CN103694683A - Color master batch for nylon - Google Patents
Color master batch for nylon Download PDFInfo
- Publication number
- CN103694683A CN103694683A CN201310737863.2A CN201310737863A CN103694683A CN 103694683 A CN103694683 A CN 103694683A CN 201310737863 A CN201310737863 A CN 201310737863A CN 103694683 A CN103694683 A CN 103694683A
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- Prior art keywords
- stabilizer
- antioxidant
- nylon
- agent
- master batch
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/17—Amines; Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3472—Five-membered rings
- C08K5/3475—Five-membered rings condensed with carbocyclic rings
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/524—Esters of phosphorous acids, e.g. of H3PO3
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2310/00—Masterbatches
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a color master batch for nylon. The color master batch consists of the following ingredients of gray coloring agent, polyamine resin, composite stabilizer, moisture absorbent, photo-induced energy storage noctilucent powder and dispersant, wherein the composite stabilizer at least comprises two of a hindered phenol antioxidant, a phosphite ester antioxidant, a cupric halide stabilizer, a hindered amine light stabilizer, a hydrolysis resistant agent, a diphenyl ketone ultraviolet absorbent and a benzotriazole ultraviolet absorbent. Compared with the prior art, the color master batch has the advantages that a synergistic effect is produced by multiple stabilizers through the compounding of the multiple stabilizers, and the stability of the material is ensured no matter in the processing process or during long-term outdoor use; the mechanical performance of the material is better; the color master batch is suitable for the design and the application of high-end nylon products having requirements on long-term weather-proofing.
Description
Technical field
The invention belongs to the technical field of coloring plastic, relate in particular to a kind of nylon Masterbatch.
Background technology
Master batch is a kind of plastics of the sixties in 20th century exploitation, the painted product innovation of fiber, and it is that pigment super quantity is attached in resin and the mixture of the polymkeric substance making uniformly.Masterbatch chief component is tinting material, carrier, dispersion agent three parts.
According to related data, learn that the average annual growth rate of demand about 7%-9% of the other countries of Asia to Masterbatch can China be 20% left and right to the average annual growth rate of demand of Masterbatch.Estimate that China will become the fastest-rising market of Masterbatch demand.Particularly colored and add master batch, China wants dependence on import.China has become the largest production state in Masterbatch market, Asia and has consumed state.Relevant expert thinks, following Masterbatch will be towards multifunction, high color content and high technology content future development.
And common nylon master batch adds in nylon raw material, cannot guarantee the stability in material work in-process and outdoor use, generally all can reduce the mechanical property of material, thereby reduce the design and use life-span of product.
Summary of the invention
The present invention is directed to deficiency of the prior art, a kind of rear nylon Masterbatch little to nylon Effect on Mechanical Properties that add is provided.
In order to solve the problems of the technologies described above, the present invention is solved by following technical proposals: a kind of nylon Masterbatch, it is characterized in that by weight percentage, composed of the following components: gray colored agent 10%-20%, polyamide resin 30%-50%, one package stabilizer 5%-15%, moisture-removing agent 10%-15%, photo-induced energy storage luminescent powder 10%-15%, dispersion agent 3%-10%; Described one package stabilizer at least comprises two kinds in Hinered phenols antioxidant, phosphite ester kind antioxidant, copper halide class stablizer, hindered amine light stabilizer, hydrolysis-resisting agent, benzophenone, Benzotriazole Ultraviolet Stabilizer.Compared with prior art, the present invention mainly adopts the composite of plurality of stable agent, make various stablizers produce synergistic effect, guarantee that material neutralizes out of doors and can guarantee stability in life-time service in the course of processing, the mechanical property of material is better, is applicable to high-end nylon product design and the application of long-term weather-proof requirement.Meanwhile, in the present invention, add photo-induced energy storage luminescent powder, made the nylon product also can be luminous at night, avoided passerby under high speed, to touch the danger of nylon rope; Added moisture-removing agent, there is the effect of removing the moisture in plastics, the performance of nylon is further improved.
