CN104403256B - It is a kind of to exempt from spraying aesthetic resin and preparation method thereof with white jade effect - Google Patents
It is a kind of to exempt from spraying aesthetic resin and preparation method thereof with white jade effect Download PDFInfo
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- CN104403256B CN104403256B CN201410711991.4A CN201410711991A CN104403256B CN 104403256 B CN104403256 B CN 104403256B CN 201410711991 A CN201410711991 A CN 201410711991A CN 104403256 B CN104403256 B CN 104403256B
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Abstract
With white jade effect exempt from spraying aesthetic resin and preparation method thereof the present invention relates to a kind of, component includes：Matrix resin, astigmatism master batch, toner, lubricant, antioxidant；Its weight part ratio is 80 90: 10 20: 0.1 0.3: 0.1 2.0: 0.1 1.0.Wherein astigmatism master batch component includes：Matrix resin, astigmatism agent, lubricant, antioxidant；Its weight part ratio is 90: 10: 0.1 2.0: 0.1 1.0.Compared with prior art, the aesthetic resin that provides of the present invention can injection molding prepare the various products with white jade effect true to nature, greatly reduce cost and the cycle of product, and the various unmanageable labyrinths of use jade material can be prepared.The present invention can widely be incorporated in the products such as handicraft and household appliances.
Description
Technical field
The present invention relates to a kind of resin and preparation method thereof, with white jade effect spraying aesthetic is exempted from more particularly, to a kind of
Resin and preparation method thereof.
Background technology
Low-carbon environment-friendly, green is sustainable, has become main trend, various countries are also supported energetically in decree regulation,
Under this overall situation, the more and more favors for obtaining consumer of the new technology of various low-carbon environment-friendlies.Wherein, one-time formed U.S.
Resin is learned because of its convenience, the environmental pollution caused in production process is greatly reduced, has obtained the concern of more and more enterprises.
With continuing to develop for technology, multi-effect can be realized by exempting from spraying aesthetic resin, such as spray painting silver, electrosilvering, pearly-lustre
Silver-colored black and starry sky flicker of red, sudden strain of a muscle and other effects, in addition, the aesthetic resin of imitative natural effect also develops constantly, there is substantial amounts of special
Profit is studied, the imitation marble effect as described in CN 1792963A, the artificial white marble effect of CN 1126151A descriptions, CN
Imitative jade effect of 1483762A descriptions etc., but these methods realize that long flow path is imitated using the method for thermosetting resin die casting
Rate is low.
White jade is a kind of expensive mineral matter, is often used to craft articles, and scientists also often can be very in searching one kind
The manual method of white jade effect is substituted well, but these methods are all to use thermosetting resin forming technique, and technique is cumbersome, and efficiency is low
Under.
The content of the invention
It is an object of the present invention to overcome the above-mentioned drawbacks of the prior art and provide one kind is based on thermoplastic resin
Fat technology, can by single injection-molded, efficiency high there is white jade effect exempt from spraying aesthetic resin and preparation method thereof.
The purpose of the present invention can be achieved through the following technical solutions：
It is a kind of to exempt from spraying aesthetic resin with white jade effect, it is prepared into using the raw material of following components and parts by weight content
Arrive：
It is preferred that, matrix resin is transparent ABS, transparent ABS/PMMA alloy, PMMA, GPPS, transparent PP or MS.
It is preferred that, toner is rutile type titanium white, including commercially available RX-236 or RX-237.
It is preferred that, lubricant is silicone oil, White Mineral Oil, fatty acid amide, barium stearate, magnesium stearate, paraffin, polyethylene
One or more in wax, ethylene bis stearic acid amide, ethylene-vinyl acetate copolymer or ethylene-acrylic acid copolymer.
It is preferred that, antioxidant be CIBA refine the Irganox 1010 of company, Irganox 1076, Irganox B900 or
Irganox 168 one or more.
