CN106928596A - A kind of anti-oxidant ground cushion of uvioresistant and preparation method thereof - Google Patents
A kind of anti-oxidant ground cushion of uvioresistant and preparation method thereof Download PDFInfo
- Publication number
- CN106928596A CN106928596A CN201710266139.4A CN201710266139A CN106928596A CN 106928596 A CN106928596 A CN 106928596A CN 201710266139 A CN201710266139 A CN 201710266139A CN 106928596 A CN106928596 A CN 106928596A
- Authority
- CN
- China
- Prior art keywords
- parts
- ground cushion
- oxidant
- weight
- uvioresistant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
- B32B27/20—Layered products comprising a layer of synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
- B32B27/22—Layered products comprising a layer of synthetic resin characterised by the use of special additives using plasticisers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
- B32B27/322—Layered products comprising a layer of synthetic resin comprising polyolefins comprising halogenated polyolefins, e.g. PTFE
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/02—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by a sequence of laminating steps, e.g. by adding new layers at consecutive laminating stations
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
- B32B5/08—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer the fibres or filaments of a layer being of different substances, e.g. conjugate fibres, mixture of different fibres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/558—Impact strength, toughness
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/71—Resistive to light or to UV
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Laminated Bodies (AREA)
Abstract
The present invention relates to ground cushion technical field, specifically related to a kind of anti-oxidant ground cushion of uvioresistant and preparation method thereof, the anti-oxidant ground cushion of the uvioresistant includes PVC base layer and fits in the silk thread braiding layer of PVC base layer upper surface, and the PVC base layer includes the raw material of following weight portion：85 105 parts of polyvinyl chloride resin, 30 40 parts of plasticizer, 20 30 parts of filler, 37 parts of stabilizer, 48 parts of impact modifier, 0.5 1.5 parts of UV resistant agent, 0.5 1.5 parts of antioxidant, 1.0 1.4 parts of lubricant.The anti-oxidant ground cushion uvioresistant of uvioresistant of the invention, antioxidant effect are good, environment-protecting asepsis, also with good intensity, toughness and anti-flammability, excellent combination property.
Description
Technical field
The present invention relates to ground cushion technical field, and in particular to a kind of anti-oxidant ground cushion of uvioresistant and preparation method thereof.
Background technology
With the development of economic construction, the living standard of people is also constantly improved, in people room and in-car all can
There are some ground cushions, ground cushion is used for completely cutting off the ice-cold of ground.Traditional woollen blanket ground cushion generally existing cleaning difficulty is big, after cleaning not
The defect of Yi Gan, mould growth and taste, to many constant using bringing.A kind of new PVC ground is occurred in that in the market
Pad, this ground cushion is almost made up of PVC material completely, easy to clean easily dry.But PVC ground cushion generally existings in the market
Easily aging defect.
The content of the invention
It is anti-it is an object of the invention to provide a kind of uvioresistant in order to overcome shortcoming and defect present in prior art
Oxidation ground cushion, the anti-oxidant ground cushion uvioresistant of the uvioresistant, antioxidant effect be good, environment-protecting asepsis, also with good intensity,
Toughness and anti-flammability, excellent combination property.
Preparation method another object of the present invention is to provide a kind of anti-oxidant ground cushion of uvioresistant, preparation method step
Rapid simple, convenient operation and control, steady quality, production efficiency is high, low production cost, is produced up to technical scale metaplasia.
The purpose of the present invention is achieved through the following technical solutions：A kind of anti-oxidant ground cushion of uvioresistant, including PVC base layer
With the silk thread braiding layer for fitting in PVC base layer upper surface, the raw material of the PVC base layer including following weight portion：
Polyvinyl chloride resin 85-105 parts
Plasticizer 30-40 parts
Filler 20-30 parts
Stabilizer 3-7 parts
Impact modifier 4-8 parts
UV resistant agent 0.5-1.5 parts
Antioxidant 0.5-1.5 parts
Lubricant 1.0-1.4 parts.
Preferably, the polyvinyl chloride resin is to compare 1 with weight by calcium carbide process PVC resin and ethylene process polyvinyl chloride resin:1-2 compositions
Mixture.By the species of strict control polyvinyl chloride resin, compounding and weight proportion, obtained ground cushion has light weight, strong to the present invention
Degree is high, insulation, fire-retardant, corrosion-resistant, high comprehensive performance the advantages of.
Preferably, the plasticizer is that 2- dioctyl phthalate diisononyl esters and dioctyl adipate are with weight ratio by hexamethylene 1
1.5-2.5:The mixture of 0.8-1.2 compositions.The present invention, can by the strict species for controlling plasticizer, compounding and weight proportion
To reduce the active force of plastic molecules interchain, the glass transition temperature of plastics, flowing temperature is set to be reduced with the fusing point of contained crystallite,
The plasticity of resin can be improved, makes product softness, resistance to low temperature good.
Preferably, the filler is the heavy carbon that particle diameter is treated in 50-100nm and through titanate coupling agent modified
Sour calcium.
