CN106977853A - A kind of antistatic mould proof ground cushion and preparation method thereof - Google Patents

A kind of antistatic mould proof ground cushion and preparation method thereof Download PDF

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Publication number
CN106977853A
CN106977853A CN201710267356.5A CN201710267356A CN106977853A CN 106977853 A CN106977853 A CN 106977853A CN 201710267356 A CN201710267356 A CN 201710267356A CN 106977853 A CN106977853 A CN 106977853A
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China
Prior art keywords
parts
antistatic
ground cushion
mixture
mould proof
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CN201710267356.5A
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Chinese (zh)
Inventor
徐祥林
罗恺青
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Guangdong Jia Agnes Textile Technology Co Ltd
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Guangdong Jia Agnes Textile Technology Co Ltd
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Priority to CN201710267356.5A priority Critical patent/CN106977853A/en
Publication of CN106977853A publication Critical patent/CN106977853A/en
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/304—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06—Homopolymers or copolymers of vinyl chloride
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/20—Properties of the layers or laminate having particular electrical or magnetic properties, e.g. piezoelectric
    • B32B2307/21—Anti-static
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/30—Properties of the layers or laminate having particular thermal properties
    • B32B2307/306—Resistant to heat
    • B32B2307/3065—Flame resistant or retardant, fire resistant or retardant
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/714—Inert, i.e. inert to chemical degradation, corrosion
    • B32B2307/7145—Rot proof, resistant to bacteria, mildew, mould, fungi
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2471/00—Floor coverings
    • B32B2471/02—Carpets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/08—Metals
    • C08K2003/0806—Silver
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C08K2003/265—Calcium, strontium or barium carbonate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/38—Boron-containing compounds
    • C08K2003/387—Borates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/002—Physical properties
    • C08K2201/003—Additives being defined by their diameter
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/017—Additives being an antistatic agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/04—Antistatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The present invention relates to ground cushion technical field, specifically related to a kind of antistatic mould proof ground cushion and preparation method thereof, the antistatic mould proof ground cushion includes PVC base layer and fits in the silk thread braiding layer of PVC base layer upper surface, and the PVC base layer includes the raw material of following parts by weight：100 120 parts of polyvinyl chloride resin, 45 55 parts of plasticizer, 5 15 parts of filler, 6 10 parts of stabilizer, 59 parts of impact modifier, 24 parts of antistatic additive, 13 parts of mould inhibitor, 1.6 2.0 parts of lubricant.The antistatic mould proof ground cushion of the present invention is antistatic and anti-mold effect is good, environment-protecting and non-poisonous, also with good intensity, toughness, anti-flammability and ageing resistace, excellent combination property.

Description

A kind of antistatic mould proof ground cushion and preparation method thereof
Technical field
The present invention relates to ground cushion technical field, and in particular to a kind of antistatic mould proof ground cushion and preparation method thereof.
Background technology
With the development of economic construction, the living standard of people is also constantly improved, in people room and in-car all can There are some ground cushions, ground cushion is used for completely cutting off the ice-cold of ground.Traditional woollen blanket ground cushion generally existing cleaning difficulty is big, after cleaning not The defect of Yi Gan, mould growth and taste, to many constant using bringing.With occurring in that a kind of new PVC in the market Pad, this ground cushion is almost made up of PVC material completely, easy to clean easily dry.But PVC ground cushion generally existings in the market Poor, the easily mouldy defect of antistatic property.
The content of the invention
In order to overcome shortcoming and defect present in prior art, it is an object of the invention to provide one kind is antistatic mould proof Ground cushion, the antistatic mould proof ground cushion is antistatic and anti-mold effect is good, environment-protecting and non-poisonous, also with good intensity, toughness, anti-flammability And ageing resistace, excellent combination property.
Another object of the present invention is to provide a kind of preparation method of antistatic mould proof ground cushion, preparation method step letter Single, convenient operation and control, steady quality, production efficiency is high, and production cost is low, up to the production of technical scale metaplasia.
The purpose of the present invention is achieved through the following technical solutions：A kind of antistatic mould proof ground cushion, including PVC base layer and patch Together in the silk thread braiding layer of PVC base layer upper surface, the PVC base layer includes the raw material of following parts by weight：
100-120 parts of polyvinyl chloride resin
45-55 parts of plasticizer
5-15 parts of filler
6-10 parts of stabilizer
5-9 parts of impact modifier
2-4 parts of antistatic additive
1-3 parts of mould inhibitor
1.6-2.0 parts of lubricant.
It is preferred that, the polyvinyl chloride resin is with weight ratio 1 by calcium carbide process PVC resin and ethylene process polyvinyl chloride resin:1-2 compositions Mixture.The present invention is by strictly controlling the species, compounding and weight proportion of polyvinyl chloride resin, and obtained ground cushion has light weight, strong Degree is high, insulation, fire-retardant, corrosion-resistant, high comprehensive performance the advantages of.