As preferred version: above-mentioned one package stabilizer at least comprises two kinds in Hinered phenols antioxidant, hindered amine light stabilizer, Benzotriazole Ultraviolet Stabilizer and phosphite ester kind antioxidant.Hinered phenols antioxidant and hindered amine light stabilizer be hydroperoxide decomposition and Trapped free radical effectively, and both are a bit similar, but hindered amine light stabilizer can cyclic regeneration, and Hinered phenols antioxidant is disposable; UV light absorber can effectively absorb sunlight middle-ultraviolet lamp, reduces by UV-induced photoaging; Phosphite ester kind antioxidant is brought into play antioxidant effect as hydrogen peroxide decomposition agent and radical trapping agent in polymkeric substance, use substantially without obvious effect separately, but play synergy with Hinered phenols antioxidant, obviously reinforcement material neutralizes out of doors and can guarantee stability in life-time service in the course of processing.
As preferably, above-mentioned one package stabilizer is comprised of Hinered phenols antioxidant, hindered amine light stabilizer, Benzotriazole Ultraviolet Stabilizer and phosphite ester kind antioxidant; By weight percentage, Hinered phenols antioxidant 25%-35% wherein, hindered amine light stabilizer 15%-25%, Benzotriazole Ultraviolet Stabilizer 20%-30%, phosphite ester kind antioxidant 20%-30%.By Hinered phenols antioxidant, phosphite ester kind antioxidant
,the quaternary system that hindered amine light stabilizer, Benzotriazole Ultraviolet Stabilizer form has good stabilising effect to the long-term weatherability of nylon product.Only use Hinered phenols antioxidant and hindered amine light stabilizer binary system, during nylon material tensile strength retention rate 50%, the required burn-in test time is 2450 hours, while containing the nylon product tensile strength retention rate 70% that above-mentioned quaternary system forms, the required burn-in test time is 6200 hours, Each performs its own functions for four kinds of stablizers, has significantly collaborative synergistic effect.
As preferably, above-mentioned dispersion agent at least comprises a kind of in ethene-vinyl acetate wax, ethylene bis stearic amide, pentaerythritol stearate.
As preferably, above-mentioned gray colored agent is a kind of in black of carbon black, ferromanganese.
The present invention compared with prior art, there is following beneficial effect: the present invention mainly adopts the composite of plurality of stable agent, make various stablizers produce synergistic effect, guarantee that material neutralizes out of doors and can guarantee stability in life-time service in the course of processing, the mechanical property of material is better, is applicable to high-end nylon product design and the application of long-term weather-proof requirement.Meanwhile, in the present invention, add photo-induced energy storage luminescent powder, made the nylon product also can be luminous at night, avoided passerby under high speed, to touch the danger of nylon rope; Added moisture-removing agent, there is the effect of removing the moisture in plastics, the performance of nylon is further improved.
Embodiment
Below in conjunction with embodiment, the present invention is described in further detail: embodiment 1.
A nylon Masterbatch, by weight percentage, composed of the following components: ferromanganese is black 10%, polyamide resin 45%, one package stabilizer 10%, moisture-removing agent 15%, photo-induced energy storage luminescent powder 15%, dispersion agent 5%.
Wherein, one package stabilizer is comprised of Hinered phenols antioxidant and phosphite ester kind antioxidant, and by weight, Hinered phenols antioxidant is one package stabilizer 60%, and phosphite ester kind antioxidant is one package stabilizer 40%; Dispersion agent is ethene-vinyl acetate wax.
Embodiment 2.
Gray colored agent 10%-20%, polyamide resin 30%-50%, one package stabilizer 5%-15%, moisture-removing agent 10%-15%, photo-induced energy storage luminescent powder 10%-15%, dispersion agent 3%-10%.
A nylon Masterbatch, by weight percentage, composed of the following components: carbon black 20%, polyamide resin 35%, one package stabilizer 15%, moisture-removing agent 10%, photo-induced energy storage luminescent powder 10%, dispersion agent 10%.