Astigmatism master batch is 90: 10: 0.1-2.0 by weight by master batch matrix resin, astigmatism agent, lubricant and antioxidant:
0.1-1.0, which is mixed with, to be obtained, wherein, the master batch matrix resin used for transparent ABS, transparent ABS/PMMA alloy, PMMA,
GPPS, transparent PP or MS, the refractive index of astigmatism agent are less than 1.42, and particle diameter can for example use commercially available I-020 at 2-3 μm,
SI-030 or EP2720；Lubricant is silicone oil, White Mineral Oil, fatty acid amide, barium stearate, magnesium stearate, paraffin, polyethylene
One or more in wax, ethylene bis stearic acid amide, ethylene-vinyl acetate copolymer or ethylene-acrylic acid copolymer；Antioxygen
Agent be CIBA refine the Irganox 1010 of company, Irganox 1076, Irganox B900 or Irganox 168 one kind or
It is several.
The preparation method for exempting from spraying aesthetic resin with white jade effect, using following steps：
(1) preparation of astigmatism master batch：It is 90: 10 by weight by master batch matrix resin, astigmatism agent, lubricant and antioxidant
: stirring 10-20min in high-speed mixer is placed in after 0.1-2.0: 0.1-1.0 mixing, it is double through metering device feeding after being well mixed
In screw extruder, the temperature for controlling double screw extruder is 180~250 DEG C, will under the conveying, shearing and mixing in screw rod
Material melting, compound, then extruded, tie rod, cooling, pelletizing step obtain astigmatism master batch；
(2) after matrix resin, astigmatism master batch, toner, lubricant and antioxidant being mixed by formula be placed in high-speed mixer
Interior stirring 10-20min, sends into double screw extruder after being well mixed through metering device, controls the temperature of double screw extruder
For 180~250 DEG C, under conveying in screw rod, shearing and mixing, by material melting, compound, then extruded, tie rod, cooling,
Pelletizing, that is, prepare and exempt from spraying aesthetic resin with white jade effect.
Compared with prior art, the present invention uses thermoplastic resin, passes through the method for single injection-molded, it is possible to obtain
Jade effect true to nature, substantially reduces molding cycle, improves production efficiency.
Embodiment
With reference to specific embodiment, the present invention is described in detail.
Embodiment 1
A kind of to exempt from spraying aesthetic resin with white jade effect, preparation method comprises the following steps：
Astigmatism master batch is placed in stirring 10-20min in high-speed mixer, after being well mixed in specific components and ratio dispensing
Through in metering device feeding double screw extruder, control the temperature of double screw extruder for 180~250 DEG C, conveying in screw rod,
Under shearing and mixing, by material melting, it is combined, then extruded, tie rod, cooling, pelletizing step obtain astigmatism master batch；Then
Aesthetic resin is equally in specific components and ratio dispensing, and preparation method is with astigmatism agglomerate preparation method, and just can obtain one kind has
White jade effect exempts from spraying aesthetic resin.
Wherein aesthetic resin component includes：Matrix resin, astigmatism master batch, toner, lubricant and antioxidant, its weight part ratio
For 90: 10: 0.2: 1.0: 0.5；
Matrix resin is transparent ABS；Toner is rutile type titanium white RX-236；Lubricant be magnesium stearate and ethene-
The mixture of acrylic copolymer；Antioxidant be CIBA refine company Irganox 1010 and Irganox 168 mixture；
Astigmatism master batch component includes：Master batch matrix resin, astigmatism agent, lubricant and antioxidant, its weight part ratio are 90: 10
∶1.0∶0.5；
Master batch matrix resin is transparent ABS；Astigmatism agent is refractive index 1.42, EP2720 of the particle diameter between 2-3 μm；Lubrication
Agent is the mixture of magnesium stearate and ethylene-acrylic acid copolymer；Antioxidant is that CIBA refines the Hes of Irganox 1010 of company
Irganox 168 mixture.
Comparative example 1
A kind of to exempt from spraying aesthetic resin with white jade effect, preparation method comprises the following steps：
Astigmatism master batch is placed in stirring 10-20min in high-speed mixer, after being well mixed in specific components and ratio dispensing
Through in metering device feeding double screw extruder, control the temperature of double screw extruder for 180~250 DEG C, conveying in screw rod,
Under shearing and mixing, by material melting, it is combined, then extruded, tie rod, cooling, pelletizing step obtain astigmatism master batch；Then
Aesthetic resin is equally in specific components and ratio dispensing, and preparation method is with astigmatism agglomerate preparation method, and just can obtain one kind has
White jade effect exempts from spraying aesthetic resin.