It is preferred that, the plasticizer is by hexamethylene 1,2- dioctyl phthalate diisononyl esters, synthesis vegetable esters and epoxy soybean Oil compares 1.5-2.5 with weight:0.8-1.2:The mixture of 1 composition.The present invention by strictly control plasticizer species, compounding and Weight proportion, can reduce the active force of plastic molecules interchain, make the glass transition temperature, flowing temperature and contained crystallite of plastics Fusing point is reduced, and can improve the plasticity of resin, makes product softness, resistance to low temperature good.
It is preferred that, the filler is particle diameter at 1-5 μm and the crystal carbonic acid through boric acid ester coupler modification Calcium.
The particle diameter of filler is smaller, and the tensile strength and impact strength to packing material are more beneficial, and the present invention is by selecting Crystal calcium carbonate is as filler and controls its particle diameter at 1-5 μm, and its crystal structure and Electronic Structure are changed, production Quantum size effect, small-size effect, skin effect and macroscopic quantum effect that common crystal calcium carbonate does not have are given birth to, therefore With good toughened and reinforced effect, it, which is added in plastics, can improve bending strength and the modulus of elasticity in static bending and thermal deformation temperature The stability of degree and size；Filler is to play its key for acting on and controlling addition, this hair with the good compatibility of resin It is bright to use the crystal calcium carbonate through boric acid ester coupler modification, the compatible of crystal calcium carbonate and polyvinyl chloride resin can be improved Property, so as to improve the intensity of material.
It is preferred that, the stabilizer is by calcium laurate, zinc laurate, the different fork-fatty alcohol-phosphorous acid of carbon-based -4,4- bis- Chelate compounds polymer and hydrotalcite compare 2-4 with weight：1.5-3.5:0.8-1.2:The mixture of 1 composition.
The present invention is different using carbon-based -4,4- bis- by strictly using calcium laurate, zinc laurate to be used as main body heat stabilizer Fork-fatty alcohol-phosphorous acid chelate compounds polymer and hydrotalcite are as auxiliary heat stabilizer, and main body heat stabilizer and auxiliary heat are steady Determine agent compounding use, make material good heat stability, with efficient weatherability, material can also be made to have in process very well Dispersiveness, compatibility and processing fluidity.
It is preferred that, the impact modifier be by haloflex, butyl acrylate/methylmethacrylate copolymer and Methyl methacrylate/butadiene/styrene copolymers compare 2-4 with weight:1.5-2.5:The mixture of 1 composition.
The present invention can improve the impact strength of material by strictly controlling the species of impact modifier, compounding and proportioning, Improve the high temperature resistant and resistance to low temperature of material, the melt viscosity of material can also be reduced, improve mobility, improve adding for plastics Work performance, extends the service life of product.
It is preferred that, the antistatic additive be by stearic acid-base trimethyl ammonium chloride, stearoylketene dimethyl-penten ammonium chloride and Trihydroxyethyl methyl quaternary amine Methylsulfate compares 1.4-2.2 with weight:0.8-1.2:The mixture of 1 composition.
Species, compounding and weight proportion of the invention by strictly controlling antistatic additive so that ground cushion, which has, preferably leads Electro ultrafiltration, thus electrostatic can be made to leak in time.
It is preferred that, the mould inhibitor be by copper 8-quinolinolate, tributyltin chloride and diethyl -2,3- glycidyl - [3- (methyl dimethoxy epoxide)] silicon propyl ammonium chloride compares 0.8-1.2 with weight：1.4-2.2:The mixture of 1 composition.
The present invention can improve the fungicidal properties of ground cushion by strictly controlling the species of mould inhibitor, compounding and proportioning.
It is preferred that, the lubricant be by OPE, pentaerythritol stearate and ethylene bis stearamide with Weight compares 1.5-2.5:1:The mixture of 0.5-1.5 compositions.
The present invention can be such that material improves in process by strictly controlling the species of lubricant, compounding and proportioning The mobility of material and the release property of product, can reduce difficulty of processing, save energy resource consumption.
The PVC base layer is also including 0.5-1.5 parts of cold-resistant toughened dose 2-6 parts, 1-3 parts of compatilizer and antiseptic.
Described cold-resistant toughened dose is with weight ratio 1 by amide-type beta crystal-type nucleater and dicarboxylic acids salt beta crystal-type nucleater： 1.2-1.8 the mixture of composition.
The present invention is used as cold-resistant toughened dose by using amide-type beta crystal-type nucleater and dicarboxylic acids salt beta crystal-type nucleater Compounding use, and control its weight ratio to be 1：1.2-1.8 so that material in -20 DEG C of low temperature toughening effect substantially, more than normal temperature When impact strength, while rigidly being significantly improved under normal temperature.
The compatilizer is with weight ratio 1 by maleic anhydride inoculated polypropylene and styrene-grafted polypropylene：1.4-2.2 group Into mixture.
The present invention by using maleic anhydride inoculated polypropylene and styrene-grafted polypropylene as compatilizer compounding use, And control its weight ratio to be 1：1.4-2.2, can improve inorganic filler and organic resin compatibility, improve stretching, the impact of product Intensity, realizes high filling, reduces resin demand, improve rheological performance, improve surface smoothness.
