CN103232640A - Spraying-free aesthetic resin composition with amber effect and preparation method thereof - Google Patents
Spraying-free aesthetic resin composition with amber effect and preparation method thereof Download PDFInfo
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Abstract
The invention provides a spraying-free aesthetic resin composition with an amber effect and a preparation method thereof. The aesthetic resin composition consists of the following components in parts by weight: 90 to 99 parts of a base material and 1.0 to 10 parts of master batch, wherein the base material comprises the following components in parts by weight: 100 parts of matrix resin, 0.1 to 2.0 parts of a lubricant, 0.1 to 1.0 part of an antioxidant, 1.0 to 5.0 parts of rosin and 1.0 to 3.0 parts of a phosphorus-based flame retardant; and the master batch comprises the following components in parts by weight: 80 to 90 parts of matrix resin, 10 to 20 parts of a filler, 0.1 to 2.0 parts of a lubricant, 0.1 to 1.0 part of an antioxidant and 0.01 to 0.1 part of toner. Compared with the prior art, the aesthetic resin provided by the invention can be formed at one step to prepare various pieces with a lifelike amber effect, so that post processing of products is avoided, environmental pollution and energy consumption are greatly reduced, and the aesthetic resin composition can be widely applied to artware, household appliances and the like.
Description
Technical field
The present invention relates to aesthstic resin and preparation method thereof, especially relate to a kind of have an amber effect exempt to spray aesthstic resin combination and preparation method thereof.
Background technology
Low-carbon environment-friendly has become one main flow trend in the world, and the relevant environmental protection act of various countries emerges in an endless stream, and under this big environmental background, the new technology of various low-carbon environment-friendlies has obtained more and more human consumers' favor.Wherein, one-time formed aesthstic resin does not have post-treatment because of it, has significantly reduced the environmental pollution that production link causes, and has received more and more people's concern.
Continuous development along with technology, nowadays exempt to spray aesthstic resin and can realize multiple effect, as the silver that sprays paint, electrosilvering, pearly-lustre are red, dodge effect such as the black and starry sky flicker of silver, in addition, the aesthstic resin of imitative natural effect also in development constantly, has a large amount of patents to study, as Chinese patent, publication number is the description of imitation marble effect among the CN1792963A, and publication number is the description of artificial white marble effect among the CN1126151A, and publication number is the description of the imitative jade effect of CN1483762A etc.
Amber is that the resin before tens million of years is buried in underground, through a kind of ambrite that forms behind certain chemical transformation, is a kind of organic gel mineral.Because it has extremely beautiful color and luster and appearance effect, amber is subjected to liking of crowd greatly.But because amber is extremely rare, increasing artificial amber is developed out product as an alternative.A lot of patent reports the have been arranged manufacturing technology of artificial amber, as Chinese patent, publication number is CN1174133A, publication number is that CN200959937Y and publication number are CN101280113A etc.But these technology all are based on the thermosetting resin technology, and technology is loaded down with trivial details, and efficient is low.
Summary of the invention
At defective of the prior art, the purpose of this invention is to provide a kind of have an amber effect exempt to spray aesthstic resin combination and preparation method thereof.
First aspect, the invention provides a kind of have an amber effect exempt to spray aesthstic resin combination, described aesthstic resin combination is made up of each component of following parts by weight:
Base-material 90～99;
Master batch 1.0～10.
Preferably, described base-material comprises each component of following weight part:
Matrix resin 100;
Lubricant 0.1～2.0;
Oxidation inhibitor 0.1～1.0;
Rosin 1.0～5.0;
Phosphorus flame retardant 1.0～3.0.
Preferably, described matrix resin is copolymerization PP, transparent ABS, GPPS or PMMA;
Described lubricant is one or several the mixture in silicone oil, white mineral oil, fatty acid amide, barium stearate, Magnesium Stearate, paraffin, polyethylene wax, ethylene bis stearic acid amide, ethylene-vinyl acetate copolymer, the ethylene-acrylic acid copolymer; Described oxidation inhibitor is refine one or more the mixture of Irganox 1010, Irganox 1076, Irganox B900, Irganox 168 of company of CIBA;
Described phosphorus flame retardant is the phosphoric acid ester phosphorus flame retardant.
