CN102516700A - Appearance-improving spraying-free aesthetic resin and its preparation method - Google Patents
Appearance-improving spraying-free aesthetic resin and its preparation method Download PDFInfo
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- CN102516700A CN102516700A CN2011104076966A CN201110407696A CN102516700A CN 102516700 A CN102516700 A CN 102516700A CN 2011104076966 A CN2011104076966 A CN 2011104076966A CN 201110407696 A CN201110407696 A CN 201110407696A CN 102516700 A CN102516700 A CN 102516700A
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Abstract
The invention relates to an appearance-improving spraying-free aesthetic resin and its preparation method. The resin comprises the following components by weight part: 90 of matrix resin, 0.1-2.0 of a lubricant, 0.1-1.0 of an antioxidant, and 10-30 of a magnetic metallic pigment masterbatch, which consists of the following components by weight part: 100 of the matrix resin, 1.0-20 of a magnetic metallic pigment, 1.0-30 of a pearlescent pigment, 0.1-2.0 of the lubricant, 0.1-1.0 of the antioxidant. The preparation method includes: preparing the magnetic metallic pigment masterbatch; and mixing the above raw materials, then conducting mixing, extrusion, bracing, cooling, and pelletizing, thus obtaining the aesthetic resin. The aesthetic resin of the invention can effectively improve the affinity of an aluminum powder pigment and a plastic substrate, mitigate flow marks and weld lines that appear during injection molding or extrusion of aluminum powder pigment-containing aesthetic resin, and simultaneously strengthens the metal effect a made piece, greatly reduces consumption of the aluminum powder pigment, and saves cost. The present invention is green and environmental aesthetics resin instead of traditional paint scheme provides technical support. The aesthetic resin and the preparation method provided in the invention provide technical support for green and environmentally friendly aesthetic resin to substitute traditional paint spraying schemes.
Description
Technical field
The invention belongs to resin formula and preparation field thereof, especially relate to a kind of improve outward appearance exempt to spray aesthstic resin and preparation method thereof.
Background technology
Along with the popularization of low-carbon environment-friendly notion, substitute exempting from of spraying paint and spray aesthstic resin and more and more receive numerous enterprises man and public concerns, demonstrate the unprecedented market competitiveness.Special-effects such as gorgeous colorful tone that not only can reaching sprays paint produces and pearly-lustre, flash effect, metal color can also realize half passing through, the inaccessible effects of metal such as full impregnated and astigmatism.The common plastics that prepare aesthstic resin have PP, ABS, PMMA, ABS/PMMA, PC, PC/ABS, ASA, polyester, PS etc.Aesthstic resin not only production efficiency is high, and cost is low, and can recycle, and is widely used in fields such as household electrical appliances, automobile, consumer electronics.
Exempting to spray aesthstic resin compares with the material that sprays paint; Though whole cost is lower; But the toner of the special-effect that is to use is more; Exempt to spray the toner that aesthstic resin integral body all contains special-effect, and the just toner of resin surface layer of decision product outward appearance, major part is in the inner toner of resin and all is wasted; On the other hand; In order to increase the effect of exempting to spray aesthstic resin; Just need to strengthen the consumption of toner, so just increased the weight of because defectives such as current mark that the flow orientation difference of metallic pigment or pearly pigment causes and weld bond have limited the effective scope of exempting to spray aesthstic resin.
Summary of the invention
The objective of the invention is to overcome the deficiency that above-mentioned conventional art of exempting to spray aesthstic resin exists, provide a kind of improve outward appearance exempt to spray aesthstic resin and preparation method thereof.The metal toner that contains magnetic among the present invention in injection moulding or extrusion because the attraction of irony equipment can be to the product surface transport; Form enrichment; The service efficiency and the opacifying power of unit mass metal toner have been improved greatly; Exempt from the spraying scheme with tradition and compare, reach same metal effect and the employed metal toner of opacifying power amount and significantly reduce, practiced thrift cost; Simultaneously, current mark and the weld bond problem of exempting to spray aesthstic resin also alleviated in the minimizing of toner, widened its color effects scope, makes the range of application of exempting to spray aesthstic resin wider.
