CN103756238A - Enhanced ABS (Acrylonitrile Butadiene Styrene)/PMMA (Polymethyl Methacrylate) alloy material - Google Patents
Enhanced ABS (Acrylonitrile Butadiene Styrene)/PMMA (Polymethyl Methacrylate) alloy material Download PDFInfo
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- CN103756238A CN103756238A CN201310732276.4A CN201310732276A CN103756238A CN 103756238 A CN103756238 A CN 103756238A CN 201310732276 A CN201310732276 A CN 201310732276A CN 103756238 A CN103756238 A CN 103756238A
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Abstract
The invention relates to an enhanced ABS (Acrylonitrile Butadiene Styrene)/PMMA (Polymethyl Methacrylate) alloy material, belonging to the technical field of high polymer materials. The enhanced ABS/PMMA alloy material comprises the following components in parts by weight: 80 to 100 parts of ABS, 60 to 80 parts of PMMA, 5 to 10 parts of aramid fiber, 1 to 2 parts of pearl powder, 2 to 4 parts of an ultraviolet light absorber UV-234, 1 to 2 parts of sebacic di(2,2,6,6-tetramethyl-4-piperidine) ester, 0.4 to 3 parts of an antioxidant, 0.2 to 0.8 part of a lubricant, and 0.5 to 2 parts of a compatilizer. According to the enhanced ABS/PMMA alloy material, the ABS is modified through PMMA and aramid fiber, and thus the prepared enhanced ABS/PMMA alloy material is high in mechanical property and dimensional stability, and outstanding in surface gloss, surface hardness and light stability, and does not easily tarnish; in addition, pearl powder added to the raw material further improves the surface gloss of the ABS/PMMA alloy material, and the applicable scope of the enhanced ABS/PMMA alloy material is expanded.
Description
Technical field
The invention belongs to technical field of polymer materials, be specifically related to a kind of reinforced ABS/PMMA alloy material.
Background technology
ABS resin is one of five large synthetic resins, its shock resistance, thermotolerance, lower temperature resistance, chemical proofing and excellent electrical properties, also there is the features such as easy processing, product size is stable, surface luster property is good, easily application, painted, can also carry out surperficial spraymetal, plating, welding, hot pressing and the secondary processing such as bonding, being widely used in the industrial circles such as machinery, automobile, electronic apparatus, instrument, weaving and building, is the thermoplastic engineering plastic that a kind of purposes is extremely wide.
The switch panel of producing at present mainly adopts ABS resin to make, but it exists surface gloss and the lower shortcoming of surface hardness, and easily variable color, and therefore how overcoming the deficiencies in the prior art is problems that current technical field of polymer materials is needed solution badly.
Summary of the invention
The object of the invention is in order to solve the deficiencies in the prior art, a kind of reinforced ABS/PMMA alloy material is provided, this alloy material has good surface gloss and surface hardness, and stability is better.
The technical solution used in the present invention is as follows:
A kind of reinforced ABS/PMMA alloy material, comprise the following component according to parts by weight meter: ABS80 ~ 100 part, PMMA60 ~ 80 part, 5 ~ 10 parts of aramid fibers, 1 ~ 2 part of pearlescence, 2 ~ 4 parts of UV light absorber UV-234, sebacic acid two (2,2,6,6-tetramethyl--4-piperidines) 1 ~ 2 part of ester, 0.4 ~ 3 part, oxidation inhibitor, 0.2 ~ 0.8 part of lubricant, 0.5 ~ 2 part of compatilizer.
Further preferably described oxidation inhibitor is the mixture that antioxidant 1076 and irgasfos 168 mass ratio are 3:1 ~ 1:5.
Further preferably described lubricant is methylene-bis stearylamide.
Further preferably described compatilizer is ethylene-acrylate-GMA multipolymer.
