CN103087456A - Heat resistance ABS material and preparation method thereof - Google Patents

Heat resistance ABS material and preparation method thereof Download PDF

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Publication number
CN103087456A
CN103087456A CN2011103351491A CN201110335149A CN103087456A CN 103087456 A CN103087456 A CN 103087456A CN 2011103351491 A CN2011103351491 A CN 2011103351491A CN 201110335149 A CN201110335149 A CN 201110335149A CN 103087456 A CN103087456 A CN 103087456A
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parts
abs
styrene
heat
butadiene
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杨俊�
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Hefei Genius New Materials Co Ltd
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Hefei Genius New Materials Co Ltd
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Abstract

The invention belongs to the technical field of polymer material modification, and discloses a heat resistance ABS material and a preparation method thereof. The heat resistance ABS material comprises the following components, by weight, 500-900 parts of an ABS resin, 100-400 parts of a polyphenylene ether resin, 0-150 parts of a compatibilizing agent, 0-250 parts of a toughening agent, 1-10 parts of a lubricant and 3-10 parts of an antioxidant. The preparation method comprises: adding 500-900 parts by weight of an ABS resin, 100-400 parts by weight of a polyphenylene ether resin, 0-150 parts by weight of a compatibilizing agent, 0-250 parts by weight of a toughening agent, 1-10 parts by weight of a lubricant and 3-10 parts by weight of an antioxidant to a high speed mixer to uniformly mix for 5-20 min; conveying the uniformly-mixed materials into a twin-screw extruder through a precise measurement material conveying device; carrying out complete fusion on the materials under screw shearing, mixing and conveying; and carrying out extrusion, strip drawing, and cooling to prepare the particle material. The heat resistance ABS has characteristics of high heat resistance, excellent mechanical property, good processability and good coloring.

Description

A kind of heat-proof ABS material and preparation method thereof
Technical field
The invention belongs to the polymer modification technical field, relate to a kind of heat-proof ABS material and preparation method thereof.
Background technology
Acrylonitrile-butadiene-styrene terpolymer (ABS) is a kind of common resins for universal use.ABS has high tenacity, easily electroplates painted, easy processing, and its over-all properties is good, is widely used in the industries such as automobile, electronic apparatus, military project, machinery.Along with the development of modern science and technology technology, the demand of ABS is also being increased fast, present ABS output comes the 5th of resin yield.
The heat-drawn wire of regular grade ABS is at 70~80 ℃, and thermotolerance is bad, life-time service at high temperature, thereby limited its use range.The heat resistance modified method of ABS comprises following several at present: the monomer of 1) introducing high rigidity in the ABS structure, as alpha-methyl styrene etc., heat-drawn wire is brought up to more than 100 ℃, but reduced mobility and shock strength, surface gloss reduces.2) use the heat-resistant copolymer blend, as maleic anhydride-styrene copolymers, maleimide copolymer, N-phenylmaleimide multipolymer etc., can significantly improve heat resisting temperature, and the add-on of regulation and control multipolymer can obtain the heat resistant product of different stage, but just is difficult to improve after it reaches certain temperature classification again.3) alloying, generally polycarbonate commonly used, polymeric amide, polyester polymer, can prepare the ABS alloy that height is heat-resisting, mechanical property is excellent.
Polyphenylene oxide is one of five large-engineering plastics, and simple polyphenylene oxide is because its relatively poor mobility is difficult to process, do not have practicality.The polyphenylene oxide that now uses is all alloying products, and for example modal is polyphenyl ether/styrene (PS) alloy, is the system of dissolving each other fully.Because polyphenylene oxide has good physical and mechanical property, excellent high temperature resistant and anti-creep properties, therefore can improve thermotolerance and the creep property of ABS with the ABS alloying.At present patent and the document about polyphenyl ether modified ABS aspect also seldom sees report, also there is no large-scale industrialization, uses polyphenyl ether modified ABS to have undoubtedly wide development space.