The particle diameter of filler is smaller, and the tensile strength and impact strength to packing material are more beneficial, and the present invention is by selecting
Powdered whiting is as filler and controls its particle diameter in 50-100nm, and its crystal structure and Electronic Structure there occurs change
Change, generate quantum size effect, small-size effect, skin effect and macroscopic quantum effect that common powdered whiting does not have
Should, therefore with good toughened and reinforced effect, its add can improve in plastics bending strength and the modulus of elasticity in static bending and
The stability of heat distortion temperature and size；Filler is to play the pass of its effect and control addition with the good compatibility of resin
Key, the present invention can improve powdered whiting and polyvinyl chloride resin using the powdered whiting treated through titanate coupling agent modified
Compatibility, so as to improve the intensity of material.
Preferably, the stabilizer is to compare 1.5-2.5 with weight by calcium stearate, zinc stearate and beta-diketon and zeolite:
1-2:1:The mixture of 0.5-1.5 compositions.
The present invention is used as main body heat stabilizer by strict using calcium stearate, zinc stearate, using beta-diketon and zeolite
Used as auxiliary heat stabilizer, main body heat stabilizer and auxiliary heat stabilizer compounding use make material good heat stability, with height
Effect weatherability, can also make material have good dispersiveness, compatibility and processing fluidity in process.
Preferably, the impact modifier is by haloflex and butyl acrylate/methylmethacrylate copolymer
2-4 is compared with weight:The mixture of 1.5-2.5 compositions.
The present invention is by the strict species for controlling impact modifier, compounding and matches, and can improve the impact strength of material,
Improve the high temperature resistant and resistance to low temperature of material, the melt viscosity of material can also be reduced, improve mobility, improve adding for plastics
Work performance, extends the service life of product.
Preferably, the ultra-violet absorber is by ultra-violet absorber UV-9, ultra-violet absorber UVP-327 and light
Stabilizer HPT compares 0.8-1.2 with weight:1:The mixture of 0.5-1.5 compositions.
The present invention can strongly absorb ultraviolet by the strict species for controlling ultra-violet absorber, compounding and weight proportion,
With excellent cooperative effect.
Preferably, the antioxidant is to compare 1-2 with weight by antioxidant 1010, antioxidant 1076 and irgasfos 168:0.8-
1.2:The mixture of 1 composition.
The present invention can delay or suppress material oxidation by the strict species for controlling antioxidant, compounding and weight proportion
The carrying out of process, so as to prevent the aging of material and extend its service life.
Preferably, the lubricant be by OPE, pentaerythritol stearate and ethylene bis stearamide with
Weight compares 1.5-2.5:1:The mixture of 0.5-1.5 compositions.
The present invention is by the strict species for controlling lubricant, compounding and matches, and material can be made to improve in process
The mobility of material and the release property of product, can reduce difficulty of processing, save energy consumption.
The PVC base layer also includes cold-resistant toughened dose 2-6 parts, compatilizer 1-3 parts and antiseptic 0.5-1.5 parts.
Described cold-resistant toughened dose is to compare 1 with weight by amide-type beta crystal-type nucleater and dicarboxylic acids salt beta crystal-type nucleater：
The mixture of 1.2-1.8 compositions.
The present invention is used as cold-resistant toughened dose by using amide-type beta crystal-type nucleater and dicarboxylic acids salt beta crystal-type nucleater
Compounding use, and it is 1 to control its weight ratio：1.2-1.8 so that material in -20 DEG C of low temperature toughening effect substantially, more than normal temperature
When impact strength, while rigidly being significantly improved under normal temperature.
The compatilizer is to compare 1 with weight by maleic anhydride inoculated polypropylene and styrene-grafted polypropylene：1.4-2.2 groups
Into mixture.
The present invention is used as compatilizer compounding use by using maleic anhydride inoculated polypropylene and styrene-grafted polypropylene,
And it is 1 to control its weight ratio：1.4-2.2, can improve inorganic filler and organic resin compatibility, improve stretching, the impact of product
Intensity, realizes filling high, reduces resin demand, improves rheological performance, improves surface smoothness.
The antiseptic is to compare 1.5-2.5 with weight by zeolite with carrying silver and the silver-colored cobalt phosphate of load：The mixture of 1 composition.
The present invention controls its weight ratio to be by using zeolite with carrying silver and carrying silver cobalt phosphate and being used as antiseptic compounding use
1.5-2.5：1 so that not only tinting strength, tinting power is high for material, good dispersion, spinnability are good, also with preferable sterilized, fungistatic effect.
The PVC base layer also includes fire retardant 1-5 parts, slipping agent 0.5-1.5 parts and 0.5-1.5 parts of pigment powder.
The fire retardant is to compare 0.5-1.5 with weight by antimony oxide and Firebrake ZB：The mixture of 1 composition.
Antimony oxide and line borate are inorganic environment-friendly fire retardant, and the present invention is by using antimony oxide and Firebrake ZB
Used as fire retardant compounding use, and it is 0.5-1.5 to control its weight ratio：1, good flame retardant effect can be reached, moreover it is possible to improve
The processing characteristics and mechanical performance of material.