The antiseptic is by zeolite with carrying silver and carries silver-colored cobalt phosphate and compare 1.5-2.5 with weight：The mixture of 1 composition.
The present invention is by using zeolite with carrying silver and carries silver-colored cobalt phosphate as antiseptic compounding use, and controls its weight ratio to be 1.5-2.5：1 so that not only tinting strength, tinting power height, good dispersion, spinnability are good for material, also with preferable sterilization, fungistatic effect.
The PVC base layer also includes 0.5-1.5 parts of 1-5 parts of fire retardant, 0.5-1.5 parts of slipping agent and pigment powder.
The fire retardant is with weight to compare 0.5-1.5 by antimony oxide and Firebrake ZB：The mixture of 1 composition.
Antimony oxide and line borate are inorganic environment-friendly fire retardant, and the present invention is by using antimony oxide and Firebrake ZB As fire retardant compounding use, and its weight ratio is controlled to be 0.5-1.5：1, good flame retardant effect can be reached, moreover it is possible to improve The processing characteristics and mechanical performance of material.
The slipping agent is with weight to compare 1.5-2.5 by erucyl amide, oleamide and N, N'- ethylene bis stearamide： 0.8-1.2：The mixture of 1 composition.
The present invention is by using erucyl amide, oleamide and N, N'- ethylene bis stearamide are as slipping agent and control Its weight ratio is 1.5-2.5：0.8-1.2：1, mechanical resistant stirring capacity and fingerprinting stress, finished product good forming effect, table can be strengthened Face is bright and clean, moreover it is possible to strengthen the extensibility of finished product, easy-to-draw not easily broken.
The pigment powder is titanium dioxide of the particle diameter at 1-5 μm；The titanium dioxide is by rutile type titanium white and anatase titanium dioxide Titanium dioxide compares 1 with weight：1.5-2.5 the mixture of composition.
The present invention using particle diameter in 1-5 μm of titanium dioxide as pigment powder, further using rutile type titanium white and sharp Titanium-type titanium dioxide compounding use, and control its weight ratio to be 1：1.5-2.5, with superior whiteness, tinting strength, tinting power, covering power, resistance to Hou Xing, heat resistance and chemical stability, particularly no toxicity.
A kind of preparation method of antistatic mould proof ground cushion, comprises the following steps：
（1）The preparation of PVC base layer：The raw material of PVC base layer is mixed, extruded shaping, PVC base layer is made；
（2）The preparation of silk thread braiding layer：By anti-skidding parallel and tension warp knitting into silk thread braiding layer；
（3）The preparation of ground cushion：By PVC base layer and the pressing of silk thread braiding layer, the mould proof ground cushion of high-antistatic is made.
The beneficial effects of the present invention are：The antistatic mould proof ground cushion of the present invention is antistatic and anti-mold effect is good, environmentally friendly nothing Poison, also with good intensity, toughness, anti-flammability and ageing resistace, excellent combination property.
The antistatic mould proof ground cushion of the present invention is made using a variety of high-environmental materials, without phthalate, without many PAH, without free phenol, not halogen-containing flame retardant, no boron compound, environmental protection is better than worlds such as European Union ROHS, DEHP, ATBC Standard, can be extensively using sphere of lifes such as ground cushions.
The preparation method step of the present invention is simple, convenient operation and control, steady quality, and production efficiency is high, and production cost is low, Up to the production of technical scale metaplasia.
Embodiment
For the ease of the understanding of those skilled in the art, with reference to embodiment, the present invention is further illustrated, real The content that the mode of applying is referred to not limitation of the invention.
Embodiment 1
A kind of antistatic mould proof ground cushion, including PVC base layer and the silk thread braiding layer for fitting in PVC base layer upper surface, it is described PVC base layer includes the raw material of following parts by weight：
100-120 parts of polyvinyl chloride resin
45-55 parts of plasticizer
5-15 parts of filler
6-10 parts of stabilizer
5-9 parts of impact modifier
2-4 parts of antistatic additive
1-3 parts of mould inhibitor
1.6-2.0 parts of lubricant.
The polyvinyl chloride resin is with weight ratio 1 by calcium carbide process PVC resin and ethylene process polyvinyl chloride resin:The mixture of 1-2 compositions.
The plasticizer is by hexamethylene 1,2- dioctyl phthalate diisononyl esters, synthesizes vegetable esters and epoxidized soybean oil with weight Compare 1.5-2.5:0.8-1.2:The mixture of 1 composition.
The filler is particle diameter at 1-5 μm and through the crystal calcium carbonate of boric acid ester coupler modification.
The stabilizer is by calcium laurate, zinc laurate, the different fork-fatty alcohol-phosphorous acid chelate compounds of carbon-based -4,4- two Polymer and hydrotalcite compare 2-4 with weight：1.5-3.5:0.8-1.2:The mixture of 1 composition.
