CN106279971A - A kind of high light PP factory formula exempting from spraying - Google Patents

A kind of high light PP factory formula exempting from spraying Download PDF

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Publication number
CN106279971A
CN106279971A CN201610616126.0A CN201610616126A CN106279971A CN 106279971 A CN106279971 A CN 106279971A CN 201610616126 A CN201610616126 A CN 201610616126A CN 106279971 A CN106279971 A CN 106279971A
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CN
China
Prior art keywords
liquid form
spraying
exempting
high light
toner
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610616126.0A
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Chinese (zh)
Inventor
郑豪
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Guangdong New Material Polytron Technologies Inc
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Guangdong New Material Polytron Technologies Inc
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Application filed by Guangdong New Material Polytron Technologies Inc filed Critical Guangdong New Material Polytron Technologies Inc
Priority to CN201610616126.0A priority Critical patent/CN106279971A/en
Publication of CN106279971A publication Critical patent/CN106279971A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/15Heterocyclic compounds having oxygen in the ring
    • C08K5/151Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
    • C08K5/1535Five-membered rings
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/49Phosphorus-containing compounds
    • C08K5/50Phosphorus bound to carbon only
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00Use of pretreated ingredients
    • C08K9/10Encapsulated ingredients

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Medicinal Preparation (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

The invention discloses a kind of high light PP factory formula exempting from spraying, including the component of following percentage by weight, 6~the oxolane of 9%, 0.1~the tetra-triphenylphosphine palladium of 0.3%, 1~the pearl essence of 2%, 1~the toner of 2%, 0.3~the lubricant of 0.5%, 0.3~the nucleator of 0.5%, 0.3~0.5% liquid form remove stricture of vagina brightener, 0.5~the flow ability modifying agent of liquid form of 0.8%, 0.3~the phase solvent of liquid form of 0.8%, surplus is PP powder.It is good that formula according to the present invention is directly produced the product surface specular removal fruit obtained, and forms the most even continuous print pearly-lustre bisque on the surface of product, and without flow liner, texture is strong, and it is made without the process of the surface such as oil spout or spraying, simplify production process, reduce production cost.

