CN105733171A - Spray-free ABS (acrylonitrile butadiene styrene copolymers) material, spray-free ABS and ABS co-extruded decoration strip and refrigerator using decoration strip - Google Patents
Spray-free ABS (acrylonitrile butadiene styrene copolymers) material, spray-free ABS and ABS co-extruded decoration strip and refrigerator using decoration strip Download PDFInfo
- Publication number
- CN105733171A CN105733171A CN201610302326.9A CN201610302326A CN105733171A CN 105733171 A CN105733171 A CN 105733171A CN 201610302326 A CN201610302326 A CN 201610302326A CN 105733171 A CN105733171 A CN 105733171A
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- Prior art keywords
- abs
- abs material
- prepared
- panel
- exempting
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
- F25D25/00—Charging, supporting, and discharging the articles to be cooled
- F25D25/02—Charging, supporting, and discharging the articles to be cooled by shelves
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention provides a novel spray-free ABS (acrylonitrile butadiene styrene copolymers) material. The ABS material is prepared from the following raw materials: 50-100 parts of ABS, 5-30 parts of toughening auxiliaries, 0.1-3 parts of pigments, 0.5-2 parts of metal aluminium powder, 0.2-1 part of light stabilizer, 0.1-2 parts of antioxidant and 0.1-3 parts of lubricating agent. The invention further provides a decoration strip prepared from the spray-free ABS material. The decoration strip can be prepared from the spray-free ABS material and common ABS by adopting a co-extrusion process, so that the excellent effects, such as high hardness, high gloss and good light resistance, can be achieved, and meanwhile, the production cost can be effectively reduced. The decoration strip can be applied to a refrigerator and has good application effects.
Description
Technical field
The present invention relates to Material Field, be specifically related to one and exempt from spraying ABS material, described in employing, exempt from the panel that spraying ABS material is prepared from and the refrigerator applying described panel.
Background technology
Refrigerator glass shelf panel used on current refrigerator market is mainly monolayer extrusion panel, carries out on panel surface spraying, thermoprint or three kinds of processing modes of true qualities, and wherein spray piece brightness is low, and scratch resistance is poor, reduction service life；Thermoprint part brightness is high, improving product outward appearance, but hardness is low, and damage resistant is poor, and result of use is not good；True qualities part hardness is high, and scratch resistance is good, but appearance is poor, samples low.
Therefore, how from the use angle of user, appearance is good, product specification is high in exploitation, and the impact of performance is good, and the refrigerator glass shelf being user-friendly to becomes an important topic.
Summary of the invention
The first object of the present invention is in that to provide a kind of and novel exempts from spraying ABS material.
Specifically, exempt from spraying ABS material described in be prepared from by the raw material including following composition:
Preferably, exempt from spraying ABS material described in be prepared from by the raw material including following composition:
It is further preferred that described in exempt from spraying ABS material be prepared from by the raw material including following composition:
Part of the present invention refers to weight portion, it is possible to be the unit of weights well known in the art such as μ g, mg, g, kg, it is also possible to be its multiple, such as 1/10,1/100,10 times, 100 times etc..
ABS of the present invention is the abbreviation of acrylonitrile butadiene styrenecopolymer, specifically refers to the terpolymer being made up of acrylonitrile, butadiene and styrene.
One or more in PMMA, AS, MBS and MABS of toughening auxiliary agent of the present invention；It is preferably PMMA, AS and MBS to mix.When adopt PMMA, AS and MBS composition mixing toughening auxiliary agent time, described PMMA, AS and MBS weight ratio be preferably 7～8:9～10:9～10.The present invention is found by great many of experiments, adopts above-mentioned preferred toughening auxiliary agent and ABS resin to share with specific proportioning, it is possible to achieve to promote toughness of material and glossiness effect, be especially applied to intensity and be obviously improved.