The impact modifier is by haloflex, butyl acrylate/methylmethacrylate copolymer and methyl-prop E pioic acid methyl ester/butadiene/styrene copolymers compare 2-4 with weight:1.5-2.5:The mixture of 1 composition.
The antistatic additive is by stearic acid-base trimethyl ammonium chloride, stearoylketene dimethyl-penten ammonium chloride and trihydroxyethyl Methyl quaternary amine Methylsulfate compares 1.4-2.2 with weight:0.8-1.2:The mixture of 1 composition.
The mould inhibitor is by copper 8-quinolinolate, tributyltin chloride and diethyl -2,3- glycidyl-[3- (methyl Dimethoxy)] silicon propyl ammonium chloride compares 0.8-1.2 with weight：1.4-2.2:The mixture of 1 composition.
The lubricant is with weight ratio by OPE, pentaerythritol stearate and ethylene bis stearamide 1.5-2.5:1:The mixture of 0.5-1.5 compositions.
The PVC base layer is also including 0.5 part of cold-resistant toughened dose 2 parts, 1 part of compatilizer and antiseptic.
Described cold-resistant toughened dose is with weight ratio 1 by amide-type beta crystal-type nucleater and dicarboxylic acids salt beta crystal-type nucleater： The mixture of 1.2 compositions.
The compatilizer is with weight ratio 1 by maleic anhydride inoculated polypropylene and styrene-grafted polypropylene：1.4 compositions Mixture.
The antiseptic is by zeolite with carrying silver and carries silver-colored cobalt phosphate with weight ratio 1.5：The mixture of 1 composition.
The PVC base layer also includes 0.5 part of 1 part of fire retardant, 0.5 part of slipping agent and pigment powder.
The fire retardant is with weight ratio 0.5 by antimony oxide and Firebrake ZB：The mixture of 1 composition.
The slipping agent is with weight to compare 1.5 by erucyl amide, oleamide and N, N'- ethylene bis stearamide：0.8：1 The mixture of composition.
The pigment powder is titanium dioxide of the particle diameter at 1 μm；The titanium dioxide is by rutile type titanium white and anatase titanium dioxide titanium White powder compares 1 with weight：The mixture of 1.5 compositions.
A kind of preparation method of antistatic mould proof ground cushion, comprises the following steps：
（1）The preparation of PVC base layer：The raw material of PVC base layer is mixed, extruded shaping, PVC base layer is made；
（2）The preparation of silk thread braiding layer：By anti-skidding parallel and tension warp knitting into silk thread braiding layer；
（3）The preparation of ground cushion：By PVC base layer and the pressing of silk thread braiding layer, the mould proof ground cushion of high-antistatic is made.
Embodiment 2
A kind of antistatic mould proof ground cushion, including PVC base layer and the silk thread braiding layer for fitting in PVC base layer upper surface, it is described PVC base layer includes the raw material of following parts by weight：
100-120 parts of polyvinyl chloride resin
45-55 parts of plasticizer
5-15 parts of filler
6-10 parts of stabilizer
5-9 parts of impact modifier
2-4 parts of antistatic additive
1-3 parts of mould inhibitor
1.6-2.0 parts of lubricant.
The polyvinyl chloride resin is with weight ratio 1 by calcium carbide process PVC resin and ethylene process polyvinyl chloride resin:The mixture of 1-2 compositions.
The plasticizer is by hexamethylene 1,2- dioctyl phthalate diisononyl esters, synthesizes vegetable esters and epoxidized soybean oil with weight Compare 1.5-2.5:0.8-1.2:The mixture of 1 composition.
The filler is particle diameter at 1-5 μm and through the crystal calcium carbonate of boric acid ester coupler modification.
The stabilizer is by calcium laurate, zinc laurate, the different fork-fatty alcohol-phosphorous acid chelate compounds of carbon-based -4,4- two Polymer and hydrotalcite compare 2-4 with weight：1.5-3.5:0.8-1.2:The mixture of 1 composition.
The impact modifier is by haloflex, butyl acrylate/methylmethacrylate copolymer and methyl-prop E pioic acid methyl ester/butadiene/styrene copolymers compare 2-4 with weight:1.5-2.5:The mixture of 1 composition.
The antistatic additive is by stearic acid-base trimethyl ammonium chloride, stearoylketene dimethyl-penten ammonium chloride and trihydroxyethyl Methyl quaternary amine Methylsulfate compares 1.4-2.2 with weight:0.8-1.2:The mixture of 1 composition.
The mould inhibitor is by copper 8-quinolinolate, tributyltin chloride and diethyl -2,3- glycidyl-[3- (methyl Dimethoxy)] silicon propyl ammonium chloride compares 0.8-1.2 with weight：1.4-2.2:The mixture of 1 composition.
The lubricant is with weight ratio by OPE, pentaerythritol stearate and ethylene bis stearamide 1.5-2.5:1:The mixture of 0.5-1.5 compositions.
The PVC base layer is also including 0.8 part of cold-resistant toughened dose 3 parts, 1.5 parts of compatilizer and antiseptic.
