CN101187076A - Color master batch for polyolefin grass fiber and its preparation method - Google Patents

Color master batch for polyolefin grass fiber and its preparation method Download PDF

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Publication number
CN101187076A
CN101187076A CNA2007100481641A CN200710048164A CN101187076A CN 101187076 A CN101187076 A CN 101187076A CN A2007100481641 A CNA2007100481641 A CN A2007100481641A CN 200710048164 A CN200710048164 A CN 200710048164A CN 101187076 A CN101187076 A CN 101187076A
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CN
China
Prior art keywords
master batch
polyolefin
color master
grass fiber
pigment
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Pending
Application number
CNA2007100481641A
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Chinese (zh)
Inventor
易红玲
沈军
郑柏存
林珩
公维光
王伟山
魏婷
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East China University of Science and Technology
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East China University of Science and Technology
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Priority to CNA2007100481641A priority Critical patent/CN101187076A/en
Publication of CN101187076A publication Critical patent/CN101187076A/en
Pending legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25—Component parts, details or accessories; Auxiliary operations
    • B29C48/92—Measuring, controlling or regulating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/04—Particle-shaped
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25—Component parts, details or accessories; Auxiliary operations
    • B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
    • B29C48/395—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
    • B29C48/40—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25—Component parts, details or accessories; Auxiliary operations
    • B29C48/94—Lubricating
    • B29C48/95—Lubricating by adding lubricant to the moulding material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00—Indexing scheme relating to extrusion moulding
    • B29C2948/92—Measuring, controlling or regulating
    • B29C2948/92504—Controlled parameter
    • B29C2948/9258—Velocity
    • B29C2948/9259—Angular velocity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00—Indexing scheme relating to extrusion moulding
    • B29C2948/92—Measuring, controlling or regulating
    • B29C2948/92504—Controlled parameter
    • B29C2948/92704—Temperature
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00—Indexing scheme relating to extrusion moulding
    • B29C2948/92—Measuring, controlling or regulating
    • B29C2948/92819—Location or phase of control
    • B29C2948/92857—Extrusion unit
    • B29C2948/92876—Feeding, melting, plasticising or pumping zones, e.g. the melt itself
    • B29C2948/92885—Screw or gear
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00—Indexing scheme relating to extrusion moulding
    • B29C2948/92—Measuring, controlling or regulating
    • B29C2948/92819—Location or phase of control
    • B29C2948/92923—Calibration, after-treatment or cooling zone

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention relates to a technology of color master batches for a polyolefin yarn fiber, which comprises pigments, plastic additives and carrier resin, wherein the plastic additives comprise dispersed lubricant, an antioxidant, a light stabilizer, a coupling agent and liquid paraffin. The process for preparation is that the pigments, a part of plastic additives and the carrier resin are added into a high-speed mixer to be mixed, and then the coupling agent and the liquid paraffin are added to be stirred in a high speed, and at last the above stirred mixture is sent to a twin-screw extruder to be extruded, cooled, dried and granulated. The invention has the characteristics of less dosage, excellent weathering resistance, easy dispersing and excellent processability, and is suitable for the yarn fiber which takes polyethylene, polypropylene and other copolymer as base materials.