The objective of the invention is to realize through following technical scheme:
The present invention relates to a kind of improve outward appearance exempt to spray aesthstic resin, this resin comprises following component and weight part:
Matrix resin 70～90,
Lubricant 0.1～2.0,
Oxidation inhibitor 0.1～1.0,
Magneticmetal pigment master batch 10～30;
Wherein, said magneticmetal pigment master batch comprises following component and weight part:
Matrix resin 100,
Magneticmetal pigment 1.0～20,
Pearly pigment 1.0～30,
Lubricant 0.1～2.0,
Oxidation inhibitor 0.1～1.0.
Preferably, described matrix resin is high gloss ABS, transparent ABS, ABS/PMMA alloy, PMMA, toughened polymethyl methacrylate (PMMA), transparent HIPS, GPPS, high light PP, PC/ABS alloy, PC, ASA, PBT, PET or PPO.
Preferably, described magneticmetal pigment comprises metal powder, magnetic and coating base material; Said metal powder is one or more in aluminium powder, silver powder, bronze, zinc powder, the copper powder, and it is shaped as sheet, silver dollar shape, bar-shaped or spherical, and its particle diameter is 1 μ m～300 μ m; Said magnetic is one or more in Z 250, chromium dioxide, the cobalt-red stone, and its weight percent content that accounts for metal powder is 20%～60%; Said coating base material is glycidyl ether based epoxy resin, glycidyl ester based epoxy resin, Racemic glycidol amine epoxy resin, line style aliphatic category epoxy resin or aliphatic category epoxy resin.
Preferably, described metal powder particle diameter is 10 μ m～100 μ m.
Preferably, described pearly pigment is that the natural indestructible pearl delustering pigment, pearl white crystallization pearly pigment, mica of particle diameter 20 μ m～500 μ m applies pearly pigment, silica-coated pearly pigment, aluminium silicate salt and apply pearly pigment, aluminum borate salt and apply pearly pigment, micanite and apply pearly pigment, bismuth oxide and apply in the pearly pigment one or more.
Preferably, described pearly pigment is mica coating pearly pigment, silica-coated pearly pigment, micanite coating pearly pigment, aluminum borate salt coating pearly pigment or the aluminium silicate salt coating pearly pigment of particle diameter 100 μ m～400 μ m.
Preferably, described pearly pigment surface coats one deck MOX at least, and said MOX comprises aluminum oxide, tindioxide, titanium oxide, red stone, weisspiessglanz or zinc oxide.
Preferably, described lubricant is one or more in silicone oil, white mineral oil, fatty acid amide, barium stearate, Magnesium Stearate, paraffin, polyethylene wax, ethylene bis stearic acid amide, Injecatable EVA Copolymer, the ethylene-acrylic acid copolymer.
Preferably, described oxidation inhibitor comprises refine one or more of Irganox 1010, Irganox 1076, Irganox B900, Irganox 168 of company of CIBA.
The invention still further relates to a kind of above-mentioned method of exempting to spray aesthstic resin of improving outward appearance for preparing, this method may further comprise the steps:
A, get the raw materials ready according to following component and weight part:
Matrix resin 100;
Magneticmetal pigment 1.0～20;
Pearly pigment 1.0～30;
Lubricant 0.1～2.0;
Oxidation inhibitor 0.1～1.0;
B, the raw material among the above-mentioned steps a placed in the high-speed mixer by prescription stir; Mix after WT-MSR is sent in the twin screw extruder; The temperature of control twin screw extruder is 180～230 ℃, in conveying, the shearing and mixing following of screw rod, with material melting, compound; Then through extrude, tie rod, cooling, pelletizing step, promptly obtain containing the master batch of magneticmetal pigment;
C, get the raw materials ready according to following component and weight part:
Matrix resin 70～90;
Lubricant 0.1～2.0;
Oxidation inhibitor 0.1～1.0;
The magneticmetal pigment master batch 10～30 that step b makes;
D, the raw material among the above-mentioned steps c placed in the high-speed mixer by prescription stir; Mix after WT-MSR is sent in the twin screw extruder; The temperature of control twin screw extruder is 180～230 ℃, in conveying, the shearing and mixing following of screw rod, with material melting, compound; Then through extrude, tie rod, cooling, pelletizing step, promptly obtain a kind of improve outward appearance exempt to spray aesthstic resin.