Preferably, described rosin is gum resin, wood rosin or starex, utilizes the distinctive form and aspect of rosin and the texture can be so that the present composition has amber effect more true to nature.
Preferably, in the described rosin resinous acid mass percent greater than 95%.
Preferably, described phosphoric acid ester phosphorus flame retardant is two (diphenyl phosphate) and Resorcinols (diphenyl phosphoester) of dihydroxyphenyl propane, and main effect is to utilize its high workability and the transparency, makes it be deposited on resin surface, improves glossiness and the surperficial texture of product.
Preferably, described master batch comprises each component of following weight part:
Matrix resin 80～90;
Filler 10～20;
Lubricant 0.1～2.0;
Oxidation inhibitor 0.1～1.0;
Toner 0.01～0.1.
Preferably, described matrix resin is the mixture of a kind of in PBT, the modified PBT or two kinds;
Described filler is one or several the mixture in calcium carbonate, talcum powder, the wollastonite;
Described lubricant is one or several the mixture in silicone oil, white mineral oil, fatty acid amide, barium stearate, Magnesium Stearate, paraffin, polyethylene wax, ethylene bis stearic acid amide, ethylene-vinyl acetate copolymer, the ethylene-acrylic acid copolymer;
Described oxidation inhibitor is refine one or several the mixture of Irganox 1010, Irganox 1076, Irganox B900, Irganox 168 of company of CIBA;
Described toner is the mixture of carbon black and inorganic Huang, a kind of or two kinds of mixtures of organic yellow.
Second aspect, the present invention also provides the aforesaid preparation method who exempts to spray aesthstic resin combination with amber effect, and described method comprises the steps:
A, each component of getting composition and parts by weight take by weighing each component;
B, successively base-material and master batch are placed in the high-speed mixer stir, mix by measuring apparatus and send in the twin screw extruder, the temperature of control twin screw extruder, conveying, shearing and mixing following at screw rod, with material melting, compound, then through extrude, tie rod, cooling, pelletizing step, successively obtain base-material and master batch, it is mixed in high-speed mixer in proportion, and what namely obtain having the amber effect exempts to spray aesthstic resin.
Preferably, churning time is 10～20min in the described high-speed mixer, and the temperature of described twin screw extruder is 180～250 ℃, and mixing time is 5～10min in high-speed mixer.
Compared with prior art, the present invention has following beneficial effect: the present invention be based on the thermoplastic resin single injection-molded make have an amber effect exempt to spray aesthstic resin combination, the present invention is through unique formulating of recipe and technological design, make the product of preparing have amber effect extremely true to nature, can be widely used in products such as artwork and household electrical appliances, the inventive method is simple, the efficient height, effect is remarkable, is applicable to large-scale industrial production.
Embodiment
The present invention is described in detail below in conjunction with specific embodiment.Following examples will help those skilled in the art further to understand the present invention, but not limit the present invention in any form.Should be pointed out that to those skilled in the art, without departing from the inventive concept of the premise, can also make some distortion and improvement.These all belong to protection scope of the present invention.
Embodiment 1
Present embodiment provide a kind of have the amber effect exempt from spray aesthstic resin combination, its preparation method may further comprise the steps:
Step 1: the content according to following component and parts by weight is got the raw materials ready:
Base-material 95;
Master batch 5;
Wherein,
(1) base-material is each component of following parts by weight: matrix resin 100, lubricant 1.0, oxidation inhibitor 0.5, rosin 3.0 and phosphorus flame retardant 2.0;
Matrix resin in the base-material is transparent ABS; Lubricant is the mixture of Magnesium Stearate and ethylene-acrylic acid copolymer; Oxidation inhibitor is the refine Irganox 1010 of company and the mixture of Irganox 168 of CIBA; Rosin is gum resin, and its main component resinous acid mass percent is 96%; Phosphorus flame retardant be dihydroxyphenyl propane two (diphenyl phosphates) (BDP);
(2) master batch is each component of following parts by weight: matrix resin 85, filler 15, lubricant 1.0, oxidation inhibitor 0.5 and toner 0.05;
Matrix resin in the master batch is the mixture of PBT and modified PBT; Filler is calcium carbonate and talcous mixture; Lubricant is the mixture of Magnesium Stearate and ethylene-acrylic acid copolymer; Oxidation inhibitor is the refine Irganox 1010 of company and the mixture of Irganox 168 of CIBA; Toner is the mixture of carbon black+inorganic Huang and organic yellow.
