CN104629165B - Exempt from spraying thermoplastic resin composition and its preparation method and application with special decorative effects - Google Patents
Exempt from spraying thermoplastic resin composition and its preparation method and application with special decorative effects Download PDFInfo
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- CN104629165B CN104629165B CN201310544161.2A CN201310544161A CN104629165B CN 104629165 B CN104629165 B CN 104629165B CN 201310544161 A CN201310544161 A CN 201310544161A CN 104629165 B CN104629165 B CN 104629165B
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- thermoplastic resin
- powder
- resin composition
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- 229920005992 thermoplastic resin Polymers 0.000 title claims abstract description 45
- 230000000694 effects Effects 0.000 title claims abstract description 39
- 239000011342 resin composition Substances 0.000 title claims abstract description 33
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- 238000005507 spraying Methods 0.000 title claims abstract description 10
- 239000000843 powder Substances 0.000 claims abstract description 84
- 229920000642 polymer Polymers 0.000 claims abstract description 21
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 17
- 239000004815 dispersion polymer Substances 0.000 claims abstract description 17
- 239000000463 material Substances 0.000 claims abstract description 16
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 14
- 239000006057 Non-nutritive feed additive Substances 0.000 claims abstract description 8
- UYTPUPDQBNUYGX-UHFFFAOYSA-N guanine Chemical compound O=C1NC(N)=NC2=C1N=CN2 UYTPUPDQBNUYGX-UHFFFAOYSA-N 0.000 claims description 31
- 239000007921 spray Substances 0.000 claims description 26
- 239000000839 emulsion Substances 0.000 claims description 25
- 239000003795 chemical substances by application Substances 0.000 claims description 20
- 239000002245 particle Substances 0.000 claims description 20
- 229910052782 aluminium Inorganic materials 0.000 claims description 19
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 17
- 239000007788 liquid Substances 0.000 claims description 17
- 239000006185 dispersion Substances 0.000 claims description 16
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical class O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 15
- 229910052751 metal Inorganic materials 0.000 claims description 15
- 239000002184 metal Substances 0.000 claims description 15
- 229920005989 resin Polymers 0.000 claims description 15
- 239000011347 resin Substances 0.000 claims description 15
- 239000011248 coating agent Substances 0.000 claims description 14
- 238000000576 coating method Methods 0.000 claims description 14
- 239000004411 aluminium Substances 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 12
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 11
- 239000000314 lubricant Substances 0.000 claims description 11
- 239000007787 solid Substances 0.000 claims description 11
- 229910052718 tin Inorganic materials 0.000 claims description 11
- 239000011135 tin Substances 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 9
- 229910052725 zinc Inorganic materials 0.000 claims description 9
- 239000011701 zinc Substances 0.000 claims description 9
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 8
- 239000010949 copper Substances 0.000 claims description 8
- 230000007797 corrosion Effects 0.000 claims description 8
- 238000005260 corrosion Methods 0.000 claims description 8
- 239000002002 slurry Substances 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 8
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 7
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 claims description 7
- 239000007864 aqueous solution Substances 0.000 claims description 7
- -1 phenylpropyl alcohol triazole Chemical class 0.000 claims description 7
- 238000001694 spray drying Methods 0.000 claims description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 6
- 239000002131 composite material Substances 0.000 claims description 6
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 claims description 6
- 229920000768 polyamine Polymers 0.000 claims description 6
- 229910052710 silicon Inorganic materials 0.000 claims description 6
- 229910044991 metal oxide Inorganic materials 0.000 claims description 5
- 150000004706 metal oxides Chemical class 0.000 claims description 5
- 239000010445 mica Substances 0.000 claims description 5
- 229910052618 mica group Inorganic materials 0.000 claims description 5
- IMQLKJBTEOYOSI-GPIVLXJGSA-N Inositol-hexakisphosphate Chemical compound OP(O)(=O)O[C@H]1[C@H](OP(O)(O)=O)[C@@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@@H]1OP(O)(O)=O IMQLKJBTEOYOSI-GPIVLXJGSA-N 0.000 claims description 4
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 4
- 229910052790 beryllium Inorganic materials 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 4
- 229920001577 copolymer Polymers 0.000 claims description 4
- 229910052802 copper Inorganic materials 0.000 claims description 4
- 239000012467 final product Substances 0.000 claims description 4
- 229910052742 iron Inorganic materials 0.000 claims description 4
- 229910052745 lead Inorganic materials 0.000 claims description 4
- 239000011133 lead Substances 0.000 claims description 4
- 229910052748 manganese Inorganic materials 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- 239000003607 modifier Substances 0.000 claims description 4
- 229910052759 nickel Inorganic materials 0.000 claims description 4
- 238000004806 packaging method and process Methods 0.000 claims description 4
- 238000005453 pelletization Methods 0.000 claims description 4
