CN103740094A - Antistatic moistureproof anti-UV (ultraviolet) color master batch for nylon - Google Patents

Antistatic moistureproof anti-UV (ultraviolet) color master batch for nylon Download PDF

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Publication number
CN103740094A
CN103740094A CN201310738606.0A CN201310738606A CN103740094A CN 103740094 A CN103740094 A CN 103740094A CN 201310738606 A CN201310738606 A CN 201310738606A CN 103740094 A CN103740094 A CN 103740094A
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CN
China
Prior art keywords
stabilizer
nylon
antioxidant
hindered amine
agent
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Pending
Application number
CN201310738606.0A
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Chinese (zh)
Inventor
张春琦
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NINGBO JINFULIANG PLASTIC SCIENCE & TECHNOLOGY Co Ltd
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NINGBO JINFULIANG PLASTIC SCIENCE & TECHNOLOGY Co Ltd
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Priority to CN201310738606.0A priority Critical patent/CN103740094A/en
Publication of CN103740094A publication Critical patent/CN103740094A/en
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02—Organic and inorganic ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/13—Phenols; Phenolates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/17—Amines; Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
    • C08K5/3472—Five-membered rings
    • C08K5/3475—Five-membered rings condensed with carbocyclic rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/52—Phosphorus bound to oxygen only
    • C08K5/524—Esters of phosphorous acids, e.g. of H3PO3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/017—Additives being an antistatic agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/04—Antistatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2310/00—Masterbatches

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses an antistatic moistureproof anti-UV (ultraviolet) color master batch for nylon, which is composed of an yellow colorant, a polyamide resin, a composite stabilizer, an antistatic agent, a moisture remover and a dispersing agent, wherein the composite stabilizer at least comprises two of hindered phenol antioxidant, phosphite antioxidant, copper halide stabilizer, hindered amine photostabilizer, anti-hydrolysis agent, diphenyl ketone and benzotriazole UV absorbent. Compared with the prior art, the various stabilizers are compounded to generate a synergistic effect, thereby ensuring the stability of the material in the working process and outdoor long-term usage process; and the material has better mechanical properties, and is suitable for design and application of high-end nylon products with requirements for long-term weather resistance. The moisture remover and antistatic agent are added to greatly enhance the properties of the nylon.

