CN104845014A - High-liquidity, high-heat resistance and good-surface appearance metal-like or pearlescent free-spraying ABS material and preparation method thereof - Google Patents
High-liquidity, high-heat resistance and good-surface appearance metal-like or pearlescent free-spraying ABS material and preparation method thereof Download PDFInfo
- Publication number
- CN104845014A CN104845014A CN201510193443.1A CN201510193443A CN104845014A CN 104845014 A CN104845014 A CN 104845014A CN 201510193443 A CN201510193443 A CN 201510193443A CN 104845014 A CN104845014 A CN 104845014A
- Authority
- CN
- China
- Prior art keywords
- metal
- resin
- master batch
- abs
- pigment master
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a high-liquidity, high-heat resistance and good-surface appearance metal-like or pearlescent free-spraying ABS material and a preparation method thereof. The high-liquidity, high-heat resistance and good-surface appearance metal-like or pearlescent free-spraying ABS material comprises, by weight, 20-55.1% of ABS resin, 10-15% of AS resin, 10-15% of high glue powder, 10-20% of a heat-resistant agent, 4-8% of a flexibilizer, 3-6% of a compatilizer, 3-6% of a surface modifier, 0.3-0.6% of an anti-oxidant, 0.2-0.4% of a light stabilizing agent, 0.4-1.0% of a lubricant, 2-4% of metal pigment master batch and 2-4% of pearlescent pigment master batch. Through use of the high-melt flow rate ABS resin, high-flow rate AS resin, heat-resistant agent, compatilizer, surface modifier, metal pigment master batch and pearlescent pigment master batch, the ABS material has excellent liquidity, heat resistance, metal-like texture and pearlescent effects. The ABS material is free of paint spraying, can be directly subjected to color injection molding to form a plastic product with metal-like or pearlescent effects, has surface appearance effects the same to paint spraying effects, can be used for automobile inner and outer decorative parts and household electrical appliance plastic housings and decorative strips.
Description
Technical field the invention belongs to polymeric material field, relates to a kind of ABS material, is specifically related to a kind ofly have high flowing, the metal of high heat-resisting, high appearance or pearl effect and exempt from spraying ABS material and preparation method thereof.
Background technology acrylonitrile-butadiene-styrene terpolymer (ABS) resin is one of maximum engineering plastics of consumption, because it has stronger resistance to impact shock, acid and alkali-resistance, dimensional stabilizing, easily processes, therefore at automobile, household electrical appliances, machinery, daily
The industries such as tool are widely used.In automotive material Application Areas, ABS material is used for automobile interior exterior decoration, mainly belongs to or pearlescent lacquer based on metal spraying; In household electrical appliances Application Areas, ABS material is used for the appearance ornamental pieces such as appliance shell, ornamental strip, also main with metal spraying
Genus or pearlescent lacquer are main.It is on the one hand scratch resistance difference problem in order to solve material that ABS material is sprayed paint, and being to make the apparent color of product more gorgeous on the other hand, reaching the fashion visual effect of metal or pearly-lustre.
ABS material is before spraying paint, and needs pass through complicated surface treatment, and to strengthen the sticking power of top coat, whole spraying process process procedure is complicated, and technology controlling and process is difficult, and product fraction defective is high, and production cost is high and recovery is difficult.Meanwhile, priming paint solvent evaporates pollutes the environment, and causes serious injury to the healthy of workman.In addition, the heat resistant requirements of auto plastics to ABS is higher; Some thin-walled properties, baroque product, require higher to the mobility of ABS material, and ABS material
Thermotolerance is poor, and mobility is also general, and therefore, exploitation has high flowing, the metal of high heat-resisting, high appearance or pearl effect and exempts from spraying ABS material and have very important significance.
Chinese patent literature
cN 201110395826.9, applying date 2011-12-04, disclosing one, to exempt from metallize effect ABS material modified, and it is made up of the material of following weight percent: ABS resin 94 ~ 99 parts, metal effect pigments 0.3 ~ 3 part, pearly pigment 0 ~ 1 part, 0.2 ~ 1 part, oxidation inhibitor, processing aid 0.2 ~ 1 part.This patent has just invented one, and to exempt from metallize effect ABS material modified, but this patent does not relate to the elaboration about having high flowing, the metal of high heat-resisting, high appearance or pearl effect and exempt to spray ABS material technology of preparing.
The weak point of this patent formulation is not use compatilizer, photostabilizer in its formula system.Because do not use compatilizer can affect the consistency of metal effect pigments, pearly pigment and ABS resin in formula system, thus effects on surface outward appearance, metal-like and pearl effect can produce considerable influence; Do not use photostabilizer can affect the light-heat aging of ABS resin in formula system, thus the use range of material can be made to be restricted.
Chinese patent literature
cN 201110428410.2, applying date 2011-12-20, disclose one and exempt from spraying and dodge silver-colored ABS resin, it is made up of the material of following weight percent: ABS resin 75-95%, dodge silver-colored aluminium powder 0.5%-30%, dispersing auxiliary 1-10%, coupling agent 1-8%, 1-20% maleic anhydride grafts.This patent has just been invented one and has been exempted from spraying and dodge silver-colored ABS resin, but this patent does not relate to the elaboration about having high flowing, the metal of high heat-resisting, high appearance or pearl effect and exempt to spray ABS material technology of preparing.
The weak point of this patent formulation is not use oxidation inhibitor, photostabilizer in its formula system.Because do not use oxidation inhibitor can affect the thermal oxidative aging of sudden strain of a muscle silver aluminium powder in formula system, ABS resin, thus the use range of material can be made to be restricted; Do not use photostabilizer can affect the light-heat aging of ABS resin in formula system, thus the use range of material can be made to be restricted.
Chinese patent literature
cN 2013102162929.6, applying date 2013-05-31disclose a kind of luster, high-hardness and high exempt from spraying ABS plastic material modified, said composition is by ABS resin 55 ~ 64 parts, AS resin 15 ~ 20 parts, PMMA resin 15 ~ 25 parts, 0.2 ~ 0.5 part, softening agent, lubricant 0.2 ~ 0.5 part, high-carbon black pigment 1 ~ 2 part, 0.2 ~ 0.4 part, oxidation inhibitor, methyl-silicone oil 0.1-0.2 part.This patent just invented a kind of luster, high-hardness and high exempt from spraying ABS plastic material modified,
But this patent does not relate to the elaboration about having high flowing, the metal of high heat-resisting, high appearance or pearl effect and exempt to spray ABS material technology of preparing.