- 235000002949 phytic acid Nutrition 0.000 claims description 4
- 239000004584 polyacrylic acid Substances 0.000 claims description 4
- 229920001296 polysiloxane Polymers 0.000 claims description 4
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 4
- 229910052709 silver Inorganic materials 0.000 claims description 4
- 239000004332 silver Substances 0.000 claims description 4
- 239000010936 titanium Substances 0.000 claims description 4
- 239000011787 zinc oxide Substances 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 3
- 239000004593 Epoxy Substances 0.000 claims description 3
- 239000004793 Polystyrene Substances 0.000 claims description 3
- 229920002125 Sokalan® Polymers 0.000 claims description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 3
- 238000013019 agitation Methods 0.000 claims description 3
- 150000001412 amines Chemical class 0.000 claims description 3
- 229920003180 amino resin Polymers 0.000 claims description 3
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- 125000005375 organosiloxane group Chemical group 0.000 claims description 3
- WQGWDDDVZFFDIG-UHFFFAOYSA-N pyrogallol Chemical compound OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 claims description 3
- 229920001909 styrene-acrylic polymer Polymers 0.000 claims description 3
- 229910052719 titanium Inorganic materials 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- PYSRRFNXTXNWCD-UHFFFAOYSA-N 3-(2-phenylethenyl)furan-2,5-dione Chemical compound O=C1OC(=O)C(C=CC=2C=CC=CC=2)=C1 PYSRRFNXTXNWCD-UHFFFAOYSA-N 0.000 claims description 2
- 239000005725 8-Hydroxyquinoline Substances 0.000 claims description 2
- NOWKCMXCCJGMRR-UHFFFAOYSA-N Aziridine Chemical compound C1CN1 NOWKCMXCCJGMRR-UHFFFAOYSA-N 0.000 claims description 2
- 229910000906 Bronze Inorganic materials 0.000 claims description 2
- 241000555268 Dendroides Species 0.000 claims description 2
- 229920002943 EPDM rubber Polymers 0.000 claims description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 2
- 241000533950 Leucojum Species 0.000 claims description 2
- 229920000877 Melamine resin Polymers 0.000 claims description 2
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 claims description 2
- 239000004677 Nylon Substances 0.000 claims description 2
- DYUQAZSOFZSPHD-UHFFFAOYSA-N Phenylpropyl alcohol Natural products CCC(O)C1=CC=CC=C1 DYUQAZSOFZSPHD-UHFFFAOYSA-N 0.000 claims description 2
- IMQLKJBTEOYOSI-UHFFFAOYSA-N Phytic acid Natural products OP(O)(=O)OC1C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C1OP(O)(O)=O IMQLKJBTEOYOSI-UHFFFAOYSA-N 0.000 claims description 2
- 239000004952 Polyamide Substances 0.000 claims description 2
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 2
- 229920000147 Styrene maleic anhydride Polymers 0.000 claims description 2
- 239000002174 Styrene-butadiene Substances 0.000 claims description 2
- 239000004433 Thermoplastic polyurethane Substances 0.000 claims description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 2
- 229920002877 acrylic styrene acrylonitrile Polymers 0.000 claims description 2
- 125000002723 alicyclic group Chemical group 0.000 claims description 2
- 125000001931 aliphatic group Chemical group 0.000 claims description 2
- 239000000956 alloy Substances 0.000 claims description 2
- 229910045601 alloy Inorganic materials 0.000 claims description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 2
- 229910000329 aluminium sulfate Inorganic materials 0.000 claims description 2
- 150000001408 amides Chemical class 0.000 claims description 2
- 229910000410 antimony oxide Inorganic materials 0.000 claims description 2
- 150000004982 aromatic amines Chemical class 0.000 claims description 2
- 125000003118 aryl group Chemical group 0.000 claims description 2
- 239000002956 ash Substances 0.000 claims description 2
- 229910000416 bismuth oxide Inorganic materials 0.000 claims description 2
- 239000004327 boric acid Substances 0.000 claims description 2
- 229910052796 boron Inorganic materials 0.000 claims description 2
- 239000010974 bronze Substances 0.000 claims description 2
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims description 2
- KVNRLNFWIYMESJ-UHFFFAOYSA-N butyronitrile Chemical compound CCCC#N KVNRLNFWIYMESJ-UHFFFAOYSA-N 0.000 claims description 2
- 239000001913 cellulose Substances 0.000 claims description 2
- 229920002678 cellulose Polymers 0.000 claims description 2
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 claims description 2
- 238000002425 crystallisation Methods 0.000 claims description 2
- 230000008025 crystallization Effects 0.000 claims description 2
- TYIXMATWDRGMPF-UHFFFAOYSA-N dibismuth;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Bi+3].[Bi+3] TYIXMATWDRGMPF-UHFFFAOYSA-N 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims description 2
- 239000003822 epoxy resin Substances 0.000 claims description 2
- 239000011737 fluorine Substances 0.000 claims description 2
- 229910052731 fluorine Inorganic materials 0.000 claims description 2
- 239000011521 glass Substances 0.000 claims description 2
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 claims description 2
- 229920000126 latex Polymers 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- 239000011777 magnesium Substances 0.000 claims description 2
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 2
- 229920001778 nylon Polymers 0.000 claims description 2
- 150000002903 organophosphorus compounds Chemical class 0.000 claims description 2
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 claims description 2
- 229960003540 oxyquinoline Drugs 0.000 claims description 2
- 150000002989 phenols Chemical class 0.000 claims description 2
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims description 2
