CN103711029B - Method for manufacturing aroma-increasing moisture retention cigarette paper - Google Patents

Method for manufacturing aroma-increasing moisture retention cigarette paper Download PDF

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CN103711029B
CN103711029B CN201310714874.9A CN201310714874A CN103711029B CN 103711029 B CN103711029 B CN 103711029B CN 201310714874 A CN201310714874 A CN 201310714874A CN 103711029 B CN103711029 B CN 103711029B
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cigarette paper
caco
filler
extract
tobacco
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CN103711029A (en
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刘德桃
陈进波
陈克复
阮蒙
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South China University of Technology SCUT
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South China University of Technology SCUT
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Abstract

The invention discloses a method for manufacturing aroma-increasing moisture retention cigarette paper. The method comprises the following steps: according to mass percent, firstly drying a CaCO3 filler till the moisture content of the filler is lower than 0.5%; emulsifying and modifying the dried CaCO3 filler under the effect of a stearic acid coupling agent for 0.5-3 minutes, dispersing 0.1-20% of tobacco extractive and fruit extractive relative to the mass percentage of the CaCO3 filler in an ethanol solution, loading an aroma-increasing component on the surface of the modified CaCO3 filler, and uniformly distributing the loaded and modified CaCO3 on paper by adopting a common papermaking technology, thus obtaining the aroma-increasing moisture retention cigarette paper. The method has the characteristics of good treatment effect, low cost, easy operation and the like; the produced novel aroma-increasing moisture retention cigarette paper has mellow fragrance, strong durability and improvement of quality of cigarettes; materials used in the method conform to the admittance criterion of additives for cigarette industries; and a relatively good processing effect can be obtained through the minor improvement in a production process.

Description

A kind of method manufacturing flavouring humectation cigarette paper
Technical field
The present invention relates to a kind of cigarette paper, particularly relate to a kind of functions of increasing aroma and keeping lubrication cigarette paper and preparation method thereof, belong to flavored type cigarette products field.
Background technology
In the last few years, domestic and international researcher mainly using tobacco waste as offal, tobacco leaf, offal etc. and extract thereof make to be used as much work as the auxiliary material of reconstituted tobacoo, and achieve some important achievement.As the people such as China An Rui (pacify auspicious, Xie Yimin, Wang Lei, Wang Fenglan, Yao Yuanjun, the preparation and property research of tobacco thin-sheet type cigarette paper, China's papermaking, 2012,31(1): be 45 ?48) that waste obtains chemi-mechanical pulp and a small amount of wood pulp and joins and be copied into tobacco thin-sheet type cigarette paper with offal, again the extract through water extracting offal is coated on cigarette paper, making tobacco sheet type cigarette paper (26g/m 2), its wooden assorted gas reduces, and excitant reduces, and quality is got a promotion, but the active ingredient of load is volatile, and protecting Xiang Gong can be poor.(the Yang Shaowen such as Yang Shaowen, Huanghai Sea group, Luo Lili, Zhu Zizhong, Shen Jingxuan, Xiao Weiyi, the research and development of brown cigarette paper and application, tobacco science and technology, 2009,5:5 ?9) select to adopt tobacco extract, black tea, acorn nut husk, walnut shell, the natural extract of cocoa shell and food coloring etc. to prepare brown cigarette paper for toner, its chroma stability and additive to the fume indication of cigarette and suction quality without negative effect.Relevant scholar by natural natural plants as peppermint extract effective constituents molecule encapsulated menthol is coated on cigarette body paper, make characteristic peppermint type cigarette tissue to coat on cigarette paper or reconstituted tobacoo and prepare mint type cigarette product (Huang Fu, Liu Bin, Wang Pingjun, the development & application of characteristic peppermint type cigarette tissue, Chinese papermaking, 2012,31(1): 42 ?44), the parent being subject to market looks at.And adopt the flavouring active component that fruit extracts to make an addition in cigarette material to use and seldom have relevant research report.
But relevant scholar is found by research, by being organic matter by the active ingredient great majority of extracting, there is volatile feature, and to be added on cigarette paper or reconstituted tobacoo by the mode of coating and easily to produce fragrance and run off serious or be difficult to lasting serious consequence, and the burn rate of cigarette, degree of ventilation, puff number can be caused, master (side) flows flue gas etc. and is difficult to control.Therefore, adopting a kind of new technology to make to add flavouring organic matter to can protect lastingly fragrant, remarkable enhancing fragrance satisfaction, therefore, under the prerequisite ensureing regular-size cigarette paper normal configuration, the high-purity glucosides class bonding state aroma substance extracted from fruit or tobacco loaded in cigarette paper, the New function of cigarette paper will be given, prepare novel flavoring humectation function cigarette goods.And this kind of high-purity glucosides class bonding state aroma substance etc. can obtain completely from a large amount of fruit products agricultural production, the new function cigarette paper of preparation will give the different function impression of cigarette and sensory evaluation.And China's research in this respect comparatively lacks, abroad in this respect due to the particularity of industry, most of achievement in research there is not yet report.
