CN105029667A - Water-soluble anise oil microemulsion for cigarettes and preparation method and application thereof - Google Patents
Water-soluble anise oil microemulsion for cigarettes and preparation method and application thereof Download PDFInfo
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- CN105029667A CN105029667A CN201510462613.1A CN201510462613A CN105029667A CN 105029667 A CN105029667 A CN 105029667A CN 201510462613 A CN201510462613 A CN 201510462613A CN 105029667 A CN105029667 A CN 105029667A
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- aniseed oil
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- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 claims description 2
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- MSHFRERJPWKJFX-UHFFFAOYSA-N 4-Methoxybenzyl alcohol Chemical class COC1=CC=C(CO)C=C1 MSHFRERJPWKJFX-UHFFFAOYSA-N 0.000 description 1
- PBBGSZCBWVPOOL-HDICACEKSA-N 4-[(1r,2s)-1-ethyl-2-(4-hydroxyphenyl)butyl]phenol Chemical compound C1([C@H](CC)[C@H](CC)C=2C=CC(O)=CC=2)=CC=C(O)C=C1 PBBGSZCBWVPOOL-HDICACEKSA-N 0.000 description 1
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Landscapes
- Colloid Chemistry (AREA)
Abstract
The invention relates to a water-soluble anise oil microemulsion for cigarettes and a preparation method and an application thereof. The water-soluble anise oil microemulsion for cigarettes is an O/W type microemulsion system that comprises anise oil, composite emulsifier, co emulsifier and water, and the water-soluble anise oil microemulsion for cigarettes can be used for cigarettes added essence blending. The water-soluble anise oil microemulsion for cigarettes improves water solubility, added essence physical state and fragrance stability of the anise oil; the water-soluble anise oil microemulsion for cigarettes can be used to prepare added essence for cigarettes to replace common anise oil and lift fennel fragrance and pungent fragrance characteristics, enrich the cigarettes fragrance and coordinate the cigarettes fragrance. By adopting the water-soluble anise oil microemulsion for cigarettes, no additional equipment for production is required; no production technology shall be changed; anise oil can be solubilized to that the anise oil can be applied in water-soluble products; product quality can be improved; product stability, fragrance characteristics and sense organs breath effect can be lifted; and a new product application method is developed.
Description
Technical field
The present invention relates to micro-emulsion technology field, specifically a kind of cigarette water-soluble aniseed oil microemulsion and its preparation method and application.
Background technology
Aniseed oil, colourless or weak yellow liquid, is dissolved in ethanol, ether, and main component is anethole, therefore for extracting the natural material of anethole, also for fumet and the medical aspect of synthetic beverage, food, tobacco etc.Aniseed oil mainly directly supplies Cooking Seasoning, or for extracting essential oil.Aniseed oil is being pharmaceutically the primary raw material synthesizing negative hormone hexestrol.Aniseed oil is that the steam distillation of raw material frequent straightening water receiving obtains by the fruit of anise or branches and leaves, and distillate obtains fennel oil finished product through cooling, clarification, water-oil separating, vacuum dehydration, flows out water and steams again, also recyclable a small amount of essential oil.
Isoesdragol obtains by the fruit of distillation containing the plant of isoesdragol, also can synthesize to chemically.Isoesdragol as the initiation material preparing anisic aldehyde, anisyl alcohol, anisic acid and ester class thereof, also for flavoring essence and toothpaste, drinks, candy, beverage and tobacco flavoring, on a small quantity in daily essence.Isoesdragol can be used for the flavouring of medicine and strong odorant agent, has the loose effect such as cold of the lower gas of appetizing, warm kidney.Isoesdragol is as medicine, there is obvious function of increasing leukocyte, main rising neutrophil leucocyte. its effect promotes that bone marrow cell is ripe and be released in peripheral blood, is used for the treatment of the leukopenia because of chemotherapy of tumors, caused by radiation, and the Neuroleptic Leukocytopenia caused by other reasons.