Wherein aesthetic resin component includes：Matrix resin, astigmatism master batch, toner, lubricant and antioxidant, its weight part ratio
For 90: 10: 0.2: 1.0: 0.5；
Matrix resin is transparent ABS；Toner is rutile type titanium white RX-236；Lubricant be magnesium stearate and ethene-
The mixture of acrylic copolymer；Antioxidant be CIBA refine company Irganox 1010 and Irganox 168 mixture；
Wherein astigmatism master batch component includes：Master batch matrix resin, astigmatism agent, lubricant and antioxidant, its weight part ratio is
90∶10∶1.0∶0.5；
Master batch matrix resin is transparent ABS；Astigmatism agent is refractive index 1.59, the SBX-4 that 4 μm of particle diameter；Lubricant is tristearin
The mixture of sour magnesium and ethylene-acrylic acid copolymer；Antioxidant is that CIBA refines the Irganox 1010 and Irganox of company
168 mixture.
Comparative example 2
A kind of to exempt from spraying aesthetic resin with white jade effect, preparation method comprises the following steps：
Astigmatism master batch is placed in stirring 10-20min in high-speed mixer, after being well mixed in specific components and ratio dispensing
Through in metering device feeding double screw extruder, control the temperature of double screw extruder for 180~250 DEG C, conveying in screw rod,
Under shearing and mixing, by material melting, it is combined, then extruded, tie rod, cooling, pelletizing step obtain astigmatism master batch；Then
Aesthetic resin is equally in specific components and ratio dispensing, and preparation method is with astigmatism agglomerate preparation method, and just can obtain one kind has
White jade effect exempts from spraying aesthetic resin.
Wherein aesthetic resin component includes：Matrix resin, astigmatism master batch, toner, lubricant and antioxidant, its weight part ratio
For 90: 10: 0.2: 1.0: 0.5；
Matrix resin is transparent ABS；Toner is anatase thpe white powder R-104；Lubricant is magnesium stearate and ethylene-propylene
The mixture of acid copolymer；Antioxidant be CIBA refine company Irganox 1010 and Irganox 168 mixture；
Wherein astigmatism master batch component includes：Master batch matrix resin, astigmatism agent, lubricant and antioxidant, its weight part ratio is
90∶10∶1.0∶0.5；
Master batch matrix resin is transparent ABS；Astigmatism agent is refractive index 1.42, EP2720 of the particle diameter between 2-3 μm；Lubrication
Agent is the mixture of magnesium stearate and ethylene-acrylic acid copolymer；Antioxidant is that CIBA refines the Hes of Irganox 1010 of company
Irganox 168 mixture；
Comparative example 3
A kind of to exempt from spraying aesthetic resin with white jade effect, preparation method comprises the following steps：
Astigmatism master batch is placed in stirring 10-20min in high-speed mixer, after being well mixed in specific components and ratio dispensing
Through in metering device feeding double screw extruder, control the temperature of double screw extruder for 180~250 DEG C, conveying in screw rod,
Under shearing and mixing, by material melting, it is combined, then extruded, tie rod, cooling, pelletizing step obtain astigmatism master batch；Then
Aesthetic resin is equally in specific components and ratio dispensing, and preparation method is with astigmatism agglomerate preparation method, and just can obtain one kind has
White jade effect exempts from spraying aesthetic resin.