Summary of the invention
The object of the invention is to the deficiency overcoming prior art existence, provide a kind of fragrance lasting, functions of increasing aroma and keeping lubrication cigarette paper that cost is low and preparation method thereof.
For the fragrance improving flavored type cigarette product is abundant, lasting effect, the present invention proposes the flavor components that extracts from tobacco or fruit by the coupling agent modified CaCO such as stearic acid 3filler load, prepares novel flavoring functional cigarette paper and cigarette by the regular-size cigarette technology of manufacturing paper with pulp, make it strength power full, protect aromatic thick, promote the differentiation quality of cigarette product.The novel flavoring cigarette product flue gas continuous stability of preparation and combustion process thermodynamic property.Can overcome that surperficial rubbing method flavouring cigarette paper fragrance easily runs off, the deficiency of combustion heat poor stability.
The object of the invention is to be achieved through the following technical solutions:
Manufacture a method for flavouring humectation cigarette paper, it is characterized in that comprising the steps:
1) paddle dryer process: by percentage to the quality, CaCO 3paddle dryer process to moisture content lower than 0.5%;
2) coupling modifier: 3000 ?under 6000 revs/min of high-speed stirred, 40 ?at 80 DEG C of temperature, by dried CaCO 3filler the emulsified modification of the effect of stearic acid coupling agent 0.5 ?30min, be cooled to room temperature after modification; Described stearic acid addition is CaCO 3quality 0.1 ?5%;
3) extraction of tobacco extract: by tobacco sample section with after pulverizing, adopts NaOH solution vibration extracting, after extracting 2 DEG C ?4 DEG C of cryogenic conditions lower seals preserve; Described tobacco sample is one or more in offal, tobacco leaf discarded object and offal;
4) fruit extract: obtain after banana, apple, strawberry, red bayberry, water chestnut, pear or coconut are squeezed the juice and squeeze the juice, resin adsorption is separated, and wash-out, obtains purified product, through 30 DEG C ?50 DEG C of low temperature dryings and 2 DEG C ?4 DEG C of Cord blood;
5) extract components load C aCO 3filler: will relative to CaCO 3packing quality percentage be 0.1 ?20% tobacco extract and fruit extract be scattered in ethanolic solution, by mulser medium speed be 2000 ?mixed at high speed effect under 5000 revs/min of conditions, flavor components is carried on the CaCO of modification 3on filling surface; Described tobacco extract and fruit extract weight ratio 1 ?99%:1 ?99%;
6) the manufacturing paper with pulp of flavouring cigarette paper: adopt common papermaking process by the flavor components load C aCO of modification 3filler, softwood pulp, hemp are according to mass ratio (20 ?50%): (30 ?70%): (10 ?30%) prepare pulp suspension, flavouring humectation cigarette paper of manufacturing paper with pulp to obtain.
For realizing the object of the invention further, preferably, described CaCO 3paddle dryer process is dried to the concentration 0.2mol/L of moisture content lower than NaOH solution described in 0.5% through 105 DEG C.Described vibration extracting adopt NaOH solution 50 ?carry out with liquor ratio 10:1 under 70 DEG C of conditions.Described resin adsorption separation Amberlite XAD ?2 resin adsorption be separated.Described wash-out adopts ether, pentane and carrene continuous backflow wash-out 3 times, each wash-out 60 ?360min, then through methanol-eluted fractions.Described pulp suspension is 0.1% by percentage to the quality.Time of described mixed at high speed effect be 30 ?40 minutes.The mass concentration of described ethanolic solution is 10%.
Compared with prior art, the present invention has following characteristics:
(1) method of the present invention is the CaCO made full use of in cigarette paper 3filler is modification body, and the flavor components of extraction is loaded to CaCO by stearic acid 3on filling surface, production technology is simple, and cost is low, invests little, is easy to popularize.
(2) compared with traditional flavor components rubbing method, adopt internal chemical carrying method can protect fragrant flavouring well, fragrance is lasting, improves the quality of cigarette product.
(3) the present invention utilizes tobacco or fruit to be raw material, and the method for employing low energy consumption, environmental protection makes full use of renewable plant resources, meets the requirement of national environmental protection and sustainable development.
Accompanying drawing explanation
Fig. 1 is embodiment 1 cigarette paper CaCO 3scanning electron microscope (SEM) photograph before modified;
Fig. 2 is embodiment 1 cigarette paper CaCO 3modified scanning electron microscope (SEM) photograph;
Fig. 3 is embodiment 1 extract load C aCO 3rear scanning electron microscope (SEM) photograph.
Detailed description of the invention
For understanding the present invention better, below in conjunction with embodiment, the invention will be further described, but embodiments of the present invention are not limit so.