Description

A kind of color master batch for polyolefin grass fiber and preparation method thereof
Technical field
The present invention relates to the artificial grass filaments fibre staining, being specifically related to the vistanex is that main raw material prepares chinampa TPO grass fiber Masterbatch and method thereof.
Background technology
The development of chinampa comes from the limitation that natural grass changes weather conditions.Technological innovation along with the artificial grass filaments fiber, the mechanical property of chinampa, security performance and comfort property move closer to natural grass, therefore the range of application of chinampa also progressively expands on the professional athletic ground, even International Football Union (FIFA) proposes and will adopt chinampa at South Africa world cups in 2010, and this indicates that the development of chinampa will enter a new stage.
The artificial grass filaments fibrous material is the core material of chinampa, and its performance has determined mechanical property, security performance and the comfort property on lawn.At present, the artificial grass filaments industry in Europe is taken its place in the front ranks of the world, and wherein dutch royal card covered with clouds group is maximum in the world artificial grass fibre manufacturer, and its Sai Erlong trade mark series of products can provide solution for the athletic ground surface layer of various ways.The preparation of artificial grass filaments fiber mainly is with matrix resin, and Masterbatch and function additive melt extrude after evenly mixing, and prepared such as stretched, typing, coiling form.Because need carrying high-intensity motion wearing and tearing and face harsh climate, the chinampa of outdoor use changes, the color on lawn also influences sportsman and spectators' visual experience with the true similarity degree of grass in addition, so the subject matter that the artificial grass filaments fibrous material faces is grass silk color weatherability and mechanical property durability.The research of artificial grass filaments at present concentrates on profile (as USP 5462778, WO 2005/005731), braiding, method for paving (as USP 4381805, USP6491991, USP 6815059, USP 6955841, WO 01/0161110, WO 2005/124028) and the performance testing apparatus design aspects such as (as USP 6854316, USP 6962073) of artificial grass filaments mostly, though patent WO2006/066777 has mentioned the prescription and the mechanical property of artificial grass filaments fibrous material, do not relate to the performance of the weather-proof aging aspect of grass silk color.
Summary of the invention
The objective of the invention is for a kind of TPO grass fiber Masterbatch and preparation method thereof that is applicable to motion or leisure place chinampa is provided, the prepared grass fiber of Masterbatch has weather-proof ageing properties of good color and mechanical property durability thus.
The object of the present invention is achieved like this:
A kind of color master batch for polyolefin grass fiber is made up of pigment, plastic additive and vector resin, it is characterized in that described plastic additive comprises: dispersed lubricant, antioxidant, light stabilizer, coupling agent and atoleine; Its weight percentages of components of described color master batch for polyolefin grass fiber is:
Pigment 20%～60%
Dispersed lubricant 5～30%
Antioxidant 0.5～2%
Light stabilizer 5～15%
Coupling agent 0.5～5%
Atoleine 1～5%
Vector resin 15～68%
Above-mentioned material is mixed after extruder is extruded cooling, oven dry, pelletizing and getting.
Described pigment is one or more mixing of white, green, blue, yellow or black pigment.
Described Chinese white is rutile type titanium white, calcium carbonate or upright powder; Viridine green is a phthalocyanine green; Blue pigment is ultramarine or phthalocyanine blue; Yellow uitramarine is azophosphine pigment, heterocyclic yellow pigments or inorganic yellow pigment; Black pigment is carbon black or iron oxide black.
Described vector resin is one or both mixing in linear low density polyethylene, the low density polyethylene (LDPE).
The melt speed of described linear low density polyethylene is 1～2.5g/10min, and the melt speed of low density polyethylene (LDPE) is 2～8g/10min.
Described dispersed lubricant is one or more the mixing in aliphatic amide type, fatty acid, metallic soap class, oxidized polyethlene wax or the low-molecular polyethylene wax.
Described antioxidant is one or more the mixing in amine, Hinered phenols, phosphite or the thioester.
Described light stabilizer is one or more the mixing in hindered amines, benzophenone class, benzotriazole, group-substituted acrylonitrile or the triazines.
Described coupling agent is a titanate esters, the mixing of one or more in silane or the aluminic acid ester.
Preparing the said polyolefins grass fiber with the method for Masterbatch is: with the dispersed lubricant in pigment and the plastic additive, antioxidant, light stabilizer and vector resin are by mixing 10～20min in the disposable adding high-speed mixer of aforementioned ratio, add coupling agent and atoleine by aforementioned ratio then, high-speed stirred 10～20min again, send into above-mentioned stirred mixture material in the double screw extruder at last, to be controlled at 170～210 ℃, screw speed be that 80～400r/min extrudes to temperature, through cooling, described master batch is made in oven dry after the pelletizing.
The present invention has that consumption is few, and weather resistance is good, easily disperses, and the characteristics of good processability are applicable to polyethylene, and polypropylene and copolymer thereof are the grass fiber of base-material.
The specific embodiment
The invention will be further elaborated below by embodiment, its objective is better understanding content of the present invention.Protection scope of the present invention is not subjected to the restriction of embodiment:
Embodiment 1
Under the normal temperature and pressure, with following component and percetage by weight: linear low density polyethylene (LLDPE) 45%, low-molecular polyethylene wax 5%, upright powder 15%, titanium dioxide 5% phthalocyanine blue 3%, azophosphine pigment 15%, iron black 2%, phenolic antioxidant 264 2%, triazines as light stabilizer 5%, titanate coupling agent 1%, atoleine 2%, after the batching, earlier with the Tissuemat E in pigment and the plastic additive, phenolic antioxidant, mix 15min in the high-speed mixer that the disposable adding rotating speed of triazines as light stabilizer and linear low density polyethylene is 1400 commentaries on classics/min, the mixture that adds titanate coupling agent and atoleine then, high-speed mixing 15min again sends into the material of above-mentioned mixing that temperature is controlled at 200 ℃ in the double screw extruder at last, screw speed is that 100r/min extrudes, through cooling, required master batch is made in oven dry after the pelletizing.
Application examples 1
80kg linear low density polyethylene (LLDPE), 20kg ethylene-vinyl acetate (EVA), prepared master batch and the 3kg processing aid of 12kg are mixed back adding screw extruder hopper, adopt the circle die head to draw monofilament, total drawing ratio is 4.5, total relaxation shrinkage is 5.7%, the drawing oven temperature is 120 ℃, and the typing oven temperature is 100 ℃.The grass silk monfil TENSILE STRENGTH that makes is 11.25cN/Tex, elongation at break is 113.48%, percent thermal shrinkage is 1.63%, after pressing the aging 3000h of ASTM G 154 standards, the TENSILE STRENGTH of grass fiber is 10.07cN/Tex, elongation at break is 105.81%, and percent thermal shrinkage is 1.17%, grass silk color total color difference≤2.
Embodiment 2
Under the normal temperature and pressure, with following component and percetage by weight: low density polyethylene (LDPE) (LDPE) 32%, ethylene bis stearic acid amide (EBS) 5%, zinc stearate 1%, ultramarine 20%, inorganic yellow pigment 21%, carbon black 2%, hindered amine light stabilizer 8%, phosphite kind antioxidant 2%, silane coupler 5%, atoleine 4%, after the batching, earlier with the EBS in pigment and the plastic additive, phosphite antioxidant, mix 15min in the high-speed mixer that the disposable adding rotating speed of hindered amine as light stabilizer and low density polyethylene (LDPE) is 1400 commentaries on classics/min, the mixture that adds titanate coupling agent and atoleine then, high-speed mixing 20min again sends into the material of above-mentioned mixing that temperature is controlled at 180 ℃ in the double screw extruder at last, screw speed is that 150r/min extrudes, through cooling, required master batch is made in oven dry after the pelletizing.
Application examples 2
435kg polypropylene (PP), the above-mentioned master batch of 50kg and 15kg processing aid are mixed the back add the screw extruder hopper, adopt towing of flat-die head flat filament, total drawing ratio is 4.7, and total relaxation shrinkage is 4.84%, the drawing oven temperature is 130 ℃, and the typing oven temperature is 115 ℃.The grass silk fibrillation flat filament tensile strength of fiber that makes is 11.15cN/Tex, elongation at break is 76.63%, percent thermal shrinkage is 0.94%, after pressing the aging 3000h of ASTM G 154 standards, the TENSILE STRENGTH of grass fiber is 10.27 cN/Tex, elongation at break is 68.74%, and percent thermal shrinkage is 0.83%, grass silk color total color difference≤3.