Summary of the invention
Technical problem to be solved by this invention is, for deficiency of the prior art, one is provided to have high flowing, high heat-resisting, the metal of high appearance or pearl effect exempt from spraying ABS material and preparation method thereof, the high melt flow rate (MFR) ABS resin of special employing, high flow rate AS resin, heat-resistant agent, compatilizer, surface-modifying agent, metallic pigment master batch, the components such as pearly pigment master batch, thus make product have high flowing, high heat-resisting, metal or pearl effect, simultaneously, thin-walled property can also be solved, the surperficial silver powder flow liner of complex structure product, the problems such as tiger fur line, effective surface appearance defects improving product.
Another object of the present invention is to the preparation method that above-mentioned ABS material is provided.
Another object of the present invention is the purposes providing above-mentioned ABS material.
For solving above technical problem, the technical scheme that the present invention takes is:
Have high flowing, the metal of high heat-resisting, high appearance or pearl effect to exempt to spray an ABS material, it is made up of the component of following weight percent:
ABS resin: 20 ~ 55.1%
AS resin: 10 ~ 15%
High glue powder: 10 ~ 15%
Heat-resistant agent: 10 ~ 20%
Toughner: 4 ~ 8%
Compatilizer: 3 ~ 6%
Surface-modifying agent: 3 ~ 6%
Oxidation inhibitor: 0.3 ~ 0.6%
Photostabilizer: 0.2 ~ 0.4%
Lubricant: 0.4 ~ 1.0%
Metallic pigment master batch: 2 ~ 4%
Pearly pigment master batch: 2 ~ 4%
Described ABS resin is acrylonitrile-butadiene-styrene copolymer, is the ABS resin of high melt flow rate (MFR), its 220 DEG C, load 10kg time melt flow rate (MFR) be 30 ~ 50g/10min.
Described AS resin is acrylonitritrile-styrene resin, is the AS resin of high melt flow rate (MFR), its 220 DEG C, load 10kg time melt flow rate (MFR) be 40 ~ 60g/10min.
Described high glue powder be vinylbenzene, third rare fine-divinyl rubber, core-shell polymers, wherein, the content of divinyl is 70%.
Described toughner is one or more combinations in styrene-butadiene-styrene, MBS, ethylene-methyl acrylate-glyceryl methacrylate multipolymer.
Described compatilizer is a kind of graftomer, and wherein grafted monomer is one or more combinations in vinylformic acid, glycidyl methacrylate, and graftomer matrix is ABS, percentage of grafting >1.0.
Described oxidation inhibitor is one or more combinations in Hinered phenols, phosphorous acid esters, is specially one or more combinations in 1010,168.
Described photostabilizer is hindered amine light stabilizer, is specially one or more combinations in 944,770.
Described lubricant is one or more combinations in stearic acid, ethylene bis stearic acid amide, pentaerythritol stearate.
Described metallic pigment master batch is one or more combinations in supported metal aluminium powder, silver powder, wherein, metallic pigment master batch carrier is powdery AS resin, the content of metal powder is 70%, its surface is through the coated process of special chemical material, metal powder shape is silver dollar shape, and its particle diameter is 190 ц m ~ 250 ц m.
Described pearly pigment master batch is the micanite coating pearly pigment, the aluminium silicate salt coating pearly pigment that have carrier.Wherein, pearly pigment master batch carrier is powdery AS resin, and the content of pearly pigment is 70%, and its surface is through the coated process of metal oxide, and its particle diameter is 40 ц m ~ 80 ц m.
A kind of have high flowing, the metal of high heat-resisting, high appearance or pearl effect and exempt from spraying ABS material and system thereof
Preparation Method, concrete preparation method comprises the steps:
(1) each raw material is taken by formula rate, by weigh up ABS resin, AS resin, toughner, compatilizer, surface-modifying agent, metallic pigment master batch, pearly pigment master batch is by high mixer pre-mixing 2-4 minute, and then add the high glue powder, the heat-resistant agent mixing 2-4 minute that weigh up, finally add load weighted oxidation inhibitor, photostabilizer, lubricant be mixed together 4-6 minute, discharging obtains Preblend.All mixing process is all carried out in high mixer, and rotating speed is 1000 ~ 1200 revs/min;
(2) Preblend prepared by step (1) is melt extruded granulation through twin screw extruder, the rotating speed of twin screw extruder is 320 ~ 400 revs/min, and temperature is 190 ~ 220 DEG C.
Above-mentioned have high flowing, the metal of high heat-resisting, high appearance or pearl effect and exempt from spraying ABS material and can be used for inner and outer decorative parts of automobile, as air outlet, air-conditioner controller, central control panel, ornamental strip etc., also can be used for household electrical appliances plastic casing, ornamental strip etc. simultaneously.
Compared with prior art, advantage of the present invention is:
1, of the present invention have high flowing, the metal of high heat-resisting, high appearance or pearl effect and exempt from spraying ABS material and adopt high melt flow rate (MFR) ABS resin and AS resin especially, can make to realize between each component homogenous plasticized, thus improve material surface outward appearance.
2, of the present invention have high flowing, the metal of high heat-resisting, high appearance or pearl effect and exempt from spraying ABS material and adopt heat-resistant agent especially, can improve the thermotolerance of material, thus expand the range of application of material.
3, of the present invention have high flowing, the metal of high heat-resisting, high appearance or pearl effect and exempt from spraying ABS material and adopt compatilizer especially, the heat-resistant agent in formula system, metallic pigment master batch, pearly pigment master batch and each component can be made to realize compatible, thus improve product surface outward appearance.
4, of the present invention have high flowing, the metal of high heat-resisting, high appearance or pearl effect and exempt from spraying ABS material and adopt surface-modifying agent especially, the metallic pigment master batch in formula system, pearly-lustre Masterbatch and each component can be made to realize compatible, thus improve product surface outward appearance.
5, of the present invention have high flowing, the metal of high heat-resisting, high appearance or pearl effect and exempt from spraying ABS material and adopt metallic pigment master batch and pearly pigment master batch especially, metallic pigment and pearly pigment can be made to realize with each component maximum dispersed, thus improve product surface outward appearance.
6, of the present invention have high flowing, the metal of high heat-resisting, high appearance or pearl effect and exempt to spray ABS material and have excellent mobility, easy processing, there is high heat resistance, metal-like or pearl effect simultaneously remarkable, in addition, the problem such as surperficial silver powder flow liner, tiger fur line of thin-walled, complex structure product can also be solved, thus improve the surface appearance defects of product.
Embodiment
Below in conjunction with specific embodiment, the present invention is described in detail.