In toughening auxiliary agent of the present invention, PMMA is the abbreviation of PMMA resin, refers to polymethyl methacrylate.Described AS is the abbreviation of AS resin, refers to acrylonitritrile-styrene resin, by acrylonitrile and styrene copolymerized macromolecular compound.Described MBS is the abbreviation of MBS resin, refers to methyl methacrylate, butadiene and cinnamic copolymer.Described MABS is the abbreviation of MABS resin, refers to methyl methacrylate, acrylonitrile, butadiene and cinnamic copolymer.
One or more in metallic aluminium powder, pearl essence of pigment of the present invention.The present invention can select pigment as required, to realize the appearance of product different colours.Wherein, metallic aluminium powder is used, it may be achieved the metal-like of product；Use pearlescent pigment, it may be achieved the pearl effect of product appearance.Above-mentioned pigment can individually add, it is possible to mixing is added.
Light stabilizer of the present invention is the conventional material that this area is commercially available, it can be ensured that the light resistance effect of each raw material.Specifically, can be selected for hindered amine light stabilizer.
Antioxidant of the present invention is the conventional material that this area is commercially available, it can be ensured that the antioxygenic property of product.Specifically, can be selected for resistance phenolic antioxidant and auxiliary antioxidant, it is preferred to use double; two Lauryl Alcohol esters, pentaerythritol ester, 2,6-tri-grades of butyl-4-methylphenols.
Lubricant of the present invention is the conventional material that this area is commercially available, can be selected for zinc stearate, barium stearate or Polyethylene Glycol, it is preferred to use zinc stearate or barium stearate.
The present invention is by being in optimized selection the formula exempting from spraying ABS material, it is possible to improve the performance of the aspects such as material glossiness, stretching and impact, under application conditions, it may be achieved the effect of pearly-lustre and metal-like.
Described spraying ABS material of exempting from can adopt the common process of this area to be prepared from.As a kind of preferred version, the method comprised the following steps can be adopted to be prepared from: take each raw material by formula, after being sufficiently mixed, add double screw extruder, 190～230 DEG C, screw speed 250～600 revs/min when mixing, extrusion, pelletize, to obtain final product.
The second object of the present invention exempts from spraying ABS material application in preparing panel described in being to provide.
Specifically, the invention provides one and exempt from spraying ABS panel, described panel includes bottom and covers the surface layer of described bottom surface；Described bottom is prepared from common ABS material for raw material；Described surface layer adopts spraying ABS material of exempting from of the present invention to be prepared from.
The present invention adopts common ABS material as bottom.Common ABS material is one of five big synthetic resin, has impact resistance, thermostability, lower temperature resistance, chemical proofing and excellent electrical properties, also has the features such as easy processing, product size is stable, lustrous surface property is good；Described spraying ABS material and the common ABS material exempted from is share and is prepared panel by the present invention, synergism between bi-material, it is possible to achieve the excellent effect such as high rigidity, high glaze and light resistance are good.
In order to exempt from the synergism between spraying ABS material and common ABS material described in realizing, the thickness of the preferred described surface layer of the present invention be 0～1mm, described bottom thickness be 1mm～3mm.
Panel of the present invention, with described spraying ABS material and the common ABS material exempted from for raw material, adopts coextrusion process to be prepared from.
Prepare the combination property of panel to improve coextrusion process, the particle diameter exempting from spraying ABS material of the present invention is 0.5mm～2mm；The particle diameter of described common ABS is 1mm～4mm.
Specifically, panel of the present invention is prepared from by the method comprised the following steps: be separately added into by described raw material in two different barrels of dual channel extruder, extrusion under 190～220 DEG C, preferably 200～210 DEG C of conditions, and cooling is sheared, to be obtained final product.
The present invention adopts coextrusion process to prepare panel, is undertaken preferably by the design parameter in preparation process, it is possible to improve the performance of the aspects such as panel glossiness, toughness and hardness.
The third object of the present invention is to provide the refrigerator applying described panel.In actual applications, described panel can be used for the glass shelf of fixing in refrigerator.