Claims (10)

1. a color master batch for polyolefin grass fiber is made up of pigment, plastic additive and vector resin, it is characterized in that described plastic additive comprises: dispersed lubricant, antioxidant, light stabilizer, coupling agent and atoleine; Its weight percentages of components of described color master batch for polyolefin grass fiber is:
Pigment 20%～60%
Dispersed lubricant 5～30%
Antioxidant 0.5～2%
Light stabilizer 5～15%
Coupling agent 0.5～5%
Atoleine 1～5%
Vector resin 15～68%
Above-mentioned material is mixed after extruder is extruded cooling, oven dry, pelletizing and getting.
2. color master batch for polyolefin grass fiber as claimed in claim 1 is characterized in that one or more the mixing of described pigment for white, green, blue, yellow or black pigment.
3. color master batch for polyolefin grass fiber as claimed in claim 2 is characterized in that described Chinese white is rutile type titanium white, calcium carbonate or upright powder; Viridine green is a phthalocyanine green; Blue pigment is ultramarine or phthalocyanine blue; Yellow uitramarine is azophosphine pigment, heterocyclic yellow pigments or inorganic yellow pigment; Black pigment is carbon black or iron oxide black.
4. color master batch for polyolefin grass fiber as claimed in claim 1 is characterized in that described vector resin is one or both mixing in linear low density polyethylene, the low density polyethylene (LDPE).
5. color master batch for polyolefin grass fiber as claimed in claim 4, the melt speed that it is characterized in that described linear low density polyethylene is 1～2.5g/10min, the melt speed of low density polyethylene (LDPE) is 2～8g/10min.
6. color master batch for polyolefin grass fiber as claimed in claim 1 is characterized in that described dispersed lubricant is one or more the mixing in aliphatic amide type, fatty acid, metallic soap class, oxidized polyethlene wax or the low-molecular polyethylene wax.
7. color master batch for polyolefin grass fiber as claimed in claim 1 is characterized in that described antioxidant is one or more the mixing in amine, Hinered phenols, phosphite or the thioester.
8. color master batch for polyolefin grass fiber as claimed in claim 1 is characterized in that described light stabilizer is one or more the mixing in hindered amines, benzophenone class, benzotriazole, group-substituted acrylonitrile or the triazines.
9. color master batch for polyolefin grass fiber as claimed in claim 1 is characterized in that described coupling agent is a titanate esters, the mixing of one or more in silane or the aluminic acid ester.
10. the preparation method of the described color master batch for polyolefin grass fiber of claim 1, it is characterized in that: with the dispersed lubricant in pigment and the plastic additive, antioxidant, light stabilizer and vector resin are by mixing 10～20min in the disposable adding high-speed mixer of aforementioned ratio, add coupling agent and atoleine by aforementioned ratio then, high-speed stirred 10～20min again, at last above-mentioned stirred mixture material is sent in the double screw extruder, temperature is controlled at 170～210 ℃, screw speed is that 80～400r/min extrudes, through cooling, described master batch is made in oven dry after the pelletizing.
CNA2007100481641A 2007-11-13 2007-11-13 Color master batch for polyolefin grass fiber and its preparation method Pending CN101187076A (en)