Step 2: base-material and master batch are placed stir 10～20min in the high-speed mixer respectively, mix by measuring apparatus and send in the twin screw extruder, the temperature of control twin screw extruder is 180～250 ℃, conveying, shearing and mixing following at screw rod, with material melting, compound, then through extrude, tie rod, cooling, pelletizing step, obtain base-material and master batch afterwards respectively, it is mixed 5～10min in proportion in high-speed mixer, what namely obtain having the amber effect exempts to spray aesthstic resin.
Embodiment 2
Present embodiment provide a kind of have the amber effect exempt from spray aesthstic resin combination, its preparation method may further comprise the steps:
Step 1: get the raw materials ready according to following component and weight part content:
Base-material 90;
Master batch 10;
Wherein,
(1) base-material is each component of following parts by weight: matrix resin 100, lubricant 0.1, oxidation inhibitor 0.1, rosin 1.0 and phosphorus flame retardant 1.0;
The matrix resin of base-material is copolymerization PP; Lubricant is silicone oil; Oxidation inhibitor is the refine Irganox B900 of company of CIBA; Rosin is starex, and its main component resinous acid mass percent is 90%; Phosphorus flame retardant be Resorcinol (diphenyl phosphoester) (RDP);
(2) master batch is each component of following parts by weight: matrix resin 85, filler 20, lubricant 0.1, oxidation inhibitor 0.1 and toner 0.01;
Matrix resin in the master batch is modified PBT; Filler is calcium carbonate; Lubricant is white mineral oil; Oxidation inhibitor is the refine Irganox 1076 of company of CIBA; Toner is carbon black+inorganic Huang;
Step 2: base-material and master batch are placed stir 10～20min in the high-speed mixer respectively, mix by measuring apparatus and send in the twin screw extruder, the temperature of control twin screw extruder is 180～250 ℃, conveying, shearing and mixing following at screw rod, with material melting, compound, then through extrude, tie rod, cooling, pelletizing step, obtain base-material and master batch respectively, it is mixed 5～10min in proportion in high-speed mixer, what namely obtain having the amber effect exempts to spray aesthstic resin.
Embodiment 3
Present embodiment provide a kind of have the amber effect exempt from spray aesthstic resin combination, its preparation method may further comprise the steps:
Step 1: get the raw materials ready according to following component and weight part content:
Base-material 99;
Master batch 1.0;
Wherein,
(1) base-material is each component of following parts by weight: matrix resin 100, lubricant 2.0, oxidation inhibitor 1.0, rosin 5.0 and phosphorus flame retardant 3.0;
Matrix resin in the base-material is PMMA; Lubricant is the mixture of barium stearate and ethylene-acrylic acid copolymer; Oxidation inhibitor is the refine Irganox 1010 of company and the mixture of Irganox 168 of CIBA; Rosin is wood rosin, and its main component resinous acid mass percent is 97%; Phosphorus flame retardant be dihydroxyphenyl propane two (diphenyl phosphates) (BDP);
(2) master batch is each component of following parts by weight: matrix resin 90, filler 10, lubricant 2.0, oxidation inhibitor 1.0 and toner 0.1;
Matrix resin in the master batch is PBT; Filler is talcum powder; Lubricant is polyethylene wax; Oxidation inhibitor is the refine Irganox 1010 of company of CIBA; Toner is the mixture of carbon black+inorganic Huang and organic yellow.
Step 2: base-material and master batch are placed stir 10～20min in the high-speed mixer respectively, mix by measuring apparatus and send in the twin screw extruder, the temperature of control twin screw extruder is 180～250 ℃, conveying, shearing and mixing following at screw rod, with material melting, compound, then through extrude, tie rod, cooling, pelletizing step, obtain base-material and master batch respectively, it is mixed 5～10min in proportion in high-speed mixer, what namely obtain having the amber effect exempts to spray aesthstic resin.