The invention provides a kind of Novel free spraying ABS material, use coextrusion process to exempt from spraying ABS and common ABS co-extrusion by described further, it is achieved panel exempts from spraying, metal or pearl effect, promotes panel appearance, effectively reduces production cost simultaneously；Described panel can be applicable to refrigerator, has a good application prospect.
Accompanying drawing explanation
Fig. 1 is the schematic diagram of panel described in embodiment 2；
Fig. 2 is the partial schematic diagram of glass shelf described in embodiment 3；
In figure: 1, surface layer (exempting from spraying ABS material)；2, bottom (common ABS material)；3, glass shelf.
Detailed description of the invention
Following example are used for illustrating the present invention, but are not limited to the scope of the present invention.
Embodiment 1: exempt from spraying ABS material
The present embodiment provides one to exempt from spraying ABS material, and it is prepared from by following composition:
Described exempt from spraying ABS material following method can be adopted to be prepared from: take each raw material by formula, after being sufficiently mixed add double screw extruder, 230 DEG C, screw speed 250 revs/min when mixing, extrusion, pelletize, to obtain final product.
Embodiment 2: exempt from spraying ABS material
The present embodiment provides one to exempt from spraying ABS material, and it is prepared from by following composition:
Described exempt from spraying ABS material following method can be adopted to be prepared from: take each raw material by formula, after being sufficiently mixed add double screw extruder, 190 DEG C, screw speed 600 revs/min when mixing, extrusion, pelletize, to obtain final product.
Embodiment 1 and embodiment 2 gained are exempted from spraying ABS material and are detected by the present invention, smeared after on the base material, material can be made to have good intensity and toughness.
Embodiment 3: panel
Present embodiments provide a kind of panel (as shown in Figure 1), including surface layer and bottom,
The thickness of described surface layer is 0～1mm；The thickness of described bottom is 1mm～3mm.Shown in panel by embodiment 1 or 2 provides exempt from spraying ABS material and common ABS material be raw material, employing coextrusion process be prepared from.
The concrete preparation method of described panel is: be separately added into by described raw material in two different barrels of dual channel extruder, extrudes under 200～210 DEG C of conditions, and cooling is sheared, to be obtained final product.Wherein, the particle diameter exempting from spraying ABS material described in is 0.5mm～2mm；The particle diameter of described common ABS is 1mm～4mm.
Adopting this area traditional test methods that gained panel is carried out performance detection, testing result is as shown in table 1；
Table 1: panel the performance test results
| Sequence number | Index name | Test result |
| 1 | Density g/cm3 | 1-1.8 |
| 2 | Hot strength, MPa | ≥50 |
| 3 | Impact strength, kJ/m2 | ≥20 |
| 4 | Bending times (secondary) | 1 |
| 5 | Vicat softening point, DEG C | 100-110 |
| 6 | Bending strength, MPa | ≥60 |
| 7 | Bending modulus, MPa | ≥2800 |
| 8 | Hardness, H | ≥1 |
Embodiment 4: refrigerator
Present embodiments providing a kind of refrigerator, be provided with glass shelf (as shown in Figure 2), described glass shelf adopts panel described in embodiment 3 to fix.
The application gained panel is applied to refrigerator, it can be ensured that in refrigerator glass shelf arrange stable, firm, and have aesthetic concurrently.
Although, above use generality explanation, detailed description of the invention and test, the present invention is described in detail, but on basis of the present invention, it is possible to it is made some modifications or improvements, and this will be apparent to those skilled in the art.Therefore, these modifications or improvements without departing from theon the basis of the spirit of the present invention, belong to the scope of protection of present invention.
Claims (18)
1. exempt from spraying ABS material for one kind, it is characterised in that be prepared from by the raw material including following composition:
One or more in PMMA, AS, MBS and MABS of described toughening auxiliary agent.