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CN101899182A (en) * 2010-07-19 2010-12-01 东莞市普凯塑料科技有限公司 Artificial turf masterbatch and preparation method thereof
CN102363335A (en) * 2011-08-09 2012-02-29 常熟市慧丰塑料制品有限公司 Propylene processing technology
CN102504599A (en) * 2011-05-13 2012-06-20 上海容志材料科技有限公司 Liquid color masterbatch composition, preparation method and application thereof
CN102516637A (en) * 2011-12-23 2012-06-27 山东东宏管业有限公司 Polyethylene (PE) plastic black master batch and production method thereof
CN102617913A (en) * 2012-03-28 2012-08-01 杭州华塑色母有限公司 Polyethylene (PE) foaming material coloring master batch
CN102634113A (en) * 2012-04-12 2012-08-15 杭州金州高分子科技有限公司 Heat-resisting and weatherproof polypropylene masterbatch material
CN102649849A (en) * 2011-11-21 2012-08-29 上海彩艳实业有限公司 Color master batch for colorizing medical composite non-woven fabric melt-blown layer and preparation method thereof
CN102816335A (en) * 2011-06-08 2012-12-12 苏州兴泰国光化学助剂有限公司 Brightening dispersion auxiliary agent used for color masterbatches and color powder
CN102816370A (en) * 2012-06-12 2012-12-12 杭州雄魁塑胶科技有限公司 Ultra-large plastic manhole composite powder formula
CN102816267A (en) * 2011-06-08 2012-12-12 苏州兴泰国光化学助剂有限公司 Brightening lubricant auxiliary agent used for engineering plastics
CN103160951A (en) * 2013-03-21 2013-06-19 齐齐哈尔大学 Negative-ion-contained artificial grass fiber and preparation method thereof
CN103172928A (en) * 2013-04-19 2013-06-26 常州一诺塑料科技有限公司 Color master batch special for polyethylene lawn silk and preparation method thereof
CN103232640A (en) * 2013-04-27 2013-08-07 上海锦湖日丽塑料有限公司 Spraying-free aesthetic resin composition with amber effect and preparation method thereof
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CN103319759A (en) * 2012-03-23 2013-09-25 东莞市三丰化工有限公司 Color master batch formula
CN103740094A (en) * 2013-12-28 2014-04-23 宁波金富亮塑料科技有限公司 Antistatic moistureproof anti-UV (ultraviolet) color master batch for nylon
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CN101899182B (en) * 2010-07-19 2012-09-05 东莞市普凯塑料科技有限公司 Artificial turf masterbatch and preparation method thereof
CN101899182A (en) * 2010-07-19 2010-12-01 东莞市普凯塑料科技有限公司 Artificial turf masterbatch and preparation method thereof
CN102504599A (en) * 2011-05-13 2012-06-20 上海容志材料科技有限公司 Liquid color masterbatch composition, preparation method and application thereof
CN102504599B (en) * 2011-05-13 2014-06-11 上海容志材料科技有限公司 Liquid color masterbatch composition, preparation method and application thereof
CN102816335B (en) * 2011-06-08 2015-01-14 苏州兴泰国光化学助剂有限公司 Brightening dispersion auxiliary agent used for color masterbatches and color powder
CN102816335A (en) * 2011-06-08 2012-12-12 苏州兴泰国光化学助剂有限公司 Brightening dispersion auxiliary agent used for color masterbatches and color powder
CN102816267A (en) * 2011-06-08 2012-12-12 苏州兴泰国光化学助剂有限公司 Brightening lubricant auxiliary agent used for engineering plastics
CN102816267B (en) * 2011-06-08 2014-04-30 苏州兴泰国光化学助剂有限公司 Brightening lubricant auxiliary agent used for engineering plastics
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