Embodiment 4
Present embodiment provide a kind of have the amber effect exempt from spray aesthstic resin combination, its preparation method may further comprise the steps:
Step 1: get the raw materials ready according to following component and weight part content:
Base-material 90;
Master batch 10;
Wherein,
(1) base-material is each component of following parts by weight: matrix resin 100, lubricant 1.5, oxidation inhibitor 0.7, rosin 4.0 and phosphorus flame retardant 1.5;
Matrix resin in the present embodiment is GPPS; Lubricant is the mixture of silicone oil and ethylene bis stearic acid amide; Oxidation inhibitor is the refine Irganox 1076 of company and the mixture of Irganox B900 of CIBA; Rosin is starex, and its main component resinous acid mass percent is 91%; Phosphorus flame retardant be dihydroxyphenyl propane two (diphenyl phosphates) (BDP);
(2) master batch is each component of following parts by weight: matrix resin 80, filler 20, lubricant 2.0, oxidation inhibitor 0.5 and toner 0.07;
Matrix resin in the master batch is the mixture of PBT and modified PBT; Filler is wollastonite; Lubricant is the mixture of fatty acid amide and ethylene-vinyl acetate copolymer; Oxidation inhibitor is the refine Irganox 1076 of company of CIBA; Toner is carbon black+organic yellow.
Step 2: base-material and master batch are placed stir 10～20min in the high-speed mixer respectively, mix by measuring apparatus and send in the twin screw extruder, the temperature of control twin screw extruder is 180～250 ℃, conveying, shearing and mixing following at screw rod, with material melting, compound, then through extrude, tie rod, cooling, pelletizing step, obtain base-material and master batch respectively, it is mixed 5～10min in proportion in high-speed mixer, what namely obtain having the amber effect exempts to spray aesthstic resin.
Embodiment 5
Present embodiment provide a kind of have the amber effect exempt from spray aesthstic resin combination, its preparation method may further comprise the steps:
Step 1: get the raw materials ready according to following component and weight part content:
Base-material 95;
Master batch 5;
Wherein,
(1) base-material is each component of following parts by weight: matrix resin 100, lubricant 0.3, oxidation inhibitor 0.7, rosin 1.8 and phosphorus flame retardant 1.5;
The matrix resin of base-material is PMMA; Lubricant is the mixture in white mineral oil, Magnesium Stearate and the ethylene-acrylic acid copolymer; Oxidation inhibitor is refine the Irganox B900 of company and the mixture of Irganox 168 of CIBA; Rosin is gum resin, and its main component resinous acid mass percent is 98%; Phosphorus flame retardant be Resorcinol (diphenyl phosphoester) (RDP);
(2) master batch is each component of following parts by weight: matrix resin 88, filler 12, lubricant 0.9, oxidation inhibitor 0.7 and toner 0.06;
The matrix resin of master batch is PBT; Filler is talcum powder; Lubricant is the mixture of fatty acid amide and ethylene-acrylic acid copolymer; Oxidation inhibitor is refine Irganox 1010, the Irganox 1076 of company and the mixture of Irganox 168 of CIBA; Toner is the mixture of carbon black+inorganic Huang and organic yellow.
Step 2: base-material and master batch are placed stir 10～20min in the high-speed mixer respectively, mix by measuring apparatus and send in the twin screw extruder, the temperature of control twin screw extruder is 180～250 ℃, conveying, shearing and mixing following at screw rod, with material melting, compound, then through extrude, tie rod, cooling, pelletizing step, obtain base-material and master batch respectively, it is mixed 5～10min in proportion in high-speed mixer, what namely obtain having the amber effect exempts to spray aesthstic resin.
Comparative Examples 1
This Comparative Examples provide a kind of have the amber effect exempt from spray aesthstic resin combination, its preparation method may further comprise the steps:
Step 1: get the raw materials ready according to following component and weight part content:
Base-material 95;
Master batch 5;
Wherein,
(1) base-material is each component of following parts by weight: matrix resin 100, lubricant 0.3, oxidation inhibitor 0.7 and phosphorus flame retardant 1.5;
The matrix resin of base-material is PMMA; Lubricant is the mixture in white mineral oil, Magnesium Stearate and the ethylene-acrylic acid copolymer; Oxidation inhibitor is refine the Irganox B900 of company and the mixture of Irganox 168 of CIBA; Phosphorus flame retardant be Resorcinol (diphenyl phosphoester) (RDP);
(2) master batch is each component of following parts by weight: matrix resin 88, filler 12, lubricant 0.9, oxidation inhibitor 0.7 and toner 0.06;
The matrix resin of master batch is PBT; Filler is talcum powder; Lubricant is the mixture of fatty acid amide and ethylene-acrylic acid copolymer; Oxidation inhibitor is refine Irganox 1010, the Irganox 1076 of company and the mixture of Irganox 168 of CIBA; Toner is the mixture of carbon black+inorganic Huang and organic yellow.