Description

The anti-UV nylon Masterbatch of a kind of anti-electrostatic, protection against the tide
Technical field
The invention belongs to the technical field of coloring plastic, relate in particular to the anti-UV nylon Masterbatch of a kind of anti-electrostatic, protection against the tide.
Background technology
Masterbatch is a kind of plastics of the sixties in 20th century exploitation, the painted product innovation of fiber, and it is that pigment super quantity is attached in resin and the mixture of the polymkeric substance making uniformly.Masterbatch chief component is tinting material, carrier, dispersion agent three parts.
According to related data, learn that the average annual growth rate of demand about 7%-9% of the other countries of Asia to Masterbatch can China be 20% left and right to the average annual growth rate of demand of Masterbatch.Estimate that China will become the fastest-rising market of Masterbatch demand.Particularly colored and add master batch, China wants dependence on import.China has become the largest production state in Masterbatch market, Asia and has consumed state.Relevant expert thinks, following Masterbatch will be towards multifunction, high color content and high technology content future development.
And common nylon master batch adds in nylon raw material, cannot guarantee the stability in material work in-process and outdoor use, generally all can reduce the mechanical property of material, thereby reduce the design and use life-span of product.
Summary of the invention
The present invention is directed to deficiency of the prior art, a kind of rear anti-UV nylon Masterbatch to the little anti-electrostatic of nylon Effect on Mechanical Properties, protection against the tide that adds is provided.
In order to solve the problems of the technologies described above, the present invention is solved by following technical proposals: the anti-UV nylon Masterbatch of a kind of anti-electrostatic, protection against the tide, it is characterized in that by weight percentage, composed of the following components: yellow colorants 15%-35%, polyamide resin 25%-35%, one package stabilizer 5%-15%, static inhibitor 10%-15%, moisture-removing agent 10%-15%, dispersion agent 3%-10%; Described one package stabilizer at least comprises two kinds in Hinered phenols antioxidant, phosphite ester kind antioxidant, copper halide class stablizer, hindered amine light stabilizer, hydrolysis-resisting agent, benzophenone, Benzotriazole Ultraviolet Stabilizer.Compared with prior art, the present invention mainly adopts the composite of plurality of stable agent, make various stablizers produce synergistic effect, guarantee that material neutralizes out of doors and can guarantee stability in life-time service in the course of processing, the mechanical property of material is better, is applicable to high-end nylon product design and the application of long-term weather-proof requirement.Meanwhile, in the present invention, added moisture-removing agent, there is the effect of removing the moisture in plastics, the performance of nylon is further improved; Added static inhibitor, obtained the technique effect of anti-electrostatic, the safety in utilization of nylon is improved greatly.
As preferred version: above-mentioned one package stabilizer at least comprises two kinds in Hinered phenols antioxidant, hindered amine light stabilizer, Benzotriazole Ultraviolet Stabilizer and phosphite ester kind antioxidant.Hinered phenols antioxidant and hindered amine light stabilizer be hydroperoxide decomposition and Trapped free radical effectively, and both are a bit similar, but hindered amine light stabilizer can cyclic regeneration, and Hinered phenols antioxidant is disposable; UV light absorber can effectively absorb sunlight middle-ultraviolet lamp, reduces by UV-induced photoaging; Phosphite ester kind antioxidant is brought into play antioxidant effect as hydrogen peroxide decomposition agent and radical trapping agent in polymkeric substance, use substantially without obvious effect separately, but play synergy with Hinered phenols antioxidant, obviously reinforcement material neutralizes out of doors and can guarantee stability in life-time service in the course of processing.
As preferably, above-mentioned one package stabilizer is comprised of Hinered phenols antioxidant, hindered amine light stabilizer, Benzotriazole Ultraviolet Stabilizer and phosphite ester kind antioxidant; By weight percentage, Hinered phenols antioxidant 25%-35% wherein, hindered amine light stabilizer 15%-25%, Benzotriazole Ultraviolet Stabilizer 20%-30%, phosphite ester kind antioxidant 20%-30%.By Hinered phenols antioxidant, phosphite ester kind antioxidant ,the quaternary system that hindered amine light stabilizer, Benzotriazole Ultraviolet Stabilizer form has good stabilising effect to the long-term weatherability of nylon product.Only use Hinered phenols antioxidant and hindered amine light stabilizer binary system, during nylon material tensile strength retention rate 50%, the required burn-in test time is 2450 hours, while containing the nylon product tensile strength retention rate 70% that above-mentioned quaternary system forms, the required burn-in test time is 6200 hours, Each performs its own functions for four kinds of stablizers, has significantly collaborative synergistic effect.
As preferably, above-mentioned dispersion agent at least comprises a kind of in ethene-vinyl acetate wax, ethylene bis stearic amide, pentaerythritol stearate.
As preferably, above-mentioned yellow colorants is a kind of in yellow of titanium nickel yellow, titanium chromium palm fibre, zinc-iron.
The present invention compared with prior art, there is following beneficial effect: the present invention mainly adopts the composite of plurality of stable agent, make various stablizers produce synergistic effect, guarantee that material neutralizes out of doors and can guarantee stability in life-time service in the course of processing, the mechanical property of material is better, is applicable to high-end nylon product design and the application of long-term weather-proof requirement.Meanwhile, in the present invention, added moisture-removing agent, there is the effect of removing the moisture in plastics, the performance of nylon is further improved; Added static inhibitor, obtained the technique effect of anti-electrostatic, the safety in utilization of nylon is improved greatly.
Embodiment
Below in conjunction with embodiment, the present invention is described in further detail: embodiment 1.
An anti-UV nylon Masterbatch for anti-electrostatic, protection against the tide, by weight percentage, composed of the following components: titanium nickel yellow 20%, polyamide resin 35%, one package stabilizer 10%, static inhibitor 15%, moisture-removing agent 15%, dispersion agent 5%; Wherein, one package stabilizer is comprised of Hinered phenols antioxidant and phosphite ester kind antioxidant, and by weight, Hinered phenols antioxidant is one package stabilizer 60%, and phosphite ester kind antioxidant is one package stabilizer 40%; Dispersion agent is ethene-vinyl acetate wax.
Embodiment 2.
An anti-UV nylon Masterbatch for anti-electrostatic, protection against the tide, by weight percentage, composed of the following components: zinc-iron Huang 30%, polyamide resin 25%, one package stabilizer 15%, static inhibitor 10%, moisture-removing agent 10%, dispersion agent 10%.
Wherein, one package stabilizer is comprised of Hinered phenols antioxidant, hindered amine light stabilizer, Benzotriazole Ultraviolet Stabilizer and phosphite ester kind antioxidant; By weight percentage, wherein Hinered phenols antioxidant 35%, hindered amine light stabilizer 15%, Benzotriazole Ultraviolet Stabilizer 30%, phosphite ester kind antioxidant 20%; Dispersion agent is pentaerythritol stearate.
Comparative example 1.
Zinc-iron Huang 30%, polyamide resin 25%, Hinered phenols antioxidant 15%, static inhibitor 10%, moisture-removing agent 10%, dispersion agent 10%.
Comparative example 2.
Zinc-iron Huang 20%, polyamide resin 35%, phosphite ester kind antioxidant 10%, static inhibitor 15%, moisture-removing agent 15%, dispersion agent 5%.
Experimental result: embodiment 1, during nylon material tensile strength retention rate 50%, the required burn-in test time is 2430 hours; Embodiment 2, and during nylon material tensile strength retention rate 70%, the required burn-in test time is 5360 hours; Comparative example 1, during nylon material tensile strength retention rate 50%, the required burn-in test time is, 1530 hours; Comparative example 2, during nylon material tensile strength retention rate 50%, the required burn-in test time is, 1620 hours.

