CN106947187A - A kind of sunlight fabric is material modified and preparation method thereof with PVC - Google Patents
A kind of sunlight fabric is material modified and preparation method thereof with PVC Download PDFInfo
- Publication number
- CN106947187A CN106947187A CN201710253975.9A CN201710253975A CN106947187A CN 106947187 A CN106947187 A CN 106947187A CN 201710253975 A CN201710253975 A CN 201710253975A CN 106947187 A CN106947187 A CN 106947187A
- Authority
- CN
- China
- Prior art keywords
- parts
- pvc
- weight
- material modified
- mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
- C08K2003/387—Borates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/08—Polymer mixtures characterised by other features containing additives to improve the compatibility between two polymers
Abstract
The present invention relates to PVC material technical field, and in particular to a kind of sunlight fabric is material modified and preparation method thereof with PVC, and the sunlight fabric includes the raw material of following parts by weight with PVC is material modified：80 120 parts of PVC with high, 40 60 parts of polymeric plasticizer, 10 15 parts of Anti- tarnishing calcium powder, 25 parts of high compound stabilizer, 1.0 1.4 parts of haloflex, 12 parts of modifying agent, 1.4 2.2 parts of age resistor, 0.6 1.0 parts of UV resistant agent, 0.1 0.5 parts of antioxidant, 0.6 1.0 parts of external lubricant.The sunlight fabric of the present invention is good with the material modified Anti- tarnishings of PVC and antiageing effect, environmental protection, and resistance to gentle weather resistance is excellent, and intensity is high, and excellent shock resistance, good flame retardation effect, processing characteristics is excellent, excellent combination property.
Description
Technical field
The present invention relates to PVC material technical field, and in particular to a kind of sunlight fabric is with PVC is material modified and its preparation side
Method.
Background technology
Polyvinyl chloride（PVC）One of earliest industrialization, widely used general-purpose thermoplastic plastic, it have light weight,
The advantages of intensity height, insulation, fire-retardant, corrosion-resistant, high comprehensive performance, cheap and extensive raw material sources；But there is also
Following shortcoming：1st, poor toughness, easily embrittlement when being hit, therefore cannot act as structural material, in addition, the fragility of polyvinyl chloride by
Temperature influence is very big, and it is -15 DEG C that general PVC product, which uses lower limit, and the use lower limit of flexible PVC is -30 DEG C；2nd, heat endurance
Difference, it begins to decomposite HCl at 100 DEG C, decomposes more rapid during higher than 150 DEG C, and PVC melting temperature is about 210
℃；3rd, PVC viscosity is high, mobility extreme difference, and it is limited to a certain extent and is used.People are frequently with addition filler, bullet
The methods such as property body, plasticizer, heat stabilizer, processing aid, heat-proof modifier and flow ability modifying agent improve PVC performance, but
It is not applied to the PVC material of sunlight fabric also in the prior art.
The content of the invention
In order to overcome shortcoming and defect present in prior art, it is an object of the invention to provide a kind of sunlight fabric use
PVC is material modified, and the sunlight fabric is good with the material modified Anti- tarnishings of PVC and antiageing effect, environmental protection, and resistance to gentle weather resistance
Excellent, intensity is high, and excellent shock resistance, good flame retardation effect, processing characteristics is excellent, excellent combination property.
Another object of the present invention is to provide the preparation method that a kind of sunlight fabric PVC is material modified, the preparation side
Method step is simple, convenient operation and control, steady quality, and production efficiency is high, and production cost is low, up to the production of technical scale metaplasia.
The purpose of the present invention is achieved through the following technical solutions：A kind of sunlight fabric is material modified with PVC, including following weight
Measure the raw material of part：
80-120 parts of PVC with high
40-60 parts of polymeric plasticizer
10-15 parts of Anti- tarnishing calcium powder
It is high compound stabilizer 2-5 parts
1.0-1.4 parts of haloflex
1-2 parts of modifying agent
1.4-2.2 parts of age resistor
0.6-1.0 parts of UV resistant agent
0.1-0.5 parts of antioxidant
0.6-1.0 parts of external lubricant.