Step 2: base-material and master batch are placed stir 10～20min in the high-speed mixer respectively, mix by measuring apparatus and send in the twin screw extruder, the temperature of control twin screw extruder is 180～250 ℃, conveying, shearing and mixing following at screw rod, with material melting, compound, then through extrude, tie rod, cooling, pelletizing step, obtain base-material and master batch respectively, it is mixed 5～10min in proportion in high-speed mixer, namely obtain exempting to spray aesthstic resin.
Comparative Examples 2
This Comparative Examples provide a kind of have the amber effect exempt from spray aesthstic resin combination, its preparation method may further comprise the steps:
Step 1: get the raw materials ready according to following component and weight part content:
Base-material 95;
Master batch 5;
Wherein,
(1) base-material is each component of following parts by weight: matrix resin 100, lubricant 0.3, oxidation inhibitor 0.7 and rosin 1.8;
The matrix resin of base-material is PMMA; Lubricant is the mixture in white mineral oil, Magnesium Stearate and the ethylene-acrylic acid copolymer; Oxidation inhibitor is refine the Irganox B900 of company and the mixture of Irganox 168 of CIBA; Rosin is gum resin, and its main component resinous acid mass percent is 98%;
(2) master batch is each component of following parts by weight: matrix resin 88, filler 12, lubricant 0.9, oxidation inhibitor 0.7 and toner 0.06;
The matrix resin of master batch is PBT; Filler is talcum powder; Lubricant is the mixture of fatty acid amide and ethylene-acrylic acid copolymer; Oxidation inhibitor is refine Irganox 1010, the Irganox 1076 of company and the mixture of Irganox 168 of CIBA; Toner is the mixture of carbon black+inorganic Huang and organic yellow.
Step 2: base-material and master batch are placed stir 10～20min in the high-speed mixer respectively, mix by measuring apparatus and send in the twin screw extruder, the temperature of control twin screw extruder is 180～250 ℃, conveying, shearing and mixing following at screw rod, with material melting, compound, then through extrude, tie rod, cooling, pelletizing step, obtain base-material and master batch respectively, it is mixed 5～10min in proportion in high-speed mixer, what namely obtain having the amber effect exempts to spray aesthstic resin.
Implementation result: be shown in Table 1, table 1 compares the result for embodiment 1～5 and Comparative Examples 1～2 prepared resin are injection molded into colour table.
Table 1
The △ number is more many, and the amber effect is more strong
The number is more many, and texture is more strong
The ☆ number is more many, and gloss is more strong
Shown by table 1 result, do not add the amber effect completely dissolve of the resin that rosin makes; Do not add phosphorus flame retardant, the surperficial texture of resin and gloss reduce, thereby greatly reduce the amber effect of resin.
In sum, above embodiment can be set according to different application scenarios, the present invention be based on the thermoplastic resin single injection-molded make have an amber effect exempt to spray aesthstic resin combination, the present invention makes the product of preparing have amber effect extremely true to nature through unique formulating of recipe and technological design, can be widely used in products such as artwork and household electrical appliances, the inventive method is simple, the efficient height, effect is remarkable, is applicable to large-scale industrial production.
More than specific embodiments of the invention are described.It will be appreciated that the present invention is not limited to above-mentioned specific implementations, those skilled in the art can make various distortion or modification within the scope of the claims, and this does not influence flesh and blood of the present invention.
Claims (10)
- One kind have the amber effect exempt from spray aesthstic resin combination, it is characterized in that described aesthstic resin combination is made up of each component of following parts by weight:Base-material 90～99;Master batch 1.0～10.
- As claimed in claim 1 have the amber effect exempt from spray aesthstic resin combination, it is characterized in that described base-material comprises each component of following parts by weight:Matrix resin 100;Lubricant 0.1～2.0;Oxidation inhibitor 0.1～1.0;Rosin 1.0～5.0;Phosphorus flame retardant 1.0～3.0.
