CN105124752A - Peppermint oil based nano-emulsion for cigarettes and preparation method and application of peppermint oil based nano-emulsion - Google Patents
Peppermint oil based nano-emulsion for cigarettes and preparation method and application of peppermint oil based nano-emulsion Download PDFInfo
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- CN105124752A CN105124752A CN201510508371.5A CN201510508371A CN105124752A CN 105124752 A CN105124752 A CN 105124752A CN 201510508371 A CN201510508371 A CN 201510508371A CN 105124752 A CN105124752 A CN 105124752A
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- 239000001525 mentha piperita l. herb oil Substances 0.000 title claims abstract description 75
- 235000019477 peppermint oil Nutrition 0.000 title claims abstract description 75
- 239000007908 nanoemulsion Substances 0.000 title claims abstract description 48
- 235000019504 cigarettes Nutrition 0.000 title claims abstract description 38
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 17
- 235000006679 Mentha X verticillata Nutrition 0.000 claims description 12
- 235000002899 Mentha suaveolens Nutrition 0.000 claims description 12
- 235000001636 Mentha x rotundifolia Nutrition 0.000 claims description 12
- 238000004945 emulsification Methods 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 12
- 241000208125 Nicotiana Species 0.000 claims description 11
- 235000002637 Nicotiana tabacum Nutrition 0.000 claims description 11
- 239000003921 oil Substances 0.000 claims description 10
- 235000019198 oils Nutrition 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 9
- 238000000265 homogenisation Methods 0.000 claims description 7
- 239000011259 mixed solution Substances 0.000 claims description 6
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims description 5
- 229920000053 polysorbate 80 Polymers 0.000 claims description 5
- 239000000244 polyoxyethylene sorbitan monooleate Substances 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 abstract description 11
- 239000000839 emulsion Substances 0.000 abstract description 5
- 239000003205 fragrance Substances 0.000 abstract description 4
- 235000016257 Mentha pulegium Nutrition 0.000 abstract description 3
- 244000246386 Mentha pulegium Species 0.000 abstract description 3
- 235000004357 Mentha x piperita Nutrition 0.000 abstract description 3
- 235000001050 hortel pimenta Nutrition 0.000 abstract description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract description 2
- 230000000694 effects Effects 0.000 abstract 1
- 230000000391 smoking effect Effects 0.000 abstract 1
- 238000005516 engineering process Methods 0.000 description 8
- 239000003094 microcapsule Substances 0.000 description 6
- 230000001804 emulsifying effect Effects 0.000 description 5
- NOOLISFMXDJSKH-UTLUCORTSA-N (+)-Neomenthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@@H]1O NOOLISFMXDJSKH-UTLUCORTSA-N 0.000 description 3
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 description 3
- 229940041616 menthol Drugs 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 244000025254 Cannabis sativa Species 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000005191 phase separation Methods 0.000 description 2
- 235000019505 tobacco product Nutrition 0.000 description 2
- 206010011732 Cyst Diseases 0.000 description 1
- 206010019233 Headaches Diseases 0.000 description 1
- 206010000269 abscess Diseases 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000012970 cakes Nutrition 0.000 description 1
- 235000020965 cold beverage Nutrition 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 208000031513 cyst Diseases 0.000 description 1
- 230000006837 decompression Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000013355 food flavoring agent Nutrition 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 235000019990 fruit wine Nutrition 0.000 description 1
- 231100000869 headache Toxicity 0.000 description 1
- 238000009830 intercalation Methods 0.000 description 1
- 230000002687 intercalation Effects 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000001256 steam distillation Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229940034610 toothpaste Drugs 0.000 description 1
- 239000000606 toothpaste Substances 0.000 description 1
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- Manufacture Of Tobacco Products (AREA)
Abstract
The invention relates to a peppermint oil based nano-emulsion for cigarettes and a preparation method and application of the peppermint oil based nano-emulsion, and belongs to the technical field of high-energy emulsion preparation. The peppermint oil based nano-emulsion for cigarettes is a system comprising peppermint oil, emulsifying agent and water. The peppermint oil based nano-emulsion for cigarettes has the advantages that alcohol solubility of peppermint oil is improved greatly and volatilization speed of peppermint oil is reduced greatly while service effect thereof is improved greatly; the peppermint oil based nano-emulsion, which is of a W/O type, is applied to production of peppermint type cigarette products to substitute for conventional peppermint oil; thus interference to a production line can be reduced and usage of peppermint oil can be reduced during production. Besides, since adding of other equipment and changing of production process are omitted from cigarette production utilizing the peppermint oil based nano-emulsion, fragrance disturbance of different types of cigarette products can be avoided while high quality of peppermint type fragrance of cigarette products is achieved during use, and smoking quality of the cigarette products is improved.