- 229910052698 phosphorus Inorganic materials 0.000 claims description 2
- 229940068041 phytic acid Drugs 0.000 claims description 2
- 239000000467 phytic acid Substances 0.000 claims description 2
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 2
- 229920002647 polyamide Polymers 0.000 claims description 2
- 229920000647 polyepoxide Polymers 0.000 claims description 2
- 229920000728 polyester Polymers 0.000 claims description 2
- 229920001225 polyester resin Polymers 0.000 claims description 2
- 239000004645 polyester resin Substances 0.000 claims description 2
- 239000004926 polymethyl methacrylate Substances 0.000 claims description 2
- 229920006380 polyphenylene oxide Polymers 0.000 claims description 2
- 229920002689 polyvinyl acetate Polymers 0.000 claims description 2
- 239000011118 polyvinyl acetate Substances 0.000 claims description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 2
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 2
- MCJGNVYPOGVAJF-UHFFFAOYSA-N quinolin-8-ol Chemical compound C1=CN=C2C(O)=CC=CC2=C1 MCJGNVYPOGVAJF-UHFFFAOYSA-N 0.000 claims description 2
- 239000002994 raw material Substances 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- 239000010703 silicon Substances 0.000 claims description 2
- 239000011115 styrene butadiene Substances 0.000 claims description 2
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 2
- 229920001935 styrene-ethylene-butadiene-styrene Polymers 0.000 claims description 2
- 239000011593 sulfur Substances 0.000 claims description 2
- 229910052717 sulfur Inorganic materials 0.000 claims description 2
- 239000004408 titanium dioxide Substances 0.000 claims description 2
- 150000003751 zinc Chemical class 0.000 claims description 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N 1,4a-dimethyl-7-propan-2-yl-2,3,4,4b,5,6,10,10a-octahydrophenanthrene-1-carboxylic acid Chemical class C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims 1
- 239000005864 Sulphur Substances 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 229920000180 alkyd Polymers 0.000 claims 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 1
- 238000009833 condensation Methods 0.000 claims 1
- 230000005494 condensation Effects 0.000 claims 1
- 229910052738 indium Inorganic materials 0.000 claims 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical group O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- 229920002223 polystyrene Polymers 0.000 claims 1
- 229920003987 resole Polymers 0.000 claims 1
- 150000004760 silicates Chemical class 0.000 claims 1
- 239000002344 surface layer Substances 0.000 claims 1
- 238000001125 extrusion Methods 0.000 abstract description 3
- 238000001746 injection moulding Methods 0.000 abstract description 2
- 230000000052 comparative effect Effects 0.000 description 11
- 239000011159 matrix material Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 238000000498 ball milling Methods 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 229920000058 polyacrylate Polymers 0.000 description 2
- 239000005056 polyisocyanate Substances 0.000 description 2
- 229920001228 polyisocyanate Polymers 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 244000043261 Hevea brasiliensis Species 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- PZZYQPZGQPZBDN-UHFFFAOYSA-N aluminium silicate Chemical class O=[Al]O[Si](=O)O[Al]=O PZZYQPZGQPZBDN-UHFFFAOYSA-N 0.000 description 1
- 125000004069 aziridinyl group Chemical group 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- XLJMAIOERFSOGZ-UHFFFAOYSA-M cyanate Chemical compound [O-]C#N XLJMAIOERFSOGZ-UHFFFAOYSA-M 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- IXSZQYVWNJNRAL-UHFFFAOYSA-N etoxazole Chemical compound CCOC1=CC(C(C)(C)C)=CC=C1C1N=C(C=2C(=CC=CC=2F)F)OC1 IXSZQYVWNJNRAL-UHFFFAOYSA-N 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 description 1
- FATBGEAMYMYZAF-UHFFFAOYSA-N oleicacidamide-heptaglycolether Natural products CCCCCCCCC=CCCCCCCCC(N)=O FATBGEAMYMYZAF-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
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- 229920006389 polyphenyl polymer Polymers 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000007592 spray painting technique Methods 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 239000003021 water soluble solvent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/10—Encapsulated ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/06—Pretreated ingredients and ingredients covered by the main groups C08K3/00 - C08K7/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0812—Aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/085—Copper
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
Exempt from spraying thermoplastic resin composition and its preparation method and application, including following component with special decorative effects the invention discloses a kind of：The 98wt% of thermoplastic resin 70；The 25wt% of polymer overmold special-effect powder microballoon 1；The 10wt% of compatilizer 0；The 1wt% of antioxidant 0.1；The 0.5wt% of processing aid 0.1；The present invention is by redisperse after special-effect powder aqueous polymer dispersion is overmolding into microballoon to thermoplastic resin, the compatibility of special-effect powder and thermoplastic resin can be obviously improved, eliminate the product current mark that surface is formed in extrusion or injection moulding process and mitigate weld bond, the spraying thermoplastic resin composition that exempts from for preparing has the special aesthetic effects such as obvious metal-like, pearly-lustre flicker, substantially increases the market range of application for exempting from sprayed on material.