Embodiment 1
Have high flowing, the metal of high heat-resisting, high appearance or the pearl effect of the present embodiment are exempted from spraying ABS material and are made up of by weight percentage following material:
ABS resin is high melt flow rate (MFR) ABS resin, and its melt flow rate (MFR) is 30g/10min, 55.1%;
AS resin is high melt flow rate (MFR) AS resin, and its melt flow rate (MFR) is 40g/10min, 10%;
High glue powder, 10%;
Heat-resistant agent, 10%;
Toughner is styrene-butadiene-styrene, 4%;
Compatilizer is acrylic acid-grafted ABS, 3%;
Surface-modifying agent, 3%;
Oxidation inhibitor is 1010,0.1%, 168,0.2%;
Photostabilizer is 944,0.1%, 770,0.1%;
Lubricant is calcium stearate, 0.4%;
Metallic pigment master batch is aluminium powder pigment master batch, 2%;
Pearly pigment master batch is micanite coating pearly pigment master batch, 2%.
Concrete preparation method comprises the steps:
(1) each raw material is taken by formula rate, by weigh up ABS resin, AS resin, toughner, compatilizer, surface-modifying agent, metallic pigment master batch, pearly pigment master batch is by high mixer pre-mixing 2-4 minute, and then add the high glue powder, the heat-resistant agent mixing 2-4 minute that weigh up, finally add load weighted oxidation inhibitor, photostabilizer, lubricant be mixed together 4-6 minute, discharging obtains Preblend.All mixing process is all carried out in high mixer, and rotating speed is 1000 ~ 1200 revs/min;
(2) Preblend prepared by step (1) is melt extruded granulation through twin screw extruder, the rotating speed of twin screw extruder is 320 ~ 400 revs/min, and temperature is 190 ~ 220 DEG C.
Embodiment 2
Have high flowing, the metal of high heat-resisting, high appearance or the pearl effect of the present embodiment are exempted from spraying ABS material and are made up of by weight percentage following material:
ABS resin is high melt flow rate (MFR) ABS resin, and its melt flow rate (MFR) is 35g/10min, 45.8%;
AS resin is high melt flow rate (MFR) AS resin, and its melt flow rate (MFR) is 45g/10min, 11%;
High glue powder, 11%;
Heat-resistant agent, 12%;
Toughner is MBS, 5%;
Compatilizer is glycidyl methacrylate graft ABS, 4%;
Surface-modifying agent, 4%;
Oxidation inhibitor is 1010,0.2%, 168,0.1%;
Photostabilizer is 944,0.1%, 770,0.2%;
Lubricant is ethylene bis stearic acid amide, 0.6%;
Metallic pigment master batch is silver powder pigment master batch, 3%;
Pearly pigment master batch is aluminium silicate salt coating pearly pigment master batch, 3%.
Concrete preparation method is with embodiments of the invention 1.
Embodiment 3
Have high flowing, the metal of high heat-resisting, high appearance or the pearl effect of the present embodiment are exempted from spraying ABS material and are made up of by weight percentage following material:
ABS resin is high melt flow rate (MFR) ABS resin, and its melt flow rate (MFR) is 40g/10min, 36.7%;
AS resin is high melt flow rate (MFR) AS resin, and its melt flow rate (MFR) is 50g/10min, 12%;
High glue powder, 12%;
Heat-resistant agent, 14%;
Toughner is ethylene-methyl acrylate-glyceryl methacrylate multipolymer, 6%;
Compatilizer is acrylic acid-grafted ABS, 5%;
Surface-modifying agent, 5%;
Oxidation inhibitor is 1010,0.2%, 168,0.2%;
Photostabilizer is 944,0.2%, 770,0.1%;
Lubricant is pentaerythritol stearate, 0.6%;
Metallic pigment master batch is aluminium powder pigment master batch, 4%;
Pearly pigment master batch is micanite coating pearly pigment master batch, 4%.
Concrete preparation method is with embodiments of the invention 1.
Embodiment 4
Have high flowing, the metal of high heat-resisting, high appearance or the pearl effect of the present embodiment are exempted from spraying ABS material and are made up of by weight percentage following material:
ABS resin is high melt flow rate (MFR) ABS resin, and its melt flow rate (MFR) is 45g/10min, 30.4%;
AS resin is high melt flow rate (MFR) AS resin, and its melt flow rate (MFR) is 55g/10min, 13%;
High glue powder, 13%;
Heat-resistant agent, 16%;
Toughner is styrene-butadiene-styrene, 7%;
Compatilizer is glycidyl methacrylate graft ABS, 6%;
Surface-modifying agent, 6%;
Oxidation inhibitor is 1010,0.2%, 168,0.3%;
Photostabilizer is 944,0.15%, 770,0.15%;
Lubricant is calcium stearate, 0.4%, and ethylene bis stearic acid amide, 0.4%;
Metallic pigment master batch is silver powder pigment master batch, 3%;
Pearly pigment master batch is aluminium silicate salt coating pearly pigment master batch, 4%.
Concrete preparation method is with embodiments of the invention 1.
Embodiment 5
Have high flowing, the metal of high heat-resisting, high appearance or the pearl effect of the present embodiment are exempted from spraying ABS material and are made up of by weight percentage following material:
ABS resin is high melt flow rate (MFR) ABS resin, and its melt flow rate (MFR) is 30g/10min, 32.3%;
AS resin is high melt flow rate (MFR) AS resin, and its melt flow rate (MFR) is 40g/10min, 14%;
High glue powder, 14%;
Heat-resistant agent, 18%;
Toughner is MBS, 8%;
Compatilizer is acrylic acid-grafted ABS, 4%;
Surface-modifying agent, 3%;
Oxidation inhibitor is 1010,0.3%, 168,0.2%;
Photostabilizer is 944,0.2%, 770,0.2%;
Lubricant is calcium stearate, 0.4%, and pentaerythritol stearate, 0.4%;
Metallic pigment master batch is aluminium powder pigment master batch, 3%;
Pearly pigment master batch is micanite coating pearly pigment master batch, 2%.
Concrete preparation method is with embodiments of the invention 1.
Embodiment 6
Have high flowing, the metal of high heat-resisting, high appearance or the pearl effect of the present embodiment are exempted from spraying ABS material and are made up of by weight percentage following material:
ABS resin is high melt flow rate (MFR) ABS resin, and its melt flow rate (MFR) is 50g/10min, 21.3%;
AS resin is high melt flow rate (MFR) AS resin, and its melt flow rate (MFR) is 60g/10min, 15%;
High glue powder, 15%;
Heat-resistant agent, 20%;
Toughner is ethylene-methyl acrylate-glyceryl methacrylate multipolymer, 8%;
Compatilizer is glycidyl methacrylate graft ABS, 5%;
Surface-modifying agent, 6%;
Oxidation inhibitor is 1010,0.3%, 168,0.3%;
Photostabilizer is 944,0.2%, 770,0.1%;
Lubricant is ethylene bis stearic acid amide, 0.4%, and pentaerythritol stearate, 0.4%;
Metallic pigment master batch is silver powder pigment master batch, 4%;
Pearly pigment master batch is aluminium silicate salt coating pearly pigment master batch, 4%.