Compared with prior art; The present invention has following beneficial effect: the present invention can effectively improve the affinity of aluminium powder pigment and plastic basis material, alleviates current mark and weld bond that the aesthstic resin that contains aluminium powder pigment occurs in injection moulding or extrusion, simultaneously; The nanometer ball of parcel aluminium powder pigment and magnetic in injection moulding or extrusion owing to the attraction of irony equipment to surface transport; Obviously strengthen the metal effect of product, greatly reduced the usage quantity of aluminium powder pigment, practiced thrift cost.The present invention replaces traditional scheme of spraying paint that technical support is provided for the aesthstic resin of environmental protection.
Embodiment
Elaborate in the face of embodiments of the invention down: present embodiment provided detailed embodiment and concrete operating process, but protection scope of the present invention is not limited to following embodiment being to implement under the prerequisite with technical scheme of the present invention.
Embodiment 1
A kind of improve outward appearance exempt to spray aesthstic resin, this method may further comprise the steps:
(1) get the raw materials ready according to following component and weight part:
Matrix resin 100;
Magneticmetal pigment 6.0;
Pearly pigment 8.0;
Lubricant 2.0;
Oxidation inhibitor 0.3;
(2) above-mentioned (1) raw material is placed in the high-speed mixer by prescription stir; Mix after WT-MSR is sent in the twin screw extruder; The temperature of control twin screw extruder is 180～230 ℃, in conveying, the shearing and mixing following of screw rod, with material melting, compound; Then through extrude, tie rod, cooling, pelletizing step, promptly obtain containing the master batch of magneticmetal pigment.
(3) get the raw materials ready according to following component and weight part:
Matrix resin 90;
Lubricant 2.0;
Oxidation inhibitor 0.3;
Magneticmetal pigment master batch 10;
(4) above-mentioned (3) raw material is placed in the high-speed mixer by prescription stir; Mix after WT-MSR is sent in the twin screw extruder; The temperature of control twin screw extruder is 180～230 ℃, in conveying, the shearing and mixing following of screw rod, with material melting, compound; Then through extrude, tie rod, cooling, pelletizing step, promptly obtain a kind of improve outward appearance exempt to spray aesthstic resin.
Wherein, matrix resin is the high gloss ABS resin;
Magneticmetal pigment is the flake aluminum and the Z 250 of bisphenol A type epoxy resin parcel, and the weight percent content that Z 250 accounts for aluminium powder is 20%, and the aluminium powder particle diameter is 40 μ m;
Pearly pigment is the sheet mica that TiO2 coats, and particle diameter is 100 μ m;
Lubricant is a Magnesium Stearate;
Oxidation inhibitor is Irganox B900;
Embodiment 2
A kind of improve outward appearance exempt to spray aesthstic resin, this method may further comprise the steps:
(1) get the raw materials ready according to following component and weight part:
Matrix resin 100;
Magneticmetal pigment 8.0;
Pearly pigment 8.0;
Lubricant 2.0;
Oxidation inhibitor 0.3;
(2) above-mentioned (1) raw material is placed in the high-speed mixer by prescription stir; Mix after WT-MSR is sent in the twin screw extruder; The temperature of control twin screw extruder is 180～230 ℃, in conveying, the shearing and mixing following of screw rod, with material melting, compound; Then through extrude, tie rod, cooling, pelletizing step, promptly obtain containing the master batch of magneticmetal pigment.
(3) get the raw materials ready according to following component and weight part:
Matrix resin 90;
Lubricant 2.0;
Oxidation inhibitor 0.3;
Magneticmetal pigment master batch 10;
(4) above-mentioned (3) raw material is placed in the high-speed mixer by prescription stir; Mix after WT-MSR is sent in the twin screw extruder; The temperature of control twin screw extruder is 180～230 ℃, in conveying, the shearing and mixing following of screw rod, with material melting, compound; Then through extrude, tie rod, cooling, pelletizing step, promptly obtain a kind of improve outward appearance exempt to spray aesthstic resin.