Embodiment 1
Manufacture a method for flavouring humectation cigarette paper, comprise the following steps:
1. cigarette paper CaCO 3the drying process of filler: by percentage to the quality, CaCO 3filler is dried to moisture content lower than 0.5% through 105 DEG C;
2. coupling modifier technique: under 4000 revs/min of high-speed stirred conditions, by dried CaCO 3filler and the mixing of stearic acid coupling agent, 50 DEG C of emulsified modification 30min of condition, are cooled to room temperature after modification; Stearic acid coupling agent consumption is relative to CaCO 3packing quality 4%; After tested, CaCO 3the activation grade of filler reaches 84%.After utilizing calcium carbonate surface process, hydrophobic changing features degree is to measure the coated activation degree of calcium carbonate surface.Concrete grammar is, take 2g sample, be placed in 250mL separatory funnel, add 200mL water, jolting 1min is come and gone with the speed of 120 times/min, then put down gently on funnel stand, leave standstill 20min, after obvious layering, lower floor's mixture is put into the crucible type filter being dried to constant weight in advance at 105 ± 5 DEG C, filter, except anhydrating, then moves in insulating box by suction filtration, is dried to constant weight at 105 ± 5 DEG C.Activation grade is calculated as follows: X=[1 ?(m2 ?m1)/m] × 100; X ?the activation grade that represents with mass percent; M ?the quality g of calcium carbonate sample; M2 ?the quality g of crucible and non-coated caco3 (countersink); M1 ?the quality g of crucible.
3. the extraction of tobacco extract: (1) tobacco extract: tobacco sample is offal; After above-mentioned tobacco sample is cut into slices respectively and pulverizing, dry with for subsequent use under 80 DEG C of conditions.Adopt the NaOH solution of 0.2mol/L to vibrate under 60 DEG C of conditions extracting (liquor ratio 10:1) to above-mentioned tobacco leaf particle, preserve at 2 DEG C of cryogenic conditions lower seals after extracting;
4. fruit extract: obtain after banana is squeezed the juice and squeeze the juice, with Amberlite XAD ?2 resin adsorption be separated into basis, adopt ether, pentane and carrene continuous backflow wash-out 3 times (each 300min), purified product is obtained again, through low temperature drying (30 DEG C) and Cord blood (2 DEG C) through methanol-eluted fractions process.
5. extract components load C aCO 3the preparation technology of filler: will relative to CaCO 3packing quality percentage be 10% tobacco extract and fruit extract (weight ratio 50%:50%) be scattered in ethanol (mass concentration is 10%), by mulser medium speed being the CaCO that flavor components to be carried on modification by mixed at high speed effect under 3500 revs/min of conditions 3on filling surface, temperature is room temperature condition.Figure 1 ?3 be CaCO 3before modified, (Fig. 1 is scanning electron microscope (SEM) photograph before modified to scanning electron microscope (SEM) photograph; Fig. 2 is modified scanning electron microscope (SEM) photograph; Fig. 3 is extract load C aCO 3rear scanning electron microscope (SEM) photograph).By the CaCO after stearic acid modified 3more coarse and some the imperceptible particle attachment of grain surface texture in its surface; And pass through after extract emulsification load, the attached full many pole fine particle in its surface, and in regularly arranged.
Through detecting: extract is at modification CaCO 3load factor reaches 42%.Utilize the load factor measuring modified calcium carbonate surface through the changes in weight degree of stearic acid modified calcium carbonate before and after load.Concrete grammar is, takes the forward and backward modified calcium carbonate sample of 2g sample load extract and is placed at 40 DEG C of vacuumizes to constant weight, and weigh.Load factor is calculated as follows: X=[1 ?(m2 ?m1)/m] × 100; X ?the load factor that represents with mass percent; M2 ?the quality g of crucible and load extract post-modification calcium carbonate sample; M1 ?the quality g of modified calcium carbonate sample after load extract.
6. the manufacturing paper with pulp of flavouring cigarette paper: adopt common papermaking process by the flavor components load C aCO of step 4 modification 3filler, softwood pulp, hemp are according to mass ratio (30%): (50%): (20%) prepares 0.1% mass concentration pulp suspension, are quantitatively 35g/cm according to manufacturing paper with pulp at sheet forming apparatus 2pattern, after dry to be detected.
After testing, CaCO can be carried on well by obtaining effective extract 3on the surface, cigarette paper sensory evaluating smoking evaluates well.Sensory evaluating smoking's method adopts overall round-robin method and method of comparison, just refers to that flue gas direct oral cavity sucks, throat swallows, nasal cavity is breathed out, and catches the overall process of smoke transportation when smokeing panel test.
Embodiment 2
Manufacture new method and the production technology thereof of flavouring humectation cigarette paper, it comprises the following steps:
1. cigarette paper CaCO 3the drying process of filler, by percentage to the quality, CaCO 3moisture content is dried to lower than 0.5% through 105 DEG C.