Concrete preparation method is with embodiments of the invention 1.
Embodiment 7
Have high flowing, the metal of high heat-resisting, high appearance or the pearl effect of the present embodiment are exempted from spraying ABS material and are made up of by weight percentage following material:
ABS resin is high melt flow rate (MFR) ABS resin, and its melt flow rate (MFR) is 45g/10min, 39.5%;
AS resin is high melt flow rate (MFR) AS resin, and its melt flow rate (MFR) is 55g/10min, 12%;
High glue powder, 11%;
Heat-resistant agent, 14%;
Toughner is styrene-butadiene-styrene, 5%;
Compatilizer is acrylic acid-grafted ABS, 6%;
Surface-modifying agent, 4%;
Oxidation inhibitor is 1010,0.4%, 168,0.2%;
Photostabilizer is 944,0.1%, 770,0.2%;
Lubricant is calcium stearate, 0.2%, and ethylene bis stearic acid amide, 0.2%, pentaerythritol stearate, 0.2%;
Metallic pigment master batch is aluminium powder pigment master batch, 3%;
Pearly pigment master batch is micanite coating pearly pigment master batch, 4%.
Concrete preparation method is with embodiments of the invention 1.
Embodiment 8
Have high flowing, the metal of high heat-resisting, high appearance or the pearl effect of the present embodiment are exempted from spraying ABS material and are made up of by weight percentage following material:
ABS resin is high melt flow rate (MFR) ABS resin, and its melt flow rate (MFR) is 30g/10min, 49.3%;
AS resin is high melt flow rate (MFR) AS resin, and its melt flow rate (MFR) is 40g/10min, 10%;
High glue powder, 12%;
Heat-resistant agent, 11%;
Toughner is MBS, 5%;
Compatilizer is glycidyl methacrylate graft ABS, 3%;
Surface-modifying agent, 3%;
Oxidation inhibitor is 1010,0.2%, 168,0.4%;
Photostabilizer is 944,0.15%, 770,0.15%;
Lubricant is calcium stearate, 0.2%, and ethylene bis stearic acid amide, 0.3%, pentaerythritol stearate, 0.3%;
Metallic pigment master batch is silver powder pigment master batch, 2%;
Pearly pigment master batch is aluminium silicate salt coating pearly pigment master batch, 3%.
Concrete preparation method is with embodiments of the invention 1.
Embodiment 9
Have high flowing, the metal of high heat-resisting, high appearance or the pearl effect of the present embodiment are exempted from spraying ABS material and are made up of by weight percentage following material:
ABS resin is high melt flow rate (MFR) ABS resin, and its melt flow rate (MFR) is 40g/10min, 28.1%;
AS resin is high melt flow rate (MFR) AS resin, and its melt flow rate (MFR) is 50g/10min, 15%;
High glue powder, 13%;
Heat-resistant agent, 19%;
Toughner is MBS, 7%;
Compatilizer is acrylic acid-grafted ABS, 4%;
Surface-modifying agent, 5%;
Oxidation inhibitor is 1010,0.3%, 168,0.3%;
Photostabilizer is 944,0.15%, 770,0.15%;
Lubricant is calcium stearate, 0.3%, and ethylene bis stearic acid amide, 0.3%, pentaerythritol stearate, 0.4%;
Metallic pigment master batch is aluminium powder pigment master batch, 3%;
Pearly pigment master batch is micanite coating pearly pigment master batch, 4%.
Concrete preparation method is with embodiments of the invention 1.
Embodiment 10
Have high flowing, the metal of high heat-resisting, high appearance or the pearl effect of the present embodiment are exempted from spraying ABS material and are made up of by weight percentage following material:
ABS resin is high melt flow rate (MFR) ABS resin, and its melt flow rate (MFR) is 35g/10min, 25.2%;
AS resin is high melt flow rate (MFR) AS resin, and its melt flow rate (MFR) is 45g/10min, 13%;
High glue powder, 14%;
Heat-resistant agent, 20%;
Toughner is styrene-butadiene-styrene, 8%;
Compatilizer is glycidyl methacrylate graft ABS, 5%;
Surface-modifying agent, 6%;
Oxidation inhibitor is 1010,0.2%, 168,0.2%;
Photostabilizer is 944,0.2%, 770,0.2%;
Lubricant is calcium stearate, 0.2%, and ethylene bis stearic acid amide, 0.4%, pentaerythritol stearate, 0.4%;
Metallic pigment master batch is silver powder pigment master batch, 4%;
Pearly pigment master batch is aluminium silicate salt coating pearly pigment master batch, 3%.
Concrete preparation method is with embodiments of the invention 1.
The material properties test result of embodiment 1-10, appearance, metal-like and pearl effect evaluation refer to table 1.
Table 1
In embodiment 1-10, specimen surface outward appearance, metal-like and pearl effect evaluation method are as follows:
Appearance, surface gloss, metal-like and pearl effect level evaluation are carried out to injection moulding model.Wherein appearance divides Three Estate: excellent, good, poor; Metal-like divides Three Estate: strong, in, weak; A pearly-lustre effect divides Three Estate: good, general, poor, take a certain evaluation grade person in the majority as the attribute ratings of this model performance.
As can be seen from Table 1, embodiment 1-10 all shows higher mobility, preferably thermotolerance, more excellent appearance, stronger metal-like and pearl effect, all can realize patent of the present invention exempts to spray ABS material preparation about the metal of height flowing, high heat-resisting, high appearance or pearl effect completely.Especially, embodiment 2-4 and embodiment 6-10 shows the most excellent effect in material flowability, thermotolerance, appearance, metal-like and pearl effect all simultaneously.
The comparative example of below testing, is used for comparing the technique effect not reaching the above embodiment of the present invention when certain component proportion changes in filling a prescription.
Comparative example 1
The ABS material of comparative example 1 adopts following material and proportioning:
ABS resin is high melt flow rate (MFR) ABS resin, and its melt flow rate (MFR) is 8g/10min, 21.3%;
AS resin is high melt flow rate (MFR) AS resin, and its melt flow rate (MFR) is 60g/10min, 15%;
High glue powder, 15%;
Heat-resistant agent, 20%;
Toughner is ethylene-methyl acrylate-glyceryl methacrylate multipolymer, 8%;
Compatilizer is glycidyl methacrylate graft ABS, 5%;
Surface-modifying agent, 6%;
Oxidation inhibitor is 1010,0.3%, 168,0.3%;
Photostabilizer is 944,0.2%, 770,0.1%;
Lubricant is ethylene bis stearic acid amide, 0.4%, and pentaerythritol stearate, 0.4%;
Metallic pigment master batch is silver powder pigment master batch, 4%;
Pearly pigment master batch is aluminium silicate salt coating pearly pigment master batch, 4%.