Microcapsules technology utilizes macromolecular material that is natural or that synthesize by solid, liquid or the gas a kind of microencapsulation technology with pellicle or sealing cyst membrane through being wrapped to form.The technique being utilized by aniseed oil microcapsules technology to be prepared into aniseed oil microcapsules has a lot of report, and aniseed oil microcapsules improve the volatile lost character of aniseed oil, have the function of slowly-releasing, controlled release.But; traditional microcapsule product exists usually in solid form; can not use in liquid food, cosmetics, essence, medicine; in addition; because the particle diameter of microcapsules is larger; it is not very high that its scale utilizes, and when addition is less, is unfavorable for realizing being uniformly distributed in the product yet.
If two or more non soluble liquids is after mixing and emulsifying, the diameter of dispersant liquid drop is between 5nm ~ 100nm, then this system is called microemulsion.Microemulsion is transparent dispersion system, the transparent or semitransparent aqueous stabilising system be usually made up of oil, water, surfactant, cosurfactant and electrolyte etc.The system that decentralized photo is oil, decentralized medium is water is called O/W type micro emulsion, otherwise is then called w/o type micro emulsion.
Microemulsified can overcome the above-mentioned defect of traditional microcapsules, and microemulsified product is thermodynamic stable system, has that degree of scatter is large, dispersed phase particles size even, and increase-volume amount is large, has ultralow interfacial tension.Aniseed oil microemulsified product has storage-stable, and evenly, the features such as mobility is large, viscosity is little, its nano level molecule, makes it to be easy to realize Targeting delivery in release.
Summary of the invention
Object of the present invention is exactly for the deficiencies in the prior art, a kind of cigarette water-soluble aniseed oil microemulsion and its preparation method and application is provided, what namely provide a kind of highly dissoluble, low volatility has nano level water-soluble aniseed oil microemulsion and preparation method thereof, the water-soluble aniseed oil microemulsion of the cigarette prepared is applied in tobacco charging essence, solve aniseed oil undissolved problem in tobacco charging essence, the microemulsified spices of the cigarette perfume (or spice) that provides a kind of and promote fennel fragrance and Xin Xiang odor characteristic, enriches cigarette perfume (or spice), coordinates.
For achieving the above object, technical scheme provided by the invention is: the water-soluble aniseed oil microemulsion of a kind of cigarette, is characterized in that: its component and mass percent are: aniseed oil 20 ~ 30%, compound emulsifying agent 15 ~ 25%, assistant for emulsifying agent 10 ~ 20%, water 30 ~ 50%.
Further, the quality of described compound emulsifying agent is 0.5 ~ 1.5 times of described aniseed oil; The mass ratio of described compound emulsifying agent and described assistant for emulsifying agent is 3:2.During configuration microemulsion, under the prerequisite not affecting microemulsified effect, this allocation ratio can be applied.
Further, described compound emulsifying agent is in emulsifier lecithin, maltitol, lactitol, sucrose fatty ester, Tween-20, polyoxyethylene sorbitan monostearate, Tween-80 two kinds or more than two kinds; Described compound emulsifying agent by selected emulsifying agent with proportions.Research finds that the microemulsified effect of compound emulsifying agent is better than the microemulsified effect of single a kind of emulsifying agent.Although a large amount of emulsifying agents contributes to the effect of microemulsified, their use should meet " food additives use standard ", and the too much membership that adds has side effects, and reduces sensory evaluating smoking's quality of essence.
Further, described assistant for emulsifying agent is ethanol, propane diols or glycerine.
Further, described cigarette is 70 ~ 99% with the envelop rate of water-soluble aniseed oil microemulsion.
A cigarette preparation method for water-soluble aniseed oil microemulsion, is characterized in that: aniseed oil, compound emulsifying agent and assistant for emulsifying agent are stirred according to after formula rate mixing, then add water and be uniformly mixed into O/W type microemulsion.This O/W type microemulsion fennel fragrance is stablized, and has solved its dissolubility in water, and does not occur being separated when high speed centrifugation is separated; Respectively store half a year at low or elevated temperatures, store 1 year at normal temperatures, all do not occur phenomenon of phase separation.