Wherein, matrix resin is high light PC/ABS alloy;
Magneticmetal pigment is the flake aluminum and the Z 250 of bisphenol A type epoxy resin parcel, and the weight percent content that Z 250 accounts for aluminium powder is 60%, and the aluminium powder particle diameter is 40 μ m;
Pearly pigment is the sheet mica that TiO2 coats, and particle diameter is 100 μ m;
Lubricant is a Magnesium Stearate;
Oxidation inhibitor is Irganox B900;
Embodiment 3
A kind of improve outward appearance exempt to spray aesthstic resin, this method may further comprise the steps:
(1) get the raw materials ready according to following component and weight part:
Matrix resin 100;
Magneticmetal pigment 8.0;
Pearly pigment 8.0;
Lubricant 2.0;
Oxidation inhibitor 0.3;
(2) above-mentioned (1) raw material is placed in the high-speed mixer by prescription stir; Mix after WT-MSR is sent in the twin screw extruder; The temperature of control twin screw extruder is 180～230 ℃, in conveying, the shearing and mixing following of screw rod, with material melting, compound; Then through extrude, tie rod, cooling, pelletizing step, promptly obtain containing the master batch of magneticmetal pigment.
(3) get the raw materials ready according to following component and weight part:
Matrix resin 90;
Lubricant 2.0;
Oxidation inhibitor 0.3;
Magneticmetal pigment master batch 10;
(4) above-mentioned (3) raw material is placed in the high-speed mixer by prescription stir; Mix after WT-MSR is sent in the twin screw extruder; The temperature of control twin screw extruder is 180～230 ℃, in conveying, the shearing and mixing following of screw rod, with material melting, compound; Then through extrude, tie rod, cooling, pelletizing step, promptly obtain a kind of improve outward appearance exempt to spray aesthstic resin.
Wherein, matrix resin is the ABS/PMMA alloy;
Magneticmetal pigment is the flake aluminum and the cobalt-red stone of bisphenol A type epoxy resin parcel, and the weight percent content that cobalt-red stone accounts for aluminium powder is 60%, and the aluminium powder particle diameter is 40 μ m;
Pearly pigment is the sheet mica that TiO2 coats, and particle diameter is 100 μ m;
Lubricant is a Magnesium Stearate;
Oxidation inhibitor is Irganox B900;
Comparative Examples 1
A kind of traditional exempting from sprays aesthstic resin, and this method may further comprise the steps:
(1) get the raw materials ready according to following component and weight part:
Matrix resin 100;
Magneticmetal pigment 5.0;
Pearly pigment 8.0;
Lubricant 2.0;
Oxidation inhibitor 0.3;
(2) above-mentioned (1) raw material is placed in the high-speed mixer by prescription stir; Mix after WT-MSR is sent in the twin screw extruder; The temperature of control twin screw extruder is 180～230 ℃, in conveying, the shearing and mixing following of screw rod, with material melting, compound; Then through extrude, tie rod, cooling, pelletizing step, promptly obtain containing the master batch of metallic pigment.
(3) get the raw materials ready according to following component and weight part:
Matrix resin 90;
Lubricant 2.0;
Oxidation inhibitor 0.3;
Magneticmetal pigment master batch 10;
(4) above-mentioned (3) raw material is placed in the high-speed mixer by prescription stir; Mix after WT-MSR is sent in the twin screw extruder; The temperature of control twin screw extruder is 220 ℃, in conveying, the shearing and mixing following of screw rod, with material melting, compound; Then through extrude, tie rod, cooling, pelletizing step, promptly obtain a kind of traditional exempting from and spray aesthstic resin.
Wherein, matrix resin is high light PPO resin;
Metallic pigment are the flake aluminum of bisphenol A type epoxy resin parcel, and particle diameter is 40 μ m;
Pearly pigment is the sheet mica that TiO2 coats, and particle diameter is 100 μ m;
Lubricant is a Magnesium Stearate;
Oxidation inhibitor is Irganox B900;
Comparative Examples 2
A kind of traditional exempting from sprays aesthstic resin, and this method may further comprise the steps:
(1) get the raw materials ready according to following component and weight part:
Matrix resin 100;
Metallic pigment 10;
Pearly pigment 8.0;
Lubricant 2.0;
Oxidation inhibitor 0.3;
(2) above-mentioned (1) raw material is placed in the high-speed mixer by prescription stir; Mix after WT-MSR is sent in the twin screw extruder; The temperature of control twin screw extruder is 180～230 ℃, in conveying, the shearing and mixing following of screw rod, with material melting, compound; Then through extrude, tie rod, cooling, pelletizing step, promptly obtain containing the master batch of metallic pigment.