Wherein, one package stabilizer is comprised of Hinered phenols antioxidant, hindered amine light stabilizer, Benzotriazole Ultraviolet Stabilizer and phosphite ester kind antioxidant; By weight percentage, wherein Hinered phenols antioxidant 35%, hindered amine light stabilizer 15%, Benzotriazole Ultraviolet Stabilizer 30%, phosphite ester kind antioxidant 20%; Dispersion agent is pentaerythritol stearate.
Comparative example 1.
Ferromanganese is black 20%, polyamide resin 35%, Hinered phenols antioxidant 15%, moisture-removing agent 10%, photo-induced energy storage luminescent powder 10%, dispersion agent 10%.
Comparative example 2.
Ferromanganese is black 20%, polyamide resin 35%, phosphite ester kind antioxidant 10%, moisture-removing agent 15%, photo-induced energy storage luminescent powder 15%, dispersion agent 5%.
Experimental result: embodiment 1, during nylon material tensile strength retention rate 50%, the required burn-in test time is 2650 hours; Embodiment 2, and during nylon material tensile strength retention rate 70%, the required burn-in test time is 5370 hours; Comparative example 1, during nylon material tensile strength retention rate 50%, the required burn-in test time is, 1660 hours; Comparative example 2, during nylon material tensile strength retention rate 50%, the required burn-in test time is, 1740 hours.
Claims (5)
1. a nylon Masterbatch, is characterized in that by weight percentage, composed of the following components: gray colored agent 10%-20%, polyamide resin 30%-50%, one package stabilizer 5%-15%, moisture-removing agent 10%-15%, photo-induced energy storage luminescent powder 10%-15%, dispersion agent 3%-10%; Described one package stabilizer at least comprises two kinds in Hinered phenols antioxidant, phosphite ester kind antioxidant, copper halide class stablizer, hindered amine light stabilizer, hydrolysis-resisting agent, benzophenone, Benzotriazole Ultraviolet Stabilizer.
2. a kind of nylon Masterbatch according to claim 1, is characterized in that: described one package stabilizer at least comprises two kinds in Hinered phenols antioxidant, hindered amine light stabilizer, Benzotriazole Ultraviolet Stabilizer and phosphite ester kind antioxidant.
3. a kind of nylon Masterbatch according to claim 2, is characterized in that: described one package stabilizer is comprised of Hinered phenols antioxidant, hindered amine light stabilizer, Benzotriazole Ultraviolet Stabilizer and phosphite ester kind antioxidant; By weight percentage, Hinered phenols antioxidant 25%-35% wherein, hindered amine light stabilizer 15%-25%, Benzotriazole Ultraviolet Stabilizer 20%-30%, phosphite ester kind antioxidant 20%-30%.
4. according to a kind of nylon Masterbatch described in arbitrary claim in claims 1 to 3, it is characterized in that: described dispersion agent at least comprises a kind of in ethene-vinyl acetate wax, ethylene bis stearic amide, pentaerythritol stearate.
5. a kind of nylon Masterbatch according to claim 4, is characterized in that: described gray colored agent is a kind of in black of carbon black, ferromanganese.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310737863.2A CN103694683A (en) | 2013-12-28 | 2013-12-28 | Color master batch for nylon |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310737863.2A CN103694683A (en) | 2013-12-28 | 2013-12-28 | Color master batch for nylon |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103694683A true CN103694683A (en) | 2014-04-02 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310737863.2A Pending CN103694683A (en) | 2013-12-28 | 2013-12-28 | Color master batch for nylon |
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| CN (1) | CN103694683A (en) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105196738A (en) * | 2015-09-10 | 2015-12-30 | 蚌埠市神龙笔业有限公司 | Manufacturing method of fluorescent wooden pencils |
