CN110130147A - Cigarette tipping paper and preparation method thereof - Google Patents
Cigarette tipping paper and preparation method thereof Download PDFInfo
- Publication number
- CN110130147A CN110130147A CN201910447048.XA CN201910447048A CN110130147A CN 110130147 A CN110130147 A CN 110130147A CN 201910447048 A CN201910447048 A CN 201910447048A CN 110130147 A CN110130147 A CN 110130147A
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- China
- Prior art keywords
- coating
- mass parts
- paper
- cigarette tipping
- tipping paper
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Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/38—Coatings with pigments characterised by the pigments
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/46—Non-macromolecular organic compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H19/58—Polymers or oligomers of diolefins, aromatic vinyl monomers or unsaturated acids or derivatives thereof
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
Abstract
The invention discloses a kind of cigarette tipping papers, including the ink layer, original paper layer and the humectation coating formed by coating being cascading, the coating includes 20~45 mass parts of water-base resin, 2~12 mass parts of hygroscopic agent, 20~40 mass parts of 3~13 mass parts of humectant, 5~10 mass parts of filler and solvent.The invention also discloses a kind of preparation methods of cigarette tipping paper.
Description
Technical field
The present invention relates to wrapping paper technical fields, more particularly to a kind of cigarette tipping paper and preparation method thereof.
Background technique
In recent years, as cigarette consumption person is to cigarette packaging industry (including cigarette-brand, cigarette tipping paper, cigarette seal paper)
Esthetic requirement is higher and higher, and more and more cigarette brands select the magnificent bloom of using effect to help painting base stock in deisgn product
With base stock of aluminizing.Ink layer has sealed the porous structure of paper surface and to result in tipping paper table back side humectation rate different.It is connecing
During filling paper production, transport and cigarette, due to the temperature change and production of stoving process, cigarette process in process flow
Workshop, the variation of tobacco factory's ambient humidity, be easy to cause tipping paper moisture uneven and curling, alice phenomenon occur, final to influence tipping
Paper is used for upper machine adaptability when cigarette.
Summary of the invention
Based on this, it is necessary to be hinged with curl, alice and aiming at the problem that cause tipping paper cigarette Shi Shangji bad adaptability,
A kind of cigarette tipping paper and preparation method thereof is provided.
A kind of cigarette tipping paper, including the ink layer, original paper layer and the humectation coating formed by coating being cascading,
The coating include 20~45 mass parts of water-base resin, 2~12 mass parts of hygroscopic agent, 3~13 mass parts of humectant, filler 5~
20~40 mass parts of 10 mass parts and solvent.
The humectant includes malto-oligosaccharide alcohol, chitosan derivatives, NCS humectant in one of the embodiments,
With one of polyacrylic acid or a variety of.
The hygroscopic agent includes polyalcohols hygroscopic agent in one of the embodiments, the polyalcohols hygroscopic agent packet
Include one of propylene glycol, glycerol and sorbierite or a variety of.
The water-base resin includes polyacrylic resin, polyvinyl alcohol resin, polycarbonate in one of the embodiments,
One of resin, phenolic modified resin and aldehydic acid modified resin are a variety of, contain hydrophilic radical after the water-base resin film forming.
The matter of the quality sum of the hygroscopic agent and the humectant and the water-base resin in one of the embodiments,
Amount is than being (10~20): (20~30).
The filler includes calcium carbonate in one of the embodiments,.
The solvent includes water and alcohol in one of the embodiments, and the mass ratio of the water and alcohol is 1:(1~1.5).
The grammes per square metre of the humectation coating is the 3%~3.5% of the original paper layer grammes per square metre in one of the embodiments,.
The original paper layer is helped selected from plain paper, high glaze and is applied in paper and aluminium plating transfer paper in one of the embodiments,
It is a kind of.
A kind of preparation method of the cigarette tipping paper, comprising:
The original paper layer is provided, the original paper layer has opposite first surface and second surface;
Ink is provided, prints on the first surface or is coated with the ink and obtain the ink layer;And
It prints in the second surface or is coated with the coating and obtain the humectation coating.