(3) get the raw materials ready according to following component and weight part:
Matrix resin 90;
Lubricant 2.0;
Oxidation inhibitor 0.3;
Magneticmetal pigment master batch 10;
(4) above-mentioned (3) raw material is placed in the high-speed mixer by prescription stir; Mix after WT-MSR is sent in the twin screw extruder; The temperature of control twin screw extruder is 220 ℃, in conveying, the shearing and mixing following of screw rod, with material melting, compound; Then through extrude, tie rod, cooling, pelletizing step, promptly obtain a kind of traditional exempting from and spray aesthstic resin.
Wherein, matrix resin is PC;
Metallic pigment are the aluminium powder of bisphenol A type epoxy resin parcel, and particle diameter is 40 μ m;
Pearly pigment is the sheet mica that TiO2 coats, and particle diameter is 100 μ m;
Lubricant is a Magnesium Stearate;
Oxidation inhibitor is Irganox B900;
Embodiment 4, compliance test result
Table 1 is for using the prepared injection moulding colour table of material of embodiment 1,2,3 and Comparative Examples 1,2, and the processing conditions of extruding batten of embodiment 3 and material characteristics etc., and table 2 is the such scheme opacity, improve the description of effect and current mark.
Can be known that by table 1,2 with embodiment 1,2 relatively, find the increase along with ferroferric oxide magnetic powder, the opacity and the flicker effect on product surface are stronger, this is because the cause that the increase of particle content makes aluminium powder strengthen to the surperficial mobility of product.
Comparative example 2 and 3; Opacity and the flicker effect of finding embodiment 3 products are stronger, and this is because cobalt-iron oxide magnetic powder is stronger than ferroferric oxide magnetic powder paramagnetism, causes the migration of aluminium powder more easily; Make the opacity and the flicker effect on surface stronger, current mark is also slighter.
Comparative example 3 injection moulding colour table with extrude batten (extruding soon), opacity and the flicker effect of finding to extrude batten are stronger, and current mark is lighter; This is because compare with injection moulding process; The used time of extrusion is longer, and the migration of magnetic aluminium powder pigment is more abundant, and surface sediment is more closely knit; And orientation is better, is difficult for producing current mark.When the extruded velocity of adjustment batten is adjusted to 1m/min by 2m/min, opacity and the flicker effect of finding to extrude at a slow speed spline surfaces are stronger, this be because of, extrusion magneticmetal pigment migration is more abundant at a slow speed.
Comparing embodiment 1 and Comparative Examples 1 are found identical content of aluminium powder, and the system opacity and the flicker effect of adding magnetic are stronger, and current mark is also slighter.Comparing embodiment 1 and Comparative Examples 2 find that the nonmagnetic powder system wants covering and the flicker effect that reaches consistent with the magnetic system, need to add more metal toner, and be much serious but the current mark of product is wanted.
Table 1
Table 2
| Sequence number | Opacity | Flicker effect | Current mark |
| 1 | ★★ | ☆☆ | ◎◎◎ |
| 2 | ★★★ | ☆☆☆ | ◎◎◎ |
| 3 | ★★★★ | ☆☆☆☆ | ◎◎ |
| 4 | ★★★★★ | ☆☆☆☆☆ | ◎ |
| 5 | ★★★★★★ | ☆☆☆☆☆☆ | ◎ |
| 6 | ★ | ☆ | ◎◎◎◎ |
| 7 | ★★ | ☆☆ | ◎◎◎◎◎ |
Annotate: ★ multilist more shows that opacity is high more;
☆ multilist more shows that flicker effect is good more;
◎ multilist more shows that current mark is serious more.