2. according to claim 1 exempting from sprays ABS material, it is characterised in that be prepared from by the raw material including following composition:
3. according to claim 1 exempting from sprays ABS material, it is characterised in that be prepared from by the raw material including following composition:
4. according to claims 1 to 3 any one exempting from spraying ABS material, it is characterised in that described toughening auxiliary agent be in PMMA, AS, MBS any one, two or three.
5. according to claim 4 exempting from sprays ABS material, it is characterised in that described toughening auxiliary agent is mixed with weight ratio 7～8:9～10:9～10 by PMMA, AS and MBS.
6. exempting from according to claims 1 to 3 any one sprays ABS material, it is characterised in that one or more in metallic aluminium powder, pearl essence of described pigment.
7. exempting from according to claims 1 to 3 any one sprays ABS material, it is characterised in that described light stabilizer is hindered amine light stabilizer；
Or/and, described antioxidant is resistance phenolic antioxidant and auxiliary antioxidant；
Or/and, described lubricant is zinc stearate, barium stearate or Polyethylene Glycol.
8. according to claim 7 exempting from sprays ABS material, it is characterised in that described antioxidant is double; two Lauryl Alcohol ester, pentaerythritol ester, 2,6-tri-grades of butyl-4-methylphenols；
Described lubricant is zinc stearate or barium stearate.
9. according to claim 1 exempting from sprays ABS material, it is characterised in that be prepared from by the raw material including following composition:
Or, the raw material including following composition it is prepared from:
10. the preparation method exempting from spraying ABS material described in claim 1～9 any one, it is characterized in that, comprise the steps: to take each raw material by formula, double screw extruder is added after being sufficiently mixed, 190～230 DEG C, screw speed 250～600 revs/min when mixing, extrusion, pelletize, to obtain final product.
11. exempt from spraying ABS material application in preparing panel described in claim 1～9 any one.
12. one kind is exempted from spraying ABS panel, it is characterised in that described panel includes bottom and covers the surface layer of described bottom surface；
Described bottom is prepared from common ABS material for raw material；Exempt from spraying ABS material described in described surface layer employing claim 1～9 any one to be prepared from.
13. panel according to claim 12, it is characterised in that the thickness of described surface layer is 0～1mm；The thickness of described bottom is 1mm～3mm.
14. the panel according to claim 12 or 13, it is characterised in that with described spraying ABS material and the common ABS material exempted from for raw material, adopt coextrusion process to be prepared from.
15. panel according to claim 14, it is characterised in that described in exempt from spraying ABS material particle diameter be 0.5mm～2mm；The particle diameter of described common ABS is 1mm～4mm.
16. panel according to claim 14, it is characterised in that described panel is prepared from by the method comprised the following steps: described raw material is separately added in two different barrels of dual channel extruder, extrude under 190～220 DEG C of conditions, cooling, shears, to obtain final product.
17. the refrigerator of panel described in application claim 12～16 any one.