Further, high speed dispersor, homogenizer or ultrasonic emulsator can be used in described whipping process.Use the method not only can accelerate the mixing of aniseed oil, compound emulsifying agent, assistant for emulsifying agent and water, the addition of emulsifying agent can also be reduced, but the particle diameter of the aniseed oil microemulsion system made is greater than aniseed oil microemulsion system prepared by mechanical agitation.
A cigarette application for water-soluble aniseed oil microemulsion, is characterized in that: described cigarette can be used for cigarette flavoring essence with water-soluble aniseed oil microemulsion to be allocated.
Further, described cigarette is 3 ~ 15% by the usage ratio of water-soluble aniseed oil microemulsion in cigarette flavoring essence.
Beneficial effect of the present invention is embodied in:
The present invention, has the following advantages using microemulsion as the carrier of aroma substance:
1, be transparency liquid, spontaneous formation thermodynamic stable system, be easy to preparation and preserve.
2, oil-in-water microemulsion can be used as the carrier of hydrophobicity aroma substance, and increase-volume amount is large.
3, there is ultralow interfacial tension, mobility is large, viscosity is little, dissolubility is high, volatility is low.
4, there is nanoscale, its nano level molecule, make it to be easy to realize Targeting delivery.
5, impel fragrance slow releasing, promote odor characteristic and the fragrance remaining time of flavoring essence.
6, the character of microemulsion system and composition are easy to control and measurement, therefore have feasibility.
The present invention is from the feature of aniseed oil, adopt micro-emulsion technology, being made by aniseed oil can the nano-composition of self-emulsifying, after directly mixing with water, can directly use as the raw material of cigarette flavoring essence allotment, solve the indissolubility of traditional aniseed oil in water and unstability, be applied in flavoring essence and can promote fennel fragrance and Xin Xiang odor characteristic, enrich cigarette perfume (or spice), to coordinate cigarette fragrant.
Aniseed oil is prepared into water-soluble aniseed oil microemulsion by the present invention first.Prepared aniseed oil microemulsion not only can solubilising aniseed oil, achieve aniseed oil to apply in water-soluble products, further improve product quality, improve product stability, odor characteristic and sensory evaluating smoking's effect, develop a kind of new products application approach.
Detailed description of the invention
Embodiment 1:
Select Tween-20 and maltitol as compound emulsifying agent, the mass ratio of two kinds of emulsifying agents is 1:4; Select ethanol as assistant for emulsifying agent, the mass ratio of compound emulsifying agent and assistant for emulsifying agent is 3:2.Get aniseed oil 1500g, the total amount of emulsifying agent and assistant for emulsifying agent is 1500g, namely get Tween-20 180g, maltitol 720g, assistant for emulsifying agent 600g, and the addition of water is 2000g.
Use mechanical agitation 30 minutes by after oil phase and Emulsion Phase mixing, be uniformly mixed, then add aqueous phase, continue stirring 30 minutes, be sub-packed in Brown Glass Brown glass bottles and jars only by requirement, be i.e. the obtained water-soluble aniseed oil microemulsion 1 of cigarette of the present invention.
After this cigarette completes with the sample preparation of water-soluble aniseed oil microemulsion 1, investigate its stability further.One method is that centrifugation 5min does not occur phenomenon of phase separation with supercentrifuge under centrifuge speed is 10000r/min condition, then this system is microemulsion; Another kind method uses out-of-date methods, carry out under low temperature (1 ~ 5 DEG C), high temperature (40 DEG C) and normal temperature respectively, the stability of the water-soluble aniseed oil microemulsion of further investigation, it respectively stored at low temperatures and high temperatures half a year, store 1 year at normal temperatures, all do not occur phenomenon of phase separation, then this system is microemulsion.
