CN106279971A - A kind of high light PP factory formula exempting from spraying - Google Patents
A kind of high light PP factory formula exempting from spraying Download PDFInfo
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- CN106279971A CN106279971A CN201610616126.0A CN201610616126A CN106279971A CN 106279971 A CN106279971 A CN 106279971A CN 201610616126 A CN201610616126 A CN 201610616126A CN 106279971 A CN106279971 A CN 106279971A
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- liquid form
- spraying
- exempting
- high light
- toner
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/15—Heterocyclic compounds having oxygen in the ring
- C08K5/151—Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
- C08K5/1535—Five-membered rings
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/50—Phosphorus bound to carbon only
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/10—Encapsulated ingredients
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Medicinal Preparation (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
The invention discloses a kind of high light PP factory formula exempting from spraying, including the component of following percentage by weight, 6~the oxolane of 9%, 0.1~the tetra-triphenylphosphine palladium of 0.3%, 1~the pearl essence of 2%, 1~the toner of 2%, 0.3~the lubricant of 0.5%, 0.3~the nucleator of 0.5%, 0.3~0.5% liquid form remove stricture of vagina brightener, 0.5~the flow ability modifying agent of liquid form of 0.8%, 0.3~the phase solvent of liquid form of 0.8%, surplus is PP powder.It is good that formula according to the present invention is directly produced the product surface specular removal fruit obtained, and forms the most even continuous print pearly-lustre bisque on the surface of product, and without flow liner, texture is strong, and it is made without the process of the surface such as oil spout or spraying, simplify production process, reduce production cost.
Description
Technical field
The present invention relates to high light PP factory formula technical field, especially relate to a kind of high light PP production exempting from spraying and join
Side.
Background technology
PP is used to have the product of high light texture as the surface that main material coordinates pearl essence and toner to carry out being molded, at note
Moulding in the product obtained, the major part such as pearl essence is coated on inside, and the pearl essence being apparent in product surface is uneven discontinuously, and
Can form flow liner at product surface, surface tactile sensation is poor, and surface height light texture is not strong, accordingly, it would be desirable to be additionally carried out oil spout or spray
Be coated with the surface such as processing to process, improve the texture on the surface of product, so can increase processing cost, complex procedures and also not environmentally,
It is therefore desirable to improved.
Summary of the invention
The deficiency existed for prior art, it is an object of the invention to provide a kind of high light PP factory formula exempting from spraying,
Being directly produced the product surface specular removal fruit obtained according to the formula of the present invention good, without flow liner, texture is strong, and is made without oil spout
Or the surface such as spraying processes.
To achieve these goals, the technical solution adopted in the present invention is.
A kind of high light PP factory formula exempting from spraying, including the component of following percentage by weight, 6~the oxolane of 9%,
0.1~the tetra-triphenylphosphine palladium of 0.3%, 1~the pearl essence of 2%, 1~the toner of 2%, 0.3~the lubricant of 0.5%, 0.3~
The nucleator of 0.5%, 0.3~0.5% liquid form remove stricture of vagina brightener, 0.5~the flow modifier of liquid form of 0.8%
Agent, 0.3~the phase solvent of liquid form of 0.8%, surplus is PP powder.
In optimal technical scheme, it is made up of the component of following percentage by weight, the oxolane of 6%, the four or three of 0.1%
Phenylphosphine palladium, the pearl essence of 1%, the toner of 1%, the lubricant of 0.3%, the nucleator of 0.3%, the liquid form of 0.3%
Remove stricture of vagina brightener, the flow ability modifying agent of the liquid form of 0.5%, the phase solvent of the liquid form of 0.3% and the PP powder of 90.2%.
In optimal technical scheme, it is made up of the component of following percentage by weight, the oxolane of 9%, the four or three of 0.2%
Phenylphosphine palladium, the pearl essence of 2%, the toner of 1%, the lubricant of 0.5%, the nucleator of 0.5%, the liquid form of 0.5%
Remove stricture of vagina brightener, the flow ability modifying agent of the liquid form of 0.8%, the phase solvent of the liquid form of 0.8% and the PP powder of 83.9%.