| CN105400184A (en) * | 2015-12-21 | 2016-03-16 | 慈溪康氏新材料有限公司 | Polyamide color master batch, and preparation method thereof |
| CN106497035A (en) * | 2016-10-19 | 2017-03-15 | 苏州瑞斯格电子科技有限公司 | A kind of PA Masterbatch with dust-proof antibiotic aging-resistant function |
| CN106968025A (en) * | 2017-05-08 | 2017-07-21 | 福建景丰科技有限公司 | A kind of elastic filament of original liquid coloring grey polyamide fibre 6 and its production method |
| CN109206639A (en) * | 2018-08-23 | 2019-01-15 | 嵊州市仲明新材料科技有限公司 | Modified plastics Masterbatch and preparation method thereof |
| CN109280370A (en) * | 2018-08-16 | 2019-01-29 | 铜山县恒丰机械有限公司 | A kind of reusable engineering machinery nylon material |
| CN110591124A (en) * | 2019-09-30 | 2019-12-20 | 华南理工大学 | Polyamide color master batch dispersed by supercritical carbon dioxide and preparation method thereof |
| CN111155192A (en) * | 2020-01-15 | 2020-05-15 | 福建中锦新材料有限公司 | Water-absorbing chinlon spinning black masterbatch and preparation method thereof |
| CN111892809A (en) * | 2020-06-23 | 2020-11-06 | 明新孟诺卡(浙江)新材料有限公司 | Color master batch for blue-color yarns and preparation method thereof |
| CN112745674A (en) * | 2020-12-26 | 2021-05-04 | 广东九彩新材料有限公司 | High-pigment carbon black-polyamide color master batch and preparation method thereof |
| CN113683883A (en) * | 2021-08-19 | 2021-11-23 | 金旸（厦门）新材料科技有限公司 | Polyamide composition and preparation method and application thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1649970A (en) * | 2002-05-01 | 2005-08-03 | 西巴特殊化学品控股有限公司 | Pigment preparations |
| CN101070392A (en) * | 2007-06-18 | 2007-11-14 | 济南朗星科技有限公司 | Method for preparing luminous thermoplastic plastic parent particles |
-
2013
- 2013-12-28 CN CN201310737863.2A patent/CN103694683A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1649970A (en) * | 2002-05-01 | 2005-08-03 | 西巴特殊化学品控股有限公司 | Pigment preparations |
| CN101070392A (en) * | 2007-06-18 | 2007-11-14 | 济南朗星科技有限公司 | Method for preparing luminous thermoplastic plastic parent particles |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105196738A (en) * | 2015-09-10 | 2015-12-30 | 蚌埠市神龙笔业有限公司 | Manufacturing method of fluorescent wooden pencils |
| CN105400184A (en) * | 2015-12-21 | 2016-03-16 | 慈溪康氏新材料有限公司 | Polyamide color master batch, and preparation method thereof |
| CN106497035A (en) * | 2016-10-19 | 2017-03-15 | 苏州瑞斯格电子科技有限公司 | A kind of PA Masterbatch with dust-proof antibiotic aging-resistant function |
| CN106968025A (en) * | 2017-05-08 | 2017-07-21 | 福建景丰科技有限公司 | A kind of elastic filament of original liquid coloring grey polyamide fibre 6 and its production method |
| CN109280370A (en) * | 2018-08-16 | 2019-01-29 | 铜山县恒丰机械有限公司 | A kind of reusable engineering machinery nylon material |
| CN109206639A (en) * | 2018-08-23 | 2019-01-15 | 嵊州市仲明新材料科技有限公司 | Modified plastics Masterbatch and preparation method thereof |
| CN110591124A (en) * | 2019-09-30 | 2019-12-20 | 华南理工大学 | Polyamide color master batch dispersed by supercritical carbon dioxide and preparation method thereof |
| CN111155192A (en) * | 2020-01-15 | 2020-05-15 | 福建中锦新材料有限公司 | Water-absorbing chinlon spinning black masterbatch and preparation method thereof |
| CN111892809A (en) * | 2020-06-23 | 2020-11-06 | 明新孟诺卡(浙江)新材料有限公司 | Color master batch for blue-color yarns and preparation method thereof |
| CN112745674A (en) * | 2020-12-26 | 2021-05-04 | 广东九彩新材料有限公司 | High-pigment carbon black-polyamide color master batch and preparation method thereof |
| CN113683883A (en) * | 2021-08-19 | 2021-11-23 | 金旸（厦门）新材料科技有限公司 | Polyamide composition and preparation method and application thereof |
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Application publication date: 20140402 |
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| RJ01 | Rejection of invention patent application after publication |