Claims (5)

1. an anti-UV nylon Masterbatch for anti-electrostatic, protection against the tide, is characterized in that by weight percentage, composed of the following components: yellow colorants 15%-35%, polyamide resin 25%-35%, one package stabilizer 5%-15%, static inhibitor 10%-15%, moisture-removing agent 10%-15%, dispersion agent 3%-10%; Described one package stabilizer at least comprises two kinds in Hinered phenols antioxidant, phosphite ester kind antioxidant, copper halide class stablizer, hindered amine light stabilizer, hydrolysis-resisting agent, benzophenone, Benzotriazole Ultraviolet Stabilizer.
2. the anti-UV nylon Masterbatch of a kind of anti-electrostatic according to claim 1, protection against the tide, is characterized in that: described one package stabilizer at least comprises two kinds in Hinered phenols antioxidant, hindered amine light stabilizer, Benzotriazole Ultraviolet Stabilizer and phosphite ester kind antioxidant.
3. the anti-UV nylon Masterbatch of a kind of anti-electrostatic according to claim 2, protection against the tide, is characterized in that: described one package stabilizer is comprised of Hinered phenols antioxidant, hindered amine light stabilizer, Benzotriazole Ultraviolet Stabilizer and phosphite ester kind antioxidant; By weight percentage, Hinered phenols antioxidant 25%-35% wherein, hindered amine light stabilizer 15%-25%, Benzotriazole Ultraviolet Stabilizer 20%-30%, phosphite ester kind antioxidant 20%-30%.
4. according to a kind of anti-electrostatic described in arbitrary claim in claims 1 to 3, moistureproof anti-UV nylon Masterbatch, it is characterized in that: described dispersion agent at least comprises a kind of in ethene-vinyl acetate wax, ethylene bis stearic amide, pentaerythritol stearate.
5. a kind of anti-electrostatic according to claim 4, moistureproof anti-UV nylon Masterbatch, is characterized in that: described yellow colorants is that titanium nickel yellow, titanium chromium are brown, a kind of in yellow of zinc-iron.
CN201310738606.0A 2013-12-28 2013-12-28 Antistatic moistureproof anti-UV (ultraviolet) color master batch for nylon Pending CN103740094A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105440580A (en) * 2014-08-13 2016-03-30 中国蓝星（集团）股份有限公司 Fiber reinforced resin matrix composite weatherability improvement composition and application thereof
CN106832716A (en) * 2016-12-28 2017-06-13 中山诗兰姆汽车零部件有限公司 A kind of Masterbatch and its application
CN108226673A (en) * 2017-12-18 2018-06-29 中国电子科技集团公司第四十七研究所 The test method of antistatic protection is carried out using antistatic nylon plate