The present invention is the most advantageously: be directly produced the product obtained according to the formula of the present invention
Specular removal fruit is good on surface, forms the most even continuous print pearly-lustre bisque on the surface of product, and without flow liner, texture is strong, and need not
Carry out the surface such as oil spout or spraying to process, simplify production process, reduce production cost.
Detailed description of the invention
The following stated is only presently preferred embodiments of the present invention, the most therefore limits protection scope of the present invention.
Embodiment one
A kind of high light PP factory formula exempting from spraying, including the component of following percentage by weight, 6~the oxolane of 9%,
0.1~the tetra-triphenylphosphine palladium of 0.3%, 1~the pearl essence of 2%, 1~the toner of 2%, 0.3~the lubricant of 0.5%, 0.3~
The nucleator of 0.5%, 0.3~0.5% liquid form remove stricture of vagina brightener, 0.5~the flow modifier of liquid form of 0.8%
Agent, 0.3~the phase solvent of liquid form of 0.8%, surplus is PP powder.
Embodiment two
A kind of high light PP factory formula exempting from spraying, is made up of the component of following percentage by weight, the oxolane of 6%,
The tetra-triphenylphosphine palladium of 0.1%, the pearl essence of 1%, the toner of 1%, the lubricant of 0.3%, the nucleator of 0.3%, 0.3%
Liquid form remove stricture of vagina brightener, the flow ability modifying agent of the liquid form of 0.5%, the phase solvent of the liquid form of 0.3% and
The PP powder of 90.2%.
By the above-mentioned component blend 2 minutes of the present embodiment, modified by twin screw, twin screw modification processing temperature 170~
200 DEG C, screw speed 260 turns, produce and obtain product material, product material re-packs test performance with, appearance color and pearl effect.Survey
Examination data are: hot strength is 25MPa, and percentage elongation is 4.3%, and bending modulus is 1450Pa, and notch impact strength is 4.7GB,
Apparent Gao Guang, without flow liner.
Embodiment three
A kind of high light PP factory formula exempting from spraying, is made up of the component of following percentage by weight, the oxolane of 9%,
The tetra-triphenylphosphine palladium of 0.2%, the pearl essence of 2%, the toner of 1%, the lubricant of 0.5%, the nucleator of 0.5%, 0.5%
Liquid form remove stricture of vagina brightener, the flow ability modifying agent of the liquid form of 0.8%, the phase solvent of the liquid form of 0.8% and
The PP powder of 83.9%.
By the above-mentioned component blend 2 minutes of the present embodiment, modified by twin screw, twin screw modification processing temperature 170~
200 DEG C, screw speed 260 turns, produce and obtain product material, product material re-packs test performance with, appearance color and pearl effect.Survey
Examination data are: hot strength is 30MPa, and percentage elongation is 4.2%, and bending modulus is 1550Pa, and notch impact strength is 4.9GB,
Apparent Gao Guang, without flow liner.
Above content is only presently preferred embodiments of the present invention, for those of ordinary skill in the art, according to the present invention's
Thought, the most all will change, and this specification content should not be construed as the present invention
Restriction.
Claims (3)
1. the high light PP factory formula exempting from spraying, it is characterised in that: include the component of following percentage by weight, 6~9%
Oxolane, 0.1~the tetra-triphenylphosphine palladium of 0.3%, 1~the pearl essence of 2%, 1~the toner of 2%, 0.3~the profit of 0.5%
Lubrication prescription, 0.3~the nucleator of 0.5%, 0.3~0.5% liquid form go stricture of vagina brightener, 0.5~the liquid form of 0.8%
Flow ability modifying agent, 0.3~the phase solvent of liquid form of 0.8%, surplus is PP powder.
A kind of high light PP factory formula exempting from spraying the most according to claim 1, it is characterised in that: by following weight percent
The component composition of ratio, the oxolane of 6%, the tetra-triphenylphosphine palladium of 0.1%, the pearl essence of 1%, the toner of 1%, 0.3%
Lubricant, the nucleator of 0.3%, the liquid form of 0.3% remove stricture of vagina brightener, the flow ability modifying agent of the liquid form of 0.5%,
The phase solvent of the liquid form of 0.3% and the PP powder of 90.2%.