2. coupling modifier technique: by dried CaCO 3filler, will relative to CaCO under high-speed stirred (4000 revs/min) effect of emulsifying agent 3packing quality percentage be the stearic acid of 3% at 50 DEG C of emulsified modification 30min of condition, be cooled to room temperature after modification;
3. the extraction of tobacco extract: tobacco sample is tobacco leaf; After tobacco sample is cut into slices respectively and pulverizing, adopt 0.2mol/LNaOH solution to vibrate under 60 DEG C of conditions extracting (liquor ratio 10:1) to above-mentioned tobacco leaf particle, preserve at low temperature (2 DEG C) condition lower seal after extracting;
4. fruit extract: obtain after apple is squeezed the juice and squeeze the juice, with Amberlite XAD ?2 resin adsorption be separated into basis, adopt ether, pentane and carrene continuous backflow wash-out 3 times (each 300min), purified product is obtained again, through low temperature drying (30 DEG C) and Cord blood (2 DEG C) through methanol-eluted fractions process.
5. extract components load C aCO 3the preparation technology of filler: will relative to CaCO 3packing quality percentage be 15% tobacco extract and fruit extract be scattered in (weight ratio 1%:99%) ethanol (mass concentration is 10%), by flavor components being carried in mulser high speed immixture the CaCO of modification 3on filling surface, emulsification rotating speed is 4500 revs/min, and temperature is room temperature condition.
6. the manufacturing paper with pulp of flavouring cigarette paper: adopt common papermaking process by the flavor components load C aCO of modification 3filler, softwood pulp, hemp are according to mass ratio (25%): (45%): (30%) prepares 0.1% consistency pulp suspensions, according to manufacturing paper with pulp at sheet forming apparatus be quantitatively 30 ?50g/cm 2pattern, after dry to be detected
After testing, adopt the method described in this example to obtain effective tobacco extract and fruit aroma component, and make CaCO by stearic acid modified 3the activation grade of filler reaches 88%, and extraction components load factor reaches 56%, and cigarette paper sensory evaluating smoking evaluate well.
Embodiment 3
Manufacture new method and the production technology thereof of flavouring humectation cigarette paper, it comprises the following steps:
1. cigarette paper CaCO 3the drying process of filler, by percentage to the quality, CaCO 3moisture content is dried to lower than 0.5% through 105 DEG C.
2. coupling modifier technique: coupling modifier technique: by dried CaCO 3filler, will relative to CaCO under high-speed stirred (4000 revs/min) effect of emulsifying agent 3packing quality percentage be the stearic acid of 5% at 50 DEG C of emulsified modification 30min of condition, be cooled to room temperature after modification;
3. the extraction of tobacco extract: tobacco sample is offal; After above-mentioned tobacco sample is cut into slices respectively and pulverizing, adopt 0.2mol/L NaOH solution to vibrate under 60 DEG C of conditions extracting (liquor ratio 10:1) to above-mentioned tobacco leaf particle, preserve at low temperature (2 DEG C) condition lower seal after extracting;
4. fruit extract: obtain after strawberry is squeezed the juice and squeeze the juice, with Amberlite XAD ?2 resin adsorption be separated into basis, adopt ether, pentane and carrene continuous backflow wash-out 3 times (each 300min), purified product is obtained again, through low temperature drying (30 DEG C) and Cord blood (2 DEG C) through methanol-eluted fractions process.
5. extract components load C aCO 3the preparation technology of filler: will relative to CaCO 3packing quality percentage be 20% tobacco extract and fruit extract (weight ratio 30%:70%) be scattered in ethanol (mass concentration is 10%), by flavor components being carried in mulser high speed immixture the CaCO of modification 3on filling surface, emulsification rotating speed is 5000 revs/min, and temperature is room temperature condition.
5. the manufacturing paper with pulp of flavouring cigarette paper: adopt common papermaking process by the flavor components load C aCO of modification 3filler, softwood pulp, hemp are according to mass ratio (45%): (35%): (20%) prepares 0.1% consistency pulp suspensions, are quantitatively 35g/cm according to manufacturing paper with pulp at sheet forming apparatus 2pattern, after dry to be detected.
After testing, adopt the method described in this example to obtain effective tobacco extract and fruit aroma component, and make CaCO by stearic acid modified 3the activation grade of filler reaches 94%, and flavouring active principle load factor reaches 48%, and cigarette paper sensory evaluating smoking evaluate well.
Embodiment 4
Manufacture new method and the production technology thereof of flavouring humectation cigarette paper, it comprises the following steps:
1. cigarette paper CaCO 3the drying process of filler, by percentage to the quality, CaCO 3moisture content is dried to lower than 0.5% through 105 DEG C.
