟草研究院 | A kind of cigarette capsule and preparation method thereof of package water |
| CN111118958A (en) * | 2020-01-08 | 2020-05-08 | 云南恩典科技产业发展有限公司 | Preparation method of water-soluble essence slow-release cigarette paper |
| CN111074674A (en) * | 2020-01-08 | 2020-04-28 | 云南恩典科技产业发展有限公司 | Slow-release essence forming paper |
| CN111909507A (en) * | 2020-07-02 | 2020-11-10 | 青岛百草新材料股份有限公司 | Radix isatidis modified polyamide masterbatch for superfine fibers |
| CN111992153A (en) * | 2020-08-10 | 2020-11-27 | 江南大学 | High-loading-capacity high-thermal-stability menthol microcapsule and preparation method thereof |
| CN111992153B (en) * | 2020-08-10 | 2022-10-18 | 江南大学 | High-loading-capacity high-thermal-stability menthol microcapsule and preparation method thereof |
| CN112544939A (en) * | 2020-12-02 | 2021-03-26 | 江西省华宝孔雀食品科技发展有限公司 | Preparation method of controlled-release essence for baking |
| CN113170873A (en) * | 2021-05-31 | 2021-07-27 | 四川省雅士科技有限公司 | Preparation method of microcapsule spicy seasoning |
| CN113502190A (en) * | 2021-07-13 | 2021-10-15 | 广州芬豪香精有限公司 | Manufacturing method of slow-volatilization fragrance-retaining essence |
| WO2023232432A1 (en) * | 2022-05-31 | 2023-12-07 | Unilever Ip Holdings B.V. | Microcapsule and method |
| CN115886226A (en) * | 2022-11-02 | 2023-04-04 | 江西省华宝孔雀食品科技发展有限公司 | Microcapsule paste essence and preparation method thereof |
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