Description
Technical field
The invention belongs to polymeric material field, and in particular to a kind of exempting from special decorative effects sprays thermoplastic resin
Oil/fat composition and its preparation method and application.
Background technology
Environmental problem is increasingly paid attention to and paid close attention to people, is exempted from spraying special-effect material product and is just progressively shown
Its competitiveness, exempting from spraying aesthetic resin can replicate gorgeous colorful tone and pearly-lustre, flash effect, metal that spray painting is produced
The special-effect such as gloss and texture, so that meet diversified, differential customer demand, and in process of production can be real
Energy-saving and emission-reduction are realized, handicraft, toy, household electrical appliances, automobile, electronic product, sports goods and office appliance etc. is can be widely applied to
Field.
At present, it is that the tool such as metal powder, pearl essence is added in resin material to exempt from the spraying more common preparation method of resin
There is the effect powder of particular color and gloss.It is distributed in matrix resin by by special-effect powder, between special-effect powder mutually
Connection, forms the film of continuous special-effect, has covered base material, shows special-effect texture, although by by special-effect
Powder is directly added into resin binder, it is possible to achieve the effect of special gloss, but the compatibility of matrix resin and special-effect powder
Difference, under the conditions of the strong pressure and Strong shear extruded or be molded, special-effect powder is extremely difficult to mobility with base resin material
Unanimously, particularly baroque product, along flow direction be orientated special-effect powder occur and occur melt flows turn to,
Flow velocity is unstable, the phenomenon such as melt converges, and causes special-effect powder skewness in the melt, is easily formed in product surface
The defect such as current mark and weld bond, seriously prevents and limits such marketing and application for exempting from sprayed on material.
The content of the invention
In order to overcome the shortcoming and deficiency of prior art, primary and foremost purpose of the invention is to provide one kind to be melted without current mark, gently
The exempting from special decorative effects of wiring sprays thermoplastic resin composition.
Thermoplastic resin composition is sprayed it is still another object of the present invention to provide above-mentioned exempting from special decorative effects
Preparation method.
The present invention is achieved by the following technical solutions：
Exempting from special decorative effects sprays thermoplastic resin composition, by weight percentage, including following component：
Thermoplastic resin 70-98wt%
Polymer overmold special-effect powder microballoon 1-25wt%
Compatilizer 0-10wt%
Antioxidant 0.1-1wt%
Processing aid 0.1-0.5wt%；
Wherein, described polymer overmold special-effect powder microballoon, by weight percentage, including following component：
Aqueous polymer dispersion 18-90wt%
Antioxygen corrosion inhibiter 0-5wt%
Special-effect powder, or aqueous special-effect slurry material 5-80wt%
Curing agent 0.2-10wt%.
The thermoplastic resin include PP, PE, ABS, PMMA, PC, ASA, PVC, polyester, nylon, PPO, PS, TPU, POM,
The alloy of one or more in acrylate and its modifier.
The compatilizer includes PE grafted maleic anhydrides, PP grafted maleic anhydrides, EVA grafted maleic anhydrides, ethylene-propylene
Copolymer and its graft, ethylene propylene diene rubber and its graft, POE grafted maleic anhydrides, ABS grafted maleic anhydrides, polyphenyl
The sulfonate of ethene, SBS grafted maleic anhydrides, SEBS grafted maleic anhydrides, styrene-maleic anhydride copolymer or acrylate
One or more in copolymer.
The antioxidant is to include Hinered phenols antioxidant, phosphite kind antioxidant, amine antioxidants, sulfur-bearing class antioxygen
One or more in agent or metallic salt antioxidant.
The processing aid is silicone series lubricant agent, acid amides series lubricant agent, stearic acid lubricant, TPO lubricant
Or one or more in ester lubricant.
The aqueous polymer dispersion includes polyaminoester emulsion, organic silicon emulsion, organic fluorine emulsion, water-base epoxy tree
Fat, polyacrylate dispersion, styrene-acrylic emulsion, silicone acrylic emulsion, ABS resin emulsion, the modified cellulose aqueous solution, polyvinyl alcohol and its
The condensation product aqueous solution, the polyacrylic acid aqueous solution, aqueous Lauxite, aqueous melamine and its etherified resin, aqueous phenolic aldehyde tree
Fat, aqueous alkide resin, aqueous polyester resin, polyvinyl acetate emulsion, ethene improved-vinyl acetate emulsion, natural rubber
The mixing of one or more in latex solution, styrene-butadiene emulsion, butyronitrile emulsion, vinyl acetate emulsion and its compound or modifier；Institute
The solid content for stating aqueous polymer dispersion is 10-60wt%.
The antioxygen corrosion inhibiter be selected from phenylpropyl alcohol triazole, phytic acid, phytate, 8-hydroxyquinoline, organic phosphorus compound, phosphoric acid and
The mixing of one or more in its derivative or pyrogallic acid.