2. coupling modifier technique: by dried CaCO 3filler, will relative to CaCO under high-speed stirred (6000 revs/min) effect of emulsifying agent 3packing quality percentage be the stearic acid of 5% at 80 DEG C of emulsified modification 30min of condition, be cooled to room temperature after modification;
3. the extraction of tobacco extract: tobacco sample is offal and discarded object thereof; After above-mentioned tobacco sample is cut into slices respectively and pulverizing, adopt 0.2mol/L NaOH solution to vibrate under 60 DEG C of conditions extracting (liquor ratio 10:1) to above-mentioned tobacco leaf particle, preserve at low temperature (2 DEG C) condition lower seal after extracting;
4. fruit extract: obtain after red bayberry is squeezed the juice and squeeze the juice, with Amberlite XAD ?2 resin adsorption be separated into basis, adopt ether, pentane and carrene continuous backflow wash-out 3 times (each 300min), purified product is obtained again, through low temperature drying (30 DEG C) and Cord blood (2 DEG C) through methanol-eluted fractions process.
5. extract components load C aCO 3the preparation technology of filler: will relative to CaCO 3packing quality percentage be 13% tobacco extract and fruit extract (weight ratio 99%:1%) be scattered in ethanol (mass concentration is 10%), by flavor components being carried in mulser high speed immixture the CaCO of modification 3on filling surface, emulsification rotating speed is 3600 revs/min, and temperature is room temperature condition.
6. the manufacturing paper with pulp of flavouring cigarette paper: adopt common papermaking process by the flavor components load C aCO of modification 3filler, softwood pulp, hemp are according to mass ratio (35%): (35%): (30%) prepares 0.1% consistency pulp suspensions, are quantitatively 35g/cm according to manufacturing paper with pulp at sheet forming apparatus 2pattern, after dry to be detected.
After testing, adopt the method described in this example to obtain effective tobacco extract and fruit aroma component, and make CaCO by stearic acid modified 3the activation grade of filler reaches 82%, and flavouring active principle load factor reaches 66%, and cigarette paper sensory evaluating smoking evaluate well.
Embodiment 5
Manufacture new method and the production technology thereof of flavouring humectation cigarette paper, it comprises the following steps:
1. cigarette paper CaCO 3the drying process of filler, by percentage to the quality, CaCO 3moisture content is dried to lower than 0.5% through 105 DEG C.
2. coupling modifier technique: by dried CaCO 3filler, will relative to CaCO under high-speed stirred (5500 revs/min) effect of emulsifying agent 3packing quality percentage be the stearic acid of 4.5% at 65 DEG C of emulsified modification 25min of condition, be cooled to room temperature after modification;
3. the extraction of tobacco extract: tobacco sample is tobacco leaf and discarded object thereof; After above-mentioned tobacco sample is cut into slices respectively and pulverizing, adopt 0.2mol/L NaOH solution to vibrate under 65 DEG C of conditions extracting (liquor ratio 10:1) to above-mentioned tobacco leaf particle, preserve at low temperature (2 DEG C) condition lower seal after extracting;
4. fruit extract: obtain after water chestnut is squeezed the juice and squeeze the juice, with Amberlite XAD ?2 resin adsorption be separated into basis, adopt ether, pentane and carrene continuous backflow wash-out 3 times (each 320min), purified product is obtained again, through low temperature drying (30 DEG C) and Cord blood (2 DEG C) through methanol-eluted fractions process.
5. extract components load C aCO 3the preparation technology of filler: will relative to CaCO 3packing quality percentage be 0.6% tobacco extract and fruit extract (weight ratio 20%:80%) be scattered in ethanol (mass concentration is 10%), by flavor components being carried in mulser high speed immixture the CaCO of modification 3on filling surface, emulsification rotating speed is 3000 revs/min, and temperature is room temperature condition.
5. the manufacturing paper with pulp of flavouring cigarette paper: adopt common papermaking process by the flavor components load C aCO of modification 3filler, softwood pulp, hemp are according to mass ratio (25%): (65%): (10%) prepares 0.1% consistency pulp suspensions, are quantitatively 35g/cm according to manufacturing paper with pulp at sheet forming apparatus 2pattern, after dry to be detected.
After testing, adopt the method described in this example to obtain effective tobacco extract and fruit aroma component, and make CaCO by stearic acid modified 3the activation grade of filler reaches 79%, and flavouring active principle load factor reaches 38%, and cigarette paper sensory evaluating smoking evaluates not good enough.
Embodiment 6
Manufacture new method and the production technology thereof of flavouring humectation cigarette paper, it comprises the following steps:
1. cigarette paper CaCO 3the drying process of filler, by percentage to the quality, CaCO 3moisture content is dried to lower than 0.5% through 105 DEG C.