The slipping agent is to compare 1.5-2.5 with weight by erucyl amide, oleamide and N, N'- ethylene bis stearamide：
0.8-1.2：The mixture of 1 composition.
The present invention passes through using erucyl amide, oleamide and N, N'- ethylene bis stearamide are as slipping agent and control
Its weight ratio is 1.5-2.5：0.8-1.2：1, mechanical resistant stirring capacity and fingerprinting stress, finished product good forming effect, table can be strengthened
Face is bright and clean, moreover it is possible to strengthen the extensibility of finished product, easy-to-draw not easily broken.
The pigment powder is titanium dioxide of the particle diameter at 1-5 μm；The titanium dioxide is by rutile type titanium white and anatase titanium dioxide
Titanium dioxide compares 1 with weight：The mixture of 1.5-2.5 compositions.
The present invention using particle diameter in 1-5 μm of titanium dioxide as pigment powder, further using rutile type titanium white and sharp
Titanium-type titanium dioxide compounding use, and it is 1 to control its weight ratio：1.5-2.5, with superior whiteness, tinting strength, tinting power, covering power, resistance to
Hou Xing, heat resistance and chemical stability, particularly no toxicity.
A kind of preparation method of the anti-oxidant ground cushion of uvioresistant, comprises the following steps：
（1）The preparation of PVC base layer：The raw material of PVC base layer is mixed, extruded shaping, PVC base layer is obtained；
（2）The preparation of silk thread braiding layer：By anti-skidding parallel and tension warp knitting into silk thread braiding layer；
（3）The preparation of ground cushion：By PVC base layer and the pressing of silk thread braiding layer, the anti-oxidant ground cushion of uvioresistant is obtained.
The beneficial effects of the present invention are：The anti-oxidant ground cushion uvioresistant of uvioresistant of the invention, antioxidant effect are good,
Environment-protecting asepsis, also with good intensity, toughness and anti-flammability, excellent combination property.
The anti-oxidant ground cushion of uvioresistant of the invention is obtained using various high-environmental materials, without phthalate, no
Containing polycyclic aromatic hydrocarbon, without free phenol, halogen-containing flame retardant, not environmentally friendly better than European Union ROHS, DEHP, ATBC etc. without boron compound
International standard, can be extensively using sphere of lifes such as ground cushions.
Preparation method step of the invention is simple, and convenient operation and control, steady quality, production efficiency is high, low production cost,
Produced up to technical scale metaplasia.
Specific embodiment
For the ease of the understanding of those skilled in the art, with reference to embodiment, the present invention is further illustrated, real
The content that the mode of applying is referred to not limitation of the invention.
Embodiment 1
A kind of anti-oxidant ground cushion of uvioresistant, including PVC base layer and the silk thread braiding layer for fitting in PVC base layer upper surface,
The PVC base layer includes the raw material of following weight portion：
85 parts of polyvinyl chloride resin
30 parts of plasticizer
20 parts of filler
3 parts of stabilizer
4 parts of impact modifier
0.5 part of UV resistant agent
0.5 part of antioxidant
1.0 parts of lubricant.
The polyvinyl chloride resin is to compare 1 with weight by calcium carbide process PVC resin and ethylene process polyvinyl chloride resin:The mixture of 1 composition.
The plasticizer is to compare 1.5 with weight by hexamethylene 1,2- dioctyl phthalate diisononyl esters and dioctyl adipate:0.8
The mixture of composition.
The filler is the powdered whiting that particle diameter is treated in 50nm and through titanate coupling agent modified.
The stabilizer is to compare 1.5 with weight by calcium stearate, zinc stearate and beta-diketon and zeolite:1:1:0.5 composition
Mixture.
The impact modifier is with weight ratio by haloflex and butyl acrylate/methylmethacrylate copolymer
2:The mixture of 1.5 compositions.
The ultra-violet absorber is by ultra-violet absorber UV-9, ultra-violet absorber UVP-327 and light stabilizer
HPT compares 0.8 with weight:1:The mixture of 0.5 composition.
The antioxidant is to compare 1 with weight by antioxidant 1010, antioxidant 1076 and irgasfos 168:0.8:1 composition it is mixed
Compound.
The lubricant is with weight ratio by OPE, pentaerythritol stearate and ethylene bis stearamide
1.5:1:The mixture of 0.5 composition.
The PVC base layer is also including 0.5 part of cold-resistant toughened dose 2 parts, 1 part of compatilizer and antiseptic.
Described cold-resistant toughened dose is to compare 1 with weight by amide-type beta crystal-type nucleater and dicarboxylic acids salt beta crystal-type nucleater：
The mixture of 1.2 compositions.
The compatilizer is to compare 1 with weight by maleic anhydride inoculated polypropylene and styrene-grafted polypropylene：1.4 compositions
Mixture.
The antiseptic is to compare 1.5 with weight by zeolite with carrying silver and the silver-colored cobalt phosphate of load：The mixture of 1 composition.