Described special-effect powder includes one or more in metal powder or pearl essence.
The metal powder is selected from one or more in aluminium powder, copper powder, bronze, silver powder, zinc powder, glass putty, iron powder, nickel powder；
The aqueous special-effect slurry material is addition water and water-soluble solvent, such as isopropanol, second in special-effect powder
Alcohol etc. and other auxiliary agents, its solid content are 10-80wt%, preferably 20-70wt%.
In the aluminium powder content of Al elements be no less than 60wt%, simultaneously containing Zn, Sn, Ni, Pb, Fe, Mg, Si, Mn, Be,
One or more of Cu, Ti or rare earth element；Being shaped as the aluminium powder is spherical, petal, dendriform, snowflake shape, cornflakes
Shape, silver dollar shape or half silver dollar shape one or more；Its particle diameter is 3-200 μm, preferably 5-100 μm.
It is oxidizable in order to avoid aluminium powder explosive in process, the defect such as bad ball milling dispersion, used by the present invention
Aluminium powder is to add surface conditioning agent such as lubricant etc. by being surface-treated, then ball milling into flake aluminum.
In the copper powder content of Cu elements be no less than 60wt%, simultaneously containing Zn, Sn, Ni, Be, Al, Mn, Fe, Pb, Si,
One or more of P, B, Ti or rare earth element；Being shaped as the copper powder is spherical, dendroid or sheet, and its particle diameter is 3-200 μ
M, preferably 5-100 μm.
Its cross section of the pearl essence has the physical arrangement similar to pearl, and kernel is the material of low optical refractive index,
Be coated on outer layer is the metal oxide of high index of refraction, and its species specifically includes mica coating pearl essence, bismoclite crystallization
Pearl essence, silica-coating pearl essence, aluminium silicate salt coating pearl essence, boric acid aluminium salt coating pearl essence, bismuth oxide coating pearl
One or more in light powder；The pearl essence surface at least coats layer of metal oxide, and the metal oxide is oxidation
One or more of aluminium, tin ash, titanium dioxide, iron oxide, antimony oxide or zinc oxide；The particle diameter of the pearl essence is 5-
500 μm, preferably 5-200 μm.
Present invention addition pearl essence can make the metal-like of frosting more obvious, because pearl essence has spy
Different physical arrangement, when being irradiated by light, can embody pearl effect so that material surface by multipath reflection and interference
Reflected light closer to metal-like.
The curing agent includes aliphatic polyamine, aromatic polyamine, alicyclic polyamine, imidazole and its derivants, mercaptan, has
Machine acid anhydrides, aziridine and its derivative, zinc oxide, zinc salt, dicyandiamide, liquid polyamide, aromatic amine, amino resins, polyisocyanate
In cyanate and its oligomer, polycarbodiimide, organosiloxane, the complex compound of boracic or the curing agent containing epoxy radicals one
Plant or various.
Polymer overmold special-effect powder microballoon of the present invention can also according to actual needs add other auxiliary agents, such as
Defoamer, dispersant, anti-settling agent etc., its consumption are conventional amount used.
The particle diameter of the polymer overmold special-effect powder microballoon is 10-1000 μm, preferably 10-300 μm；Wherein special effect
The weight percent content that fruit powder accounts for microballoon is 5-80wt%, preferably 5-50wt%.
The preparation method of polymer overmold special-effect powder microballoon of the present invention, specifically includes following steps：
a）First, antioxygen corrosion inhibiter, dispersed with stirring 10-30min is added to obtain in aqueous polymer dispersion under normal temperature
Dispersion liquid；Under agitation, to special-effect powder, or aqueous special-effect slurry material is slowly added in dispersion liquid, then
Curing agent is added while stirring, and continues to stir 30-120min, make special-effect powder fully dispersed and coated by dispersion liquid, most
The composite dispersion liquid of polymer overmold special-effect powder is obtained afterwards；
b）By composite dispersion liquid dried process, polymer overmold special-effect powder microballoon is obtained.
Preferably, wherein step（b）Described in drying for spray drying, the intake air temperature of the spray-drying process
It it is 150-300 DEG C, preferably 170-250 DEG C, air outlet temperature is 50-130 DEG C, preferably 70-100 DEG C.
Exempting from special decorative effects of the present invention sprays the preparation method of thermoplastic resin composition, including such as
Lower step：Each raw material is inserted into high-speed mixer according to the above ratio to be well mixed；The mixture that will be obtained inserts twin-screw extrusion
Kneaded in machine, pelletizing, packaging, obtain final product after cooling.
Exempting from special decorative effects of the present invention sprays thermoplastic resin composition can be in electronic apparatus, physical culture
It is used widely in articles for use, office appliance, traffic and transport field.
The present invention compared with prior art, has the advantages that：
The present invention after special-effect powder aqueous polymer dispersion is overmolding into microballoon redisperse to thermoplastic resin
In fat, the compatibility of special-effect powder and thermoplastic resin can be obviously improved, improve special-effect powder endurance of cutting and
Its in extrusion or injection moulding process with the flowing uniformity of melt so that eliminate the current mark of product surface, mitigate weld bond, prepare
The spraying thermoplastic resin composition that exempts from for obtaining has obvious metal-like or special aesthetic effect, substantially increases and exempts from
The market range of application of sprayed on material.