Concrete preparation method is with embodiments of the invention 1.
Compare with the embodiment of the present invention 6, the ABS resin melt flow rate (MFR) in embodiment 6 is 50g/10min, belongs to high melt flow rate (MFR) ABS resin; ABS resin melt flow rate (MFR) in comparative example 1 is 8g/10min, belongs to low melt flow speed ABS resin, cannot make to realize between each component homogenous plasticized, thus cannot improve material surface outward appearance.
Comparative example 2
The ABS material of comparative example 2 adopts following material and proportioning:
ABS resin is high melt flow rate (MFR) ABS resin, and its melt flow rate (MFR) is 50g/10min, 21.3%;
AS resin is high melt flow rate (MFR) AS resin, and its melt flow rate (MFR) is 10g/10min, 15%;
High glue powder, 15%;
Heat-resistant agent, 20%;
Toughner is ethylene-methyl acrylate-glyceryl methacrylate multipolymer, 8%;
Compatilizer is glycidyl methacrylate graft ABS, 5%;
Surface-modifying agent, 6%;
Oxidation inhibitor is 1010,0.3%, 168,0.3%;
Photostabilizer is 944,0.2%, 770,0.1%;
Lubricant is ethylene bis stearic acid amide, 0.4%, and pentaerythritol stearate, 0.4%;
Metallic pigment master batch is silver powder pigment master batch, 4%;
Pearly pigment master batch is aluminium silicate salt coating pearly pigment master batch, 4%.
Concrete preparation method is with embodiments of the invention 1.
Compare with the embodiment of the present invention 6, the AS resin melt flowing speed in embodiment 6 is 60g/10min, belongs to high melt flow rate (MFR) AS resin; AS resin melt flowing speed in comparative example 2 is 10g/10min, belongs to low melt flow speed AS resin respectively, cannot make to realize between each component homogenous plasticized, thus cannot improve material surface outward appearance.
Comparative example 3
The ABS material of comparative example 3 adopts following material and proportioning:
ABS resin is high melt flow rate (MFR) ABS resin, and its melt flow rate (MFR) is 50g/10min, 26.3%;
AS resin is high melt flow rate (MFR) AS resin, and its melt flow rate (MFR) is 60g/10min, 15%;
High glue powder, 15%;
Heat-resistant agent, 20%;
Toughner is ethylene-methyl acrylate-glyceryl methacrylate multipolymer, 8%;
Surface-modifying agent, 6%;
Oxidation inhibitor is 1010,0.3%, 168,0.3%;
Photostabilizer is 944,0.2%, 770,0.1%;
Lubricant is ethylene bis stearic acid amide, 0.4%, and pentaerythritol stearate, 0.4%;
Metallic pigment master batch is silver powder pigment master batch, 4%;
Pearly pigment master batch is aluminium silicate salt coating pearly pigment master batch, 4%.
Concrete preparation method is with embodiments of the invention 1.
Compare with embodiments of the invention 6, containing compatilizer in embodiment 6, compatilizer is 5%; Without compatilizer in comparative example 3, the heat-resistant agent in formula system, metallic pigment master batch, pearly pigment master batch and each component cannot be made to realize compatible, thus material surface outward appearance cannot be improved.
Comparative example 4
The ABS material of comparative example 4 adopts following material and proportioning:
ABS resin is high melt flow rate (MFR) ABS resin, and its melt flow rate (MFR) is 50g/10min, 27.3%;
AS resin is high melt flow rate (MFR) AS resin, and its melt flow rate (MFR) is 60g/10min, 15%;
High glue powder, 15%;
Heat-resistant agent, 20%;
Toughner is ethylene-methyl acrylate-glyceryl methacrylate multipolymer, 8%;
Compatilizer is glycidyl methacrylate graft ABS, 5%;
Oxidation inhibitor is 1010,0.3%, 168,0.3%;
Photostabilizer is 944,0.2%, 770,0.1%;
Lubricant is ethylene bis stearic acid amide, 0.4%, and pentaerythritol stearate, 0.4%;
Metallic pigment master batch is silver powder pigment master batch, 4%;
Pearly pigment master batch is aluminium silicate salt coating pearly pigment master batch, 4%.
Concrete preparation method is with embodiments of the invention 1.
Compare with embodiments of the invention 6, containing surface-modifying agent in embodiment 6, surface-modifying agent is 6%; Without surface-modifying agent in comparative example 4, the metallic pigment master batch in formula system, pearly-lustre Masterbatch and each component cannot be made to realize compatible, thus material surface outward appearance cannot be improved.
Comparative example 5
The ABS material of comparative example 5 adopts following material and proportioning:
ABS resin is high melt flow rate (MFR) ABS resin, and its melt flow rate (MFR) is 50g/10min, 41.3%;
AS resin is high melt flow rate (MFR) AS resin, and its melt flow rate (MFR) is 60g/10min, 15%;
High glue powder, 15%;
Toughner is ethylene-methyl acrylate-glyceryl methacrylate multipolymer, 8%;
Compatilizer is glycidyl methacrylate graft ABS, 5%;
Surface-modifying agent, 6%;
Oxidation inhibitor is 1010,0.3%, 168,0.3%;
Photostabilizer is 944,0.2%, 770,0.1%;
Lubricant is ethylene bis stearic acid amide, 0.4%, and pentaerythritol stearate, 0.4%;
Metallic pigment master batch is silver powder pigment master batch, 4%;
Pearly pigment master batch is aluminium silicate salt coating pearly pigment master batch, 4%.
Concrete preparation method is with embodiments of the invention 1.
Compare with embodiments of the invention 6, containing heat-resistant agent in embodiment 6, heat-resistant agent is 20%; Without heat-resistant agent in comparative example 5, the thermotolerance of material cannot be improved, thus affect the widespread use of material.
Comparative example 6
The ABS material of comparative example 6 adopts following material and proportioning:
ABS resin is high melt flow rate (MFR) ABS resin, and its melt flow rate (MFR) is 50g/10min, 21.3%;
AS resin is high melt flow rate (MFR) AS resin, and its melt flow rate (MFR) is 60g/10min, 15%;
High glue powder, 15%;
Heat-resistant agent, 20%;
Toughner is ethylene-methyl acrylate-glyceryl methacrylate multipolymer, 8%;
Compatilizer is glycidyl methacrylate graft ABS, 5%;
Surface-modifying agent, 6%;
Oxidation inhibitor is 1010,0.3%, 168,0.3%;
Photostabilizer is 944,0.2%, 770,0.1%;
Lubricant is ethylene bis stearic acid amide, 0.4%, and pentaerythritol stearate, 0.4%;
Metallic pigment are silver powder pigment, 4%;
Pearly pigment is aluminium silicate salt coating pearly pigment, 4%.