Embodiment 2:
Select Tween-20 and polyoxyethylene sorbitan monostearate as compound emulsifying agent, the ratio of two kinds of emulsifying agents is 1:1, and assistant for emulsifying agent selects propane diols, and the ratio of compound emulsifying agent and assistant for emulsifying agent is 3:2.Get aniseed oil 1200g, the total amount of emulsifying agent and assistant for emulsifying agent is 2000g, namely get Tween-20 600g, polyoxyethylene sorbitan monostearate 600g, assistant for emulsifying agent 800g, and the addition of water is 1800g.
Use mechanical agitation 30 minutes by after oil phase and Emulsion Phase mixing, be uniformly mixed, then add aqueous phase, continue stirring 30 minutes, be sub-packed in Brown Glass Brown glass bottles and jars only by requirement, be i.e. the obtained water-soluble aniseed oil microemulsion 2 of cigarette of the present invention.
After this cigarette completes with the sample preparation of water-soluble aniseed oil microemulsion 2, investigate its stability further.One method is that centrifugation 5min does not occur phenomenon of phase separation with supercentrifuge under centrifuge speed is 10000r/min condition, then this system is microemulsion; Another kind method uses out-of-date methods, carry out under low temperature (1 ~ 5 DEG C), high temperature (40 DEG C) and normal temperature respectively, the stability of the water-soluble aniseed oil microemulsion of further investigation, it respectively stored at low temperatures and high temperatures half a year, store 1 year at normal temperatures, all do not occur phenomenon of phase separation, then this system is microemulsion.
Embodiment 3:
Select polyoxyethylene sorbitan monostearate and Tween-80 as compound emulsifying agent, the ratio of two kinds of emulsifying agents is 1:3, and assistant for emulsifying agent selects glycerine, and compound emulsifying agent and assistant for emulsifying agent ratio are 3:2.Get aniseed oil 800g, the total amount of emulsifying agent and assistant for emulsifying agent is 1200g, namely gets polyoxyethylene sorbitan monostearate 180g, Tween-80 540g, assistant for emulsifying agent 480g, the addition 2000g of water.
Just use mechanical agitation 30 minutes after oil phase and Emulsion Phase mixing, be uniformly mixed, then add aqueous phase, continue stirring 30 minutes, be sub-packed in Brown Glass Brown glass bottles and jars only by requirement, be i.e. the obtained water-soluble aniseed oil microemulsion 3 of cigarette of the present invention.
After this cigarette completes with the sample preparation of water-soluble aniseed oil microemulsion 3, investigate its stability further.One method is that centrifugation 5min does not occur phenomenon of phase separation with supercentrifuge under centrifuge speed is 10000r/min condition, then this system is microemulsion; Another kind method uses out-of-date methods, carry out under low temperature (1 ~ 5 DEG C), high temperature (40 DEG C) and normal temperature respectively, the stability of the water-soluble aniseed oil microemulsion of further investigation, it respectively stored at low temperatures and high temperatures half a year, store 1 year at normal temperatures, all do not occur phenomenon of phase separation, then this system is microemulsion.
Embodiment 4:
The water-soluble aniseed oil microemulsion 1 ~ 3 of the cigarette that above embodiment prepares, by cigarette with water-soluble aniseed oil microemulsion cigarette flavoring essence allotment in usage ratio be 10%, allotment obtain cigarette flavoring essence 1 ~ 3.Get aniseed oil by same usage ratio allotment cigarette flavoring essence, as a control group.
By professional and technical personnel to cigarette with water-soluble aniseed oil microemulsion 1 ~ 3 and aniseed oil the physical state in essence sample, fragrance stability and sensory evaluating smoking's effect verify, result shows that the water-soluble aniseed oil microemulsion of above-mentioned cigarette is dispersed in flavoring essence, essence physical state and fragrance are stablized, promote fennel fragrance and Xin Xiang odor characteristic, enrich cigarette perfume (or spice), coordinate cigarette perfume, there is good sensory evaluating smoking's effect.
The above, be only the specific embodiment of the present invention, it should be pointed out that any those of ordinary skill in the art are in the technical scope disclosed by the present invention, the change that can expect easily or replacement, all should be encompassed within protection scope of the present invention.