Specific embodiment
The present invention is further illustrated below by specific embodiment, following examples are the present invention preferably embodiment party
Formula, but embodiments of the present invention are not limited by following embodiments.
The preparation of embodiment 1-6 polymer overmold special-effect powder microballoons：
By the formula in table 1, first, antioxygen corrosion inhibiter, dispersed with stirring are added under normal temperature in aqueous polymer dispersion
15min, obtains dispersion liquid；Under agitation, to being slowly added to special-effect powder, or aqueous special-effect powder in dispersion liquid
Slurry, then adds curing agent while stirring, and continues to stir 30-120min, makes special-effect powder fully dispersed and is disperseed
Liquid is coated, and the composite dispersion liquid of polymer overmold special-effect powder is finally obtained；By composite dispersion liquid spray drying treatment, obtain
Polymer overmold special-effect powder microballoon, the intake air temperature of spray-drying process is 150-300 DEG C, and air outlet temperature is 50-
130℃。
The specific proportioning of each composition of 1 embodiment of table 1 ~ 6（wt%）
In embodiment 1：Aqueous polymer dispersion is polyaminoester emulsion, and its solid content is 10wt%；Metal powder is through surface
The flake aluminum for the treatment of, the content of Al elements is 60wt% in aluminium powder, and Zn and Sn is contained simultaneously；Its particle diameter is 100 μm；Antioxygen delays
Erosion agent is to be changed to pyrogallic acid；Curing agent is polyisocyanates.
In embodiment 2：Aqueous polymer dispersion is polyacrylate dispersion, and its solid content is 30wt%；Metal powder be through
The flake copper of surface treatment, the content of Cu elements is 70wt% in copper powder, and Zn and Sn is contained simultaneously；Its particle diameter is 5 μm；Antioxygen
Corrosion inhibiter is BTA；Curing agent is polycarbodiimide.
In embodiment 3：Aqueous polymer dispersion is the polyacrylic acid aqueous solution, and its solid content is 40wt%；Special-effect powder
It is silica-coating pearl essence, its particle diameter is 20 μm；Curing agent is amino resins.
In embodiment 4：Aqueous polymer dispersion is ethene improved-vinyl acetate emulsion, and its solid content is 50wt%；
Special-effect powder is that mica coats pearl essence, and its particle diameter is 200 μm；Curing agent is aziridine.
In embodiment 5：Aqueous polymer dispersion is aqueous epoxy resins, and its solid content is 60wt%；Special-effect powder is
The mixture of zinc powder and silica-coating pearl essence；Curing agent is dicyandiamide.
In embodiment 6：Aqueous polymer dispersion is styrene-acrylic emulsion, and its solid content is 20wt%；Special-effect powder is silver powder
With the mixture that mica coats pearl essence；Curing agent is organosiloxane.
Embodiment 7-13 has the preparation for exempting from spraying thermoplastic resin composition of special decorative effects：
By the formula in table 2 by thermoplastic resin, polymer overmold special-effect powder microballoon, compatilizer, antioxidant,
Processing aid is inserted high-speed mixer and is well mixed；The mixture that will be obtained is inserted in double screw extruder and kneaded,
Pelletizing, packaging, obtain final product after cooling.Acquired results are shown in Table 2：
Compatilizer is ABS grafted maleic anhydrides
Antioxidant is amine antioxidants 445,
Processing aid is oleamide.
Comparative example 1-6：Tradition is exempted to spray the preparation of thermoplastic resin composition：
By the formula in table 2 by thermoplastic resin, metal powder/special-effect powder, compatilizer, antioxidant, processing aid
High-speed mixer is inserted to be well mixed；The mixture that will be obtained is inserted in double screw extruder and kneaded, pelletizing, packaging after cooling,
Obtain final product.Acquired results are shown in Table 2：
In comparative example 1：Metal powder is surface treated flake aluminum, and the content of Al elements is 60wt% in aluminium powder, while
Contain Zn and Sn；Its particle diameter is 100 μm.
In comparative example 2：Metal powder is surface treated flake aluminum, and the content of Al elements is 60wt% in aluminium powder, while
Contain Zn and Sn；Its particle diameter is 100 μm.
In comparative example 3：Metal powder is surface treated flake copper, and the content of Cu elements is 70wt% in copper powder, while
Contain Zn and Sn；Its particle diameter is 5 μm.
In comparative example 4：Special-effect powder is silica-coating pearl essence, and its particle diameter is 20 μm.
In comparative example 5：Special-effect powder is that mica coats pearl essence.
In comparative example 6：Special-effect powder is the mixture that special-effect powder is zinc powder and silica-coating pearl essence.