The PVC base layer also includes 0.5 part of 1 part of fire retardant, 0.5 part of slipping agent and pigment powder.
The fire retardant is to compare 0.5 with weight by antimony oxide and Firebrake ZB：The mixture of 1 composition.
The slipping agent is to compare 1.5 with weight by erucyl amide, oleamide and N, N'- ethylene bis stearamide：0.8：1
The mixture of composition.
The pigment powder is titanium dioxide of the particle diameter at 1 μm；The titanium dioxide is by rutile type titanium white and anatase titanium dioxide titanium
White powder compares 1 with weight：The mixture of 1.5 compositions.
A kind of preparation method of the anti-oxidant ground cushion of uvioresistant, comprises the following steps：
（1）The preparation of PVC base layer：The raw material of PVC base layer is mixed, extruded shaping, PVC base layer is obtained；
（2）The preparation of silk thread braiding layer：By anti-skidding parallel and tension warp knitting into silk thread braiding layer；
（3）The preparation of ground cushion：By PVC base layer and the pressing of silk thread braiding layer, the anti-oxidant ground cushion of uvioresistant is obtained.
Embodiment 2
A kind of anti-oxidant ground cushion of uvioresistant, including PVC base layer and the silk thread braiding layer for fitting in PVC base layer upper surface,
The PVC base layer includes the raw material of following weight portion：
90 parts of polyvinyl chloride resin
32 parts of plasticizer
22 parts of filler
4 parts of stabilizer
5 parts of impact modifier
0.8 part of UV resistant agent
0.8 part of antioxidant
1.1 parts of lubricant.
The polyvinyl chloride resin is to compare 1 with weight by calcium carbide process PVC resin and ethylene process polyvinyl chloride resin:The mixture of 1.2 compositions.
The plasticizer is to compare 1.8 with weight by hexamethylene 1,2- dioctyl phthalate diisononyl esters and dioctyl adipate:0.9
The mixture of composition.
The filler is the powdered whiting that particle diameter is treated in 60nm and through titanate coupling agent modified.
The stabilizer is to compare 1.8 with weight by calcium stearate, zinc stearate and beta-diketon and zeolite:1.2:1:0.8 group
Into mixture.
The impact modifier is with weight ratio by haloflex and butyl acrylate/methylmethacrylate copolymer
2.5:The mixture of 1.8 compositions.
The ultra-violet absorber is by ultra-violet absorber UV-9, ultra-violet absorber UVP-327 and light stabilizer
HPT compares 0.9 with weight:1:The mixture of 0.8 composition.
The antioxidant is to compare 1.2 with weight by antioxidant 1010, antioxidant 1076 and irgasfos 168:0.9:1 composition
Mixture.
The lubricant is with weight ratio by OPE, pentaerythritol stearate and ethylene bis stearamide
1.8:1:The mixture of 0.8 composition.
The PVC base layer is also including 0.8 part of cold-resistant toughened dose 3 parts, 1.5 parts of compatilizer and antiseptic.
Described cold-resistant toughened dose is to compare 1 with weight by amide-type beta crystal-type nucleater and dicarboxylic acids salt beta crystal-type nucleater：
The mixture of 1.4 compositions.
The compatilizer is to compare 1 with weight by maleic anhydride inoculated polypropylene and styrene-grafted polypropylene：1.6 compositions
Mixture.
The antiseptic is to compare 1.8 with weight by zeolite with carrying silver and the silver-colored cobalt phosphate of load：The mixture of 1 composition.
The PVC base layer also includes 0.8 part of 2 parts of fire retardant, 0.8 part of slipping agent and pigment powder.
The fire retardant is to compare 0.8 with weight by antimony oxide and Firebrake ZB：The mixture of 1 composition.
The slipping agent is to compare 1.8 with weight by erucyl amide, oleamide and N, N'- ethylene bis stearamide：0.9：1
The mixture of composition.
The pigment powder is titanium dioxide of the particle diameter at 2 μm；The titanium dioxide is by rutile type titanium white and anatase titanium dioxide titanium
White powder compares 1 with weight：The mixture of 1.8 compositions.
A kind of preparation method of the anti-oxidant ground cushion of uvioresistant, comprises the following steps：
（1）The preparation of PVC base layer：The raw material of PVC base layer is mixed, extruded shaping, PVC base layer is obtained；
（2）The preparation of silk thread braiding layer：By anti-skidding parallel and tension warp knitting into silk thread braiding layer；
（3）The preparation of ground cushion：By PVC base layer and the pressing of silk thread braiding layer, the anti-oxidant ground cushion of uvioresistant is obtained.
Embodiment 3
A kind of anti-oxidant ground cushion of uvioresistant, including PVC base layer and the silk thread braiding layer for fitting in PVC base layer upper surface,
The PVC base layer includes the raw material of following weight portion：
95 parts of polyvinyl chloride resin
35 parts of plasticizer
25 parts of filler
5 parts of stabilizer
6 parts of impact modifier
1 part of UV resistant agent
1 part of antioxidant
1.2 parts of lubricant.