The coating of the invention can be played in the humectation coating that the surface of the separate ink layer of original paper layer is formed to original
The closure of paper layer and the effect of humidity-preserving type, so that the ink layer and bottom that avoid tipping paper caused by moisture unevenness due to rolling up
Bent and alice problem.Water-base resin in the coating makes the coating surface of the body paper have certain closure, reduces
The sensibility that body paper changes Environmental Water.The hygroscopic agent has stronger hygroscopic effect, is formed in the humectation coating
Moisture absorption barrier locks the moisture in the body paper.The humectant has closure and humidity-preserving type, so that the water of the original paper layer
Divide and do not exchanged with the moisture in environment, avoids the moisture of the ink layer and the humectation coating inhomogenous.The filler
So that the coating surface has certain hardness.The closing of the sealing process, hygroscopic agent and humectant of the water-base resin and
Moisture retention and the durometer properties of the filler can act synergistically, and guarantee that the moisture of body paper is relatively stable, improve tipping paper with environment
Alice caused by changing and curling guarantee the planarization during tipping paper cigarette, machine adaptability and cigarette efficiency in raising.And
And the glue compatibility of the water-base resin and cigarette is good, improves cigarette effect.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of the cigarette tipping paper of one embodiment of the invention.
Specific embodiment
In order to make the objectives, technical solutions, and advantages of the present invention clearer, by the following examples, it and combines attached
Figure, is further elaborated cigarette tipping paper and preparation method thereof of the invention.It should be appreciated that tool described herein
Body embodiment only to explain the present invention, is not intended to limit the present invention.
The embodiment of the present invention provides a kind of cigarette tipping paper, including ink layer 200, the original paper layer 100 being cascading
With the humectation coating 300 formed by coating, the coating include 20~45 mass parts of water-base resin, 2~12 mass parts of hygroscopic agent,
20~40 mass parts of 3~13 mass parts of humectant, 5~10 mass parts of filler and solvent.
The humectation coating that the coating of the embodiment of the present invention is formed on the surface of the separate ink layer 200 of original paper layer 100
300 can play the role of the closure and humidity-preserving type to original paper layer 100, to avoid the ink layer 200 and bottom of tipping paper
Due to being crimped and alice problem caused by moisture unevenness.Water-base resin in the coating makes the coating surface of the body paper
With certain closure, the sensibility that body paper changes Environmental Water is reduced.The hygroscopic agent is made with stronger moisture absorption
With, the humectation coating 300 formed moisture absorption barrier, lock the moisture in the body paper.The humectant have closure and
Humidity-preserving type avoids the ink layer 200 and institute so that the moisture in the moisture and environment of the original paper layer 100 does not exchange
The moisture for stating humectation coating 300 is inhomogenous.The filler makes the coating surface have certain hardness.The water-base resin
Sealing process, hygroscopic agent and humectant closing and moisture retention and the durometer properties of the filler can act synergistically, guarantee former
The moisture of paper is relatively stable, improves tipping paper with alice caused by environmental change and curling, during guaranteeing tipping paper cigarette
Planarization, machine adaptability and cigarette efficiency in raising.Also, the glue compatibility of the water-base resin and cigarette is good, improves
Cigarette effect.
In one embodiment, the hygroscopic agent may include polyalcohols hygroscopic agent, and the polyalcohols hygroscopic agent includes
One of propylene glycol, glycerol and sorbierite are a variety of.Due to the polyhydroxy structure of polyalcohols itself, so that the hygroscopic agent
With stronger moisture pick-up properties.The humectant may include malto-oligosaccharide alcohol, chitosan derivatives, NCS humectant and gather
One of acrylic acid is a variety of.The humectant can close body paper while with moisture absorption, avoid in the body paper
Water loss into environment and the moisture in environment is avoided to enter in body paper.The hygroscopic agent and humectant collaboration are made
With, guarantee the moisture stabilization of the original paper layer 100 of the cigarette tipping paper, be conducive to keep tipping paper planarization and upper machine adapt to
Property.Also, the humectant not will cause subsequent cigarette process for the coating of cigarette tipping paper and the problem of peculiar smell occurs.
In one embodiment, the water-base resin may include polyacrylic resin, polyvinyl alcohol resin, polycarbonate resin
One of rouge, phenolic modified resin and aldehydic acid modified resin are a variety of, the good hydrophilic property of the water-base resin of the type, i.e. institute
Contain a large amount of hydrophilic radical after stating water-base resin film forming.And the closed performance of the water-base resin of the type is more preferable, and
It is more preferable with the dispersibility of the other components in the coating, be conducive to the mixing uniformity of the coating, advantageously ensure that described
The planarization of humectation coating 300.