A kind of high light PP factory formula exempting from spraying the most according to claim 1, it is characterised in that: by following weight percent
The component composition of ratio, the oxolane of 9%, the tetra-triphenylphosphine palladium of 0.2%, the pearl essence of 2%, the toner of 1%, 0.5%
Lubricant, the nucleator of 0.5%, the liquid form of 0.5% remove stricture of vagina brightener, the flow ability modifying agent of the liquid form of 0.8%,
The phase solvent of the liquid form of 0.8% and the PP powder of 83.9%.
Priority Applications (1)
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CN201610616126.0A CN106279971A (en) | 2016-07-29 | 2016-07-29 | A kind of high light PP factory formula exempting from spraying |
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CN201610616126.0A CN106279971A (en) | 2016-07-29 | 2016-07-29 | A kind of high light PP factory formula exempting from spraying |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109320873A (en) * | 2018-09-17 | 2019-02-12 | 孔庆玲 | A kind of metal effect exempts from the lamps and lanterns plastics and preparation method thereof that paint |
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CN102585365A (en) * | 2012-02-16 | 2012-07-18 | 金发科技股份有限公司 | Coating-free polypropylene composition with paint brightness and metal texture and preparation method thereof |
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CN103232640A (en) * | 2013-04-27 | 2013-08-07 | 上海锦湖日丽塑料有限公司 | Spraying-free aesthetic resin composition with amber effect and preparation method thereof |
CN103910941A (en) * | 2014-04-04 | 2014-07-09 | 金发科技股份有限公司 | Spraying-free polypropylene composite with aesthetic effect, and preparation method and applications of polypropylene composite |
CN103910937A (en) * | 2014-04-04 | 2014-07-09 | 金发科技股份有限公司 | Scratch-resistant high-gloss spraying-free polypropylene composition with aesthetic effect as well as preparation method and application of composition |
CN104479229A (en) * | 2014-12-17 | 2015-04-01 | 安徽科聚新材料有限公司 | Spray-free baking varnish metal-like polypropylene material and preparation method thereof |
CN104530569A (en) * | 2015-01-30 | 2015-04-22 | 山东道恩高分子材料股份有限公司 | Environment-friendly high-glossiness colorful polypropylene material and manufacturing method thereof |
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2016
- 2016-07-29 CN CN201610616126.0A patent/CN106279971A/en active Pending
Patent Citations (8)
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CN102516700A (en) * | 2011-12-09 | 2012-06-27 | 上海锦湖日丽塑料有限公司 | Appearance-improving spraying-free aesthetic resin and its preparation method |
CN102585365A (en) * | 2012-02-16 | 2012-07-18 | 金发科技股份有限公司 | Coating-free polypropylene composition with paint brightness and metal texture and preparation method thereof |
CN102942742A (en) * | 2012-12-04 | 2013-02-27 | 上海日之升新技术发展有限公司 | Spray coating-free propene polymer (PP) material with high gloss and metal or pearly-lustre flashing effect and preparation method thereof |
CN103232640A (en) * | 2013-04-27 | 2013-08-07 | 上海锦湖日丽塑料有限公司 | Spraying-free aesthetic resin composition with amber effect and preparation method thereof |
CN103910941A (en) * | 2014-04-04 | 2014-07-09 | 金发科技股份有限公司 | Spraying-free polypropylene composite with aesthetic effect, and preparation method and applications of polypropylene composite |
CN103910937A (en) * | 2014-04-04 | 2014-07-09 | 金发科技股份有限公司 | Scratch-resistant high-gloss spraying-free polypropylene composition with aesthetic effect as well as preparation method and application of composition |
CN104479229A (en) * | 2014-12-17 | 2015-04-01 | 安徽科聚新材料有限公司 | Spray-free baking varnish metal-like polypropylene material and preparation method thereof |
CN104530569A (en) * | 2015-01-30 | 2015-04-22 | 山东道恩高分子材料股份有限公司 | Environment-friendly high-glossiness colorful polypropylene material and manufacturing method thereof |
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CN109320873A (en) * | 2018-09-17 | 2019-02-12 | 孔庆玲 | A kind of metal effect exempts from the lamps and lanterns plastics and preparation method thereof that paint |
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Application publication date: 20170104 |
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