Described cold-resistant toughened dose is with weight ratio 1 by amide-type beta crystal-type nucleater and dicarboxylic acids salt beta crystal-type nucleater： The mixture of 1.4 compositions.
The compatilizer is with weight ratio 1 by maleic anhydride inoculated polypropylene and styrene-grafted polypropylene：1.6 compositions Mixture.
The antiseptic is by zeolite with carrying silver and carries silver-colored cobalt phosphate with weight ratio 1.8：The mixture of 1 composition.
The PVC base layer also includes 0.8 part of 2 parts of fire retardant, 0.8 part of slipping agent and pigment powder.
The fire retardant is with weight ratio 0.8 by antimony oxide and Firebrake ZB：The mixture of 1 composition.
The slipping agent is with weight to compare 1.8 by erucyl amide, oleamide and N, N'- ethylene bis stearamide：0.9：1 The mixture of composition.
The pigment powder is titanium dioxide of the particle diameter at 2 μm；The titanium dioxide is by rutile type titanium white and anatase titanium dioxide titanium White powder compares 1 with weight：The mixture of 1.8 compositions.
A kind of preparation method of antistatic mould proof ground cushion, comprises the following steps：
（1）The preparation of PVC base layer：The raw material of PVC base layer is mixed, extruded shaping, PVC base layer is made；
（2）The preparation of silk thread braiding layer：By anti-skidding parallel and tension warp knitting into silk thread braiding layer；
（3）The preparation of ground cushion：By PVC base layer and the pressing of silk thread braiding layer, the mould proof ground cushion of high-antistatic is made.
Embodiment 3
A kind of antistatic mould proof ground cushion, including PVC base layer and the silk thread braiding layer for fitting in PVC base layer upper surface, it is described PVC base layer includes the raw material of following parts by weight：
100-120 parts of polyvinyl chloride resin
45-55 parts of plasticizer
5-15 parts of filler
6-10 parts of stabilizer
5-9 parts of impact modifier
2-4 parts of antistatic additive
1-3 parts of mould inhibitor
1.6-2.0 parts of lubricant.
The polyvinyl chloride resin is with weight ratio 1 by calcium carbide process PVC resin and ethylene process polyvinyl chloride resin:The mixture of 1-2 compositions.
The plasticizer is by hexamethylene 1,2- dioctyl phthalate diisononyl esters, synthesizes vegetable esters and epoxidized soybean oil with weight Compare 1.5-2.5:0.8-1.2:The mixture of 1 composition.
The filler is particle diameter at 1-5 μm and through the crystal calcium carbonate of boric acid ester coupler modification.
The stabilizer is by calcium laurate, zinc laurate, the different fork-fatty alcohol-phosphorous acid chelate compounds of carbon-based -4,4- two Polymer and hydrotalcite compare 2-4 with weight：1.5-3.5:0.8-1.2:The mixture of 1 composition.
The impact modifier is by haloflex, butyl acrylate/methylmethacrylate copolymer and methyl-prop E pioic acid methyl ester/butadiene/styrene copolymers compare 2-4 with weight:1.5-2.5:The mixture of 1 composition.
The antistatic additive is by stearic acid-base trimethyl ammonium chloride, stearoylketene dimethyl-penten ammonium chloride and trihydroxyethyl Methyl quaternary amine Methylsulfate compares 1.4-2.2 with weight:0.8-1.2:The mixture of 1 composition.
The mould inhibitor is by copper 8-quinolinolate, tributyltin chloride and diethyl -2,3- glycidyl-[3- (methyl Dimethoxy)] silicon propyl ammonium chloride compares 0.8-1.2 with weight：1.4-2.2:The mixture of 1 composition.
The lubricant is with weight ratio by OPE, pentaerythritol stearate and ethylene bis stearamide 1.5-2.5:1:The mixture of 0.5-1.5 compositions.
The PVC base layer is also including 1 part of cold-resistant toughened dose 4 parts, 2 parts of compatilizer and antiseptic.
Described cold-resistant toughened dose is with weight ratio 1 by amide-type beta crystal-type nucleater and dicarboxylic acids salt beta crystal-type nucleater： The mixture of 1.5 compositions.
The compatilizer is with weight ratio 1 by maleic anhydride inoculated polypropylene and styrene-grafted polypropylene：1.8 compositions Mixture.
The antiseptic is by zeolite with carrying silver and carries silver-colored cobalt phosphate with weight ratio 2：The mixture of 1 composition.
The PVC base layer also includes 1 part of 3 parts of fire retardant, 1 part of slipping agent and pigment powder.
The fire retardant is with weight ratio 1 by antimony oxide and Firebrake ZB：The mixture of 1 composition.
The slipping agent is with weight to compare 2 by erucyl amide, oleamide and N, N'- ethylene bis stearamide：1：1 composition Mixture.
The pigment powder is titanium dioxide of the particle diameter at 3 μm；The titanium dioxide is by rutile type titanium white and anatase titanium dioxide titanium White powder compares 1 with weight：The mixture of 2 compositions.