Summary of the invention
For the defective of prior art, the purpose of this invention is to provide a kind of heat-proof ABS material, the ABS material that obtains has high heat resistance and excellent mechanical property, and good stability of the dimension is easy to the characteristics such as forming process.
Another object of the present invention is to provide a kind of above-mentioned ABS material preparation method, has raw material sources characteristics wide, easy and simple to handle.
Technical scheme of the present invention is as follows:
The invention provides a kind of heat-proof ABS material, this ABS material is made by the component that comprises following parts by weight:
500~900 parts of ABS resinoids,
100~400 parts of polyphenylene oxide resinoids,
0~150 part of compatilizer,
0~250 part of toughner,
1~10 part of lubricant,
3~10 parts, oxidation inhibitor.
Described ABS resinoid is selected from one or more the material in acrylonitrile-butadiene-styrene copolymer (ABS), acrylonitritrile-styrene resin (AS) or acrylonitrile-styrene-acrylic ester terpolymer (ASA).
Described polyphenylene oxide resinoid is selected from one or more the material in polyphenylene oxide (PPE), polystyrene or Modification of High-impact Polystyrene polyphenylene oxide (mPPO).
described compatilizer is selected from maleic anhydride grafted acrylonitrile-butadiene-styrene copolymer (ABS-g-mah), maleic anhydride grafted polystyrene (PS-g-mah), maleic anhydride graft styrene-butadiene-styrene (SBS-g-mah), maleic anhydride graft hydrogenated styrene-butadiene-styrene multipolymer (SEBS-g-mah), the material of one or more in glycidyl methacrylate graft hydrogenated styrene-butadiene-styrene multipolymer (SEBE-g-gma) or maleic anhydride-styrene copolymers (SMA).
Described toughner is selected from one or more the material in high-impact polystyrene (HIPS), ABS high glue powder, styrene-butadiene-styrene (SBS), hydrogenated styrene-butadiene-styrene multipolymer (SEBS); Wherein: the ABS high glue powder is that a kind of rubber content is 55~75% ABS powder.
Described lubricant is selected from N, the material of one or more in N '-ethylene bis stearamide (EBS), stearic acid, Zinic stearas, calcium stearate, Magnesium Stearate, polyethylene wax, clorafin or methyl-silicone oil.
Described oxidation inhibitor is selected from β-(3,5-di-t-butyl hydroxy phenyl) vinylformic acid ten caprylates (antioxidant 1076), three-(2, the 4-tert-butyl-phenyl) phosphorous acid ester (irgasfos 168) or 3,9-two [1,1-dimethyl-2-[(3-tertiary butyl-4-hydroxy-5-aminomethyl phenyl) propionyloxy] ethyl]-2, the material of one or more in 4,8,10-, four oxaspiros [5.5] undecane (oxidation inhibitor AO80).
The present invention also provides a kind of above-mentioned heat-proof ABS material preparation method, and the method comprises the following steps:
With the polyphenylene oxide resinoid of the ABS resinoid of 500~900 parts of dryings, 100~400 parts of dryings, 0~150 part of compatilizer, 0~250 part of toughner, 1~10 part of lubricant and 3~10 parts of oxidation inhibitor, add in high-speed mixer to mix mixing time 5~20min; By the pay-off of delicate metering, the material that mixes is sent in twin screw extruder, material the shearing of screw rod, mixing and carry under fusion fully, extrude finally by crossing, tie rod, cooling after, make pellet.
The ABS resinoid of described drying is to dry 2~4h under 90~120 ℃.
The polyphenylene oxide resinoid of described drying is to dry 3~4h under 100~140 ℃.
The length-to-diameter ratio of described twin screw extruder is 20~60: 1, and with the twin screw extruder of accurate temperature control and vacuum-pumping equipment, each temperature setting of distinguishing of screw rod is set to 210~280 ℃.
The present invention compares with prior art, has the following advantages and beneficial effect:
Heat-proof ABS material provided by the present invention has superior thermotolerance, and mechanical property is excellent, be easy to painted, processing, and cost is lower, is suitable for the fields such as the interior exterior trim of notebook computer shell, electric appliance housing and automobile.