The polyvinyl chloride resin is to compare 1 with weight by calcium carbide process PVC resin and ethylene process polyvinyl chloride resin:The mixture of 1.5 compositions.
The plasticizer is to compare 2 with weight by hexamethylene 1,2- dioctyl phthalate diisononyl esters and dioctyl adipate:1 composition
Mixture.
The filler is the powdered whiting that particle diameter is treated in 75nm and through titanate coupling agent modified.
The stabilizer is to compare 2 with weight by calcium stearate, zinc stearate and beta-diketon and zeolite:1.5:1:1 composition
Mixture.
The impact modifier is with weight ratio by haloflex and butyl acrylate/methylmethacrylate copolymer
3:The mixture of 2 compositions.
The ultra-violet absorber is by ultra-violet absorber UV-9, ultra-violet absorber UVP-327 and light stabilizer
HPT compares 1 with weight:1:The mixture of 1 composition.
The antioxidant is to compare 1.5 with weight by antioxidant 1010, antioxidant 1076 and irgasfos 168:1:1 composition it is mixed
Compound.
The lubricant is to compare 2 with weight by OPE, pentaerythritol stearate and ethylene bis stearamide:
1:The mixture of 1 composition.
The PVC base layer is also including 1 part of cold-resistant toughened dose 4 parts, 2 parts of compatilizer and antiseptic.
Described cold-resistant toughened dose is to compare 1 with weight by amide-type beta crystal-type nucleater and dicarboxylic acids salt beta crystal-type nucleater：
The mixture of 1.5 compositions.
The compatilizer is to compare 1 with weight by maleic anhydride inoculated polypropylene and styrene-grafted polypropylene：1.8 compositions
Mixture.
The antiseptic is to compare 2 with weight by zeolite with carrying silver and the silver-colored cobalt phosphate of load：The mixture of 1 composition.
The PVC base layer also includes 1 part of 3 parts of fire retardant, 1 part of slipping agent and pigment powder.
The fire retardant is to compare 1 with weight by antimony oxide and Firebrake ZB：The mixture of 1 composition.
The slipping agent is to compare 2 with weight by erucyl amide, oleamide and N, N'- ethylene bis stearamide：1：1 composition
Mixture.
The pigment powder is titanium dioxide of the particle diameter at 3 μm；The titanium dioxide is by rutile type titanium white and anatase titanium dioxide titanium
White powder compares 1 with weight：The mixture of 2 compositions.
A kind of preparation method of the anti-oxidant ground cushion of uvioresistant, comprises the following steps：
（1）The preparation of PVC base layer：The raw material of PVC base layer is mixed, extruded shaping, PVC base layer is obtained；
（2）The preparation of silk thread braiding layer：By anti-skidding parallel and tension warp knitting into silk thread braiding layer；
（3）The preparation of ground cushion：By PVC base layer and the pressing of silk thread braiding layer, the anti-oxidant ground cushion of uvioresistant is obtained.
Embodiment 4
A kind of anti-oxidant ground cushion of uvioresistant, including PVC base layer and the silk thread braiding layer for fitting in PVC base layer upper surface,
The PVC base layer includes the raw material of following weight portion：
100 parts of polyvinyl chloride resin
38 parts of plasticizer
28 parts of filler
6 parts of stabilizer
7 parts of impact modifier
1.2 parts of UV resistant agent
1.2 parts of antioxidant
1.3 parts of lubricant.
The polyvinyl chloride resin is to compare 1 with weight by calcium carbide process PVC resin and ethylene process polyvinyl chloride resin:The mixture of 1.8 compositions.
The plasticizer is to compare 2.2 with weight by hexamethylene 1,2- dioctyl phthalate diisononyl esters and dioctyl adipate:1.1
The mixture of composition.
The filler is the powdered whiting that particle diameter is treated in 90nm and through titanate coupling agent modified.
The stabilizer is to compare 2.2 with weight by calcium stearate, zinc stearate and beta-diketon and zeolite:1.8:1:1.2 groups
Into mixture.
The impact modifier is with weight ratio by haloflex and butyl acrylate/methylmethacrylate copolymer
3.5:The mixture of 2.2 compositions.
The ultra-violet absorber is by ultra-violet absorber UV-9, ultra-violet absorber UVP-327 and light stabilizer
HPT compares 1.1 with weight:1:The mixture of 1.2 compositions.
The antioxidant is to compare 1.8 with weight by antioxidant 1010, antioxidant 1076 and irgasfos 168:1.1:1 composition
Mixture.
The lubricant is with weight ratio by OPE, pentaerythritol stearate and ethylene bis stearamide
2.2:1:The mixture of 1.2 compositions.
The PVC base layer is also including 1.2 parts of cold-resistant toughened dose 5 parts, 2.5 parts of compatilizer and antiseptic.
Described cold-resistant toughened dose is to compare 1 with weight by amide-type beta crystal-type nucleater and dicarboxylic acids salt beta crystal-type nucleater：
The mixture of 1.6 compositions.