The preparation method of above-mentioned reinforced ABS/PMMA alloy material is by ABS, PMMA, aramid fiber, pearlescence, UV light absorber UV-234, sebacic acid two (2,2,6,6-tetramethyl--4-piperidines) ester, oxidation inhibitor, lubricant put into high-speed mixer high-speed stirring together with compatilizer, after mixing, through twin screw extruder, melt extrude granulation, obtain reinforced ABS/PMMA alloy material of the present invention.
compared with prior art, its beneficial effect is in the present invention:(1) the present invention adopts PMMA and aramid fiber to carry out modified ABS, and the product making not only has good mechanical property and dimensional stability, also has good surface gloss and surface hardness, easily machine-shaping; (2) product of the present invention has good light stability, not easy to change, meanwhile, adds pearlescence in raw material, has further strengthened the surface gloss of ABS/PMMA alloy material; (3) application range of products of the present invention is wider, not only can, for the manufacture of switch panel, also can be used for the fields such as machinery, building.
Specific embodiment
Below in conjunction with embodiment, the present invention is described in further detail.
Embodiment 1
A kind of reinforced ABS/PMMA alloy material, comprise the following component according to parts by weight meter: ABS80 part, PMMA60 part, 5 parts of aramid fibers, 1 part of pearlescence, 2 parts of UV light absorber UV-234, sebacic acid two (2,2,6,6-tetramethyl--4-piperidines) 1 part of ester, 0.3 part of antioxidant 1076,0.1 part of irgasfos 168,0.2 part of methylene-bis stearylamide, 0.5 part of ethylene-acrylate-GMA multipolymer.
The preparation method of the present embodiment reinforced ABS/PMMA alloy material is by ABS, PMMA, aramid fiber, pearlescence, UV light absorber UV-234, sebacic acid two (2,2,6,6-tetramethyl--4-piperidines) ester, irgasfos 168, methylene-bis stearylamide put into high-speed mixer high-speed stirring together with ethylene-acrylate-GMA multipolymer, after mixing, through twin screw extruder, melt extrude granulation, obtain reinforced ABS/PMMA alloy material of the present embodiment.
Embodiment 2
A kind of reinforced ABS/PMMA alloy material, comprise the following component according to parts by weight meter: ABS100 part, PMMA80 part, 10 parts of aramid fibers, 2 parts of pearlescences, 4 parts of UV light absorber UV-234, sebacic acid two (2,2,6,6-tetramethyl--4-piperidines) 2 parts of esters, 0.5 part of antioxidant 1076,2.5 parts of irgasfos 168s, 0.8 part of methylene-bis stearylamide, 2 parts of ethylene-acrylate-GMA multipolymers.
The preparation method of the present embodiment reinforced ABS/PMMA alloy material is identical with the preparation method of embodiment 1.
Embodiment 3
A kind of reinforced ABS/PMMA alloy material, comprise the following component according to parts by weight meter: ABS93 part, PMMA67 part, 7 parts of aramid fibers, 1.2 parts of pearlescences, 3 parts of UV light absorber UV-234, sebacic acid two (2,2,6,6-tetramethyl--4-piperidines) 1.6 parts of esters, 1 part of antioxidant 1076,1 part of irgasfos 168,0.5 part of methylene-bis stearylamide, ethylene-acrylate-GMA copolymer 1 part.
The preparation method of the present embodiment reinforced ABS/PMMA alloy material is identical with the preparation method of embodiment 1.
To the performance test of the embodiment of the present invention 1 ~ 3 products obtained therefrom, result is as shown in table 1.
Table 1 embodiment of the present invention 1 ~ 3 product performance test data
Claims (4)
1. reinforced ABS/PMMA alloy material, it is characterized in that comprising the following component according to parts by weight meter: ABS80 ~ 100 part, PMMA60 ~ 80 part, 5 ~ 10 parts of aramid fibers, 1 ~ 2 part of pearlescence, 2 ~ 4 parts of UV light absorber UV-234, sebacic acid two (2,2,6,6-tetramethyl--4-piperidines) 1 ~ 2 part of ester, 0.4 ~ 3 part, oxidation inhibitor, 0.2 ~ 0.8 part of lubricant, 0.5 ~ 2 part of compatilizer.
2. reinforced ABS/PMMA alloy material according to claim 1, is characterized in that described oxidation inhibitor is the mixture that antioxidant 1076 and irgasfos 168 mass ratio are 3:1 ~ 1:5.
3. reinforced ABS/PMMA alloy material according to claim 1, is characterized in that described lubricant is methylene-bis stearylamide.