It is preferred that, the PVC with high is SG-0 type polyvinyl chloride resin of the degree of polymerization in 1800-2000.The present invention is logical
Cross using above-mentioned polyvinyl chloride resin, obtained PVC is material modified to have high light weight, intensity, insulation, fire-retardant, corrosion-resistant, comprehensive
Can be excellent the advantages of.
The polymeric plasticizer is by epoxidized soybean oil, synthesizes vegetable esters and polyester plasticizer with weight and compare 1-2:0.8-
1.2:The mixture of 1 composition.Species, compounding and weight proportion of the invention by strictly controlling polymeric plasticizer, can drop
The active force of low plastic molecules interchain, making the glass transition temperature, flowing temperature and the fusing point of contained crystallite of plastics reduces, and can carry
The plasticity of high resin, makes product softness, resistance to low temperature good.
It is preferred that, the Anti- tarnishing calcium powder is the precipitated calcium carbonate that particle diameter is handled at 1-10 μm and through chelating agent.
The particle diameter of filler is smaller, and the tensile strength and impact strength to packing material are more beneficial, and the present invention is by selecting
Precipitated calcium carbonate is as filler and controls its particle diameter at 1-10 μm, and its crystal structure and Electronic Structure are changed,
Quantum size effect, small-size effect, skin effect and macroscopic quantum effect that conventional lightweight calcium carbonate does not have are generated,
Therefore with good toughened and reinforced effect, it, which is added in the edge band of the present invention, can improve bending strength and elasticity of flexure mould
The stability of amount and heat distortion temperature and size；Filler is to play its effect and control addition with the good compatibility of resin
The key of amount, the present invention can carry the compatible of precipitated calcium carbonate and polyvinyl chloride resin using the precipitated calcium carbonate that is handled through chelating agent
Property, so as to improve the intensity of material.
It is preferred that, the high compound stabilizer is with weight ratio by calcium stearate, zinc stearate and beta-diketon and zeolite
1.5-2.5:1-2:1:The mixture of 0.5-1.5 compositions.
The present invention is used as main body heat stabilizer by strictly using calcium stearate, zinc stearate, using beta-diketon and zeolite
As auxiliary heat stabilizer, main body heat stabilizer and auxiliary heat stabilizer compounding use make material good heat stability, with height
Weatherability is imitated, material can also be made to have good dispersiveness, compatibility and processing fluidity in process.
It is preferred that, the haloflex is haloflex of the chlorinty in 25%-45%.
The present invention, in 25%-45% haloflex, can improve the impact strength of material by using chlorinty, improve
The high temperature resistant and resistance to low temperature of material.
The modifying agent be by butyl acrylate/methylmethacrylate copolymer and methyl methacrylate/butadiene/
Styrol copolymer compares 1.5-2.5 with weight:The mixture of 1 composition.
The present invention can improve the impact strength of material, improve by strictly controlling the species of modifying agent, compounding and proportioning
The high temperature resistant and resistance to low temperature of material, can also reduce the melt viscosity of material, improve mobility, improve the processability of plastics
Can, extend the service life of product.
It is preferred that, the age resistor is to compare 0.8-1.2 by antioxidant A, antioxidant A W and anti-aging agent RD with weight:1:1.6-
The mixture of 2.4 compositions.
The present invention is by strictly controlling the species of age resistor, compounding and proportioning, and obtained PVC is material modified to be had preferably
Anti-aging effect.
It is preferred that, the ultra-violet absorber is by ultra-violet absorber UV-9, ultra-violet absorber UVP-327 and light
Stabilizer HPT compares 0.8-1.2 with weight:1:The mixture of 0.5-1.5 compositions.