The compatilizer is to compare 1 with weight by maleic anhydride inoculated polypropylene and styrene-grafted polypropylene：2 compositions it is mixed
Compound.
The antiseptic is to compare 2.2 with weight by zeolite with carrying silver and the silver-colored cobalt phosphate of load：The mixture of 1 composition.
The PVC base layer also includes 1.2 parts of 4 parts of fire retardant, 1.2 parts of slipping agent and pigment powder.
The fire retardant is to compare 1.2 with weight by antimony oxide and Firebrake ZB：The mixture of 1 composition.
The slipping agent is to compare 2.2 with weight by erucyl amide, oleamide and N, N'- ethylene bis stearamide：1.1：1
The mixture of composition.
The pigment powder is titanium dioxide of the particle diameter at 4 μm；The titanium dioxide is by rutile type titanium white and anatase titanium dioxide titanium
White powder compares 1 with weight：The mixture of 2.2 compositions.
A kind of preparation method of the anti-oxidant ground cushion of uvioresistant, comprises the following steps：
（1）The preparation of PVC base layer：The raw material of PVC base layer is mixed, extruded shaping, PVC base layer is obtained；
（2）The preparation of silk thread braiding layer：By anti-skidding parallel and tension warp knitting into silk thread braiding layer；
（3）The preparation of ground cushion：By PVC base layer and the pressing of silk thread braiding layer, the anti-oxidant ground cushion of uvioresistant is obtained.
Embodiment 5
A kind of anti-oxidant ground cushion of uvioresistant, including PVC base layer and the silk thread braiding layer for fitting in PVC base layer upper surface,
The PVC base layer includes the raw material of following weight portion：
105 parts of polyvinyl chloride resin
40 parts of plasticizer
30 parts of filler
7 parts of stabilizer
8 parts of impact modifier
1.5 parts of UV resistant agent
1.5 parts of antioxidant
1.4 parts of lubricant.
The polyvinyl chloride resin is to compare 1 with weight by calcium carbide process PVC resin and ethylene process polyvinyl chloride resin:The mixture of 2 compositions.
The plasticizer is to compare 2.5 with weight by hexamethylene 1,2- dioctyl phthalate diisononyl esters and dioctyl adipate:1.2
The mixture of composition.
The filler is the powdered whiting that particle diameter is treated in 100nm and through titanate coupling agent modified.
The stabilizer is to compare 2.5 with weight by calcium stearate, zinc stearate and beta-diketon and zeolite:2:1:1.5 compositions
Mixture.
The impact modifier is with weight ratio by haloflex and butyl acrylate/methylmethacrylate copolymer
4:The mixture of 2.5 compositions.
The ultra-violet absorber is by ultra-violet absorber UV-9, ultra-violet absorber UVP-327 and light stabilizer
HPT compares 1.2 with weight:1:The mixture of 1.5 compositions.
The antioxidant is to compare 2 with weight by antioxidant 1010, antioxidant 1076 and irgasfos 168:1.2:1 composition it is mixed
Compound.
The lubricant is with weight ratio by OPE, pentaerythritol stearate and ethylene bis stearamide
2.5:1:The mixture of 1.5 compositions.
The PVC base layer is also including 1.5 parts of cold-resistant toughened dose 6 parts, 3 parts of compatilizer and antiseptic.
Described cold-resistant toughened dose is to compare 1 with weight by amide-type beta crystal-type nucleater and dicarboxylic acids salt beta crystal-type nucleater：
The mixture of 1.8 compositions.
The compatilizer is to compare 1 with weight by maleic anhydride inoculated polypropylene and styrene-grafted polypropylene：2.2 compositions
Mixture.
The antiseptic is to compare 2.5 with weight by zeolite with carrying silver and the silver-colored cobalt phosphate of load：The mixture of 1 composition.
The PVC base layer also includes 1.5 parts of 5 parts of fire retardant, 1.5 parts of slipping agent and pigment powder.
The fire retardant is to compare 1.5 with weight by antimony oxide and Firebrake ZB：The mixture of 1 composition.
The slipping agent is to compare 2.5 with weight by erucyl amide, oleamide and N, N'- ethylene bis stearamide：1.2：1
The mixture of composition.
The pigment powder is titanium dioxide of the particle diameter at 5 μm；The titanium dioxide is by rutile type titanium white and anatase titanium dioxide titanium
White powder compares 1 with weight：The mixture of 2.5 compositions.
A kind of preparation method of the anti-oxidant ground cushion of uvioresistant, comprises the following steps：
（1）The preparation of PVC base layer：The raw material of PVC base layer is mixed, extruded shaping, PVC base layer is obtained；
（2）The preparation of silk thread braiding layer：By anti-skidding parallel and tension warp knitting into silk thread braiding layer；
（3）The preparation of ground cushion：By PVC base layer and the pressing of silk thread braiding layer, the anti-oxidant ground cushion of uvioresistant is obtained.
The mechanical and physical performance of the anti-oxidant ground cushion of uvioresistant obtained in embodiments of the invention 1-5 is as shown in table 1.