Claims (9)
1. the water-soluble aniseed oil microemulsion of cigarette, is characterized in that: its component and mass percent are: aniseed oil 20 ~ 30%, compound emulsifying agent 15 ~ 25%, assistant for emulsifying agent 10 ~ 20%, water 30 ~ 50%.
2. the water-soluble aniseed oil microemulsion of cigarette according to claim 1, is characterized in that: the quality of described compound emulsifying agent is 0.5 ~ 1.5 times of described aniseed oil; The mass ratio of described compound emulsifying agent and described assistant for emulsifying agent is 3:2.
3. the water-soluble aniseed oil microemulsion of cigarette according to claim 1, is characterized in that: described compound emulsifying agent is in emulsifier lecithin, maltitol, lactitol, sucrose fatty ester, Tween-20, polyoxyethylene sorbitan monostearate, Tween-80 two kinds or more than two kinds; Described compound emulsifying agent by selected emulsifying agent with proportions.
4. the water-soluble aniseed oil microemulsion of cigarette according to claim 1, is characterized in that: described assistant for emulsifying agent is ethanol, propane diols or glycerine.
5. the water-soluble aniseed oil microemulsion of cigarette according to claim 1, is characterized in that: described cigarette is 70 ~ 99% with the envelop rate of water-soluble aniseed oil microemulsion.
6. a cigarette according to claim 1 preparation method of water-soluble aniseed oil microemulsion, it is characterized in that: aniseed oil, compound emulsifying agent and assistant for emulsifying agent are stirred according to after formula rate mixing, then adds water and be uniformly mixed into O/W type microemulsion.
7. the cigarette according to claim 6 preparation method of water-soluble aniseed oil microemulsion, is characterized in that: can use high speed dispersor, homogenizer or ultrasonic emulsator in described whipping process.
8. a cigarette according to claim 1 application for water-soluble aniseed oil microemulsion, is characterized in that: described cigarette can be used for cigarette flavoring essence with water-soluble aniseed oil microemulsion to be allocated.
9. the cigarette according to claim 8 application of water-soluble aniseed oil microemulsion, is characterized in that: described cigarette is 5 ~ 15% by the usage ratio of water-soluble aniseed oil microemulsion in cigarette flavoring essence.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510462613.1A CN105029667A (en) | 2015-07-31 | 2015-07-31 | Water-soluble anise oil microemulsion for cigarettes and preparation method and application thereof |
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| CN201510462613.1A CN105029667A (en) | 2015-07-31 | 2015-07-31 | Water-soluble anise oil microemulsion for cigarettes and preparation method and application thereof |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
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| CN106590931A (en) * | 2016-12-14 | 2017-04-26 | 江西中烟工业有限责任公司 | Preparation method of cigarette protein-polysaccharide composite emulsion carrier system and application of carrier system in cigarettes |
| CN107937134A (en) * | 2017-12-13 | 2018-04-20 | 湖北中烟工业有限责任公司 | Preparation method for the sweet orange oil Microemulsions For Use of cigarette blending |
| CN107937134B (en) * | 2017-12-13 | 2021-04-02 | 湖北中烟工业有限责任公司 | Preparation method of sweet orange oil microemulsion for cigarette flavoring |
| CN109957449A (en) * | 2017-12-25 | 2019-07-02 | 广州华芳烟用香精有限公司 | A kind of soluble perfume and preparation method thereof |
| CN114214117A (en) * | 2021-12-13 | 2022-03-22 | 云南中烟工业有限责任公司 | Method for improving release balance of limonene in bergamot oil essence |
| CN114259893A (en) * | 2021-12-13 | 2022-04-01 | 云南中烟工业有限责任公司 | Preparation method of microemulsion spice with high stability and high utilization rate and application of microemulsion spice in improving cigarette tobacco quality |
| CN114214117B (en) * | 2021-12-13 | 2023-09-15 | 云南中烟工业有限责任公司 | Method for improving limonene release balance in bergamot oil essence |
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