Species, compounding and weight proportion of the invention by strictly controlling ultra-violet absorber, ultraviolet can be absorbed strongly,
With excellent cooperative effect.
It is preferred that, the antioxidant is to compare 1-2 by antioxidant 1010, antioxidant 1076 and irgasfos 168 with weight:0.8-
1.2:The mixture of 1 composition.
Species, compounding and weight proportion of the invention by strictly controlling antioxidant, can delay or suppress material oxidation
The progress of process, so as to prevent the aging of material and extend its service life.
It is preferred that, the external lubricant is to compare 0.8- by chlorinated paraffin, microcrystalline wax and OPE with weight
1.2:1:The mixture of 1.4-2.2 compositions.
The present invention by strictly controlling the species, compounding and weight proportion of external lubricant, can improve polymer melt with
The friction of the hot metal surface of coating apparatus is processed, it is poor with polymer compatibility, easily toward external migration out of melt, so
The thin layer that can be lubricated in the interface formation of plastic melt and metal.
The sunlight fabric is material modified also including cold-resistant toughened dose 2-6 parts, 1-3 parts of compatilizer and antiseptic with PVC
0.5-1.5 parts.
Described cold-resistant toughened dose is with weight ratio 1 by amide-type beta crystal-type nucleater and dicarboxylic acids salt beta crystal-type nucleater：
The mixture of 1.2-1.8 compositions.
The present invention is used as cold-resistant toughened dose by using amide-type beta crystal-type nucleater and dicarboxylic acids salt beta crystal-type nucleater
Compounding use, and it is 1 to control its weight ratio：1.2-1.8 so that material in -20 DEG C of low temperature toughening effect substantially, more than normal temperature
When impact strength, while rigidly being significantly improved under normal temperature.
The compatilizer is with weight ratio 1 by maleic anhydride inoculated polypropylene and styrene-grafted polypropylene：1.4-2.2 groups
Into mixture.
The present invention by using maleic anhydride inoculated polypropylene and styrene-grafted polypropylene as compatilizer compounding use,
And it is 1 to control its weight ratio：1.4-2.2, can improve inorganic filler and organic resin compatibility, improve stretching, the impact of product
Intensity, realizes high filling, reduces resin demand, improve rheological performance, improve surface smoothness.
The antiseptic is to compare 1.5-2.5 by zeolite with carrying silver and the silver-colored cobalt phosphate of load with weight：The mixture of 1 composition.
The present invention is by using zeolite with carrying silver and carries silver-colored cobalt phosphate as antiseptic compounding use, and controls its weight ratio to be
1.5-2.5：1 so that not only tinting strength, tinting power height, good dispersion, spinnability are good for material, also with preferable sterilized, fungistatic effect.
The sunlight fabric also includes 1-5 parts of fire retardant, 0.5-1.5 parts of slipping agent and pigment powder with PVC is material modified
0.5-1.5 parts.
The fire retardant is to compare 0.5-1.5 by antimony oxide and Firebrake ZB with weight：The mixture of 1 composition.
Antimony oxide and line borate are inorganic environment-friendly fire retardant, and the present invention is by using antimony oxide and Firebrake ZB
As fire retardant compounding use, and it is 0.5-1.5 to control its weight ratio：1, good flame retardant effect can be reached, moreover it is possible to improve
The processing characteristics and mechanical performance of material.
The slipping agent is to compare 1.5-2.5 by erucyl amide, oleamide and N, N'- ethylene bis stearamide with weight：
0.8-1.2：The mixture of 1 composition.
The present invention is by using erucyl amide, oleamide and N, N'- ethylene bis stearamide are as slipping agent and control
Its weight ratio is 1.5-2.5：0.8-1.2：1, mechanical resistant stirring capacity and fingerprinting stress, finished product good forming effect, table can be strengthened
Face is bright and clean, moreover it is possible to strengthen the extensibility of finished product, easy-to-draw not easily broken.