Table 1
| Test event | Standard value | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 |
| Ultraviolet light and aging is tested（h） | ≥504 | 1008 | 1008 | 1008 | 1008 | 1008 |
| Tensile strength（MPa） | ≥15.0 | 22.3 | 24.4 | 25.6 | 26.1 | 23.2 |
| Bending strength（MPa） | ≥15.0 | 46.8 | 48.7 | 51.6 | 54.4 | 45.2 |
| Elongation at break（%） | ≥150 | 299 | 304 | 311 | 322 | 302 |
| Heat distortion temperature（℃） | ≥50.0 | 115.4 | 118.2 | 120.5 | 122.4 | 116.2 |
| Impact brittle temperature（℃） | ≤-20 | -35 | -35 | -40 | -40 | -35 |
| Heat-stable time at 200 DEG C（min） | ≥60 | 90 | 110 | 120 | 120 | 100 |
| Hardness/Shore D | ≥50 | 79 | 82 | 84 | 85 | 80 |
| It is fire-retardant | V0 | V0 | V0 | V0 | V0 | V0 |
As it can be seen from table 1 the anti-oxidant ground cushion uvioresistant of the obtained uvioresistant of the present invention, antioxidant effect are good, environmentally friendly nothing
Poison, also with good intensity, toughness and anti-flammability, excellent combination property.The anti-oxidant ground cushion of uvioresistant of the invention is used
Various high-environmental materials are obtained, without phthalate, without polycyclic aromatic hydrocarbon, and without free phenol, not halogen-containing flame retardant, nothing
Boron compound, environmental protection, can be extensively using sphere of lifes such as ground cushions better than international standards such as European Union ROHS, DEHP, ATBC.
Above-described embodiment is the present invention preferably implementation, and in addition, the present invention can be realized with other manner,
Any obvious replacement is within protection scope of the present invention on the premise of not departing from present inventive concept.
Claims (10)
1. the anti-oxidant ground cushion of a kind of uvioresistant, it is characterised in that：Including PVC base layer and fit in PVC base layer upper surface
Silk thread braiding layer, PVC base layer includes the raw material of following weight portion：
Polyvinyl chloride resin 85-105 parts
Plasticizer 30-40 parts
Filler 20-30 parts
Stabilizer 3-7 parts
Impact modifier 4-8 parts
UV resistant agent 0.5-1.5 parts
Antioxidant 0.5-1.5 parts
Lubricant 1.0-1.4 parts.
2. the anti-oxidant ground cushion of a kind of uvioresistant according to claim 1, it is characterised in that：The polyvinyl chloride resin is by electricity
Stone method polyvinyl chloride resin and ethylene process polyvinyl chloride resin compare 1 with weight:The mixture of 1-2 compositions.
3. the anti-oxidant ground cushion of a kind of uvioresistant according to claim 1, it is characterised in that：The plasticizer is by hexamethylene
Alkane 1,2- dioctyl phthalate diisononyl esters and dioctyl adipate compare 1.5-2.5 with weight:The mixture of 0.8-1.2 compositions.
4. the anti-oxidant ground cushion of a kind of uvioresistant according to claim 1, it is characterised in that：The filler exists for particle diameter
50-100nm and the powdered whiting treated through titanate coupling agent modified.
5. the anti-oxidant ground cushion of a kind of uvioresistant according to claim 1, it is characterised in that：The stabilizer is by tristearin
Sour calcium, zinc stearate and beta-diketon and zeolite compare 1.5-2.5 with weight:1-2:1:The mixture of 0.5-1.5 compositions.
6. the anti-oxidant ground cushion of a kind of uvioresistant according to claim 1, it is characterised in that：The impact modifier be by
Haloflex and butyl acrylate/methylmethacrylate copolymer compare 2-4 with weight:The mixture of 1.5-2.5 compositions.
7. the anti-oxidant ground cushion of a kind of uvioresistant according to claim 1, it is characterised in that：The ultra-violet absorber is
0.8-1.2 is compared with weight by ultra-violet absorber UV-9, ultra-violet absorber UVP-327 and light stabilizer HPT:1:0.5-1.5
The mixture of composition.
8. the anti-oxidant ground cushion of a kind of uvioresistant according to claim 1, it is characterised in that：The antioxidant is by antioxygen
Agent 1010, antioxidant 1076 and irgasfos 168 compare 1-2 with weight:0.8-1.2:The mixture of 1 composition.
9. the anti-oxidant ground cushion of a kind of uvioresistant according to claim 1, it is characterised in that：The lubricant is by aoxidizing
Tissuemat E, pentaerythritol stearate and ethylene bis stearamide compare 1.5-2.5 with weight:1:The mixing of 0.5-1.5 compositions
Thing.
