CN103709735A - Wear-resistant anti-UV color master batch for nylon - Google Patents
Wear-resistant anti-UV color master batch for nylon Download PDFInfo
- Publication number
- CN103709735A CN103709735A CN201310738612.6A CN201310738612A CN103709735A CN 103709735 A CN103709735 A CN 103709735A CN 201310738612 A CN201310738612 A CN 201310738612A CN 103709735 A CN103709735 A CN 103709735A
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- China
- Prior art keywords
- stabilizer
- nylon
- antioxidant
- wear
- hindered amine
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/17—Amines; Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3472—Five-membered rings
- C08K5/3475—Five-membered rings condensed with carbocyclic rings
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/524—Esters of phosphorous acids, e.g. of H3PO3
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2310/00—Masterbatches
Abstract
The invention discloses a wear-resistant anti-UV color master batch for nylon, which is composed of a black colorant, a polyamide resin, a composite stabilizer, nano powdery solid particles, an infrared reflection pigment and a dispersing agent, wherein the composite stabilizer at least comprises two of hindered phenol antioxidant, phosphite antioxidant, copper halide stabilizer, hindered amine photostabilizer, anti-hydrolysis agent, diphenyl ketone and benzotriazole UV absorbent. Compared with the prior art, the various stabilizers are compounded to generate a synergistic effect, thereby ensuring the stability of the material in the working process and outdoor long-term usage process; and the material has better mechanical properties, and is suitable for design and application of high-end nylon products with requirements for long-term weather resistance. The infrared reflection pigment and nano powdery solid particles are added to greatly improve the service life and safety of the nylon.
Description
Technical field
The invention belongs to the technical field of coloring plastic, relate in particular to a kind of wear-resisting anti-UV nylon Masterbatch.
Background technology
Masterbatch is a kind of plastics of the sixties in 20th century exploitation, the painted product innovation of fiber, and it is that pigment super quantity is attached in resin and the mixture of the polymkeric substance making uniformly.Masterbatch chief component is tinting material, carrier, dispersion agent three parts.
According to related data, learn that the average annual growth rate of demand about 7%-9% of the other countries of Asia to Masterbatch can China be 20% left and right to the average annual growth rate of demand of Masterbatch.Estimate that China will become the fastest-rising market of Masterbatch demand.Particularly colored and add master batch, China wants dependence on import.China has become the largest production state in Masterbatch market, Asia and has consumed state.Relevant expert thinks, following Masterbatch will be towards multifunction, high color content and high technology content future development.
And common nylon master batch adds in nylon raw material, cannot guarantee the stability in material work in-process and outdoor use, generally all can reduce the mechanical property of material, thereby reduce the design and use life-span of product.
Summary of the invention
The present invention is directed to deficiency of the prior art, a kind of rear wear-resisting anti-UV nylon Masterbatch little to nylon Effect on Mechanical Properties that add is provided.
In order to solve the problems of the technologies described above, the present invention is solved by following technical proposals: a kind of wear-resisting anti-UV nylon Masterbatch, it is characterized in that by weight percentage, composed of the following components: black colorant 15%-35%, polyamide resin 25%-35%, one package stabilizer 5%-15%, nanoscale powder shape solid particulate 10%-15%, infrared reflecting paint 10%-15%, dispersion agent 3%-10%; Described one package stabilizer at least comprises two kinds in Hinered phenols antioxidant, phosphite ester kind antioxidant, copper halide class stablizer, hindered amine light stabilizer, hydrolysis-resisting agent, benzophenone, Benzotriazole Ultraviolet Stabilizer.Compared with prior art, the present invention mainly adopts the composite of plurality of stable agent, make various stablizers produce synergistic effect, guarantee that material neutralizes out of doors and can guarantee stability in life-time service in the course of processing, the mechanical property of material is better, is applicable to high-end nylon product design and the application of long-term weather-proof requirement.Meanwhile, added infrared reflecting paint in the present invention, the temperature in the time of can reducing nylon product and use out of doors, further strengthens its ageing resistance; Added nanoscale powder shape solid particulate, contributed to improve the wear resisting property of nylon, the work-ing life of nylon and security are improved greatly.
As preferred version: above-mentioned one package stabilizer at least comprises two kinds in Hinered phenols antioxidant, hindered amine light stabilizer, Benzotriazole Ultraviolet Stabilizer and phosphite ester kind antioxidant.Hinered phenols antioxidant and hindered amine light stabilizer be hydroperoxide decomposition and Trapped free radical effectively, and both are a bit similar, but hindered amine light stabilizer can cyclic regeneration, and Hinered phenols antioxidant is disposable; UV light absorber can effectively absorb sunlight middle-ultraviolet lamp, reduces by UV-induced photoaging; Phosphite ester kind antioxidant is brought into play antioxidant effect as hydrogen peroxide decomposition agent and radical trapping agent in polymkeric substance, use substantially without obvious effect separately, but play synergy with Hinered phenols antioxidant, obviously reinforcement material neutralizes out of doors and can guarantee stability in life-time service in the course of processing.