The pigment powder is titanium dioxide of the particle diameter at 1-5 μm；The titanium dioxide is by rutile type titanium white and anatase titanium dioxide
Titanium dioxide compares 1 with weight：The mixture of 1.5-2.5 compositions.
The present invention using particle diameter in 1-5 μm of titanium dioxide as pigment powder, further using rutile type titanium white and sharp
Titanium-type titanium dioxide compounding use, and it is 1 to control its weight ratio：1.5-2.5, with superior whiteness, tinting strength, tinting power, covering power, resistance to
Hou Xing, heat resistance and chemical stability, particularly no toxicity.
A kind of sunlight fabric is comprised the following steps with preparation method material modified PVC：
（1）Above-mentioned raw materials are weighed by the parts by weight of constitutive material, are mixed；
（2）Mixed raw material is put into high speed blender, 15-25min is stirred at a temperature of 100-140 DEG C；
（3）By the raw material after stirring by double screw extruder extruding pelletization, sunlight fabric is made material modified with PVC；It is described
The extruder temperature of double screw extruder is：One 138-160 DEG C of area's temperature, two 135-160 DEG C of area's temperature, three area temperature 135-155
DEG C, 130-148 DEG C of the area's temperature of four area temperature 132-150 DEG CHe five.
The beneficial effects of the present invention are：The sunlight fabric material modified Anti- tarnishings of PVC and the antiageing effect of the present invention
It is good, environmental protection, and resistance to gentle weather resistance is excellent, intensity is high, and excellent shock resistance, good flame retardation effect, processing characteristics is excellent, comprehensive
Close excellent performance.
The present invention is using the sunlight fabric material modified smooth in appearance of PVC made from a variety of high-environmental materials, without adjacent benzene
Diformate, without polycyclic aromatic hydrocarbon, without free phenol, not halogen-containing flame retardant, no boron compound, environmental protection better than European Union ROHS,
The international standards such as DEHP, ATBC, can be widely applied to the sphere of lifes such as sunlight fabric.
The preparation method step of the present invention is simple, convenient operation and control, steady quality, and production efficiency is high, and production cost is low,
Up to the production of technical scale metaplasia.
Embodiment
For the ease of the understanding of those skilled in the art, with reference to embodiment, the present invention is further illustrated, real
The content that the mode of applying is referred to not limitation of the invention.
Embodiment 1
A kind of sunlight fabric is material modified with PVC, includes the raw material of following parts by weight：
80 parts of PVC with high
40 parts of polymeric plasticizer
10 parts of Anti- tarnishing calcium powder
High 2 parts of compound stabilizer
1.0 parts of haloflex
1 part of modifying agent
1.4 parts of age resistor
0.6 part of UV resistant agent
0.1 part of antioxidant
0.6 part of external lubricant.
The PVC with high is SG-0 type polyvinyl chloride resin of the degree of polymerization 1800；The polymeric plasticizer be by
Epoxidized soybean oil, synthesis vegetable esters and polyester plasticizer are with weight ratio 1:0.8:The mixture of 1 composition.
The Anti- tarnishing calcium powder is the precipitated calcium carbonate that particle diameter is handled at 1 μm and through chelating agent.
The high compound stabilizer is with weight ratio 1.5 by calcium stearate, zinc stearate and beta-diketon and zeolite:1:1:
The mixture of 0.5 composition.
The haloflex is haloflex of the chlorinty 25%；The modifying agent is by butyl acrylate/methyl
Methyl acrylate copolymer and methyl methacrylate/butadiene/styrene copolymers are with weight ratio 1.5:The mixing of 1 composition
Thing.
The age resistor is with weight ratio 0.8 by antioxidant A, antioxidant A W and anti-aging agent RD:1:The mixing of 1.6 compositions
Thing.
The ultra-violet absorber is by ultra-violet absorber UV-9, ultra-violet absorber UVP-327 and light stabilizer
HPT compares 0.8 with weight:1:The mixture of 0.5 composition.