Description

A kind of high light PP factory formula exempting from spraying
Technical field
The present invention relates to high light PP factory formula technical field, especially relate to a kind of high light PP production exempting from spraying and join Side.
Background technology
PP is used to have the product of high light texture as the surface that main material coordinates pearl essence and toner to carry out being molded, at note Moulding in the product obtained, the major part such as pearl essence is coated on inside, and the pearl essence being apparent in product surface is uneven discontinuously, and Can form flow liner at product surface, surface tactile sensation is poor, and surface height light texture is not strong, accordingly, it would be desirable to be additionally carried out oil spout or spray Be coated with the surface such as processing to process, improve the texture on the surface of product, so can increase processing cost, complex procedures and also not environmentally, It is therefore desirable to improved.
Summary of the invention
The deficiency existed for prior art, it is an object of the invention to provide a kind of high light PP factory formula exempting from spraying, Being directly produced the product surface specular removal fruit obtained according to the formula of the present invention good, without flow liner, texture is strong, and is made without oil spout Or the surface such as spraying processes.
To achieve these goals, the technical solution adopted in the present invention is.
A kind of high light PP factory formula exempting from spraying, including the component of following percentage by weight, 6~the oxolane of 9%, 0.1~the tetra-triphenylphosphine palladium of 0.3%, 1~the pearl essence of 2%, 1~the toner of 2%, 0.3~the lubricant of 0.5%, 0.3~ The nucleator of 0.5%, 0.3~0.5% liquid form remove stricture of vagina brightener, 0.5~the flow modifier of liquid form of 0.8% Agent, 0.3~the phase solvent of liquid form of 0.8%, surplus is PP powder.
In optimal technical scheme, it is made up of the component of following percentage by weight, the oxolane of 6%, the four or three of 0.1% Phenylphosphine palladium, the pearl essence of 1%, the toner of 1%, the lubricant of 0.3%, the nucleator of 0.3%, the liquid form of 0.3% Remove stricture of vagina brightener, the flow ability modifying agent of the liquid form of 0.5%, the phase solvent of the liquid form of 0.3% and the PP powder of 90.2%.
In optimal technical scheme, it is made up of the component of following percentage by weight, the oxolane of 9%, the four or three of 0.2% Phenylphosphine palladium, the pearl essence of 2%, the toner of 1%, the lubricant of 0.5%, the nucleator of 0.5%, the liquid form of 0.5% Remove stricture of vagina brightener, the flow ability modifying agent of the liquid form of 0.8%, the phase solvent of the liquid form of 0.8% and the PP powder of 83.9%.
The present invention is the most advantageously: be directly produced the product obtained according to the formula of the present invention Specular removal fruit is good on surface, forms the most even continuous print pearly-lustre bisque on the surface of product, and without flow liner, texture is strong, and need not Carry out the surface such as oil spout or spraying to process, simplify production process, reduce production cost.
Detailed description of the invention
The following stated is only presently preferred embodiments of the present invention, the most therefore limits protection scope of the present invention.
Embodiment one
A kind of high light PP factory formula exempting from spraying, including the component of following percentage by weight, 6~the oxolane of 9%, 0.1~the tetra-triphenylphosphine palladium of 0.3%, 1~the pearl essence of 2%, 1~the toner of 2%, 0.3~the lubricant of 0.5%, 0.3~ The nucleator of 0.5%, 0.3~0.5% liquid form remove stricture of vagina brightener, 0.5~the flow modifier of liquid form of 0.8% Agent, 0.3~the phase solvent of liquid form of 0.8%, surplus is PP powder.
Embodiment two
A kind of high light PP factory formula exempting from spraying, is made up of the component of following percentage by weight, the oxolane of 6%, The tetra-triphenylphosphine palladium of 0.1%, the pearl essence of 1%, the toner of 1%, the lubricant of 0.3%, the nucleator of 0.3%, 0.3% Liquid form remove stricture of vagina brightener, the flow ability modifying agent of the liquid form of 0.5%, the phase solvent of the liquid form of 0.3% and The PP powder of 90.2%.
By the above-mentioned component blend 2 minutes of the present embodiment, modified by twin screw, twin screw modification processing temperature 170~ 200 DEG C, screw speed 260 turns, produce and obtain product material, product material re-packs test performance with, appearance color and pearl effect.Survey Examination data are: hot strength is 25MPa, and percentage elongation is 4.3%, and bending modulus is 1450Pa, and notch impact strength is 4.7GB, Apparent Gao Guang, without flow liner.
Embodiment three
A kind of high light PP factory formula exempting from spraying, is made up of the component of following percentage by weight, the oxolane of 9%, The tetra-triphenylphosphine palladium of 0.2%, the pearl essence of 2%, the toner of 1%, the lubricant of 0.5%, the nucleator of 0.5%, 0.5% Liquid form remove stricture of vagina brightener, the flow ability modifying agent of the liquid form of 0.8%, the phase solvent of the liquid form of 0.8% and The PP powder of 83.9%.
By the above-mentioned component blend 2 minutes of the present embodiment, modified by twin screw, twin screw modification processing temperature 170~ 200 DEG C, screw speed 260 turns, produce and obtain product material, product material re-packs test performance with, appearance color and pearl effect.Survey Examination data are: hot strength is 30MPa, and percentage elongation is 4.2%, and bending modulus is 1550Pa, and notch impact strength is 4.9GB, Apparent Gao Guang, without flow liner.
Above content is only presently preferred embodiments of the present invention, for those of ordinary skill in the art, according to the present invention's Thought, the most all will change, and this specification content should not be construed as the present invention Restriction.

Claims (3)

1. the high light PP factory formula exempting from spraying, it is characterised in that: include the component of following percentage by weight, 6~9% Oxolane, 0.1~the tetra-triphenylphosphine palladium of 0.3%, 1~the pearl essence of 2%, 1~the toner of 2%, 0.3~the profit of 0.5% Lubrication prescription, 0.3~the nucleator of 0.5%, 0.3~0.5% liquid form go stricture of vagina brightener, 0.5~the liquid form of 0.8% Flow ability modifying agent, 0.3~the phase solvent of liquid form of 0.8%, surplus is PP powder.
A kind of high light PP factory formula exempting from spraying the most according to claim 1, it is characterised in that: by following weight percent The component composition of ratio, the oxolane of 6%, the tetra-triphenylphosphine palladium of 0.1%, the pearl essence of 1%, the toner of 1%, 0.3% Lubricant, the nucleator of 0.3%, the liquid form of 0.3% remove stricture of vagina brightener, the flow ability modifying agent of the liquid form of 0.5%, The phase solvent of the liquid form of 0.3% and the PP powder of 90.2%.
A kind of high light PP factory formula exempting from spraying the most according to claim 1, it is characterised in that: by following weight percent The component composition of ratio, the oxolane of 9%, the tetra-triphenylphosphine palladium of 0.2%, the pearl essence of 2%, the toner of 1%, 0.5% Lubricant, the nucleator of 0.5%, the liquid form of 0.5% remove stricture of vagina brightener, the flow ability modifying agent of the liquid form of 0.8%, The phase solvent of the liquid form of 0.8% and the PP powder of 83.9%.
CN201610616126.0A 2016-07-29 2016-07-29 A kind of high light PP factory formula exempting from spraying Pending CN106279971A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610616126.0A CN106279971A (en) 2016-07-29 2016-07-29 A kind of high light PP factory formula exempting from spraying