The ratio of the water-base resin and the hygroscopic agent, humectant should cooperate, and guarantee the same of the closure
When can reach better humectation effect, guarantee the planarization of the cigarette tipping paper.It will if the aqueous resin content is excessively high
The step of humectation coating 300 for causing the coating to be formed is thicker, and the hardness and stiffness of paper increase, is unfavorable for subsequent cigarette.
If the hygroscopic agent and humectant too high levels, will lead to paper fibre imbibition, the picking phenomenon of paper is caused.Preferably, institute
It states hygroscopic agent and the quality sum of the humectant and the mass ratio of the water-base resin can be (10~20): (20~30).
In one embodiment, the filler may include calcium carbonate.
Preferably, the solvent may include water and alcohol, on the one hand alcoholic solution is conducive to the water-base resin as solvent
With the dissolution of the humectant, another party is conducive to the humectation coating 300 that the solvent in the coating evaporates and forms solid-like.
The alcohol can be selected from ethyl alcohol.Preferably, the mass ratio of the water and alcohol can be 1:(1~1.5).
In one embodiment, the coating can also include dispersing aid, and the dispersing aid is for reducing the coating
Viscosity, improve the mobility of each component in the coating, make each component of the coating disperse in the solvent more
It is even, save jitter time.The dispersing aid can in BKY111, DISPERBYK-193 and DISPERBYK-180 one
Kind is a variety of.
In one embodiment, the grammes per square metre (g/m of the humectation coating 3002) it can be the 100 grammes per square metre (g/m of original paper layer2)
3%~3.5%.In the range, the humectation coating 300 can preferably realize the closing to the original paper layer 100 and
Humectation, and the cigarette effect that the cigarette tipping paper will not be destroyed itself.
In one embodiment, the original paper layer 100 can be helped selected from plain paper, high glaze applies in paper and aluminium plating transfer paper
It is a kind of.The grammes per square metre of the original paper layer 100 can be 30g/m2~230g/m2。
In one embodiment, the thickness of the original paper layer 100 can be 60 μm~280 μm.The thickness of the ink layer 200
It can be 8 μm~15 μm.The thickness of the humectation coating 300 can be 6 μm~12 μm.
The embodiment of the present invention also provides the preparation method of cigarette tipping paper described in one kind, comprising:
S110, provides the original paper layer 100, and the original paper layer 100 has opposite first surface and second surface;
S120, provides ink, prints on the first surface or is coated with the ink and obtains the ink layer 200;With
And
S130 prints in the second surface or is coated with the coating and obtains the humectation coating 300.
The step S120 can also include the steps that for the ink after the printing or coating being dried, the drying
Temperature can be 50 DEG C~80 DEG C.The step S130 can also include that the coating after the printing or coating is dried
Step, the drying temperature can be 50 DEG C~80 DEG C.
The embodiment of the present invention also provides a kind of cigarette, including the cigarette tipping paper.The cigarette can also include mutual
The tobacco segment and filter segment of connection.The tipping paper is wrapped in the outside of the filter segment and Partial Tobacco section, and being used for will be described
Filter segment is connect with the tobacco segment.
Embodiment 1
Weigh raw material according to following mass fraction: 25 mass parts of polyacrylic resin, 7 mass parts of propylene glycol, malt are oligomeric
8 mass parts of sugar alcohol, 15 mass parts of 7 mass parts of calcium carbonate, 15 mass parts of water and ethyl alcohol.By raw material, 1000rpm is stirred at room temperature
It 0.5 hour, is uniformly mixed and obtains coating.
The common body paper is provided, the common body paper has opposite first surface and second surface.By ink in institute
It states and is printed on first surface and be dried to obtain ink layer 200 at 60 DEG C.The coating is printed in the second surface and at 60 DEG C
It is dried to obtain humectation coating 300, to obtain tipping paper.The grammes per square metre of humectation coating 300 is the 3% of body paper grammes per square metre.
Embodiment 2
Embodiment 2 is substantially the same manner as Example 1, and difference is only that the grammes per square metre of humectation coating 300 is 100 grammes per square metre of original paper layer
1%.
Embodiment 3
Embodiment 3 is substantially the same manner as Example 1, and distinguishing the polyacrylic resin being only that in coating is 40 mass parts, third
Glycol is 2 mass parts, malto-oligosaccharide alcohol is 4 mass parts.Coating composition are as follows: 40 mass parts of polyacrylic resin, 2 matter of propylene glycol
Measure part, 4 mass parts of malto-oligosaccharide alcohol, 5 mass parts of sorbierite, 15 mass of 7 mass parts of calcium carbonate, 15 mass parts of water and ethyl alcohol
Part.