As preferably, above-mentioned one package stabilizer is comprised of Hinered phenols antioxidant, hindered amine light stabilizer, Benzotriazole Ultraviolet Stabilizer and phosphite ester kind antioxidant; By weight percentage, Hinered phenols antioxidant 25%-35% wherein, hindered amine light stabilizer 15%-25%, Benzotriazole Ultraviolet Stabilizer 20%-30%, phosphite ester kind antioxidant 20%-30%.By Hinered phenols antioxidant, phosphite ester kind antioxidant
,the quaternary system that hindered amine light stabilizer, Benzotriazole Ultraviolet Stabilizer form has good stabilising effect to the long-term weatherability of nylon product.Only use Hinered phenols antioxidant and hindered amine light stabilizer binary system, during nylon material tensile strength retention rate 50%, the required burn-in test time is 2450 hours, while containing the nylon product tensile strength retention rate 70% that above-mentioned quaternary system forms, the required burn-in test time is 6200 hours, Each performs its own functions for four kinds of stablizers, has significantly collaborative synergistic effect.
As preferably, above-mentioned dispersion agent at least comprises a kind of in ethene-vinyl acetate wax, ethylene bis stearic amide, pentaerythritol stearate.
As preferably, above-mentioned black colorant is a kind of in black of carbon black, nigrosine, ferromanganese.
The present invention compared with prior art, there is following beneficial effect: the present invention mainly adopts the composite of plurality of stable agent, make various stablizers produce synergistic effect, guarantee that material neutralizes out of doors and can guarantee stability in life-time service in the course of processing, the mechanical property of material is better, is applicable to high-end nylon product design and the application of long-term weather-proof requirement.Meanwhile, added infrared reflecting paint in the present invention, the temperature in the time of can reducing nylon product and use out of doors, further strengthens its ageing resistance; Added nanoscale powder shape solid particulate, contributed to improve the wear resisting property of nylon, the work-ing life of nylon and security are improved greatly.
Embodiment
Below in conjunction with embodiment, the present invention is described in further detail: embodiment 1.
A wear-resisting anti-UV nylon Masterbatch, by weight percentage, composed of the following components: carbon black 20%, polyamide resin 35%, one package stabilizer 10%, nanoscale powder shape solid particulate 15%, infrared reflecting paint 15%, dispersion agent 5%.
Wherein, one package stabilizer is comprised of Hinered phenols antioxidant and phosphite ester kind antioxidant, and by weight, Hinered phenols antioxidant is one package stabilizer 60%, and phosphite ester kind antioxidant is one package stabilizer 40%; Dispersion agent is ethene-vinyl acetate wax.
Embodiment 2.
A wear-resisting anti-UV nylon Masterbatch, by weight percentage, composed of the following components: ferromanganese is black 30%, polyamide resin 25%, one package stabilizer 15%, nanoscale powder shape solid particulate 10%, infrared reflecting paint 10%, dispersion agent 10%.
Wherein, one package stabilizer is comprised of Hinered phenols antioxidant, hindered amine light stabilizer, Benzotriazole Ultraviolet Stabilizer and phosphite ester kind antioxidant; By weight percentage, wherein Hinered phenols antioxidant 35%, hindered amine light stabilizer 15%, Benzotriazole Ultraviolet Stabilizer 30%, phosphite ester kind antioxidant 20%; Dispersion agent is pentaerythritol stearate.
Comparative example 1.
Ferromanganese is black 30%, polyamide resin 25%, Hinered phenols antioxidant 15%, nanoscale powder shape solid particulate 10%, infrared reflecting paint 10%, dispersion agent 10%.
Comparative example 2.
Ferromanganese is black 20%, polyamide resin 35%, phosphite ester kind antioxidant 10%, nanoscale powder shape solid particulate 15%, infrared reflecting paint 15%, dispersion agent 5%.
Experimental result: embodiment 1, during nylon material tensile strength retention rate 50%, the required burn-in test time is 2510 hours; Embodiment 2, and during nylon material tensile strength retention rate 70%, the required burn-in test time is 5420 hours; Comparative example 1, during nylon material tensile strength retention rate 50%, the required burn-in test time is, 1680 hours; Comparative example 2, during nylon material tensile strength retention rate 50%, the required burn-in test time is, 1740 hours.
Claims (5)
1. a wear-resisting anti-UV nylon Masterbatch, it is characterized in that by weight percentage, composed of the following components: black colorant 15%-35%, polyamide resin 25%-35%, one package stabilizer 5%-15%, nanoscale powder shape solid particulate 10%-15%, infrared reflecting paint 10%-15%, dispersion agent 3%-10%; Described one package stabilizer at least comprises two kinds in Hinered phenols antioxidant, phosphite ester kind antioxidant, copper halide class stablizer, hindered amine light stabilizer, hydrolysis-resisting agent, benzophenone, Benzotriazole Ultraviolet Stabilizer.