The specific proportioning of each composition in the embodiment 7-13 of table 2 and comparative example 1-6（wt%）And its test performance knot
Note：+ more expression current marks are more
More than zero represents that weld bond is more serious
- represent do not exist current mark or weld bond, or it is unobvious
Be can be seen that in the case where ensureing that other components and content are essentially identical by the Comparative result in upper table 2, implemented
Example 7-13 is mixed using polymer overmold special-effect powder microballoon with matrix resin, in comparative example 1-6 that special-effect powder is direct
It is added in matrix resin, comparing embodiment 7-12 and comparative example 1-6, finds micro- with polymer-coated metal powder and pearl essence
Ball mix with matrix resin obtained by product surface substantially without current mark, weld bond is lighter, and with more preferable aesthetic effect.
Claims (21)
1. exempting from special decorative effects sprays thermoplastic resin composition, by weight percentage, including following component：
Thermoplastic resin 70-98wt%
Polymer overmold special-effect powder microballoon 1-25wt%
Compatilizer 0-10wt%
Antioxidant 0.1-1wt%
Processing aid 0.1-0.5wt%；
Wherein, described polymer overmold special-effect powder microballoon, by weight percentage, including following component：
Aqueous polymer dispersion 18-90wt%
Antioxygen corrosion inhibiter 0-5wt%
Special-effect powder, or aqueous special-effect slurry material 5-80wt%
Curing agent 0.2-10wt%
The antioxygen corrosion inhibiter is selected from phenylpropyl alcohol triazole, phytic acid, phytate, 8-hydroxyquinoline, organic phosphorus compound, phosphoric acid and its spreads out
The mixing of one or more in biological, pyrogallic acid;
The aqueous polymer dispersion includes polyaminoester emulsion, organic silicon emulsion, organic fluorine emulsion, aqueous epoxy resins, poly-
Acrylic acid ester emulsion, styrene-acrylic emulsion, silicone acrylic emulsion, ABS resin emulsion, the modified cellulose aqueous solution, polyvinyl alcohol and its condensation
The thing aqueous solution, the polyacrylic acid aqueous solution, aqueous Lauxite, aqueous melamine and its etherified resin, resol resins, water
Property alkyd resin, aqueous polyester resin, polyvinyl acetate emulsion, nature rubber latex, styrene-butadiene emulsion, butyronitrile emulsion, second third
The mixing of one or more in emulsion and its compound and modifier.
2. exempting from special decorative effects according to claim 1 sprays thermoplastic resin composition, it is characterised in that
The thermoplastic resin is selected from PP, PE, ABS, PMMA, PC, ASA, PVC, polyester, nylon, PPO, PS, TPU, POM, acrylate
The alloy of one or more in resin and its modifier.
3. exempting from special decorative effects according to claim 1 sprays thermoplastic resin composition, it is characterised in that
The compatilizer include PE grafted maleic anhydrides, PP grafted maleic anhydrides, EVA grafted maleic anhydrides, ethylene-propylene copolymer and
Its graft, ethylene propylene diene rubber and its graft, POE grafted maleic anhydrides, ABS grafted maleic anhydrides, the sulphur of polystyrene
In hydrochlorate, SBS grafted maleic anhydrides, SEBS grafted maleic anhydrides, styrene-maleic anhydride copolymer or acrylate copolymer
One or more；The antioxidant is Hinered phenols antioxidant, phosphite kind antioxidant, amine antioxidants, sulfur-bearing class resist
One or more in oxygen agent or metallic salt antioxidant；The processing aid is silicone series lubricant agent, acid amides series lubricant agent, hard
One or more in resin acid series lubricant agent, TPO lubricant or ester lubricant.
4. exempting from special decorative effects according to claim 1 sprays thermoplastic resin composition, it is characterised in that
The solid content of the aqueous polymer dispersion is 10-60wt%.
5. exempting from special decorative effects according to claim 1 sprays thermoplastic resin composition, it is characterised in that
The special-effect powder includes one or more in metal powder or pearl essence.
6. exempting from special decorative effects according to claim 5 sprays thermoplastic resin composition, it is characterised in that
The metal powder is selected from one or more in aluminium powder, copper powder, bronze, silver powder, zinc powder, glass putty, iron powder, nickel powder；It is described aqueous
The solid content of metal powder slurry is 10-80wt%.
7. exempting from special decorative effects according to claim 6 sprays thermoplastic resin composition, it is characterised in that
The solid content of the water-based metal slurry material is 20-70wt%.
8. exempting from special decorative effects according to claim 6 sprays thermoplastic resin composition, it is characterised in that
The content of Al elements is no less than 60wt% in the aluminium powder, simultaneously containing Zn, Sn, Ni, Pb, Fe, Mg, Si, Mn, Be, Cu, Ti or
One or more of rare earth element；Being shaped as the aluminium powder is spherical, petal, dendriform, snowflake shape, cornflakes shape, silver dollar
Shape or half silver dollar shape one or more；Its particle diameter is 3-200 μm.
9. exempting from special decorative effects according to claim 8 sprays thermoplastic resin composition, it is characterised in that
The particle diameter of the aluminium powder is 5-100 μm.