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1649970A (en) * 2002-05-01 2005-08-03 西巴特殊化学品控股有限公司 Pigment preparations
CN101187076A (en) * 2007-11-13 2008-05-28 华东理工大学 Color master batch for polyolefin grass fiber and its preparation method
CN101691438A (en) * 2009-09-22 2010-04-07 广州市波斯塑胶颜料有限公司 ABS color master batch
CN102070820A (en) * 2010-12-01 2011-05-25 浙江七色鹿色母粒有限公司 Polyethylene of raised temperature resistance (PE-RT) master batch and preparation method thereof
CN102417704A (en) * 2011-10-10 2012-04-18 福建奥峰科技有限公司 Weather-resistant flame-retardant polycarbonate (PC) composition, and preparation method and application thereof
CN103289184A (en) * 2012-02-27 2013-09-11 上海蓉新化工有限公司 Anti-oxidative color masterbatch and preparation method and application thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1649970A (en) * 2002-05-01 2005-08-03 西巴特殊化学品控股有限公司 Pigment preparations
CN101187076A (en) * 2007-11-13 2008-05-28 华东理工大学 Color master batch for polyolefin grass fiber and its preparation method
CN101691438A (en) * 2009-09-22 2010-04-07 广州市波斯塑胶颜料有限公司 ABS color master batch
CN102070820A (en) * 2010-12-01 2011-05-25 浙江七色鹿色母粒有限公司 Polyethylene of raised temperature resistance (PE-RT) master batch and preparation method thereof
CN102417704A (en) * 2011-10-10 2012-04-18 福建奥峰科技有限公司 Weather-resistant flame-retardant polycarbonate (PC) composition, and preparation method and application thereof
CN103289184A (en) * 2012-02-27 2013-09-11 上海蓉新化工有限公司 Anti-oxidative color masterbatch and preparation method and application thereof

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105440580A (en) * 2014-08-13 2016-03-30 中国蓝星（集团）股份有限公司 Fiber reinforced resin matrix composite weatherability improvement composition and application thereof
CN105440580B (en) * 2014-08-13 2018-08-31 中国蓝星（集团）股份有限公司 Improve composition and its application of fiber-reinforced resin matrix compound material weatherability
CN106832716A (en) * 2016-12-28 2017-06-13 中山诗兰姆汽车零部件有限公司 A kind of Masterbatch and its application
CN106832716B (en) * 2016-12-28 2019-09-27 中山诗兰姆汽车零部件有限公司 A kind of Masterbatch and its application
CN108226673A (en) * 2017-12-18 2018-06-29 中国电子科技集团公司第四十七研究所 The test method of antistatic protection is carried out using antistatic nylon plate

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Application publication date: 20140423

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