2. coupling modifier technique: by dried CaCO 3filler, will relative to CaCO under high-speed stirred (5000 revs/min) effect of emulsifying agent 3packing quality percentage be the stearic acid of 2.5% at 80 DEG C of emulsified modification 26min of condition, be cooled to room temperature after modification;
3. the extraction of tobacco extract: tobacco sample is offal and discarded object thereof; After above-mentioned tobacco sample is cut into slices respectively and pulverizing, adopt 0.2mol/L NaOH solution to vibrate under 80 DEG C of conditions extracting (liquor ratio 10:1) to above-mentioned tobacco leaf particle, preserve at low temperature (2 DEG C) condition lower seal after extracting;
4. fruit extract: obtain after pear is squeezed the juice and squeeze the juice, with Amberlite XAD ?2 resin adsorption be separated into basis, adopt ether, pentane and carrene continuous backflow wash-out 3 times (each 300min), purified product is obtained again, through low temperature drying (30 DEG C) and Cord blood (2 DEG C) through methanol-eluted fractions process.
5. extract components load C aCO 3the preparation technology of filler: will relative to CaCO 3packing quality percentage be 5% tobacco extract and fruit extract (weight ratio 70%:30%) be scattered in ethanol (mass concentration is 10%), by flavor components being carried in mulser high speed immixture the CaCO of modification 3on filling surface, emulsification rotating speed is 4000 revs/min, and temperature is room temperature condition.
6. the manufacturing paper with pulp of flavouring cigarette paper: adopt common papermaking process by the flavor components load C aCO of modification 3filler, softwood pulp, hemp are according to mass ratio (45%): (45%): (10%) prepares 0.1% consistency pulp suspensions, according to manufacturing paper with pulp at sheet forming apparatus be quantitatively 30 ?50g/cm 2pattern, after dry to be detected.
After testing, adopt the method described in this example to obtain effective tobacco extract and fruit aroma component, and make CaCO by stearic acid modified 3the activation grade of filler reaches 81%, and flavouring active principle load factor reaches 69%, and cigarette paper sensory evaluating smoking evaluates excellent.
Embodiment 7
Manufacture new method and the production technology thereof of flavouring humectation cigarette paper, it comprises the following steps:
1. cigarette paper CaCO 3the drying process of filler, by percentage to the quality, CaCO 3moisture content is dried to lower than 0.5% through 105 DEG C.
2. coupling modifier technique: by dried CaCO 3filler, will relative to CaCO under high-speed stirred (3000 revs/min) effect of emulsifying agent 3packing quality percentage be the stearic acid of 5% at 80 DEG C of emulsified modification 30min of condition, be cooled to room temperature after modification;
3. the extraction of tobacco extract: tobacco sample is offal; After tobacco sample is cut into slices respectively and pulverizing, adopt 0.2mol/LNaOH solution to vibrate under 60 DEG C of conditions extracting (liquor ratio 10:1) to above-mentioned tobacco leaf particle, preserve at low temperature (2 DEG C) condition lower seal after extracting;
4. fruit extract: obtain after coconut is squeezed the juice and squeeze the juice, with Amberlite XAD ?2 resin adsorption be separated into basis, adopt ether, pentane and carrene continuous backflow wash-out 3 times (each 60min), purified product is obtained again, through low temperature drying (30 DEG C) and Cord blood (2 DEG C) through methanol-eluted fractions process.
5. extract components load C aCO 3the preparation technology of filler: will relative to CaCO 3packing quality percentage be 8% tobacco extract and fruit extract (weight ratio 40%:60%) be scattered in ethanol (mass concentration is 10%), by flavor components being carried in mulser high speed immixture the CaCO of modification 3on filling surface, emulsification rotating speed be 2000 ?5000 revs/min, temperature is room temperature condition.
6. the manufacturing paper with pulp of flavouring cigarette paper: adopt common papermaking process by the flavor components load C aCO of modification 3filler, softwood pulp, hemp are according to mass ratio (35%): (50%): (15%) prepares 0.1% consistency pulp suspensions, are quantitatively 35g/cm according to manufacturing paper with pulp at sheet forming apparatus 2pattern, after dry to be detected.
After testing, adopt the method described in this example to obtain effective tobacco extract and fruit aroma component, and make CaCO by stearic acid modified 3the activation grade of filler reaches 99%, and flavouring active principle load factor reaches 75%, and cigarette paper sensory evaluating smoking evaluates excellent.
Embodiment 8
Manufacture new method and the production technology thereof of flavouring humectation cigarette paper, it comprises the following steps:
1. cigarette paper CaCO 3the drying process of filler, by percentage to the quality, CaCO 3moisture content is dried to lower than 0.5% through 105 DEG C.
2. coupling modifier technique: by dried CaCO 3filler, will relative to CaCO under high-speed stirred (5000 revs/min) effect of emulsifying agent 3packing quality percentage be the stearic acid of 3.5% at 70 DEG C of emulsified modification 20min of condition, be cooled to room temperature after modification;
3. the extraction of tobacco extract: tobacco sample is tobacco leaf; After tobacco sample is cut into slices respectively and pulverizing, adopt 0.2mol/LNaOH solution to vibrate under 55 DEG C of conditions extracting (liquor ratio 10:1) to above-mentioned tobacco leaf particle, preserve at low temperature (2 DEG C) condition lower seal after extracting;
4. fruit extract: obtain after banana and apple (mass ratio is 1:1) are squeezed the juice respectively and squeeze the juice, with Amberlite XAD ?2 resin adsorption be separated into basis, adopt ether, pentane and carrene continuous backflow wash-out 3 times (each 220min), purified product is obtained again, through low temperature drying (30 DEG C) and Cord blood (2 DEG C) through methanol-eluted fractions process.