Comparative example 1
Comparative example 1 is substantially the same manner as Example 1, and it includes body paper and ink layer 200 that difference, which is only that wrapping paper only, does not include
Humectation coating 300.
Comparative example 2
Comparative example 2 is substantially the same manner as Example 1, and difference is only that the oiliness ring that polyacrylic resin is replaced with etc. to quality
Oxygen resin.Coating composition are as follows: 25 mass parts of oiliness epoxy resin, 7 mass parts of propylene glycol, 8 mass parts of malto-oligosaccharide alcohol, carbonic acid
15 mass parts of 7 mass parts of calcium, 15 mass parts of water and ethyl alcohol.
Comparative example 3
Comparative example 3 is substantially the same manner as Example 1, and difference is only that not include humectant in coating.Coating composition are as follows: poly- third
25 mass parts of olefin(e) acid resin, 7 mass parts of propylene glycol, 15 mass parts of 7 mass parts of calcium carbonate, 15 mass parts of water and ethyl alcohol.
Comparative example 4
Comparative example 4 is substantially the same manner as Example 1, and difference is only that not include calcium carbonate in coating.Coating composition are as follows: poly- third
25 mass parts of olefin(e) acid resin, 7 mass parts of propylene glycol, 15 mass parts of 8 mass parts of malto-oligosaccharide alcohol, 15 mass parts of water and ethyl alcohol.
It is 70 DEG C by temperature is placed in after the tipping paper of embodiment 1-3 and comparative example 1-4 weighing (W1), relative humidity is
It is placed 24 hours in 20% climatic chamber, records the weight change and metamorphosis of tipping paper.As a result as shown in table 1 below.
Table 1
It can find out from table 1, the percentage of water loss after embodiment 1-3 is placed is respectively 0.68%, 1.56% and 1.04%, and
Wrapping paper still keeps planarization after placement, and volume does not occur and sticks up.And comparative example 1-4 place after percentage of water loss be respectively 4.86%,
2.76%, 3.3% and 2.22%, and tipping paper no longer planarization after placement, volume occurs and sticks up.To sum up, the embodiment of the present invention
The coating that is formed of bottom surface of the coating body paper that is printed on ink layer 200 there is preferable closing body paper and humectation ability, can
Prevent the moisture penetration of body paper from coming out, so as to solve to have the tipping paper of ink layer 200 to be placed in temperature height or drying
The volume as caused by the dehydration of bottom surface sticks up problem in environment, to guarantee the long-term planarization of tipping paper.Also, experiments have shown that coating
In resin middle type and water-base resin, humectant and filler ratio cooperate, be conducive to improve coating closing
Property and humectation.
It is 25 DEG C by temperature is placed in after the weighing of the tipping paper of embodiment 1-3 and comparative example 1-4, relative humidity is 80%
It is placed 24 hours in climatic chamber, records the weight (W2) and metamorphosis of tipping paper.As a result as shown in table 2 below.
Table 2
It can find out from table 2, the water absorption rate after embodiment 1-3 is placed is respectively 0.38%, 0.86% and 0.22%, and
Wrapping paper still keeps planarization after placement, and volume does not occur and sticks up.And comparative example 1-3 place after water absorption rate be respectively 5.34%,
1.78%, 3.22% and 2.72%, and wrapping paper no longer planarization after placement, volume occurs and sticks up.To sum up, the embodiment of the present invention
The coating that is formed of bottom surface of the coating body paper that is printed on ink layer 200 there is preferable closing body paper and humectation ability, can
Prevent the moisture penetration in environment from entering tipping paper, so as to solve to have the tipping paper of ink layer 200 be placed in humidity compared with
In high environment as bottom surface absorb water and caused by volume stick up problem, to guarantee the long-term planarization of tipping paper.Also, experiment card
The middle type of resin in bright coating and the ratio of water-base resin, humectant and filler cooperate, and are conducive to improve coating
Closure and humectation.
Each technical characteristic of embodiment described above can be combined arbitrarily, for simplicity of description, not to above-mentioned reality
It applies all possible combination of each technical characteristic in example to be all described, as long as however, the combination of these technical characteristics is not deposited
In contradiction, all should be considered as described in this specification.
The embodiments described above only express several embodiments of the present invention, and the description thereof is more specific and detailed, but simultaneously
Limitations on the scope of the patent of the present invention therefore cannot be interpreted as.It should be pointed out that for those of ordinary skill in the art
For, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to guarantor of the invention
Protect range.Therefore, the scope of protection of the patent of the invention shall be subject to the appended claims.