The antioxidant is with weight ratio 1 by antioxidant 1010, antioxidant 1076 and irgasfos 168:0.8:1 composition it is mixed
Compound.
The external lubricant is with weight ratio 0.8 by chlorinated paraffin, microcrystalline wax and OPE:1:1.4 compositions
Mixture.
The sunlight fabric is material modified also including 0.5 part of cold-resistant toughened dose 2 parts, 1 part of compatilizer and antiseptic with PVC.
Described cold-resistant toughened dose is with weight ratio 1 by amide-type beta crystal-type nucleater and dicarboxylic acids salt beta crystal-type nucleater：
The mixture of 1.2 compositions.
The compatilizer is with weight ratio 1 by maleic anhydride inoculated polypropylene and styrene-grafted polypropylene：1.4 compositions
Mixture.
The antiseptic is by zeolite with carrying silver and carries silver-colored cobalt phosphate with weight ratio 1.5：The mixture of 1 composition.
The sunlight fabric also includes 0.5 part of 1 part of fire retardant, 0.5 part of slipping agent and pigment powder with PVC is material modified.
The fire retardant is with weight ratio 0.5 by antimony oxide and Firebrake ZB：The mixture of 1 composition.
The slipping agent is to compare 1.5 by erucyl amide, oleamide and N, N'- ethylene bis stearamide with weight：0.8：1
The mixture of composition.
The pigment powder is titanium dioxide of the particle diameter at 1 μm；The titanium dioxide is by rutile type titanium white and anatase titanium dioxide titanium
White powder compares 1 with weight：The mixture of 1.5 compositions.
A kind of sunlight fabric is comprised the following steps with preparation method material modified PVC：
（1）Above-mentioned raw materials are weighed by the parts by weight of constitutive material, are mixed；
（2）Mixed raw material is put into high speed blender, 15min is stirred at a temperature of 100 DEG C；
（3）By the raw material after stirring by double screw extruder extruding pelletization, sunlight fabric is made material modified with PVC；It is described
The extruder temperature of double screw extruder is：One 138 DEG C of area's temperature, 135 DEG C of two area's temperature, 135 DEG C of three area's temperature, four area's temperature
130 DEG C of 132 DEG CHe, five area's temperature.
Embodiment 2
A kind of sunlight fabric is material modified with PVC, includes the raw material of following parts by weight：
90 parts of PVC with high
45 parts of polymeric plasticizer
11 parts of Anti- tarnishing calcium powder
High 3 parts of compound stabilizer
1.1 parts of haloflex
1.2 parts of modifying agent
1.6 parts of age resistor
0.7 part of UV resistant agent
0.2 part of antioxidant
0.7 part of external lubricant.
The PVC with high is SG-0 type polyvinyl chloride resin of the degree of polymerization 1850；The polymeric plasticizer be by
Epoxidized soybean oil, synthesis vegetable esters and polyester plasticizer are with weight ratio 1.2:0.9:The mixture of 1 composition.
The Anti- tarnishing calcium powder is the precipitated calcium carbonate that particle diameter is handled at 3 μm and through chelating agent.
The high compound stabilizer is with weight ratio 1.8 by calcium stearate, zinc stearate and beta-diketon and zeolite:1.2:1:
The mixture of 0.8 composition.
The haloflex is haloflex of the chlorinty 30%；The modifying agent is by butyl acrylate/methyl
Methyl acrylate copolymer and methyl methacrylate/butadiene/styrene copolymers are with weight ratio 1.8:The mixing of 1 composition
Thing.
The age resistor is with weight ratio 0.9 by antioxidant A, antioxidant A W and anti-aging agent RD:1:The mixing of 1.8 compositions
Thing.
The ultra-violet absorber is by ultra-violet absorber UV-9, ultra-violet absorber UVP-327 and light stabilizer
HPT compares 0.9 with weight:1:The mixture of 0.8 composition.