Concrete preparation method comprises the steps:
(1) each raw material is taken by formula rate, by weigh up ABS resin, AS resin, toughner, compatilizer, surface-modifying agent is by high mixer pre-mixing 2-4 minute, and then add the high glue powder, heat-resistant agent, metallic pigment, the pearly pigment mixing 2-4 minute that weigh up, finally add load weighted oxidation inhibitor, photostabilizer, lubricant be mixed together 4-6 minute, discharging obtains Preblend.All mixing process is all carried out in high mixer, and rotating speed is 1000 ~ 1200 revs/min;
(2) Preblend prepared by step (1) is melt extruded granulation through twin screw extruder, the rotating speed of twin screw extruder is 320 ~ 400 revs/min, and temperature is 190 ~ 220 DEG C.
Compare with embodiments of the invention 6, metallic pigment master batch in embodiment 6 is supported metal silver powder, wherein, metallic pigment master batch carrier is powdery AS resin, the content of metal powder is 70%, its surface is through the coated process of special chemical material, and metal powder shape is silver dollar shape, and particle diameter is 190 ~ 250 ц m; Pearly pigment master batch is the aluminium silicate salt coating pearly pigment having carrier.Wherein pearly pigment master batch carrier is powdery AS resin, and the content of pearly pigment is 70%, its surface through the coated process of metal oxide, its particle diameter 40 ц m ~ 80 ц m; Metallic pigment in comparative example 6 are silver powder pigment, carrier free, its surface is also without the coated process of special chemical material, pearly pigment is common pearly pigment, carrier free, its surface, also without the coated process of metal oxide, cannot make metallic pigment, pearly pigment realize with each component maximum dispersed, thus cannot improve material surface outward appearance.
Comparative example 1-6 is using embodiment 6 as sample for reference, and its effect assessment is assess performance test result, the appearance of injection moulding model, metal-like and pearl effect, and concrete opinion rating refers to table 2.
Table 2
As can be seen from Table 2, compare with embodiments of the invention 6, the mobility of comparative example 1, appearance extreme difference, its reason adopts low melt flow speed ABS resin; The mobility of comparative example 2, appearance also extreme difference, its reason adopts low melt flow speed AS resin; The appearance extreme difference of comparative example 3, its reason does not adopt compatilizer; The appearance of comparative example 4 is also poor, and its reason does not adopt surface-modifying agent; The thermotolerance extreme difference of comparative example 5, its reason does not adopt heat-resistant agent; The metal-like of comparative example 6 is weak, pearl effect is poor, and its reason is the metallic pigment in formula is silver powder pigment, carrier free, its surface is also without the coated process of special chemical material, pearly pigment is common pearly pigment, carrier free, and its surface is also without the coated process of metal oxide.
By table 1, table 2 can be found out, patent of the present invention adopts the ABS resin of high melt flow rate (MFR) especially, the AS resin of high flow rate, high glue powder, heat-resistant agent, toughner, compatilizer, surface-modifying agent, metallic pigment master batch, exempting from prepared by the components such as pearly pigment master batch sprays ABS material material and has excellent mobility, thermotolerance, metal-like and pearl effect, this material does not need to spray paint, directly can be injection molded into the plastic part with metal or pearl effect with look, can be widely used in and comprise the flowing of needs height, high heat-resisting, thin-walled and baroque large-scale product, its surface appearance effects is suitable with effect of spraying paint, this material manufacture is simple simultaneously, cost is low, manufacturing processed is environment friendly and pollution-free, can be used for inner and outer decorative parts of automobile, as air outlet, air-conditioner controller, central control panel, ornamental strip etc., also can be used for household electrical appliances plastic casing simultaneously, ornamental strip etc.
In addition to the implementation, patent of the present invention can also have other embodiments.All employings are equal to the technical scheme of replacement or equivalent transformation formation, all drop on the protection domain of patent requirements of the present invention.
Claims (10)
1. one kind has high flowing, the metal of high heat-resisting, high appearance or pearl effect and exempts from spraying ABS material and preparation method thereof, and it is characterized in that, it is made up of the component of following weight percent:
ABS resin: 20 ~ 55.1%
AS resin: 10 ~ 15%
High glue powder: 10 ~ 15%
Heat-resistant agent: 10 ~ 20%
Toughner: 4 ~ 8%
Compatilizer: 3 ~ 6%
Surface-modifying agent: 3 ~ 6%
Oxidation inhibitor: 0.3 ~ 0.6%
Photostabilizer: 0.2 ~ 0.4%
Lubricant: 0.4 ~ 1.0%
Metallic pigment master batch: 2 ~ 4%
Pearly pigment master batch: 2 ~ 4%
Wherein, described ABS resin is acrylonitrile-butadiene-styrene terpolymer, is the ABS of high melt flow rate (MFR), its 220 DEG C, load 10kg time melt flow rate (MFR) be 30 ~ 50g/10min; Described AS resin is acrylonitritrile-styrene resin, is the AS of high melt flow rate (MFR), its 220 DEG C, load 10kg time melt flow rate (MFR) be 40 ~ 60g/10min.
2. according to claim 1 have high flowing, the metal of high heat-resisting, high appearance or pearl effect and exempt to spray ABS material, it is characterized in that, described high glue powder be vinylbenzene, third rare fine-divinyl rubber core-shell polymers, wherein, the content of divinyl is 70%.
3. according to claim 1 have high flowing, the metal of high heat-resisting, high appearance or pearl effect and exempt to spray ABS material, it is characterized in that, described toughner is one or more combinations in styrene-butadiene-styrene, MBS, ethylene-methyl acrylate-glyceryl methacrylate multipolymer.
4. according to claim 1 have high flowing, the metal of high heat-resisting, high appearance or pearl effect and exempt to spray ABS material, it is characterized in that, described compatilizer is graftomer, wherein grafted monomer is one or more combinations in vinylformic acid, glycidyl methacrylate, graftomer matrix is ABS, percentage of grafting >1.0.
5. according to claim 1 have high flowing, the metal of high heat-resisting, high appearance or pearl effect and exempt to spray ABS material, and it is characterized in that, described oxidation inhibitor is one or more combinations in Hinered phenols, phosphorous acid esters.
6. according to claim 1 have high flowing, the metal of high heat-resisting, high appearance or pearl effect and exempt to spray ABS material, and it is characterized in that, described photostabilizer is hindered amine light stabilizer.
7. according to claim 1 have high flowing, the metal of high heat-resisting, high appearance or pearl effect and exempt to spray ABS material, it is characterized in that, described lubricant is one or more combinations in stearic acid, ethylene bis stearic acid amide, pentaerythritol stearate.