In sum,, can obtain super flaring effect, the high white aesthstic resin that hides, the sprayingization of exempting from of the aesthstic resin of white is significant through optimization design of the present invention.
Embodiment 5
A kind of improve outward appearance exempt to spray aesthstic resin, this method may further comprise the steps:
(1) get the raw materials ready according to following component and weight part:
Matrix resin 100;
Magneticmetal pigment 1.0;
Pearly pigment 1.0;
Lubricant 1.0;
Oxidation inhibitor 0.1;
(2) above-mentioned (1) raw material is placed in the high-speed mixer by prescription stir; Mix after WT-MSR is sent in the twin screw extruder; The temperature of control twin screw extruder is 180～230 ℃, in conveying, the shearing and mixing following of screw rod, with material melting, compound; Then through extrude, tie rod, cooling, pelletizing step, promptly obtain containing the master batch of magneticmetal pigment.
(3) get the raw materials ready according to following component and weight part:
Matrix resin 70;
Lubricant 0.1;
Oxidation inhibitor 0.1;
Magneticmetal pigment master batch 30;
(4) above-mentioned (3) raw material is placed in the high-speed mixer by prescription stir; Mix after WT-MSR is sent in the twin screw extruder; The temperature of control twin screw extruder is 180～230 ℃, in conveying, the shearing and mixing following of screw rod, with material melting, compound; Then through extrude, tie rod, cooling, pelletizing step, promptly obtain a kind of improve outward appearance exempt to spray aesthstic resin.
Wherein, matrix resin is the ASA resin;
Magneticmetal pigment is the silver dollar shape bronze and the chromium dioxide of glycidyl ester based epoxy resin parcel, and the weight percent content that chromium dioxide accounts for bronze is 20%, and the bronze particle diameter is 17 μ m;
Pearly pigment is the sheet mica that TiO2 coats, and particle diameter is 200 μ m;
Lubricant is an Injecatable EVA Copolymer;
Oxidation inhibitor is Irganox 1076;
Embodiment 6
(1) get the raw materials ready according to following component and weight part:
Matrix resin 100;
Magneticmetal pigment 20;
Pearly pigment 30;
Lubricant 2.0;
Oxidation inhibitor 0.3;
(2) above-mentioned (1) raw material is placed in the high-speed mixer by prescription stir; Mix after WT-MSR is sent in the twin screw extruder; The temperature of control twin screw extruder is 180～230 ℃, in conveying, the shearing and mixing following of screw rod, with material melting, compound; Then through extrude, tie rod, cooling, pelletizing step, promptly obtain containing the master batch of magneticmetal pigment.
(3) get the raw materials ready according to following component and weight part:
Matrix resin 80;
Lubricant 2.0;
Oxidation inhibitor 0.3;
Magneticmetal pigment master batch 20;
(4) above-mentioned (3) raw material is placed in the high-speed mixer by prescription stir; Mix after WT-MSR is sent in the twin screw extruder; The temperature of control twin screw extruder is 180～230 ℃, in conveying, the shearing and mixing following of screw rod, with material melting, compound; Then through extrude, tie rod, cooling, pelletizing step, promptly obtain a kind of improve outward appearance exempt to spray aesthstic resin.
Wherein, matrix resin is high light PP resin;
Magneticmetal pigment is the spherical copper powder and the Z 250 of Racemic glycidol amine epoxy resin parcel, and the weight percent content that Z 250 accounts for copper powder is 60%, and copper powder size is 25 μ m;
Pearly pigment is that the aluminum borate salt that double-deck red stone coats applies pearly pigment, and particle diameter is 400 μ m;
Lubricant is a white mineral oil;
Oxidation inhibitor is Irganox 168;
Embodiment 7
Present embodiment is with embodiment 6, and institute's difference is:
Matrix resin is transparent HIPS;
Magneticmetal pigment is the bar-shaped zinc powder and the cobalt-red stone of line style aliphatic category epoxy resin parcel, and the weight percent content that cobalt-red stone accounts for zinc powder is 40%, and the zinc powder particle diameter is 10 μ m;
Pearly pigment is that the aluminium silicate salt that weisspiessglanz coats applies pearly pigment, and particle diameter is 500 μ m;
Lubricant is barium stearate and Magnesium Stearate;
Oxidation inhibitor is Irganox 1010 and Irganox 168.