10. exempting from special decorative effects according to claim 6 sprays thermoplastic resin composition, and its feature exists
In, in the copper powder content of Cu elements be no less than 60wt%, simultaneously containing Zn, Sn, Ni, Be, Al, Mn, Fe, Pb, Si, P, B,
One or more of Ti or rare earth element；Being shaped as the copper powder is spherical, dendroid or sheet, and its particle diameter is 3-200 μm.
11. exempting from special decorative effects according to claim 10 spray thermoplastic resin composition, and its feature exists
In the particle diameter of the copper powder is 5-100 μm.
12. exempting from special decorative effects according to claim 5 spray thermoplastic resin composition, and its feature exists
In the pearl essence includes mica coating pearl essence, bismoclite crystallization pearl essence, silica-coating pearl essence, alumina silicate
Salt coating pearl essence, boric acid aluminium salt coating pearl essence, bismuth oxide coating pearl essence in one or more；The pearl essence surface
Layer of metal oxide is at least coated, the metal oxide is aluminum oxide, tin ash, titanium dioxide, iron oxide, antimony oxide
Or one or more of zinc oxide；The particle diameter of the pearl essence is 5-500 μm.
13. exempting from special decorative effects according to claim 12 spray thermoplastic resin composition, and its feature exists
In the particle diameter of the pearl essence is 5-200 μm.
14. exempting from special decorative effects according to claim 1 spray thermoplastic resin composition, and its feature exists
In the curing agent includes aliphatic polyamine, aromatic polyamine, alicyclic polyamine, imidazole and its derivants, mercaptan, organic acid
Acid anhydride, aziridine and its derivative, zinc oxide, zinc salt, dicyandiamide, liquid polyamide, aromatic amine, amino resins, polyisocyanic acid
One kind in ester and its oligomer, polycarbodiimide, organosiloxane, the complex compound of boracic or the curing agent containing epoxy radicals or
It is various.
15. exempting from special decorative effects according to claim 1 spray thermoplastic resin composition, and its feature exists
In the particle diameter of the polymer overmold special-effect powder microballoon is 10-1000 μm；Wherein special-effect powder accounts for the weight hundred of microballoon
It is 5-80wt% to divide than content.
16. exempting from special decorative effects according to claim 15 spray thermoplastic resin composition, and its feature exists
In the particle diameter of the polymer overmold special-effect powder microballoon is 10-300 μm；Wherein special-effect powder accounts for the weight hundred of microballoon
It is 5-50wt% to divide than content.
17. exempting from special decorative effects according to claim 1 spray thermoplastic resin composition, and its feature exists
In the preparation method of the polymer overmold special-effect powder microballoon specifically includes following steps：
a）First, antioxygen corrosion inhibiter, dispersed with stirring 10-30min is added to be disperseed in aqueous polymer dispersion under normal temperature
Liquid；Under agitation, to special-effect powder, or aqueous special-effect slurry material is slowly added in dispersion liquid, then side is stirred
Mix side and add curing agent, and continue to stir 30-120min, make special-effect powder fully dispersed and coated by dispersion liquid, finally make
Obtain the composite dispersion liquid of polymer overmold special-effect powder；
b）By composite dispersion liquid dried process, polymer overmold special-effect powder microballoon is obtained.
Exempting from special decorative effects described in 18. claims 17 sprays thermoplastic resin composition, it is characterised in that step
Suddenly（b）Described in drying be spray drying, the intake air temperature of the spray-drying process is 150-300 DEG C, air outlet temperature
Spend is 50-130 DEG C.
Exempting from special decorative effects described in 19. claims 18 sprays thermoplastic resin composition, it is characterised in that institute
It is 170-250 DEG C to state the intake air temperature of spray-drying process, and air outlet temperature is 70-100 DEG C.
Exempting from special decorative effects described in 20. claim any one of 1-19 sprays the preparation of thermoplastic resin composition
Method, it is characterised in that comprise the following steps：Each raw material is inserted into high-speed mixer according to the above ratio to be well mixed；To obtain
Mixture insert in double screw extruder and knead, pelletizing after cooling, packaging are obtained final product.
Exempt from spraying thermoplastic resin composition in electronics with special decorative effects described in 21. claim any one of 1-19
Application in electrical equipment, sports goods, office appliance, traffic and transport field.
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| CN102643505A (en) * | 2012-03-19 | 2012-08-22 | 上海锦湖日丽塑料有限公司 | Spraying-free aesthetic resin composition with magnetism and preparation method thereof |
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2013
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1053075A (en) * | 1990-01-02 | 1991-07-17 | 陶氏化学公司 | Have the three peak distribution ABS compositions that good gloss and gloss susceptibility reduce |
| CN102516700A (en) * | 2011-12-09 | 2012-06-27 | 上海锦湖日丽塑料有限公司 | Appearance-improving spraying-free aesthetic resin and its preparation method |
| CN102643505A (en) * | 2012-03-19 | 2012-08-22 | 上海锦湖日丽塑料有限公司 | Spraying-free aesthetic resin composition with magnetism and preparation method thereof |
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