- As claimed in claim 2 have the amber effect exempt from spray aesthstic resin combination, it is characterized in that described matrix resin is copolymerization PP, transparent ABS, GPPS or PMMA;Described lubricant is one or several the mixture in silicone oil, white mineral oil, fatty acid amide, barium stearate, Magnesium Stearate, paraffin, polyethylene wax, ethylene bis stearic acid amide, ethylene-vinyl acetate copolymer, the ethylene-acrylic acid copolymer;Described oxidation inhibitor is refine one or more the mixture of Irganox 1010, Irganox 1076, Irganox B900, Irganox 168 of company of CIBA;Described phosphorus flame retardant is the phosphoric acid ester phosphorus flame retardant.
- As claimed in claim 2 have the amber effect exempt from spray aesthstic resin combination, it is characterized in that described rosin is gum resin, wood rosin or starex.
- As claimed in claim 4 have the amber effect exempt from spray aesthstic resin combination, it is characterized in that the resinous acid mass percent is greater than 95% in the described rosin.
- As claimed in claim 2 have the amber effect exempt from spray aesthstic resin combination, it is characterized in that described phosphorus flame retardant is two (diphenyl phosphate) and Resorcinols (diphenyl phosphoester) of dihydroxyphenyl propane.
- As claimed in claim 1 have the amber effect exempt from spray aesthstic resin combination, it is characterized in that described master batch comprises each component of following parts by weight:Matrix resin 80～90;Filler 10～20;Lubricant 0.1～2.0;Oxidation inhibitor 0.1～1.0;Toner 0.01～0.1.
- As claimed in claim 7 have the amber effect exempt from spray aesthstic resin combination, it is characterized in that described matrix resin is the mixture of a kind of in PBT, the modified PBT or two kinds;Described filler is one or several the mixture in calcium carbonate, talcum powder, the wollastonite;Described lubricant is one or several the mixture in silicone oil, white mineral oil, fatty acid amide, barium stearate, Magnesium Stearate, paraffin, polyethylene wax, ethylene bis stearic acid amide, ethylene-vinyl acetate copolymer, the ethylene-acrylic acid copolymer;Described oxidation inhibitor is refine one or several the mixture of Irganox 1010, Irganox 1076, Irganox B900, Irganox 168 of company of CIBA;Described toner is the mixture of carbon black and inorganic Huang, a kind of or two kinds of mixtures of organic yellow.
- 9. the preparation method who exempts to spray aesthstic resin combination with amber effect as claimed in claim 1 is characterized in that described method comprises the steps:A, take by weighing each component according to the described component of claim 1 and parts by weight;B, successively base-material and master batch are placed in the high-speed mixer stir, mix by measuring apparatus and send in the twin screw extruder, the temperature of control twin screw extruder, conveying, shearing and mixing following at screw rod, with material melting, compound, then through extrude, tie rod, cooling, pelletizing step, successively obtain base-material and master batch, it is mixed in high-speed mixer in proportion, and what namely obtain having the amber effect exempts to spray aesthstic resin.
- 10. the preparation method who exempts to spray aesthstic resin combination with amber effect as claimed in claim 9, it is characterized in that, churning time is 10～20min in the described high-speed mixer, the temperature of described twin screw extruder is 180～250 ℃, and mixing time is 5～10min in high-speed mixer.
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| CN104403256B (en) * | 2014-11-28 | 2017-07-21 | 上海锦湖日丽塑料有限公司 | It is a kind of to exempt from spraying aesthetic resin and preparation method thereof with white jade effect |
| CN106279971A (en) * | 2016-07-29 | 2017-01-04 | 广东壹豪新材料科技股份有限公司 | A kind of high light PP factory formula exempting from spraying |
| CN106867211A (en) * | 2017-03-20 | 2017-06-20 | 四川中物材料股份有限公司 | A kind of low haze is high heat-resisting to exempt from PBT composite of primary coat and preparation method thereof |
| CN111909452A (en) * | 2020-08-13 | 2020-11-10 | 山东东方宏业化工有限公司 | Homo-polypropylene and preparation method thereof |
| CN111909452B (en) * | 2020-08-13 | 2022-06-28 | 山东东方宏业化工有限公司 | Homo-polypropylene and preparation method thereof |
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Application publication date: 20130807 |