Description
Technical field
The present invention relates to technical field of cigarettes, be specifically related to a kind of cigarette peppermint oil nanoemulsions and its preparation method and application.
Background technology
Peppermint oil has another name called asia peppermint oil, natural menthence, de-cerebrol, with the aerial part complete stool of herbaceos perennial peppermint grass (dry herb, cured leaf, fresh grass) for raw material, the peppermint oil obtained through steam distillation, then obtain through decompression distillation again after step freezing method (14 DEG C, 10 DEG C ,-5 DEG C) separation remove portion (45 ~ 55%) menthol.
Peppermint oil is mainly used in treatment anemopyretic cold, headache hot eyes, abscess of throat, pruitus etc. in medical and health.In oral hygiene goods, as toothpaste, tooth powder, also can be used for gum base type candy, fruit wine, cake, cold drink, essence and flavoring agent, floral water etc.
Traditional mint type flavouring essence for tobacco is produced and is mainly used menthol, to be directly used in tobacco perfuming after alcohol dilution.Adopt and there is many deficiencies in this way: pollute cigarette production line and working environment, affect the normal production of other type cigarette products; On pipe tobacco, white crystals point has been produced after solvent volatilization.In addition, the cigarette products of simple employing menthol perfuming, when burning and sucking, the mint flavored combustion intensity along with cigarette progressively reduces, and can not obtain the sensation of mint flavored even release.
Microcapsules technology utilizes macromolecular material that is natural or that synthesize by solid, liquid or the gas a kind of microencapsulation technology with pellicle or sealing cyst membrane through being wrapped to form.The technique being utilized by peppermint oil microcapsules technology to be prepared into peppermint oil microcapsules has a lot of report, and peppermint oil microcapsules improve the volatile lost character of peppermint oil.But traditional microcapsule product exists usually in solid form, the less stable in liquid essence, is mainly used in the production of mint type filter tip in tobacco product.
Use peppermint oil nanoemulsions, the fragrance of dissimilar cigarette products can be avoided to disturb, and the igniting and sucking quality of cigarette products can be improved.
The nanometer emulsified above-mentioned defect that can overcome traditional microcapsules, and nanometer emulsified technology, compared with traditional emulsifying technology, adopts ultrasonic emulsification and high pressure homogenization method to prepare nanoemulsions in preparation process.Therefore, the more traditional emulsion of nanoemulsions have less and evenly domain size distribution, the thermodynamics and kinetics stability of emulsifying product is higher, and the emulsifying product stability obtained is also high.And its nano level molecule, make it release more even, be easy to control.
Summary of the invention
The technical problem to be solved in the present invention is open a kind of cigarette peppermint oil nanoemulsions and its preparation method and application, namely provides the peppermint oil emulsion with Nano Particle of a kind of high stability, low volatility, makes it be applied in mint type cigarette goods.
For solving above technical problem, technical scheme provided by the invention is, a kind of cigarette peppermint oil nanoemulsions, and its composition is by percentage to the quality: water 1 ~ 20%, emulsifying agent 5 ~ 25%, supplies 100% with peppermint oil.
Preferred technical scheme is, emulsifying agent is polyoxyethylene sorbitan monooleate.
A preparation method for cigarette peppermint oil nanoemulsions, comprises the following steps:
A the peppermint oil in ratio described in () precise, is placed in container, and accurately add the emulsifying agent in described ratio, stirs, and obtains oil phase emulsifier mixed solution;
B the pure water in ratio described in () precise, joins pure water in (a) step gained oil phase emulsifier mixed solution, is uniformly mixed;
C () adopts ultrasonic emulsification and high pressure homogenization method that (b) step gained mixture is prepared stable w/o type peppermint oil nanoemulsions.