Embodiment
The present invention is further illustrated below in conjunction with embodiment.
Embodiment 1
Press the row weight part and take each component raw material:
880 parts of ABS (Zhenjiang is very beautiful, PA757,95 ℃ of Vicat softening points),
100 parts of PPE (blue star, LXR 040),
20 parts of compatilizer SEBS-g-mah (light of energy, 5601),
5 parts of oxidation inhibitor AO80,
1 part of Lubricate EBS.
(1) ABS is dried 3h under 100 ℃, PPE is dried 3h under 130 ℃;
The ABS of (2) step (1) being dried and PPE add with compatilizer, oxidation inhibitor, lubricant and mix 5min in high-speed mixer;
(3) material that mixes in step (2) is sent in twin screw extruder by the pay-off of delicate metering, material the shearing of screw rod, mixing and carry under fusion fully, extrude finally by crossing, tie rod, cooling after, make pellet.Wherein the twin screw extruder length-to-diameter ratio is 40: 1, and with the twin screw extruder of accurate temperature control and vacuum-pumping equipment, each section Temperature Setting is at 220~250 ℃.Prepared heat-proof ABS performance is as shown in table 1.
Embodiment 2
Press the row weight part and take each component raw material:
700 parts of ABS (Zhenjiang is very beautiful, PA757,95 ℃ of Vicat softening points),
230 parts of mPPO (husky uncle is basic, SE1X-701, HIPS modification),
Toughner SBS (the Ba Ling petrochemical industry, YH-805) 70 parts,
3 parts of irgasfos 168s,
3 parts of Lubricate EBSs.
(1) ABS that selects is dried 4h under 90 ℃, the mPPO that selects is dried 2h under 140 ℃;
The ABS of (2) step (1) being dried and mPPO add with toughner, oxidation inhibitor, lubricant and mix 10min in high-speed mixer;
(3) material that mixes in step (2) is sent in twin screw extruder by the pay-off of delicate metering, material the shearing of screw rod, mixing and carry under fusion fully, extrude finally by crossing, tie rod, cooling after, make pellet.Wherein the twin screw extruder length-to-diameter ratio is 60: 1, and with the twin screw extruder of accurate temperature control and vacuum-pumping equipment, each section Temperature Setting is at 240~280 ℃.Prepared heat-proof ABS performance is as shown in table 1.
Embodiment 3
Press the row weight part and take each component raw material:
550 parts of AS (LG Yongxing, 80HF, 105 ℃ of Vicat softening points),
130 parts of mPPO (husky uncle is basic, SE1X-701, HIPS modification),
250 parts of toughner ABS high glue powders (Jin Hu, 181H), ABS high glue powder are that a kind of rubber content is 55~75% ABS powder.
50 parts of compatilizer ABS-g-mah (Jieshijie Novel Materials Co., Ltd, Shanghai),
20 parts of compatilizer SMA (SSD5-218),
3 parts of antioxidant 1076s,
7 parts of irgasfos 168s,
5 parts of lubricants (calcium stearate);
(1) AS that selects is dried 2h under 120 ℃, the mPPO that selects is dried 4h under 100 ℃;
The AS of (2) step (1) being dried and mPPO add with toughner, compatilizer, oxidation inhibitor, lubricant and mix 20min in high-speed mixer;
(3) material that mixes in step (2) is sent in twin screw extruder by the pay-off of delicate metering, material the shearing of screw rod, mixing and carry under fusion fully, extrude finally by crossing, tie rod, cooling after, make pellet.Wherein the twin screw extruder length-to-diameter ratio is 20: 1, and with the twin screw extruder of accurate temperature control and vacuum-pumping equipment, each section Temperature Setting is at 230~260 ℃.Prepared heat-proof ABS performance is as shown in table 1.