8. according to claim 1 have high flowing, the metal of high heat-resisting, high appearance or pearl effect and exempt to spray ABS material, it is characterized in that, described metallic pigment master batch is one or more combinations in supported metal aluminium powder, silver powder 4, wherein, metallic pigment master batch carrier is powdery AS resin, and the content of metal powder is 70%, and its surface is through the coated process of special chemical material, metal powder shape is silver dollar shape, and its particle diameter is 190 ~ 250 ц m.
9. according to claim 1 have high flowing, the metal of high heat-resisting, high appearance or pearl effect and exempt to spray ABS material, it is characterized in that, described pearly pigment master batch is the micanite coating pearly pigment, the aluminium silicate salt coating pearly pigment that have carrier, wherein, pearly pigment master batch carrier is powdery AS resin, the content of pearly pigment is 70%, and its surface is through the coated process of metal oxide, and its particle diameter is 40 ц m ~ 80 ц m.
10. according to claim 1 have the preparation method that high flowing, the metal of high heat-resisting, high appearance or pearl effect exempt to spray ABS material, it is characterized in that comprising the following steps:
(1) each raw material is taken by formula rate, by weigh up ABS resin, AS resin, toughner, compatilizer, surface-modifying agent, metallic pigment master batch, pearly pigment master batch is by high mixer pre-mixing 2-4 minute, and then add the high glue powder, the heat-resistant agent mixing 2-4 minute that weigh up, finally add load weighted oxidation inhibitor, photostabilizer, lubricant be mixed together 4-6 minute, discharging obtains Preblend, all mixing process is all carried out in high mixer, and rotating speed is 1000 ~ 1200 revs/min;
(2) Preblend prepared by step (1) is melt extruded granulation through twin screw extruder, the rotating speed of twin screw extruder is 320 ~ 400 revs/min, and temperature is 190 ~ 220 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510193443.1A CN104845014A (en) | 2015-04-22 | 2015-04-22 | High-liquidity, high-heat resistance and good-surface appearance metal-like or pearlescent free-spraying ABS material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510193443.1A CN104845014A (en) | 2015-04-22 | 2015-04-22 | High-liquidity, high-heat resistance and good-surface appearance metal-like or pearlescent free-spraying ABS material and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104845014A true CN104845014A (en) | 2015-08-19 |
Family
ID=53845027
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510193443.1A Pending CN104845014A (en) | 2015-04-22 | 2015-04-22 | High-liquidity, high-heat resistance and good-surface appearance metal-like or pearlescent free-spraying ABS material and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104845014A (en) |
Cited By (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105199294A (en) * | 2015-09-25 | 2015-12-30 | 银禧工程塑料（东莞）有限公司 | High-gloss spraying-free ABS (acrylonitrile butadiene styrene) composite material with special effect and preparation method thereof |
| CN105482352A (en) * | 2015-12-17 | 2016-04-13 | 厦门美佳美新材料科技有限公司 | Novel pearly-luster ABS material and processing method |
| CN105733171A (en) * | 2016-05-05 | 2016-07-06 | 合肥华凌股份有限公司 | Spray-free ABS (acrylonitrile butadiene styrene copolymers) material, spray-free ABS and ABS co-extruded decoration strip and refrigerator using decoration strip |
| CN105802116A (en) * | 2016-04-29 | 2016-07-27 | 上汽通用五菱汽车股份有限公司 | Spraying-free high-metal-gloss transparent ABS material and preparation method |
| CN106009471A (en) * | 2016-06-24 | 2016-10-12 | 深圳市同益实业股份有限公司 | Resin material and preparation method thereof |
| CN107645872A (en) * | 2016-08-03 | 2018-01-30 | 广东欧珀移动通信有限公司 | A kind of insulator, metal shell, manufacture method and mobile terminal |
| CN107915944A (en) * | 2017-11-10 | 2018-04-17 | 中山长虹电器有限公司 | It is a kind of that there is bright pearly-lustre, high flowing, the translucent ABS material of high intensity |
| CN109135061A (en) * | 2018-08-17 | 2019-01-04 | 三椒口腔健康股份有限公司 | A kind of marbling toothbrush handle and preparation method thereof |
| CN109503922A (en) * | 2018-11-19 | 2019-03-22 | 深圳免喷材料科技有限公司 | A kind of preparation method of pigment functional agglomerate and products thereof and application |
| CN109836764A (en) * | 2019-03-04 | 2019-06-04 | 广州科苑新型材料有限公司 | A kind of silver color is exempted to spray ABS material and the preparation method and application thereof |
| CN109957207A (en) * | 2019-04-02 | 2019-07-02 | 清远市绚淳环保新材料有限公司 | It is a kind of to exempt from spraying metal aluminium pigment and preparation method thereof with brittle performance |
| CN110157138A (en) * | 2018-02-12 | 2019-08-23 | 合肥杰事杰新材料股份有限公司 | One kind is exempted to spray pearly-lustre ABS material and preparation method thereof |
| CN110330761A (en) * | 2019-07-25 | 2019-10-15 | 小熊电器股份有限公司 | One kind exempting from painted plastic and preparation method thereof |
| CN110643136A (en) * | 2019-09-25 | 2020-01-03 | 广东格瑞新材料股份有限公司 | Spraying-free ABS material and preparation method thereof |
| CN111234497A (en) * | 2020-01-10 | 2020-06-05 | 金旸（厦门）新材料科技有限公司 | Cold-resistant metal texture spraying-free PC/ABS alloy for automotive interior and preparation method thereof |
| US10879948B2 (en) | 2016-08-03 | 2020-12-29 | Guangdong Oppo Mobile Telecommunications Corp., Ltd. | Metallic shell, method for manufacturing the same and mobile terminal having the same |
| CN113462115A (en) * | 2021-06-29 | 2021-10-01 | 上海艾镇新材料有限公司 | High-weather-resistance spraying-free ABS (acrylonitrile butadiene styrene) composite material and preparation method thereof |
| CN114525010A (en) * | 2022-03-16 | 2022-05-24 | 成都金发科技新材料有限公司 | ABS composition and preparation method and application thereof |
-
2015
- 2015-04-22 CN CN201510193443.1A patent/CN104845014A/en active Pending
Cited By (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105199294A (en) * | 2015-09-25 | 2015-12-30 | 银禧工程塑料（东莞）有限公司 | High-gloss spraying-free ABS (acrylonitrile butadiene styrene) composite material with special effect and preparation method thereof |
| CN105482352A (en) * | 2015-12-17 | 2016-04-13 | 厦门美佳美新材料科技有限公司 | Novel pearly-luster ABS material and processing method |
| CN105802116A (en) * | 2016-04-29 | 2016-07-27 | 上汽通用五菱汽车股份有限公司 | Spraying-free high-metal-gloss transparent ABS material and preparation method |