A kind of preparation method of antistatic mould proof ground cushion, comprises the following steps：
（1）The preparation of PVC base layer：The raw material of PVC base layer is mixed, extruded shaping, PVC base layer is made；
（2）The preparation of silk thread braiding layer：By anti-skidding parallel and tension warp knitting into silk thread braiding layer；
（3）The preparation of ground cushion：By PVC base layer and the pressing of silk thread braiding layer, the mould proof ground cushion of high-antistatic is made.
Embodiment 4
A kind of antistatic mould proof ground cushion, including PVC base layer and the silk thread braiding layer for fitting in PVC base layer upper surface, it is described PVC base layer includes the raw material of following parts by weight：
100-120 parts of polyvinyl chloride resin
45-55 parts of plasticizer
5-15 parts of filler
6-10 parts of stabilizer
5-9 parts of impact modifier
2-4 parts of antistatic additive
1-3 parts of mould inhibitor
1.6-2.0 parts of lubricant.
The polyvinyl chloride resin is with weight ratio 1 by calcium carbide process PVC resin and ethylene process polyvinyl chloride resin:The mixture of 1-2 compositions.
The plasticizer is by hexamethylene 1,2- dioctyl phthalate diisononyl esters, synthesizes vegetable esters and epoxidized soybean oil with weight Compare 1.5-2.5:0.8-1.2:The mixture of 1 composition.
The filler is particle diameter at 1-5 μm and through the crystal calcium carbonate of boric acid ester coupler modification.
The stabilizer is by calcium laurate, zinc laurate, the different fork-fatty alcohol-phosphorous acid chelate compounds of carbon-based -4,4- two Polymer and hydrotalcite compare 2-4 with weight：1.5-3.5:0.8-1.2:The mixture of 1 composition.
The impact modifier is by haloflex, butyl acrylate/methylmethacrylate copolymer and methyl-prop E pioic acid methyl ester/butadiene/styrene copolymers compare 2-4 with weight:1.5-2.5:The mixture of 1 composition.
The antistatic additive is by stearic acid-base trimethyl ammonium chloride, stearoylketene dimethyl-penten ammonium chloride and trihydroxyethyl Methyl quaternary amine Methylsulfate compares 1.4-2.2 with weight:0.8-1.2:The mixture of 1 composition.
The mould inhibitor is by copper 8-quinolinolate, tributyltin chloride and diethyl -2,3- glycidyl-[3- (methyl Dimethoxy)] silicon propyl ammonium chloride compares 0.8-1.2 with weight：1.4-2.2:The mixture of 1 composition.
The lubricant is with weight ratio by OPE, pentaerythritol stearate and ethylene bis stearamide 1.5-2.5:1:The mixture of 0.5-1.5 compositions.
The PVC base layer is also including 1.2 parts of cold-resistant toughened dose 5 parts, 2.5 parts of compatilizer and antiseptic.
Described cold-resistant toughened dose is with weight ratio 1 by amide-type beta crystal-type nucleater and dicarboxylic acids salt beta crystal-type nucleater： The mixture of 1.6 compositions.
The compatilizer is with weight ratio 1 by maleic anhydride inoculated polypropylene and styrene-grafted polypropylene：2 compositions it is mixed Compound.
The antiseptic is by zeolite with carrying silver and carries silver-colored cobalt phosphate with weight ratio 2.2：The mixture of 1 composition.
The PVC base layer also includes 1.2 parts of 4 parts of fire retardant, 1.2 parts of slipping agent and pigment powder.
The fire retardant is with weight ratio 1.2 by antimony oxide and Firebrake ZB：The mixture of 1 composition.
The slipping agent is with weight to compare 2.2 by erucyl amide, oleamide and N, N'- ethylene bis stearamide：1.1：1 The mixture of composition.
The pigment powder is titanium dioxide of the particle diameter at 4 μm；The titanium dioxide is by rutile type titanium white and anatase titanium dioxide titanium White powder compares 1 with weight：The mixture of 2.2 compositions.
A kind of preparation method of antistatic mould proof ground cushion, comprises the following steps：
（1）The preparation of PVC base layer：The raw material of PVC base layer is mixed, extruded shaping, PVC base layer is made；
（2）The preparation of silk thread braiding layer：By anti-skidding parallel and tension warp knitting into silk thread braiding layer；
（3）The preparation of ground cushion：By PVC base layer and the pressing of silk thread braiding layer, the mould proof ground cushion of high-antistatic is made.
Embodiment 5
A kind of antistatic mould proof ground cushion, including PVC base layer and the silk thread braiding layer for fitting in PVC base layer upper surface, it is described PVC base layer includes the raw material of following parts by weight：
100-120 parts of polyvinyl chloride resin
45-55 parts of plasticizer
5-15 parts of filler
6-10 parts of stabilizer
5-9 parts of impact modifier
2-4 parts of antistatic additive
1-3 parts of mould inhibitor
1.6-2.0 parts of lubricant.
The polyvinyl chloride resin is with weight ratio 1 by calcium carbide process PVC resin and ethylene process polyvinyl chloride resin:The mixture of 1-2 compositions.