Wherein aesthetic resin component includes：Matrix resin, astigmatism master batch, toner, lubricant and antioxidant, its weight part ratio
For 90: 10: 0.05: 1.0: 0.5；
Matrix resin is transparent ABS；Toner is rutile type titanium white RX-236；Lubricant be magnesium stearate and ethene-
The mixture of acrylic copolymer；Antioxidant be CIBA refine company Irganox 1010 and Irganox 168 mixture；
Wherein astigmatism master batch component includes：Master batch matrix resin, astigmatism agent, lubricant and antioxidant, its weight part ratio is
90∶10∶1.0∶0.5；
Master batch matrix resin be transparent ABS；Astigmatism agent is refractive index 1.42, EP2720 of the particle diameter between 2-3 μm；Profit
Lubrication prescription is the mixture of magnesium stearate and ethylene-acrylic acid copolymer；Antioxidant is that CIBA refines the Irganox 1010 of company
With Irganox 168 mixture；
Comparative example 4
A kind of to exempt from spraying aesthetic resin with white jade effect, preparation method comprises the following steps：
Astigmatism master batch is placed in stirring 10-20min in high-speed mixer, after being well mixed in specific components and ratio dispensing
Through in metering device feeding double screw extruder, control the temperature of double screw extruder for 180~250 DEG C, conveying in screw rod,
Under shearing and mixing, by material melting, it is combined, then extruded, tie rod, cooling, pelletizing step obtain astigmatism master batch；Then
Aesthetic resin is equally in specific components and ratio dispensing, and preparation method is with astigmatism agglomerate preparation method, and just can obtain one kind has
White jade effect exempts from spraying aesthetic resin.
Wherein aesthetic resin component includes：Matrix resin, astigmatism master batch, toner, lubricant and antioxidant, its weight part ratio
For 90: 10: 0.5: 1.0: 0.5；
Matrix resin is transparent ABS；Toner is rutile type titanium white RX-236；Lubricant be magnesium stearate and ethene-
The mixture of acrylic copolymer；Antioxidant be CIBA refine company Irganox 1010 and Irganox 168 mixture；
Wherein astigmatism master batch component includes：Master batch matrix resin, astigmatism agent, lubricant and antioxidant, its weight part ratio is
90∶10∶1.0∶0.5；
Master batch matrix resin is transparent ABS；Astigmatism agent is refractive index 1.42, EP2720 of the particle diameter between 2-3 μm；Lubrication
Agent is the mixture of magnesium stearate and ethylene-acrylic acid copolymer；Antioxidant is that CIBA refines the Hes of Irganox 1010 of company
Irganox 168 mixture；
Embodiment 2
Bloom injection colour table is prepared using the material of embodiment 1 and comparative example 1,2,3 and 4, compares its white jade effect strong
Weak and light transmittance, table 1 is parameter and white jade effect and the data of light transmittance.
Table 1
Note：More than zero represents that light transmittance is higher, and ◎ represents that white jade effect is better.
Comparative example 1 and comparative example 1 are found, the refractive index of light diffusing agent is adjusted into 1.59, white jade effect from 1.42
Substantially reduce.
Comparative example 1 and comparative example 2 find, changes the crystal formation of titanium dioxide into anatase titanium dioxide from rutile-type, transmitance and
White jade effect is all reduced.
Comparative example 1 and comparative example 3 are found, the consumption of titanium dioxide are adjusted into 0.05 from 0.2, transmitance rises,
But jade effect also reduced.
Comparative example 1 and comparative example 4 are found, the consumption of titanium dioxide are adjusted into 0.5 from 0.2, transmitance is reduced, beautiful
Stone effect degradation.
Embodiment 3
A kind of to exempt from spraying aesthetic resin with white jade effect, preparation method comprises the following steps：
Astigmatism master batch is placed in stirring 10-20min in high-speed mixer, after being well mixed in specific components and ratio dispensing
Through in metering device feeding double screw extruder, control the temperature of double screw extruder for 180~250 DEG C, conveying in screw rod,
Under shearing and mixing, by material melting, it is combined, then extruded, tie rod, cooling, pelletizing step obtain astigmatism master batch；Then
Aesthetic resin is equally in specific components and ratio dispensing, and preparation method is with astigmatism agglomerate preparation method, and just can obtain one kind has
White jade effect exempts from spraying aesthetic resin.