Claims (10)
1. a kind of cigarette tipping paper, which is characterized in that including be cascading ink layer, original paper layer and formed by coating
Humectation coating, the coating include 20~45 mass parts of water-base resin, 2~12 mass parts of hygroscopic agent, 3~13 mass of humectant
Part, 20~40 mass parts of 5~10 mass parts of filler and solvent.
2. cigarette tipping paper according to claim 1, which is characterized in that the humectant includes malto-oligosaccharide alcohol, shell
One of polysaccharid derivative, NCS humectant and polyacrylic acid are a variety of.
3. cigarette tipping paper according to claim 1, which is characterized in that the hygroscopic agent includes polyalcohols hygroscopic agent,
The polyalcohols hygroscopic agent includes one of propylene glycol, glycerol and sorbierite or a variety of.
4. cigarette tipping paper according to claim 1, which is characterized in that the water-base resin include polyacrylic resin,
One of polyvinyl alcohol resin, polycarbonate resin, phenolic modified resin and aldehydic acid modified resin are a variety of, the aqueous tree
Contain hydrophilic radical after rouge film forming.
5. cigarette tipping paper according to claim 1, which is characterized in that the quality of the hygroscopic agent and the humectant it
With with the mass ratio of the water-base resin be (10~20): (20~30).
6. cigarette tipping paper according to claim 1, which is characterized in that the filler includes calcium carbonate.
7. cigarette tipping paper according to claim 1, which is characterized in that the solvent includes water and alcohol, the water and alcohol
Mass ratio be 1:(1~1.5).
8. cigarette tipping paper according to claim 1, which is characterized in that the grammes per square metre of the humectation coating is the original paper layer
The 3%~3.5% of grammes per square metre.
9. cigarette tipping paper according to claim 1, which is characterized in that the original paper layer is selected from plain paper, high glaze helps
Apply one of paper and aluminium plating transfer paper.
10. a kind of preparation method of -9 described in any item cigarette tipping papers according to claim 1, comprising:
The original paper layer is provided, the original paper layer has opposite first surface and second surface;
Ink is provided, prints on the first surface or is coated with the ink and obtain the ink layer;And
It prints in the second surface or is coated with the coating and obtain the humectation coating.
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CN110652030A (en) * | 2019-09-26 | 2020-01-07 | 安徽集友纸业包装有限公司 | Sour and sweet gloss oil, preparation method thereof, tipping paper for cigarettes and cigarettes |
CN111501404A (en) * | 2020-04-28 | 2020-08-07 | 曲靖麒麟福牌印刷有限公司 | High-temperature-resistant antibacterial tipping paper gloss oil and preparation method thereof |
CN114013159A (en) * | 2021-11-17 | 2022-02-08 | 青岛嘉泽包装有限公司 | Production method of tipping paper for cigarettes with improved moisture and deformation resistance |
CN115726223A (en) * | 2022-12-01 | 2023-03-03 | 安徽集友纸业包装有限公司 | Cigarette tipping paper and preparation method and application thereof |
CN116356604A (en) * | 2022-12-30 | 2023-06-30 | 安徽集友纸业包装有限公司 | Cigarette tipping paper containing anti-adhesive layer, preparation method and application |
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CN110652030A (en) * | 2019-09-26 | 2020-01-07 | 安徽集友纸业包装有限公司 | Sour and sweet gloss oil, preparation method thereof, tipping paper for cigarettes and cigarettes |
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CN111501404A (en) * | 2020-04-28 | 2020-08-07 | 曲靖麒麟福牌印刷有限公司 | High-temperature-resistant antibacterial tipping paper gloss oil and preparation method thereof |
CN114013159A (en) * | 2021-11-17 | 2022-02-08 | 青岛嘉泽包装有限公司 | Production method of tipping paper for cigarettes with improved moisture and deformation resistance |
CN115726223A (en) * | 2022-12-01 | 2023-03-03 | 安徽集友纸业包装有限公司 | Cigarette tipping paper and preparation method and application thereof |
CN115726223B (en) * | 2022-12-01 | 2023-10-31 | 安徽集友纸业包装有限公司 | Tipping paper for cigarettes and preparation method and application thereof |
CN116356604A (en) * | 2022-12-30 | 2023-06-30 | 安徽集友纸业包装有限公司 | Cigarette tipping paper containing anti-adhesive layer, preparation method and application |
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