18. refrigerator according to claim 17, it is characterised in that described panel is for fixing the glass shelf in refrigerator.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610302326.9A CN105733171B (en) | 2016-05-05 | 2016-05-05 | One kind is exempted to spray ABS material, exempts to spray ABS and ABS co-extrusions panel and its refrigerator used |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610302326.9A CN105733171B (en) | 2016-05-05 | 2016-05-05 | One kind is exempted to spray ABS material, exempts to spray ABS and ABS co-extrusions panel and its refrigerator used |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105733171A true CN105733171A (en) | 2016-07-06 |
| CN105733171B CN105733171B (en) | 2018-04-17 |
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| CN201610302326.9A Active CN105733171B (en) | 2016-05-05 | 2016-05-05 | One kind is exempted to spray ABS material, exempts to spray ABS and ABS co-extrusions panel and its refrigerator used |
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106751408A (en) * | 2016-12-27 | 2017-05-31 | 浙江普利特新材料有限公司 | A kind of high surface hardness ABS aesthetic resin composites and preparation method thereof |
| CN107146727A (en) * | 2017-06-30 | 2017-09-08 | 胡石金 | Keycap and its production method with stealthy character effect, production method application |
| CN107202466A (en) * | 2017-05-04 | 2017-09-26 | 合肥华凌股份有限公司 | Refrigerator shelf and its panel, refrigerator and panel preparation method |
| CN108641272A (en) * | 2018-05-03 | 2018-10-12 | 苏州优利金新材料有限公司 | A kind of metallic silver exempts to spray ABS material and preparation method thereof |
| CN109836764A (en) * | 2019-03-04 | 2019-06-04 | 广州科苑新型材料有限公司 | A kind of silver color is exempted to spray ABS material and the preparation method and application thereof |
| CN109971112A (en) * | 2019-03-29 | 2019-07-05 | 华中科技大学 | It is a kind of to exempt from spraying ABS composite material and preparation method suitable for FDM |
| CN110157138A (en) * | 2018-02-12 | 2019-08-23 | 合肥杰事杰新材料股份有限公司 | One kind is exempted to spray pearly-lustre ABS material and preparation method thereof |
| CN110819061A (en) * | 2019-12-06 | 2020-02-21 | 广东圆融新材料有限公司 | Easy-to-clean spraying-free ABS/PMMA alloy material and preparation method thereof |
| CN111793317A (en) * | 2020-07-27 | 2020-10-20 | 五行科技股份有限公司 | High-density spraying-free metal-like ABS (acrylonitrile butadiene styrene) composite material and preparation method thereof |
| CN114644807A (en) * | 2022-04-28 | 2022-06-21 | 长虹美菱股份有限公司 | Plant fiber modified ABS material and refrigerator decoration strip prepared from same |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106751408A (en) * | 2016-12-27 | 2017-05-31 | 浙江普利特新材料有限公司 | A kind of high surface hardness ABS aesthetic resin composites and preparation method thereof |
| CN107202466A (en) * | 2017-05-04 | 2017-09-26 | 合肥华凌股份有限公司 | Refrigerator shelf and its panel, refrigerator and panel preparation method |
| CN107146727A (en) * | 2017-06-30 | 2017-09-08 | 胡石金 | Keycap and its production method with stealthy character effect, production method application |
| CN107146727B (en) * | 2017-06-30 | 2019-10-18 | 胡石金 | The production method and production method application of keycap with stealthy character effect |
| CN110157138A (en) * | 2018-02-12 | 2019-08-23 | 合肥杰事杰新材料股份有限公司 | One kind is exempted to spray pearly-lustre ABS material and preparation method thereof |
| CN108641272A (en) * | 2018-05-03 | 2018-10-12 | 苏州优利金新材料有限公司 | A kind of metallic silver exempts to spray ABS material and preparation method thereof |
| CN109836764A (en) * | 2019-03-04 | 2019-06-04 | 广州科苑新型材料有限公司 | A kind of silver color is exempted to spray ABS material and the preparation method and application thereof |
| CN109836764B (en) * | 2019-03-04 | 2021-07-06 | 广州科苑新型材料有限公司 | Silver spraying-free ABS material and preparation method and application thereof |
| CN109971112A (en) * | 2019-03-29 | 2019-07-05 | 华中科技大学 | It is a kind of to exempt from spraying ABS composite material and preparation method suitable for FDM |
| CN110819061A (en) * | 2019-12-06 | 2020-02-21 | 广东圆融新材料有限公司 | Easy-to-clean spraying-free ABS/PMMA alloy material and preparation method thereof |
| CN111793317A (en) * | 2020-07-27 | 2020-10-20 | 五行科技股份有限公司 | High-density spraying-free metal-like ABS (acrylonitrile butadiene styrene) composite material and preparation method thereof |
| CN114644807A (en) * | 2022-04-28 | 2022-06-21 | 长虹美菱股份有限公司 | Plant fiber modified ABS material and refrigerator decoration strip prepared from same |
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