Embodiment 8
Present embodiment is with embodiment 6, and institute's difference is:
Matrix resin is PET;
Magneticmetal pigment is the bar-shaped silver powder and the chromium dioxide of aliphatic category epoxy resin parcel, and the weight percent content that chromium dioxide accounts for silver powder is 35%, and the silver powder particle diameter is 100 μ m;
Pearly pigment is the natural indestructible pearl delustering pigment that tindioxide coats, and particle diameter is 50 μ m.
Lubricant is an ethylene-acrylic acid copolymer;
Oxidation inhibitor is Irganox 1010.
Embodiment 9
Present embodiment is with embodiment 6, and institute's difference is:
In the step (1), the lubricant weight part is: 0.1, and the oxidation inhibitor weight part is: 1.0;
In the step (3), the oxidation inhibitor weight part is: 1.0;
Matrix resin is GPPS;
Magneticmetal pigment is the bar-shaped aluminium powder and the cobalt-red stone of glycidyl ether based epoxy resin parcel, and the weight percent content that cobalt-red stone accounts for aluminium powder is 30%, and the aluminium powder particle diameter is 1 μ m;
Pearly pigment is the silica-coated pearly pigment that zinc oxide coats, and particle diameter is 20 μ m.
Lubricant is fatty acid amide and paraffin;
Oxidation inhibitor is Irganox 1076.
Embodiment 10
Present embodiment is with embodiment 6, and institute's difference is:
Magneticmetal pigment is the bar-shaped copper powder and the Z 250 of Racemic glycidol amine epoxy resin parcel, and the weight percent content that Z 250 accounts for copper powder is 55%, and copper powder size is 300 μ m;
Pearly pigment is that the bismuth oxide of alumina-coated applies pearly pigment, and particle diameter is 300 μ m;
Lubricant is an ethylene bis stearic acid amide.
Scope of the present invention does not receive the restriction of said specific embodiments, and said embodiment is only desired also to comprise the method and the component of functional equivalent in the scope of the invention as the single example of illustrating all respects of the present invention.In fact, except content as herein described, those skilled in the art can easily grasp multiple improvement of the present invention with reference to the description and the accompanying drawing of preceding text.Said improvement also falls within the scope of appended claims.
Claims (10)
- One kind improve outward appearance exempt from spray aesthstic resin, it is characterized in that this resin comprises following component and weight part:Matrix resin 70～90,Lubricant 0.1～2.0,Oxidation inhibitor 0.1～1.0,Magneticmetal pigment master batch 10～30;Wherein, said magneticmetal pigment master batch comprises following component and weight part:Matrix resin 100,Magneticmetal pigment 1.0～20,Pearly pigment 1.0～30,Lubricant 0.1～2.0,Oxidation inhibitor 0.1～1.0.
- 2. according to claim 1 improve outward appearance exempt to spray aesthstic resin; It is characterized in that described matrix resin is high gloss ABS, transparent ABS, ABS/PMMA alloy, PMMA, toughened polymethyl methacrylate (PMMA), transparent HIPS, GPPS, high light PP, PC/ABS alloy, PC, ASA, PBT, PET or PPO.
- 3. according to claim 1 improve outward appearance exempt from spray aesthstic resin, it is characterized in that described magneticmetal pigment comprises metal powder, magnetic and coating base material; Said metal powder is one or more in aluminium powder, silver powder, bronze, zinc powder, the copper powder, and it is shaped as sheet, silver dollar shape, bar-shaped or spherical, and its particle diameter is 1 μ m～300 μ m; Said magnetic is one or more in Z 250, chromium dioxide, the cobalt-red stone, and its weight percent content that accounts for metal powder is 20%～60%; Said coating base material is glycidyl ether based epoxy resin, glycidyl ester based epoxy resin, Racemic glycidol amine epoxy resin, line style aliphatic category epoxy resin or aliphatic category epoxy resin.
- 4. according to claim 3 improve outward appearance exempt from spray aesthstic resin, it is characterized in that described metal powder particle diameter is 10 μ m～100 μ m.