10. the preparation method of the anti-oxidant ground cushion of a kind of uvioresistant as described in claim any one of 1-9, it is characterised in that：
Comprise the following steps：
（1）The preparation of PVC base layer：The raw material of PVC base layer is mixed, extruded shaping, PVC base layer is obtained；
（2）The preparation of silk thread braiding layer：By anti-skidding parallel and tension warp knitting into silk thread braiding layer；
（3）The preparation of ground cushion：By PVC base layer and the pressing of silk thread braiding layer, the anti-oxidant ground cushion of uvioresistant is obtained.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710266139.4A CN106928596A (en) | 2017-04-21 | 2017-04-21 | A kind of anti-oxidant ground cushion of uvioresistant and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710266139.4A CN106928596A (en) | 2017-04-21 | 2017-04-21 | A kind of anti-oxidant ground cushion of uvioresistant and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106928596A true CN106928596A (en) | 2017-07-07 |
Family
ID=59437939
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710266139.4A Pending CN106928596A (en) | 2017-04-21 | 2017-04-21 | A kind of anti-oxidant ground cushion of uvioresistant and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106928596A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108610578A (en) * | 2018-05-22 | 2018-10-02 | 安徽申科塑业有限公司 | A kind of energy conservation and environmental protection polyvinyl chloride plastic film material |
| CN108864618A (en) * | 2018-07-25 | 2018-11-23 | 李丹丹 | A kind of high antibacterial wear-resisting PVC resin material and preparation method thereof |
| CN109486061A (en) * | 2018-11-20 | 2019-03-19 | 东莞市正品五金电子有限公司 | A kind of anti-aging PVC granulating formula |
| CN110847532A (en) * | 2019-11-15 | 2020-02-28 | 广东雅丽斯佳新材料有限公司 | High-strength high-toughness textilene wall cloth |
| CN113459603A (en) * | 2021-06-07 | 2021-10-01 | 佛山市鑫宏美装饰材料有限公司 | Flocking tablecloth |
-
2017
- 2017-04-21 CN CN201710266139.4A patent/CN106928596A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108610578A (en) * | 2018-05-22 | 2018-10-02 | 安徽申科塑业有限公司 | A kind of energy conservation and environmental protection polyvinyl chloride plastic film material |
| CN108864618A (en) * | 2018-07-25 | 2018-11-23 | 李丹丹 | A kind of high antibacterial wear-resisting PVC resin material and preparation method thereof |
| CN109486061A (en) * | 2018-11-20 | 2019-03-19 | 东莞市正品五金电子有限公司 | A kind of anti-aging PVC granulating formula |
| CN110847532A (en) * | 2019-11-15 | 2020-02-28 | 广东雅丽斯佳新材料有限公司 | High-strength high-toughness textilene wall cloth |
| CN113459603A (en) * | 2021-06-07 | 2021-10-01 | 佛山市鑫宏美装饰材料有限公司 | Flocking tablecloth |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106928596A (en) | A kind of anti-oxidant ground cushion of uvioresistant and preparation method thereof | |
| CN106947187A (en) | A kind of sunlight fabric is material modified and preparation method thereof with PVC | |
| CN106977848A (en) | A kind of automotive line is material modified and preparation method thereof with PVC | |
| CN106977849A (en) | A kind of curtain is material modified and preparation method thereof with PVC | |
| CN106905642A (en) | A kind of anti-skid wearable ground cushion and preparation method thereof | |
| CN108164820A (en) | A kind of plant fiber/PP composite materials and preparation method thereof | |
| CN106977853A (en) | A kind of antistatic mould proof ground cushion and preparation method thereof | |
| CN103059554A (en) | Preparation method of thermoplastic polyurethane elastomer | |
| CN106947185A (en) | A kind of table mat is material modified and preparation method thereof with PVC | |
| CN106905641A (en) | A kind of wallpaper cloth is material modified and preparation method thereof with PVC | |
| CN106916394A (en) | A kind of anti-slip carpet is material modified and preparation method thereof with PVC | |
| CN106977846A (en) | A kind of waterproof oil resistant carpet is material modified and preparation method thereof with PVC | |
| CN106916395A (en) | A kind of waterproof oil resistant ground cushion and preparation method thereof | |
| CN103694682A (en) | Color master batch for antimicrobial and anti-UV nylon | |
| CN107011622A (en) | A kind of super abrasive POM/PTFE sheet materials and preparation method thereof | |
| CN105419167A (en) | Carpet environmental protection PVC modified material and preparation method therefor | |
| CN106928597A (en) | A kind of fire-retardant ground cushion of high resiliency and preparation method thereof | |
| CN102702609A (en) | Polyethylene composite material used for bionic vine | |
| CN106947186A (en) | A kind of beach chair cloth is material modified and preparation method thereof with PVC | |
| CN106928668A (en) | A kind of modified PET slab and its extruding forming method | |
| CN106977896A (en) | A kind of wear-resisting PC ABS alloy materials and preparation method thereof | |
| CN106967274A (en) | A kind of enhanced POM plate material and preparation method thereof | |
| CN109651834A (en) | A kind of environmentally friendly vehicle foot pad material and preparation method thereof | |
| CN104177735A (en) | Orange peel glass sheet and preparation method thereof | |
| CN103694685A (en) | White anti-UV (ultraviolet) nylon color masterbatch |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20170707 |