The plasticizer is by hexamethylene 1,2- dioctyl phthalate diisononyl esters, synthesizes vegetable esters and epoxidized soybean oil with weight Compare 1.5-2.5:0.8-1.2:The mixture of 1 composition.
The filler is particle diameter at 1-5 μm and through the crystal calcium carbonate of boric acid ester coupler modification.
The stabilizer is by calcium laurate, zinc laurate, the different fork-fatty alcohol-phosphorous acid chelate compounds of carbon-based -4,4- two Polymer and hydrotalcite compare 2-4 with weight：1.5-3.5:0.8-1.2:The mixture of 1 composition.
The impact modifier is by haloflex, butyl acrylate/methylmethacrylate copolymer and methyl-prop E pioic acid methyl ester/butadiene/styrene copolymers compare 2-4 with weight:1.5-2.5:The mixture of 1 composition.
The antistatic additive is by stearic acid-base trimethyl ammonium chloride, stearoylketene dimethyl-penten ammonium chloride and trihydroxyethyl Methyl quaternary amine Methylsulfate compares 1.4-2.2 with weight:0.8-1.2:The mixture of 1 composition.
The mould inhibitor is by copper 8-quinolinolate, tributyltin chloride and diethyl -2,3- glycidyl-[3- (methyl Dimethoxy)] silicon propyl ammonium chloride compares 0.8-1.2 with weight：1.4-2.2:The mixture of 1 composition.
The lubricant is with weight ratio by OPE, pentaerythritol stearate and ethylene bis stearamide 1.5-2.5:1:The mixture of 0.5-1.5 compositions.
The PVC base layer is also including 1.5 parts of cold-resistant toughened dose 6 parts, 3 parts of compatilizer and antiseptic.
Described cold-resistant toughened dose is with weight ratio 1 by amide-type beta crystal-type nucleater and dicarboxylic acids salt beta crystal-type nucleater： The mixture of 1.8 compositions.
The compatilizer is with weight ratio 1 by maleic anhydride inoculated polypropylene and styrene-grafted polypropylene：2.2 compositions Mixture.
The antiseptic is by zeolite with carrying silver and carries silver-colored cobalt phosphate with weight ratio 2.5：The mixture of 1 composition.
The PVC base layer also includes 1.5 parts of 5 parts of fire retardant, 1.5 parts of slipping agent and pigment powder.
The fire retardant is with weight ratio 1.5 by antimony oxide and Firebrake ZB：The mixture of 1 composition.
The slipping agent is with weight to compare 2.5 by erucyl amide, oleamide and N, N'- ethylene bis stearamide：1.2：1 The mixture of composition.
The pigment powder is titanium dioxide of the particle diameter at 5 μm；The titanium dioxide is by rutile type titanium white and anatase titanium dioxide titanium White powder compares 1 with weight：The mixture of 2.5 compositions.
A kind of preparation method of antistatic mould proof ground cushion, comprises the following steps：
（1）The preparation of PVC base layer：The raw material of PVC base layer is mixed, extruded shaping, PVC base layer is made；
（2）The preparation of silk thread braiding layer：By anti-skidding parallel and tension warp knitting into silk thread braiding layer；
（3）The preparation of ground cushion：By PVC base layer and the pressing of silk thread braiding layer, the mould proof ground cushion of high-antistatic is made.
The mechanical and physical performance of antistatic mould proof ground cushion is as shown in table 1 made from embodiments of the invention 1-5.
Table 1
Test event Standard value Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5
Resistivity（Ω） ≥1.0×109 4.9×1013 3.2×1014 5.1×1014 6.7×1013 8.5×1013
Fungicidal properties Typically Preferably Preferably Preferably Preferably Preferably
Tensile strength（MPa） ≥15.0 23.2 25.3 26.6 27.1 24.2
Bending strength（MPa） ≥15.0 46.2 48.1 51.2 53.8 44.6
Elongation at break（%） ≥150 297 302 309 320 299
Heat distortion temperature（℃） ≥50.0 115.6 118.5 120.7 123.3 116.4
Impact brittle temperature（℃） ≤-20 -25 -25 -30 -30 -25
Heat-stable time at 200 DEG C（min） ≥60 90 110 120 120 100
Hardness/Shore D ≥50 80 83 85 86 81
It is fire-retardant V0 V0 V0 V0 V0 V0
As it can be seen from table 1 antistatic mould proof ground cushion produced by the present invention is antistatic and anti-mold effect is good, and it is environment-protecting and non-poisonous, also have There are good intensity, toughness, anti-flammability and ageing resistace, excellent combination property.The antistatic mould proof ground cushion of the present invention is used A variety of high-environmental materials are made, without phthalate, without polycyclic aromatic hydrocarbon, without free phenol, not halogen-containing flame retardant, nothing Boron compound, environmental protection, can be extensively using sphere of lifes such as ground cushions better than international standards such as European Union ROHS, DEHP, ATBC.
Above-described embodiment is the present invention preferably implementation, and in addition, the present invention can be realized with other manner, Any obvious replacement is within protection scope of the present invention on the premise of not departing from present inventive concept.