Embodiment 2
It is a kind of to exempt from spraying aesthetic resin with white jade effect, it is prepared into using the raw material of following components and parts by weight content
Arrive：Matrix resin 90；Astigmatism master batch 10；Toner 0.3；Lubricant 2.0；Antioxidant 1.0.
Wherein, matrix resin is transparent ABS/PMMA alloy, and toner is rutile type titanium white, for example, can use commercially available
RX-237.Lubricant is ethylene bis stearic acid amide, and antioxidant is that CIBA refines the Irganox 168 of company.
Astigmatism master batch is mixed by master batch matrix resin, astigmatism agent, lubricant and antioxidant by weight for 90: 10: 2.0: 1.0
Conjunction is prepared, wherein, the master batch matrix resin used is PMMAS, and the refractive index of astigmatism agent is less than 1.42, particle diameter at 2-3 μm,
Commercially available EP2720 can for example be used；Lubricant is the mixture of paraffin and Tissuemat E；Antioxidant is that CIBA refines company
Irganox 1076.
The preparation method for exempting from spraying aesthetic resin with white jade effect, using following steps：
(1) preparation of astigmatism master batch：It is 90: 10 by weight by master batch matrix resin, astigmatism agent, lubricant and antioxidant
: stirring 20min in high-speed mixer is placed in after 2.0: 1.0 mixing, double screw extruder is sent into through metering device after being well mixed
In, the temperature for controlling double screw extruder is 250 DEG C, under the conveying, shearing and mixing in screw rod, by material melting, is combined, so
By extrusion, tie rod, cooling, pelletizing step, astigmatism master batch is obtained；
(2) after matrix resin, astigmatism master batch, toner, lubricant and antioxidant being mixed by formula be placed in high-speed mixer
Interior stirring 20min, sends into double screw extruder, the temperature for controlling double screw extruder is after being well mixed through metering device
250 DEG C, under the conveying, shearing and mixing in screw rod, by material melting, it is combined, then extruded, tie rod, cooling, pelletizing, i.e.,
Prepare and exempt from spraying aesthetic resin with white jade effect.
Embodiment 3
It is a kind of to exempt from spraying aesthetic resin with white jade effect, it is prepared into using the raw material of following components and parts by weight content
Arrive：Matrix resin 80；Astigmatism master batch 20；Toner 0.1；Lubricant 0.1；Antioxidant 0.1.
Wherein, the matrix resin used is Transparent ABS Resin, and toner is rutile type titanium white, can be used commercially available
RX-236, lubricant is silicone oil, and antioxidant is that CIBA refines the Irganox 1010 of company.
Astigmatism master batch is mixed by master batch matrix resin, astigmatism agent, lubricant and antioxidant by weight for 90: 10: 0.1: 0.1
Conjunction is prepared, wherein, the master batch matrix resin used is transparent ABS, and the refractive index of astigmatism agent is less than 1.42, and particle diameter is in 2-3 μ
M, for example, can use commercially available I-020；Lubricant is silicone oil；Antioxidant is that CIBA refines the Irganox 1010 of company.
The preparation method for exempting from spraying aesthetic resin with white jade effect, using following steps：
(1) preparation of astigmatism master batch：It is 90: 10 by weight by master batch matrix resin, astigmatism agent, lubricant and antioxidant
: stirring 10min in high-speed mixer is placed in after 0.1: 0.1 mixing, double screw extruder is sent into through metering device after being well mixed
In, the temperature for controlling double screw extruder is 180 DEG C, under the conveying, shearing and mixing in screw rod, by material melting, is combined, so
By extrusion, tie rod, cooling, pelletizing step, astigmatism master batch is obtained；
(2) after matrix resin, astigmatism master batch, toner, lubricant and antioxidant being mixed by formula be placed in high-speed mixer
Interior stirring 10min, sends into double screw extruder, the temperature for controlling double screw extruder is after being well mixed through metering device
180 DEG C, under the conveying, shearing and mixing in screw rod, by material melting, it is combined, then extruded, tie rod, cooling, pelletizing, i.e.,
Prepare and exempt from spraying aesthetic resin with white jade effect.