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610616126.0A CN106279971A (en) 2016-07-29 2016-07-29 A kind of high light PP factory formula exempting from spraying

Publications (1)

Publication Number Publication Date
CN106279971A true CN106279971A (en) 2017-01-04

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109320873A (en) * 2018-09-17 2019-02-12 孔庆玲 A kind of metal effect exempts from the lamps and lanterns plastics and preparation method thereof that paint

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102516700A (en) * 2011-12-09 2012-06-27 上海锦湖日丽塑料有限公司 Appearance-improving spraying-free aesthetic resin and its preparation method
CN102585365A (en) * 2012-02-16 2012-07-18 金发科技股份有限公司 Coating-free polypropylene composition with paint brightness and metal texture and preparation method thereof
CN102942742A (en) * 2012-12-04 2013-02-27 上海日之升新技术发展有限公司 Spray coating-free propene polymer (PP) material with high gloss and metal or pearly-lustre flashing effect and preparation method thereof
CN103232640A (en) * 2013-04-27 2013-08-07 上海锦湖日丽塑料有限公司 Spraying-free aesthetic resin composition with amber effect and preparation method thereof
CN103910941A (en) * 2014-04-04 2014-07-09 金发科技股份有限公司 Spraying-free polypropylene composite with aesthetic effect, and preparation method and applications of polypropylene composite
CN103910937A (en) * 2014-04-04 2014-07-09 金发科技股份有限公司 Scratch-resistant high-gloss spraying-free polypropylene composition with aesthetic effect as well as preparation method and application of composition
CN104479229A (en) * 2014-12-17 2015-04-01 安徽科聚新材料有限公司 Spray-free baking varnish metal-like polypropylene material and preparation method thereof
CN104530569A (en) * 2015-01-30 2015-04-22 山东道恩高分子材料股份有限公司 Environment-friendly high-glossiness colorful polypropylene material and manufacturing method thereof

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102516700A (en) * 2011-12-09 2012-06-27 上海锦湖日丽塑料有限公司 Appearance-improving spraying-free aesthetic resin and its preparation method
CN102585365A (en) * 2012-02-16 2012-07-18 金发科技股份有限公司 Coating-free polypropylene composition with paint brightness and metal texture and preparation method thereof
CN102942742A (en) * 2012-12-04 2013-02-27 上海日之升新技术发展有限公司 Spray coating-free propene polymer (PP) material with high gloss and metal or pearly-lustre flashing effect and preparation method thereof
CN103232640A (en) * 2013-04-27 2013-08-07 上海锦湖日丽塑料有限公司 Spraying-free aesthetic resin composition with amber effect and preparation method thereof
CN103910941A (en) * 2014-04-04 2014-07-09 金发科技股份有限公司 Spraying-free polypropylene composite with aesthetic effect, and preparation method and applications of polypropylene composite
CN103910937A (en) * 2014-04-04 2014-07-09 金发科技股份有限公司 Scratch-resistant high-gloss spraying-free polypropylene composition with aesthetic effect as well as preparation method and application of composition
CN104479229A (en) * 2014-12-17 2015-04-01 安徽科聚新材料有限公司 Spray-free baking varnish metal-like polypropylene material and preparation method thereof
CN104530569A (en) * 2015-01-30 2015-04-22 山东道恩高分子材料股份有限公司 Environment-friendly high-glossiness colorful polypropylene material and manufacturing method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109320873A (en) * 2018-09-17 2019-02-12 孔庆玲 A kind of metal effect exempts from the lamps and lanterns plastics and preparation method thereof that paint

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Application publication date: 20170104

RJ01 Rejection of invention patent application after publication