- 5. according to claim 1 improve outward appearance exempt to spray aesthstic resin; It is characterized in that described pearly pigment is that natural indestructible pearl delustering pigment, pearl white crystallization pearly pigment, the mica of particle diameter 20 μ m～500 μ m applies one or more in pearly pigment, silica-coated pearly pigment, aluminium silicate salt coating pearly pigment, aluminum borate salt coating pearly pigment, micanite coating pearly pigment, the bismuth oxide coating pearly pigment.
- 6. according to claim 1 improve outward appearance exempt to spray aesthstic resin; It is characterized in that described pearly pigment is that the mica of particle diameter 100 μ m～400 μ m applies pearly pigment, silica-coated pearly pigment, micanite coating pearly pigment, aluminum borate salt applies pearly pigment or aluminium silicate salt applies pearly pigment.
- According to claim 1,5 or 6 described improve outward appearance exempt to spray aesthstic resin; It is characterized in that; Described pearly pigment surface coats one deck MOX at least, and said MOX comprises aluminum oxide, tindioxide, titanium oxide, red stone, weisspiessglanz or zinc oxide.
- 8. according to claim 1 improve outward appearance exempt to spray aesthstic resin; It is characterized in that described lubricant is one or more in silicone oil, white mineral oil, fatty acid amide, barium stearate, Magnesium Stearate, paraffin, polyethylene wax, ethylene bis stearic acid amide, Injecatable EVA Copolymer, the ethylene-acrylic acid copolymer.
- 9. according to claim 1 improve outward appearance exempt from spray aesthstic resin, it is characterized in that described oxidation inhibitor comprises refine one or more of Irganox 1010, Irganox 1076, Irganox B900, Irganox 168 of company of CIBA.
- 10. one kind prepares the said method of exempting to spray aesthstic resin of improving outward appearance of claim 1, it is characterized in that this method may further comprise the steps:A, get the raw materials ready according to following component and weight part:Matrix resin 100;Magneticmetal pigment 1.0～20;Pearly pigment 1.0～30;Lubricant 0.1～2.0;Oxidation inhibitor 0.1～1.0;B, the raw material among the above-mentioned steps a placed in the high-speed mixer by prescription stir; Mix after WT-MSR is sent in the twin screw extruder; The temperature of control twin screw extruder is 180～230 ℃, in conveying, the shearing and mixing following of screw rod, with material melting, compound; Then through extrude, tie rod, cooling, pelletizing step, promptly obtain containing the master batch of magneticmetal pigment;C, get the raw materials ready according to following component and weight part:Matrix resin 70～90;Lubricant 0.1～2.0;Oxidation inhibitor 0.1～1.0;Magneticmetal pigment master batch 10～30;D, the raw material among the above-mentioned steps c placed in the high-speed mixer by prescription stir; Mix after WT-MSR is sent in the twin screw extruder; The temperature of control twin screw extruder is 180～230 ℃, in conveying, the shearing and mixing following of screw rod, with material melting, compound; Then through extrude, tie rod, cooling, pelletizing step, promptly obtain a kind of improve outward appearance exempt to spray aesthstic resin.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110407696 CN102516700B (en) | 2011-12-09 | 2011-12-09 | Appearance-improving spraying-free aesthetic resin and its preparation method |
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| Application Number | Priority Date | Filing Date | Title |
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| CN 201110407696 CN102516700B (en) | 2011-12-09 | 2011-12-09 | Appearance-improving spraying-free aesthetic resin and its preparation method |
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| Publication Number | Publication Date |
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| CN102516700A true CN102516700A (en) | 2012-06-27 |
| CN102516700B CN102516700B (en) | 2013-06-12 |
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Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1053075A (en) * | 1990-01-02 | 1991-07-17 | 陶氏化学公司 | Have the three peak distribution ABS compositions that good gloss and gloss susceptibility reduce |
-
2011
- 2011-12-09 CN CN 201110407696 patent/CN102516700B/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1053075A (en) * | 1990-01-02 | 1991-07-17 | 陶氏化学公司 | Have the three peak distribution ABS compositions that good gloss and gloss susceptibility reduce |
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