2. a kind of wear-resisting anti-UV nylon Masterbatch according to claim 1, is characterized in that: described one package stabilizer at least comprises two kinds in Hinered phenols antioxidant, hindered amine light stabilizer, Benzotriazole Ultraviolet Stabilizer and phosphite ester kind antioxidant.
3. a kind of wear-resisting anti-UV nylon Masterbatch according to claim 2, is characterized in that: described one package stabilizer is comprised of Hinered phenols antioxidant, hindered amine light stabilizer, Benzotriazole Ultraviolet Stabilizer and phosphite ester kind antioxidant; By weight percentage, Hinered phenols antioxidant 25%-35% wherein, hindered amine light stabilizer 15%-25%, Benzotriazole Ultraviolet Stabilizer 20%-30%, phosphite ester kind antioxidant 20%-30%.
4. according to a kind of wear-resisting anti-UV nylon Masterbatch described in arbitrary claim in claims 1 to 3, it is characterized in that: described dispersion agent at least comprises a kind of in ethene-vinyl acetate wax, ethylene bis stearic amide, pentaerythritol stearate.
5. a kind of wear-resisting anti-UV nylon Masterbatch according to claim 4, is characterized in that: described black colorant is a kind of in black of carbon black, nigrosine, ferromanganese.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310738612.6A CN103709735A (en) | 2013-12-28 | 2013-12-28 | Wear-resistant anti-UV color master batch for nylon |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310738612.6A CN103709735A (en) | 2013-12-28 | 2013-12-28 | Wear-resistant anti-UV color master batch for nylon |
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| Publication Number | Publication Date |
|---|---|
| CN103709735A true CN103709735A (en) | 2014-04-09 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310738612.6A Pending CN103709735A (en) | 2013-12-28 | 2013-12-28 | Wear-resistant anti-UV color master batch for nylon |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106589914A (en) * | 2016-11-03 | 2017-04-26 | 苏州圣鑫莱新材料有限公司 | Nano PA color master batch |
| CN113683883A (en) * | 2021-08-19 | 2021-11-23 | 金旸（厦门）新材料科技有限公司 | Polyamide composition and preparation method and application thereof |
Citations (5)
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|---|---|---|---|---|
| CN1649970A (en) * | 2002-05-01 | 2005-08-03 | 西巴特殊化学品控股有限公司 | Pigment preparations |
| US7550041B2 (en) * | 2004-11-01 | 2009-06-23 | Ciba Specialty Chemicals Corporation | Highly concentrated flowable pigment composition and process for its manufacture |
| CN102838828A (en) * | 2011-06-20 | 2012-12-26 | 上海安凸塑料添加剂有限公司 | Bright-black functional black masterbatch for ABS engineering plastics and preparation method thereof |
| CN103275370A (en) * | 2012-12-28 | 2013-09-04 | 东莞市普凯塑料科技有限公司 | Ultraviolet light shielding, anti-bacterial, antifouling multifunctional color master batch and preparation method thereof |
| CN103289389A (en) * | 2013-05-31 | 2013-09-11 | 上海彩艳实业有限公司 | Color master batch of chinlon BCF (bulked continuous filament) carpet yarn and preparation method of color master batch |
-
2013
- 2013-12-28 CN CN201310738612.6A patent/CN103709735A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1649970A (en) * | 2002-05-01 | 2005-08-03 | 西巴特殊化学品控股有限公司 | Pigment preparations |
| US7550041B2 (en) * | 2004-11-01 | 2009-06-23 | Ciba Specialty Chemicals Corporation | Highly concentrated flowable pigment composition and process for its manufacture |
| CN102838828A (en) * | 2011-06-20 | 2012-12-26 | 上海安凸塑料添加剂有限公司 | Bright-black functional black masterbatch for ABS engineering plastics and preparation method thereof |
| CN103275370A (en) * | 2012-12-28 | 2013-09-04 | 东莞市普凯塑料科技有限公司 | Ultraviolet light shielding, anti-bacterial, antifouling multifunctional color master batch and preparation method thereof |
| CN103289389A (en) * | 2013-05-31 | 2013-09-11 | 上海彩艳实业有限公司 | Color master batch of chinlon BCF (bulked continuous filament) carpet yarn and preparation method of color master batch |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106589914A (en) * | 2016-11-03 | 2017-04-26 | 苏州圣鑫莱新材料有限公司 | Nano PA color master batch |
| CN113683883A (en) * | 2021-08-19 | 2021-11-23 | 金旸（厦门）新材料科技有限公司 | Polyamide composition and preparation method and application thereof |
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Application publication date: 20140409 |