Embodiment 4
Press the row weight part and take each component raw material:
500 parts of ABS (Zhenjiang is very beautiful, PA757,95 ℃ of Vicat softening points),
300 parts of PPE (blue star, LXR 040),
100 parts of compatilizer PS-g-mah (Jieshijie Novel Materials Co., Ltd, Shanghai),
50 parts of compatilizer SBS-g-mah (Jieshijie Novel Materials Co., Ltd, Shanghai),
50 parts of toughner HIPS,
2 parts of antioxidant 1076s,
3 parts of irgasfos 168s,
10 parts of lubricants (calcium stearate);
(1) ABS that selects is dried 3h under 100 ℃, the PPE that selects is dried 4h under 130 ℃;
The ABS of (2) step (1) being dried and PPE add with toughner, compatilizer, oxidation inhibitor, lubricant and mix 10min in high-speed mixer;
(3) material that mixes in step (2) is sent in twin screw extruder by the pay-off of delicate metering, material the shearing of screw rod, mixing and carry under fusion fully, extrude finally by crossing, tie rod, cooling after, make pellet.Wherein the twin screw extruder length-to-diameter ratio is 44: 1, and with the twin screw extruder of accurate temperature control and vacuum-pumping equipment, each section Temperature Setting is at 240~280 ℃.Prepared heat-proof ABS performance is as shown in table 1.
Embodiment 5
Press the row weight part and take each component raw material:
500 parts of ABS (Zhenjiang is very beautiful, PA757,95 ℃ of Vicat softening points),
400 parts of mPPO (husky uncle is basic, SE1X-701, HIPS modification),
Toughner SEBS (the Ba Ling petrochemical industry, YH-602) 100 parts,
2 parts of antioxidant 1076s,
4 parts of irgasfos 168s,
5 parts of lubricant stearic acid calcium;
(1) ABS that selects is dried 3h under 100 ℃, the PPE that selects is dried 4h under 130 ℃;
The ABS of (2) step (1) being dried and mPPO add with toughner, oxidation inhibitor, lubricant and mix 10min in high-speed mixer;
(3) material that mixes in step (2) is sent in twin screw extruder by the pay-off of delicate metering, material the shearing of screw rod, mixing and carry under fusion fully, extrude finally by crossing, tie rod, cooling after, make pellet.Wherein the twin screw extruder length-to-diameter ratio is 44: 1, and with the twin screw extruder of accurate temperature control and vacuum-pumping equipment, each section Temperature Setting is at 240~280 ℃.Prepared heat-proof ABS performance is as shown in table 1.
Embodiment 6
Press the row weight part and take each component raw material:
ASA (strange beautiful, PW957) 650 parts,
250 parts of PPE (blue star, LXR 040),
100 parts of compatilizer SEBS-g-gma (Jieshijie Novel Materials Co., Ltd, Shanghai),
2 parts of antioxidant 1076s,
4 parts of irgasfos 168s,
5 parts of lubricant clorafins;
(1) ABS that selects is dried 3h under 100 ℃, the PPE that selects is dried 4h under 130 ℃;
The ABS of (2) step (1) being dried and PPE add with compatilizer, oxidation inhibitor, lubricant and mix 10min in high-speed mixer;
(3) material that mixes in step (2) is sent in twin screw extruder by the pay-off of delicate metering, material the shearing of screw rod, mixing and carry under fusion fully, extrude finally by crossing, tie rod, cooling after, make pellet.Wherein the twin screw extruder length-to-diameter ratio is 44: 1, and with the twin screw extruder of accurate temperature control and vacuum-pumping equipment, each section Temperature Setting is at 240~280 ℃.Prepared heat-proof ABS performance is as shown in table 1.