5. extract components load C aCO 3the preparation technology of filler: will relative to CaCO 3packing quality percentage be 10% tobacco extract and fruit extract (weight ratio 10%:90%) be scattered in ethanol (mass concentration is 10%), by flavor components being carried in mulser high speed immixture the CaCO of modification 3on filling surface, emulsification rotating speed is 3500 revs/min, and temperature is room temperature condition.
6. the manufacturing paper with pulp of flavouring cigarette paper: adopt common papermaking process by the flavor components load C aCO of modification 3filler, softwood pulp, hemp are according to mass ratio (40%): (40%): (20%) prepares 0.1% consistency pulp suspensions, are quantitatively 35g/cm according to manufacturing paper with pulp at sheet forming apparatus 2pattern, after dry to be detected.
After testing, adopt the method described in this example to obtain effective tobacco extract and fruit aroma component, and make CaCO by stearic acid modified 3the activation grade of filler reaches 91%, and flavouring active principle load factor reaches 68%, and cigarette paper sensory evaluating smoking evaluates excellent.
Embodiment 9
Manufacture new method and the production technology thereof of flavouring humectation cigarette paper, it comprises the following steps:
1. cigarette paper CaCO 3the drying process of filler, by percentage to the quality, CaCO 3moisture content is dried to lower than 0.5% through 105 DEG C.
2. coupling modifier technique: by dried CaCO 3filler, will relative to CaCO under high-speed stirred (5600 revs/min) effect of emulsifying agent 3packing quality percentage be the stearic acid of 4.5% at 75 DEG C of emulsified modification 25min of condition, be cooled to room temperature after modification;
3. the extraction of tobacco extract: tobacco sample is offal; After above-mentioned tobacco sample is cut into slices respectively and pulverizing, adopt 0.2mol/L NaOH solution to vibrate under 60 DEG C of conditions extracting (liquor ratio 10:1) to above-mentioned tobacco leaf particle, preserve at low temperature (2 DEG C) condition lower seal after extracting;
4. fruit extract: obtain after banana, apple and strawberry (mass ratio 1:1:1) are squeezed the juice respectively and squeeze the juice, with AmberliteXAD ?2 resin adsorption be separated into basis, adopt ether, pentane and carrene continuous backflow wash-out 3 times (each 250min), purified product is obtained again, through low temperature drying (30 DEG C) and Cord blood (2 DEG C) through methanol-eluted fractions process.
5. extract components load C aCO 3the preparation technology of filler: will relative to CaCO 3packing quality percentage be 20% tobacco extract and fruit extract (weight ratio 90%:10%) be scattered in ethanol (mass concentration is 10%), by flavor components being carried in mulser high speed immixture the CaCO of modification 3on filling surface, emulsification rotating speed is 5000 revs/min, and temperature is room temperature condition.
6. the manufacturing paper with pulp of flavouring cigarette paper: adopt common papermaking process by the flavor components load C aCO of modification 3filler, softwood pulp, hemp are according to mass ratio (30%): (50%): (20%) prepares 0.1% consistency pulp suspensions, are quantitatively 35g/cm according to manufacturing paper with pulp at sheet forming apparatus 2pattern, after dry to be detected.
After testing, adopt the method described in this example to obtain effective tobacco extract and fruit aroma component, and make CaCO by stearic acid modified 3the activation grade of filler reaches 96%, and flavouring active principle load factor reaches 77%, and cigarette paper sensory evaluating smoking evaluates excellent.
Embodiment 10
Manufacture new method and the production technology thereof of flavouring humectation cigarette paper, it comprises the following steps:
1. cigarette paper CaCO 3the drying process of filler, by percentage to the quality, CaCO 3moisture content is dried to lower than 0.5% through 105 DEG C.
2. coupling modifier technique: by dried CaCO 3filler, will relative to CaCO under high-speed stirred (5200 revs/min) effect of emulsifying agent 3packing quality percentage be the stearic acid of 3.5% at 65 DEG C of emulsified modification 10min of condition, be cooled to room temperature after modification;
3. the extraction of tobacco extract: tobacco sample is offal, tobacco leaf or offal and discarded object thereof; After above-mentioned tobacco sample is cut into slices respectively and pulverizing, adopt 0.2mol/L NaOH solution to vibrate under 55 DEG C of conditions extracting (liquor ratio 10:1) to above-mentioned tobacco leaf particle, preserve at low temperature (2 DEG C) condition lower seal after extracting;
4. fruit extract: banana, apple, strawberry, red bayberry, water chestnut, pear, coconut (mass ratio is 1:1:1:1:1:1:1) are obtained after squeezing the juice respectively and squeezes the juice, with Amberlite XAD ?2 resin adsorption be separated into basis, adopt ether, pentane and carrene continuous backflow wash-out 3 times (each 220min), purified product is obtained again, through low temperature drying (30 DEG C) and Cord blood (2 DEG C) through methanol-eluted fractions process.