| CN105733171A (en) * | 2016-05-05 | 2016-07-06 | 合肥华凌股份有限公司 | Spray-free ABS (acrylonitrile butadiene styrene copolymers) material, spray-free ABS and ABS co-extruded decoration strip and refrigerator using decoration strip |
| CN106009471A (en) * | 2016-06-24 | 2016-10-12 | 深圳市同益实业股份有限公司 | Resin material and preparation method thereof |
| CN106009471B (en) * | 2016-06-24 | 2019-09-03 | 深圳市前海同益技术研发有限公司 | Resin material and preparation method thereof |
| CN107645872A (en) * | 2016-08-03 | 2018-01-30 | 广东欧珀移动通信有限公司 | A kind of insulator, metal shell, manufacture method and mobile terminal |
| US10879948B2 (en) | 2016-08-03 | 2020-12-29 | Guangdong Oppo Mobile Telecommunications Corp., Ltd. | Metallic shell, method for manufacturing the same and mobile terminal having the same |
| CN107915944A (en) * | 2017-11-10 | 2018-04-17 | 中山长虹电器有限公司 | It is a kind of that there is bright pearly-lustre, high flowing, the translucent ABS material of high intensity |
| CN110157138A (en) * | 2018-02-12 | 2019-08-23 | 合肥杰事杰新材料股份有限公司 | One kind is exempted to spray pearly-lustre ABS material and preparation method thereof |
| CN109135061A (en) * | 2018-08-17 | 2019-01-04 | 三椒口腔健康股份有限公司 | A kind of marbling toothbrush handle and preparation method thereof |
| CN109503922A (en) * | 2018-11-19 | 2019-03-22 | 深圳免喷材料科技有限公司 | A kind of preparation method of pigment functional agglomerate and products thereof and application |
| CN109503922B (en) * | 2018-11-19 | 2021-11-19 | 深圳免喷材料科技有限公司 | Preparation method of pigment functional master batch, product and application thereof |
| CN109836764A (en) * | 2019-03-04 | 2019-06-04 | 广州科苑新型材料有限公司 | A kind of silver color is exempted to spray ABS material and the preparation method and application thereof |
| CN109836764B (en) * | 2019-03-04 | 2021-07-06 | 广州科苑新型材料有限公司 | Silver spraying-free ABS material and preparation method and application thereof |
| CN109957207A (en) * | 2019-04-02 | 2019-07-02 | 清远市绚淳环保新材料有限公司 | It is a kind of to exempt from spraying metal aluminium pigment and preparation method thereof with brittle performance |
| CN110330761A (en) * | 2019-07-25 | 2019-10-15 | 小熊电器股份有限公司 | One kind exempting from painted plastic and preparation method thereof |
| CN110330761B (en) * | 2019-07-25 | 2022-02-01 | 小熊电器股份有限公司 | Spraying-free plastic and preparation method thereof |
| CN110643136A (en) * | 2019-09-25 | 2020-01-03 | 广东格瑞新材料股份有限公司 | Spraying-free ABS material and preparation method thereof |
| CN111234497A (en) * | 2020-01-10 | 2020-06-05 | 金旸（厦门）新材料科技有限公司 | Cold-resistant metal texture spraying-free PC/ABS alloy for automotive interior and preparation method thereof |
| CN113462115A (en) * | 2021-06-29 | 2021-10-01 | 上海艾镇新材料有限公司 | High-weather-resistance spraying-free ABS (acrylonitrile butadiene styrene) composite material and preparation method thereof |
| CN114525010A (en) * | 2022-03-16 | 2022-05-24 | 成都金发科技新材料有限公司 | ABS composition and preparation method and application thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104845014A (en) | High-liquidity, high-heat resistance and good-surface appearance metal-like or pearlescent free-spraying ABS material and preparation method thereof | |
| CN104629165B (en) | Exempt from spraying thermoplastic resin composition and its preparation method and application with special decorative effects | |
| CN104629268B (en) | Have special decorative effects exempts from spraying polymer blend and its preparation method and application | |
| CN107987503B (en) | Spraying-free high-impact PC alloy material with metallic luster and preparation method thereof | |
| EP3789456B1 (en) | Polyamide resin composition having high metal texture and preparation method of polyamide resin composition | |
| CN104693602A (en) | High-flowability high-glossiness no-surface-defect colored metallic-pearl-effect spraying-free polypropylene automobile material and preparation method thereof | |
| CN104693603A (en) | Microcellular foaming free-spraying polypropylene material with capabilities of realizing lightweight, environmental protection and metal effect and preparation method of microcellular foaming free-spraying polypropylene material | |
| CN107541043B (en) | High glaze exempts to spray PC/ABS alloy material and preparation method thereof | |
| CN106519530B (en) | A kind of composite material and preparation method | |
| CN106084493A (en) | A kind of metal-like for automobile exterior trimming parts exempts from spray coating polypropylene composite and preparation method thereof | |
| CN110128777A (en) | Low smell heat-resistant high impact-resistant ABS material of a kind of dumb light and preparation method thereof | |
| CN103965578B (en) | Extinctive PC/ABS (Poly Carbonate/Acrylonitrile Butadiene Styrene) plastic alloy and manufacturing method thereof | |
| CN101445638A (en) | PMMA/ABS modified resin and method for forming particles thereof | |
| CN104629164B (en) | Spraying-free polyolefin composition with special aesthetic effect and a preparation method and application thereof | |
| CN113416372B (en) | Spraying-free metallic high-gloss high-weather-resistance PMMA/ASA alloy material and preparation method thereof | |
| CN107778750A (en) | A kind of weather-proof intermingling material with high brightness metal-like of damage resistant | |
| CN102964710A (en) | Antibacterial poly styrene (PS) plastic without chromatic aberration and preparation method of plastic | |
| CN102492254A (en) | Spray-free metal-effect ABS (Acrylonitrile Butadiene Styrene) modified material and preparation method thereof | |
| CN113683876A (en) | Spraying-free high-flow high-impact flame-retardant PC material with metal texture and preparation method and application thereof | |
| CN102585366A (en) | Polypropylene composition with copper-colored metal texture, and preparation method and application thereof | |
| CN104804354A (en) | Spraying-free weather-proof metal texture ASA composite and preparation method thereof | |
| CN108559178A (en) | A kind of metallic silver exempts to spray PP materials and preparation method thereof | |
| CN109503922B (en) | Preparation method of pigment functional master batch, product and application thereof | |
| CN104629300B (en) | Have special decorative effects exempts from spraying PC composition and its preparation method and application | |
| CN104629343B (en) | Exempt from spraying TPU compositions and its preparation method and application with special decorative effects |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20150819 |
|
| WD01 | Invention patent application deemed withdrawn after publication |