4. reinforced ABS/PMMA alloy material according to claim 1, is characterized in that described compatilizer is ethylene-acrylate-GMA multipolymer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310732276.4A CN103756238A (en) | 2013-12-27 | 2013-12-27 | Enhanced ABS (Acrylonitrile Butadiene Styrene)/PMMA (Polymethyl Methacrylate) alloy material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310732276.4A CN103756238A (en) | 2013-12-27 | 2013-12-27 | Enhanced ABS (Acrylonitrile Butadiene Styrene)/PMMA (Polymethyl Methacrylate) alloy material |
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| CN103756238A true CN103756238A (en) | 2014-04-30 |
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| CN201310732276.4A Withdrawn CN103756238A (en) | 2013-12-27 | 2013-12-27 | Enhanced ABS (Acrylonitrile Butadiene Styrene)/PMMA (Polymethyl Methacrylate) alloy material |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105419203A (en) * | 2015-12-21 | 2016-03-23 | 上海锦湖日丽塑料有限公司 | Gasoline-resistant toughening PMMA resin and preparation method therefor |
| CN108623963A (en) * | 2017-03-26 | 2018-10-09 | 合肥杰事杰新材料股份有限公司 | A kind of intellectual water closet PP Pipe Compound ABS/PMMA alloy materials and preparation method thereof |
| CN109294222A (en) * | 2018-09-20 | 2019-02-01 | 安徽江淮汽车集团股份有限公司 | A kind of PA6-PMMA composite material and preparation method |
| CN111234443A (en) * | 2020-01-20 | 2020-06-05 | 上海锦湖日丽塑料有限公司 | Yellowing-resistant PMMA/ABS spraying-free resin and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102492255A (en) * | 2011-12-05 | 2012-06-13 | 四川长虹电器股份有限公司 | ABS/PMMA (Acrylonitrile Butadiene Styrene/Polymethyl Methacrylate) composite material and preparation method thereof |
| CN103435950A (en) * | 2012-12-20 | 2013-12-11 | 安徽科聚新材料有限公司 | PMMA/ABS composite material, and preparation method and application thereof |
-
2013
- 2013-12-27 CN CN201310732276.4A patent/CN103756238A/en not_active Withdrawn
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102492255A (en) * | 2011-12-05 | 2012-06-13 | 四川长虹电器股份有限公司 | ABS/PMMA (Acrylonitrile Butadiene Styrene/Polymethyl Methacrylate) composite material and preparation method thereof |
| CN103435950A (en) * | 2012-12-20 | 2013-12-11 | 安徽科聚新材料有限公司 | PMMA/ABS composite material, and preparation method and application thereof |
Non-Patent Citations (1)
| Title |
|---|
| 夏英等: "芳纶1414增强ABS复合材料的性能研究", 《塑料科技》, vol. 39, no. 1, 31 January 2011 (2011-01-31), pages 51 - 53 * |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105419203A (en) * | 2015-12-21 | 2016-03-23 | 上海锦湖日丽塑料有限公司 | Gasoline-resistant toughening PMMA resin and preparation method therefor |
| CN105419203B (en) * | 2015-12-21 | 2018-05-04 | 上海锦湖日丽塑料有限公司 | A kind of toughened polymethyl methacrylate (PMMA) of resistance to gasoline resin and preparation method thereof |
| CN108623963A (en) * | 2017-03-26 | 2018-10-09 | 合肥杰事杰新材料股份有限公司 | A kind of intellectual water closet PP Pipe Compound ABS/PMMA alloy materials and preparation method thereof |
| CN108623963B (en) * | 2017-03-26 | 2022-03-11 | 合肥杰事杰新材料股份有限公司 | ABS/PMMA alloy material special for intelligent toilet and preparation method thereof |
| CN109294222A (en) * | 2018-09-20 | 2019-02-01 | 安徽江淮汽车集团股份有限公司 | A kind of PA6-PMMA composite material and preparation method |
| CN111234443A (en) * | 2020-01-20 | 2020-06-05 | 上海锦湖日丽塑料有限公司 | Yellowing-resistant PMMA/ABS spraying-free resin and preparation method thereof |
| CN111234443B (en) * | 2020-01-20 | 2022-09-20 | 上海锦湖日丽塑料有限公司 | Yellowing-resistant PMMA/ABS spraying-free resin and preparation method thereof |
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Application publication date: 20140430 |