5. extract components load C aCO 3the preparation technology of filler: will relative to CaCO 3packing quality percentage be 15% tobacco extract and fruit extract (weight ratio 50%:50%) be scattered in ethanol (mass concentration is 10%), by flavor components being carried in mulser high speed immixture the CaCO of modification 3on filling surface, emulsification rotating speed is 4000 revs/min, and temperature is room temperature condition.
5. the manufacturing paper with pulp of flavouring cigarette paper: adopt common papermaking process by the flavor components load C aCO of modification 3filler, softwood pulp, hemp are according to mass ratio (40%): (50%): (10%) prepares 0.1% consistency pulp suspensions, are quantitatively 35g/cm according to manufacturing paper with pulp at sheet forming apparatus 2pattern, after dry to be detected.
After testing, adopt the method described in this example to obtain effective tobacco extract and fruit aroma component, and make CaCO by stearic acid modified 3the activation grade of filler reaches 88%, and flavouring active principle load factor reaches 79%, and cigarette paper sensory evaluating smoking evaluates excellent.

Claims (9)

1. manufacture a method for flavouring humectation cigarette paper, it is characterized in that comprising the steps:
1) paddle dryer process: by percentage to the quality, CaCO 3paddle dryer process to moisture content lower than 0.5%;
2) coupling modifier: 3000 ?under 6000 revs/min of high-speed stirred, 40 ?at 80 DEG C of temperature, by dried CaCO 3filler the emulsified modification of the effect of stearic acid coupling agent 0.5 ?30min, be cooled to room temperature after modification; Described stearic acid addition is CaCO 3quality 0.1 ?5%;
3) extraction of tobacco extract: by tobacco sample section with after pulverizing, adopts NaOH solution vibration extracting, after extracting 2 DEG C ?4 DEG C of cryogenic conditions lower seals preserve; Described tobacco sample is one or more in offal, tobacco leaf discarded object and offal;
4) fruit extract: obtain after banana, apple, strawberry, red bayberry, water chestnut, pear or coconut are squeezed the juice and squeeze the juice, resin adsorption is separated, and wash-out, obtains purified product, through 30 DEG C ?50 DEG C of low temperature dryings and 2 DEG C ?4 DEG C of Cord blood;
5) extract components load C aCO 3filler: will relative to CaCO 3packing quality percentage be 0.1 ?20% tobacco extract and fruit extract be scattered in ethanolic solution, by mulser medium speed be 2000 ?mixed at high speed effect under 5000 revs/min of conditions, flavor components is carried on the CaCO of modification 3on filling surface; Described tobacco extract and fruit extract weight ratio 1 ?99%:1 ?99%;
6) the manufacturing paper with pulp of flavouring cigarette paper: adopt common papermaking process by the flavor components load C aCO of modification 3filler, softwood pulp, hemp are according to mass ratio (20 ?50%): (30 ?70%): (10 ?30%) prepare pulp suspension, flavouring humectation cigarette paper of manufacturing paper with pulp to obtain.
2. the method for manufacture flavouring humectation cigarette paper according to claim 1, is characterized in that: described CaCO 3paddle dryer process is dried to moisture content lower than 0.5% through 105 DEG C.
3. the method for manufacture flavouring humectation cigarette paper according to claim 1, is characterized in that: the concentration 0.2mol/L of described NaOH solution.
4. the method for manufacture flavouring humectation cigarette paper according to claim 1, is characterized in that: described vibration extracting adopt NaOH solution 50 ?carry out with liquor ratio 10:1 under 70 DEG C of conditions.
5. the method for manufacture flavouring humectation cigarette paper according to claim 1, is characterized in that: described resin adsorption separation Amberlite XAD ?2 resin adsorption be separated.
6. the method for manufacture flavouring humectation cigarette paper according to claim 1, is characterized in that: described wash-out adopts ether, pentane and carrene continuous backflow wash-out 3 times, each wash-out 60 ?360min, then through methanol-eluted fractions.
7. the method for manufacture flavouring humectation cigarette paper according to claim 1, is characterized in that: described pulp suspension is 0.1% by percentage to the quality.
8. the method for manufacture flavouring humectation cigarette paper according to claim 1, is characterized in that: time of described mixed at high speed effect be 30 ?40 minutes.
9. the method for manufacture flavouring humectation cigarette paper according to claim 1, is characterized in that: the mass concentration of described ethanolic solution is 10%.
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