Further, the described ultrasonic emulsification of step (c) adopts ultrasonic power 500 ~ 1000W, and high-pressure homogeneous employing pressure 50 ~ 200MPa, homogenization cycles is 1 ~ 20 time.
An application for cigarette peppermint oil nanoemulsions, peppermint oil nanoemulsions use amount in pipe tobacco is 500ppm, is sprayed at uniformly on pipe tobacco, for making mint aroma cigarette.
The invention has the beneficial effects as follows the feature from peppermint oil, adopt high energy emulsifying technology, select suitable oil phase, polyoxyethylene sorbitan monooleate (Tween 80) is used to be emulsifying agent, by ultrasonic emulsification and high-pressure homogeneous emulsifying device, prepare cigarette peppermint oil nanoemulsions.This system changes the oil-soluble of peppermint oil, increases its dissolubility, can be directly used in the perfuming of tobacco product; Meanwhile, strong volatility and the unstability of traditional mint type essence is avoided by high energy emulsification; , replace traditional peppermint oil with this w/o type peppermint oil nanoemulsions, can reduce the interference to production line in process of production, reduce peppermint oil consumption, the result of use of peppermint oil significantly improves; And compared with traditional emulsion, nanoemulsions is little due to its particle diameter, is uniformly dispersed, and emulsion intercalation method significantly improves, be easy to improve storage stability; Peppermint oil is prepared into the peppermint oil nanoemulsions that can spray by the present invention first, prepared peppermint oil nanoemulsions not only can solubilising peppermint oil, and also reduce peppermint oil evaporation rate, be sprayed on pipe tobacco without the residual crystalline solid of white, when burning and sucking, mint flavored release is even, improves the igniting and sucking quality of cigarette products; Do not need increase equipment when adopting this nanoemulsions to produce and do not change production technology, the fragrance of dissimilar cigarette products can be avoided to disturb, and make product reach good mint type flavouring essence quality in use.
Detailed description of the invention
In order to explain the present invention better, illustrate main contents of the present invention further below in conjunction with specific embodiment, but content of the present invention is not only confined to following examples.
A kind of cigarette peppermint oil nanoemulsions, its composition is by percentage to the quality: water 1 ~ 20%, and emulsifying agent 5 ~ 25%, supplies 100% with peppermint oil; Emulsifying agent is polyoxyethylene sorbitan monooleate.
A preparation method for cigarette peppermint oil nanoemulsions, comprises the following steps:
A the peppermint oil in ratio described in () precise, is placed in container, and accurately add the emulsifying agent in described ratio, stirs, and obtains oil phase emulsifier mixed solution;
B the pure water in ratio described in () precise, joins pure water in (a) step gained oil phase emulsifier mixed solution, is uniformly mixed;
C () adopts ultrasonic emulsification and high pressure homogenization method that (b) step gained mixture is prepared stable w/o type peppermint oil nanoemulsions.
Ultrasonic emulsification adopts ultrasonic power 500 ~ 1000W, and high-pressure homogeneous employing pressure 50 ~ 200MPa, homogenization cycles is 1 ~ 20 time.
Embodiment 1:
Get emulsifying agent 20g, be dissolved in 60g peppermint oil, obtained emulsifying agent and oil mixture, and stir and spend the night, get pure water 20g, under vigorous stirring pure water is added, use ultrasonic emulsification and high-pressure homogeneously prepare peppermint oil nanoemulsions.After prepared by w/o type peppermint oil nanoemulsions, investigate peppermint oil nanoemulsions stability further.One method uses supercentrifuge 30000r/min, and rotate 5min, do not occur phenomenon of phase separation, then this system is nanoemulsions; Another kind method is with using aging process, carry out under low temperature (1 ~ 5 DEG C), high temperature (40 DEG C) and normal temperature respectively, the stability of further investigation peppermint oil nanoemulsions, stores 1 year under storing half a year, normal temperature at low temperatures and high temperatures, does not occur phenomenon of phase separation.