Comparative example 1
Press the row weight part and take each component raw material:
850 parts of ABS (Zhenjiang is very beautiful, PA757,95 ℃ of Vicat softening points),
Heat-resistant agent vinylbenzene-150 parts of N phenyl maleimide-acrylonitrile copolymers (electrochemical),
1 part of antioxidant 1076,
3 parts of irgasfos 168s,
3 parts of Lubricate EBSs;
(1) ABS that selects is dried 3h under 100 ℃;
(2) ABS with step (1) oven dry adds mixing 10min in high-speed mixer with toughner, compatilizer, oxidation inhibitor, lubricant;
(3) material that mixes in step (2) is sent in twin screw extruder by the pay-off of delicate metering, material the shearing of screw rod, mixing and carry under fusion fully, extrude finally by crossing, tie rod, cooling after, make pellet.Wherein the twin screw extruder length-to-diameter ratio is 44: 1, and each section Temperature Setting is at 210~250 ℃.Prepared heat-proof ABS performance is as shown in table 1.
Comparative example 2
Press the row weight part and take each component raw material:
620 parts of ABS (Zhenjiang is very beautiful, PA757,95 ℃ of Vicat softening points),
Heat-resistant agent vinylbenzene-280 parts of N phenyl maleimide-acrylonitrile copolymers (electrochemical),
100 parts of toughner ABS high glue powders (Jin Hu, 181H),
1 part of antioxidant 1076,
3 parts of irgasfos 168s,
3 parts of Lubricate EBSs;
(1) ABS that selects is dried 3h under 100 ℃;
(2) ABS of oven dry in step (1) is added with toughner, compatilizer, oxidation inhibitor, lubricant mix 10min in high-speed mixer;
(3) material that mixes in step (2) is sent in twin screw extruder by the pay-off of delicate metering, material the shearing of screw rod, mixing and carry under fusion fully, extrude finally by crossing, tie rod, cooling after, make pellet.Wherein the twin screw extruder length-to-diameter ratio is 44: 1, and each section Temperature Setting is at 210~250 ℃.Prepared heat-proof ABS performance is as shown in table 1.
Table 1
Remarks: testing standard is ASTM.
Can find out according to table 1 data, in the inventive method the consumption of polyphenylene oxide is still less when obtaining the similar heat resistant product of performance; The similar embodiment 4 that feeds intake compares with comparative example 2, and both difference on resistance toheat and mechanical property are obvious, and the Vicat softening point of embodiment 4 is wanted high 10 ℃ of left and right, and mechanical property is better.Therefore use polyphenyl ether modified ABS material will obviously be better than common heat-resistant agent modified ABS material.
The above-mentioned description to embodiment is can understand and apply the invention for ease of those skilled in the art.The person skilled in the art obviously can easily make various modifications to these embodiment, and in the General Principle of this explanation is applied to other embodiment and needn't pass through performing creative labour.Therefore, the invention is not restricted to the embodiment here, those skilled in the art are according to announcement of the present invention, and not breaking away from the improvement that category of the present invention makes and revise all should be within protection scope of the present invention.

Claims (10)

1. heat-proof ABS material, it is characterized in that: this ABS material is made by the component that comprises following parts by weight:
500~900 parts of ABS resinoids,
100~400 parts of polyphenylene oxide resinoids,
0~150 part of compatilizer,
0~250 part of toughner,
1~10 part of lubricant,
3~10 parts, oxidation inhibitor.
2. heat-proof ABS material according to claim 1 is characterized in that: described ABS resinoid is selected from one or more the material in acrylonitrile-butadiene-styrene copolymer, acrylonitritrile-styrene resin or acrylonitrile-styrene-acrylic ester terpolymer.
3. heat-proof ABS material according to claim 1 is characterized in that: described polyphenylene oxide resinoid is selected from one or more the material in polyphenylene oxide, polystyrene or Modification of High-impact Polystyrene polyphenylene oxide.
4. heat-proof ABS material according to claim 1 is characterized in that: described compatilizer is selected from one or more the material in maleic anhydride grafted acrylonitrile-butadiene-styrene copolymer, maleic anhydride grafted polystyrene, maleic anhydride graft styrene-butadiene-styrene, maleic anhydride graft hydrogenated styrene-butadiene-styrene multipolymer, glycidyl methacrylate graft hydrogenated styrene-butadiene-styrene multipolymer or maleic anhydride-styrene copolymers.