Claims (5)
1. a kind of exempt from spraying aesthetic resin with white jade effect, it is characterised in that using following components and parts by weight contents
Raw material is prepared：
Described astigmatism master batch is 90 by weight by master batch matrix resin, astigmatism agent, lubricant and antioxidant：10：0.1-
2.0：0.1-1.0, which is mixed with, to be obtained,
Described master batch matrix resin be transparent ABS, transparent ABS/PMMA alloy, PMMA, GPPS, transparent PP or MS,
The refractive index of described astigmatism agent is less than 1.42, and particle diameter is at 2-3 μm；
Described lubricant is silicone oil, White Mineral Oil, fatty acid amide, barium stearate, magnesium stearate, paraffin, Tissuemat E, ethylene
One or more in double stearic amides, ethylene-vinyl acetate copolymer or ethylene-acrylic acid copolymer；
Described antioxidant be CIBA refine the Irganox 1010 of company, Irganox 1076, Irganox B900 or
Irganox 168 one or more；
Described toner is rutile type titanium white.
A kind of exempt from spraying aesthetic resin with white jade effect 2. according to claim 1, it is characterised in that described base
Body resin is transparent ABS, transparent ABS/PMMA alloy, PMMA, GPPS, transparent PP or MS.
A kind of exempt from spraying aesthetic resin with white jade effect 3. according to claim 1, it is characterised in that described dissipates
Photo etching is commercially available EP2720.
A kind of exempt from spraying aesthetic resin with white jade effect 4. according to claim 1, it is characterised in that described color
Powder includes commercially available RX-236 or RX-237.
5. the preparation method for exempting from spraying aesthetic resin with white jade effect according to any one of claim 1-4, its
It is characterised by, this method uses following steps：
(1) preparation of astigmatism master batch：It is 90 by weight by master batch matrix resin, astigmatism agent, lubricant and antioxidant：10：
0.1-2.0：Stirring 10-20min in high-speed mixer is placed in after 0.1-1.0 mixing, it is double through metering device feeding after being well mixed
In screw extruder, the temperature for controlling double screw extruder is 180~250 DEG C, will under the conveying, shearing and mixing in screw rod
Material melting, compound, then extruded, tie rod, cooling, pelletizing step obtain astigmatism master batch；
(2) it is placed in high-speed mixer and stirs after mixing matrix resin, astigmatism master batch, toner, lubricant and antioxidant by formula
10-20min is mixed, is sent into after being well mixed through metering device in double screw extruder, the temperature for controlling double screw extruder is 180
~250 DEG C, under the conveying, shearing and mixing in screw rod, by material melting, compound, then extruded, tie rod, cooling, pelletizing,
Prepare and exempt from spraying aesthetic resin with white jade effect.
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Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105255093B (en) * | 2015-11-03 | 2018-03-02 | 四川长虹电器股份有限公司 | ABS composite material of imitation marble effect and preparation method thereof |
| CN106009470A (en) * | 2016-06-24 | 2016-10-12 | 深圳市同益实业股份有限公司 | Resin material and preparation method thereof |
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| CN102464855A (en) * | 2010-11-15 | 2012-05-23 | 上海锦湖日丽塑料有限公司 | Aesthetic resin for improving white blink effect and preparation method thereof |
| CN102516700A (en) * | 2011-12-09 | 2012-06-27 | 上海锦湖日丽塑料有限公司 | Appearance-improving spraying-free aesthetic resin and its preparation method |
| CN102816420A (en) * | 2011-06-10 | 2012-12-12 | 泰州科逸新材料有限公司 | Jade-like bulk molding compound and preparation method thereof |
| CN103232640A (en) * | 2013-04-27 | 2013-08-07 | 上海锦湖日丽塑料有限公司 | Spraying-free aesthetic resin composition with amber effect and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101392082A (en) * | 2008-10-28 | 2009-03-25 | 宁波色母粒有限公司 | Polypropylene jade green-like color master batch and preparation method thereof |
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| CN102516700A (en) * | 2011-12-09 | 2012-06-27 | 上海锦湖日丽塑料有限公司 | Appearance-improving spraying-free aesthetic resin and its preparation method |
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