Claims (10)

1. a kind of antistatic mould proof ground cushion, it is characterised in that：Including PVC base layer and the silk for fitting in PVC base layer upper surface Line braiding layer, the PVC base layer includes the raw material of following parts by weight：
100-120 parts of polyvinyl chloride resin
45-55 parts of plasticizer
5-15 parts of filler
6-10 parts of stabilizer
5-9 parts of impact modifier
2-4 parts of antistatic additive
1-3 parts of mould inhibitor
1.6-2.0 parts of lubricant.
2. the antistatic mould proof ground cushion of one kind according to claim 1, it is characterised in that：The polyvinyl chloride resin is by carbide Polyvinyl chloride resin and ethylene process polyvinyl chloride resin are with weight ratio 1:The mixture of 1-2 compositions.
3. the antistatic mould proof ground cushion of one kind according to claim 1, it is characterised in that：The plasticizer be by hexamethylene 1, 2- dioctyl phthalate diisononyl esters, synthesis vegetable esters and epoxidized soybean oil compare 1.5-2.5 with weight:0.8-1.2:The mixing of 1 composition Thing.
4. the antistatic mould proof ground cushion of one kind according to claim 1, it is characterised in that：The filler is particle diameter in 1-5 μ M and through the crystal calcium carbonate of boric acid ester coupler modification.
5. the antistatic mould proof ground cushion of one kind according to claim 1, it is characterised in that：The stabilizer is by laurate Different fork-fatty alcohol-phosphorous acid chelate compounds the polymer of calcium, zinc laurate, carbon-based -4,4- two and hydrotalcite compare 2-4 with weight： 1.5-3.5:0.8-1.2:The mixture of 1 composition.
6. the antistatic mould proof ground cushion of one kind according to claim 1, it is characterised in that：The impact modifier is by chlorination Polyethylene, butyl acrylate/methylmethacrylate copolymer and methyl methacrylate/butadiene/styrene copolymers with Weight compares 2-4:1.5-2.5:The mixture of 1 composition.
7. the antistatic mould proof ground cushion of one kind according to claim 1, it is characterised in that：The antistatic additive is by stearic acid Base trimethyl ammonium chloride, stearoylketene dimethyl-penten ammonium chloride and trihydroxyethyl methyl quaternary amine Methylsulfate compare 1.4- with weight 2.2:0.8-1.2:The mixture of 1 composition.
8. the antistatic mould proof ground cushion of one kind according to claim 1, it is characterised in that：The mould inhibitor is by 8- hydroxyl quinolines Quinoline copper, tributyltin chloride and diethyl -2,3- glycidyl-[3- (methyl dimethoxy epoxide)] silicon propyl ammonium chloride are with weight ratio 0.8-1.2：1.4-2.2:The mixture of 1 composition.
9. the antistatic mould proof ground cushion of one kind according to claim 1, it is characterised in that：The lubricant is by aoxidizing poly- second Alkene wax, pentaerythritol stearate and ethylene bis stearamide compare 1.5-2.5 with weight:1:The mixture of 0.5-1.5 compositions.
10. a kind of preparation method of antistatic mould proof ground cushion as described in claim any one of 1-9, it is characterised in that：Including Following steps：
（1）The preparation of PVC base layer：The raw material of PVC base layer is mixed, extruded shaping, PVC base layer is made；
（2）The preparation of silk thread braiding layer：By anti-skidding parallel and tension warp knitting into silk thread braiding layer；
（3）The preparation of ground cushion：By PVC base layer and the pressing of silk thread braiding layer, the mould proof ground cushion of high-antistatic is made.
CN201710267356.5A 2017-04-21 2017-04-21 A kind of antistatic mould proof ground cushion and preparation method thereof Pending CN106977853A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109111657A (en) * 2018-08-17 2019-01-01 安徽瑞腾塑业有限公司 A kind of insulation PVC plastic
CN109610185A (en) * 2018-12-18 2019-04-12 思嘉环保材料科技（上海）有限公司 A kind of preparation method of PVC fabric
CN111499989A (en) * 2020-05-25 2020-08-07 江苏大海塑料股份有限公司 Nontoxic antibacterial compression-resistant plastic master batch and preparation method thereof
CN112940405A (en) * 2019-11-26 2021-06-11 东莞市乐晟塑胶科技有限公司 Antistatic plastic

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109111657A (en) * 2018-08-17 2019-01-01 安徽瑞腾塑业有限公司 A kind of insulation PVC plastic
CN109610185A (en) * 2018-12-18 2019-04-12 思嘉环保材料科技（上海）有限公司 A kind of preparation method of PVC fabric
CN112940405A (en) * 2019-11-26 2021-06-11 东莞市乐晟塑胶科技有限公司 Antistatic plastic
CN111499989A (en) * 2020-05-25 2020-08-07 江苏大海塑料股份有限公司 Nontoxic antibacterial compression-resistant plastic master batch and preparation method thereof

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Application publication date: 20170725