5. heat-proof ABS material according to claim 1 is characterized in that: described toughner is selected from one or more the material in high-impact polystyrene, ABS high glue powder, styrene-butadiene-styrene, hydrogenated styrene-butadiene-styrene multipolymer; Wherein: the ABS high glue powder is that a kind of rubber content is 55~75% ABS powder.
6. heat-proof ABS material according to claim 1, it is characterized in that: described lubricant is selected from N, the material of one or more in N '-ethylene bis stearamide, stearic acid, Zinic stearas, calcium stearate, Magnesium Stearate, polyethylene wax, clorafin or methyl-silicone oil.
7. heat-proof ABS material according to claim 1, it is characterized in that: described oxidation inhibitor is selected from β-(3,5-di-t-butyl hydroxy phenyl) vinylformic acid ten caprylates, three-(2, the 4-tert-butyl-phenyl) phosphorous acid ester or 3,9-pair [1,1-dimethyl-2-[(3-tertiary butyl-4-hydroxy-5-aminomethyl phenyl) propionyloxy] ethyl]-2,4, the material of one or more in 8,10-, four oxaspiros [5.5] undecane.
8. the arbitrary described heat-proof ABS material preparation method of claim 1 to 7, it is characterized in that: the method comprises the following steps: with the polyphenylene oxide resinoid of the ABS resinoid of 500~900 parts of dryings, 100~400 parts of dryings, 0~150 part of compatilizer, 0~250 part of toughner, 1~10 part of lubricant and 3~10 parts of oxidation inhibitor, add in high-speed mixer to mix mixing time 5~20min; By the pay-off of delicate metering, the material that mixes is sent in twin screw extruder, material the shearing of screw rod, mixing and carry under fusion fully, extrude finally by crossing, tie rod, cooling after, make pellet.
9. heat-proof ABS material preparation method according to claim 8, it is characterized in that: the ABS resinoid of described drying is to dry 2~4h under 90~120 ℃; The polyphenylene oxide resinoid of described drying is to dry 3~4h under 100~140 ℃.
10. heat-proof ABS material preparation method according to claim 8, it is characterized in that: the length-to-diameter ratio of described twin screw extruder is 20~60: 1, with the twin screw extruder of accurate temperature control and vacuum-pumping equipment, each temperature setting of distinguishing of screw rod is set to 210~280 ℃.
CN2011103351491A 2011-10-28 2011-10-28 Heat resistance ABS material and preparation method thereof Pending CN103087456A (en)

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Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103333455A (en) * 2013-07-19 2013-10-02 上海锦湖日丽塑料有限公司 High-temperature creep resisting ABS resin composite and preparation method thereof
CN103441162A (en) * 2013-09-06 2013-12-11 苏州柯莱美高分子材料科技有限公司 Solar energy backboard of solar energy battery assembly and solar energy battery assembly
CN103525070A (en) * 2013-09-02 2014-01-22 吴江市物华五金制品有限公司 Modified PPO (Poly Phenylene Oxide) plastic alloy and preparation method thereof
CN103772893A (en) * 2014-01-24 2014-05-07 南通红石科技发展有限公司 Heat-resistant ABS (Acrylonitrile Butadiene Styrene) material and preparation method thereof
CN104109339A (en) * 2014-07-18 2014-10-22 滁州诺恩金塑制品有限公司 ABS (acrylonitrile-butadiene-styrene) plastic for air conditioner shells
CN104672752A (en) * 2015-02-04 2015-06-03 苏州康华净化系统工程有限公司 Weatherproof ABS (acrylonitrile-butadiene-styrene) material for cleaning shop and preparation method of weatherproof ABS material