Embodiment 2:
Get emulsifying agent 25g, be dissolved in 60g peppermint oil, obtained emulsifying agent and oil mixture, and stir and spend the night, get pure water 15g, under vigorous stirring pure water is added, use ultrasonic emulsification and high-pressure homogeneously prepare peppermint oil nanoemulsions.After prepared by w/o type peppermint oil nanoemulsions, investigate peppermint oil nanoemulsions stability further according to the method for embodiment 1.
Embodiment 3:
Get emulsifying agent 15g, be dissolved in 70g peppermint oil, obtained emulsifying agent and oil mixture, and stir and spend the night, get pure water 15g, under vigorous stirring pure water is added, use ultrasonic emulsification and high-pressure homogeneously prepare peppermint oil nanoemulsions.After prepared by w/o type peppermint oil nanoemulsions, investigate the stability of peppermint oil nanoemulsions further according to the method for embodiment 1.
Embodiment 4:
The cigarette application of peppermint oil nanoemulsions, peppermint oil nanoemulsions use amount in pipe tobacco is 500ppm, is sprayed at uniformly on pipe tobacco, for making mint aroma cigarette.Do not occur the white crystals body that traditional peppermint oil is residual on pipe tobacco, when burning and sucking, mint flavored release is even, and aroma quality is stablized, and improves the igniting and sucking quality of cigarette products.
Claims (5)
1. a cigarette peppermint oil nanoemulsions, is characterized in that: its composition is by percentage to the quality: water 1 ~ 20%, emulsifying agent 5 ~ 25%, supplies 100% with peppermint oil.
2. cigarette peppermint oil nanoemulsions according to claim 1, is characterized in that: described emulsifying agent is polyoxyethylene sorbitan monooleate.
3. a preparation method for cigarette peppermint oil nanoemulsions according to claim 1, is characterized in that comprising the following steps:
A the peppermint oil in ratio described in () precise, is placed in container, and accurately add the emulsifying agent in described ratio, stirs, and obtains oil phase emulsifier mixed solution;
B the pure water in ratio described in () precise, joins pure water in (a) step gained oil phase emulsifier mixed solution, is uniformly mixed;
C () adopts ultrasonic emulsification and high pressure homogenization method that (b) step gained mixture is prepared stable w/o type peppermint oil nanoemulsions.
4. the preparation method of cigarette peppermint oil nanoemulsions according to claim 3, it is characterized in that: the described ultrasonic emulsification of step (c) adopts ultrasonic power 500 ~ 1000W, high-pressure homogeneous employing pressure 50 ~ 200MPa, homogenization cycles is 1 ~ 20 time.
5. the application of cigarette peppermint oil nanoemulsions according to claim 1, is characterized in that: peppermint oil nanoemulsions use amount in pipe tobacco is 500ppm, is sprayed at uniformly on pipe tobacco, for making mint aroma cigarette.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106590931A (en) * | 2016-12-14 | 2017-04-26 | 江西中烟工业有限责任公司 | Preparation method of cigarette protein-polysaccharide composite emulsion carrier system and application of carrier system in cigarettes |
| CN107937134A (en) * | 2017-12-13 | 2018-04-20 | 湖北中烟工业有限责任公司 | Preparation method for the sweet orange oil Microemulsions For Use of cigarette blending |
| CN111100756A (en) * | 2019-12-31 | 2020-05-05 | 广州华芳烟用香精有限公司 | Micro-emulsified mint essence for cigarette paper, and preparation method and application thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107937134A (en) * | 2017-12-13 | 2018-04-20 | 湖北中烟工业有限责任公司 | Preparation method for the sweet orange oil Microemulsions For Use of cigarette blending |
| CN107937134B (en) * | 2017-12-13 | 2021-04-02 | 湖北中烟工业有限责任公司 | Preparation method of sweet orange oil microemulsion for cigarette flavoring |
| CN111100756A (en) * | 2019-12-31 | 2020-05-05 | 广州华芳烟用香精有限公司 | Micro-emulsified mint essence for cigarette paper, and preparation method and application thereof |
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Application publication date: 20151209 |