CN104672747A (en) * 2013-11-28 2015-06-03 上海杰事杰新材料(集团)股份有限公司 Heat-resisting ABS (Acrylonitrile Butadiene StyreneAcrylonitrile Butadiene Styrene) material and preparation method thereof
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CN109135160A (en) * 2018-08-10 2019-01-04 阜南县鲲鹏塑业科技有限公司 A kind of high strength heat resistant flame-proof ABS alloy material
CN109651769A (en) * 2017-10-12 2019-04-19 天津星瑞包装科技有限公司 A kind of ABS/PETG composite material and preparation method that high heat resistance enhancing is modified
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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1510081A (en) * 2002-11-27 2004-07-07 通用电气公司 Flame retardant resin composition
CN1557870A (en) * 2004-02-11 2004-12-29 广东盛恒昌化学工业有限公司 Natural-like multifunctional color batch and use thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1510081A (en) * 2002-11-27 2004-07-07 通用电气公司 Flame retardant resin composition
CN1557870A (en) * 2004-02-11 2004-12-29 广东盛恒昌化学工业有限公司 Natural-like multifunctional color batch and use thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
严一丰等: "《塑料稳定剂及其应用》", 31 March 2008, article "抗氧剂GA-80", pages: 231-232 *

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CN103333455A (en) * 2013-07-19 2013-10-02 上海锦湖日丽塑料有限公司 High-temperature creep resisting ABS resin composite and preparation method thereof
CN103333455B (en) * 2013-07-19 2016-05-18 上海锦湖日丽塑料有限公司 A kind of ABS resin composition and method of making the same of high temperature resistant creep
CN103525070A (en) * 2013-09-02 2014-01-22 吴江市物华五金制品有限公司 Modified PPO (Poly Phenylene Oxide) plastic alloy and preparation method thereof
CN103441162B (en) * 2013-09-06 2016-04-13 苏州柯莱美高分子材料科技有限公司 The solar energy backboard of solar module and solar module
CN103441162A (en) * 2013-09-06 2013-12-11 苏州柯莱美高分子材料科技有限公司 Solar energy backboard of solar energy battery assembly and solar energy battery assembly
CN104672747A (en) * 2013-11-28 2015-06-03 上海杰事杰新材料(集团)股份有限公司 Heat-resisting ABS (Acrylonitrile Butadiene StyreneAcrylonitrile Butadiene Styrene) material and preparation method thereof
CN103772893A (en) * 2014-01-24 2014-05-07 南通红石科技发展有限公司 Heat-resistant ABS (Acrylonitrile Butadiene Styrene) material and preparation method thereof
CN104109339A (en) * 2014-07-18 2014-10-22 滁州诺恩金塑制品有限公司 ABS (acrylonitrile-butadiene-styrene) plastic for air conditioner shells
CN104672752A (en) * 2015-02-04 2015-06-03 苏州康华净化系统工程有限公司 Weatherproof ABS (acrylonitrile-butadiene-styrene) material for cleaning shop and preparation method of weatherproof ABS material
CN105103820A (en) * 2015-07-11 2015-12-02 安阳工学院 Agricultural product storage equipment
CN109651769A (en) * 2017-10-12 2019-04-19 天津星瑞包装科技有限公司 A kind of ABS/PETG composite material and preparation method that high heat resistance enhancing is modified
CN107629392A (en) * 2017-10-16 2018-01-26 天津大沽化工股份有限公司 A kind of method of reduction ABS products spray painting usage amount
CN109135160A (en) * 2018-08-10 2019-01-04 阜南县鲲鹏塑业科技有限公司 A kind of high strength heat resistant flame-proof ABS alloy material
CN112876841A (en) * 2021-01-15 2021-06-01 万华化学(四川)有限公司 Halogen-free flame-retardant long glass fiber reinforced nylon 12 material with high RTI value as well as preparation method and application thereof
CN113024984A (en) * 2021-03-11 2021-06-25 德星技术(苏州)有限公司 Reverse osmosis element central tube and preparation method thereof
CN113088012A (en) * 2021-05-18 2021-07-09 珠海格力新材料有限公司 Antibacterial and mildewproof ABS master batch and preparation method thereof

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