The antioxidant is with weight ratio 1.2 by antioxidant 1010, antioxidant 1076 and irgasfos 168:0.9:1 composition
Mixture.
The external lubricant is with weight ratio 0.9 by chlorinated paraffin, microcrystalline wax and OPE:1:1.6 compositions
Mixture.
The sunlight fabric is material modified also including cold-resistant toughened dose 3 parts, 1.5 parts of compatilizer and antiseptic 0.8 with PVC
Part.
Described cold-resistant toughened dose is with weight ratio 1 by amide-type beta crystal-type nucleater and dicarboxylic acids salt beta crystal-type nucleater：
The mixture of 1.4 compositions.
The compatilizer is with weight ratio 1 by maleic anhydride inoculated polypropylene and styrene-grafted polypropylene：1.6 compositions
Mixture.
The antiseptic is by zeolite with carrying silver and carries silver-colored cobalt phosphate with weight ratio 1.8：The mixture of 1 composition.
The sunlight fabric also includes 0.8 part of 2 parts of fire retardant, 0.8 part of slipping agent and pigment powder with PVC is material modified.
The fire retardant is with weight ratio 0.8 by antimony oxide and Firebrake ZB：The mixture of 1 composition.
The slipping agent is to compare 1.8 by erucyl amide, oleamide and N, N'- ethylene bis stearamide with weight：0.9：1
The mixture of composition.
The pigment powder is titanium dioxide of the particle diameter at 2 μm；The titanium dioxide is by rutile type titanium white and anatase titanium dioxide titanium
White powder compares 1 with weight：The mixture of 1.8 compositions.
A kind of sunlight fabric is comprised the following steps with preparation method material modified PVC：
（1）Above-mentioned raw materials are weighed by the parts by weight of constitutive material, are mixed；
（2）Mixed raw material is put into high speed blender, 18min is stirred at a temperature of 110 DEG C；
（3）By the raw material after stirring by double screw extruder extruding pelletization, sunlight fabric is made material modified with PVC；It is described
The extruder temperature of double screw extruder is：One 144 DEG C of area's temperature, 141 DEG C of two area's temperature, 140 DEG C of three area's temperature, four area's temperature
135 DEG C of 136 DEG CHe, five area's temperature.
Embodiment 3
A kind of sunlight fabric is material modified with PVC, includes the raw material of following parts by weight：
100 parts of PVC with high
50 parts of polymeric plasticizer
12 parts of Anti- tarnishing calcium powder
High 3.5 parts of compound stabilizer
1.2 parts of haloflex
1.5 parts of modifying agent
1.8 parts of age resistor
0.8 part of UV resistant agent
0.3 part of antioxidant
0.8 part of external lubricant.
The PVC with high is SG-0 type polyvinyl chloride resin of the degree of polymerization 1900；The polymeric plasticizer be by
Epoxidized soybean oil, synthesis vegetable esters and polyester plasticizer are with weight ratio 1.5:1:The mixture of 1 composition.
The Anti- tarnishing calcium powder is the precipitated calcium carbonate that particle diameter is handled at 5 μm and through chelating agent.
The high compound stabilizer is with weight ratio 2 by calcium stearate, zinc stearate and beta-diketon and zeolite:1.5:1:1
The mixture of composition.
The haloflex is haloflex of the chlorinty 35%；The modifying agent is by butyl acrylate/methyl
Methyl acrylate copolymer and methyl methacrylate/butadiene/styrene copolymers are with weight ratio 2:The mixture of 1 composition.
The age resistor is with weight ratio 1 by antioxidant A, antioxidant A W and anti-aging agent RD:1:The mixture of 2 compositions.
The ultra-violet absorber is by ultra-violet absorber UV-9, ultra-violet absorber UVP-327 and light stabilizer
HPT compares 1 with weight:1:The mixture of 1 composition.
The antioxidant is with weight ratio 1.5 by antioxidant 1010, antioxidant 1076 and irgasfos 168:1:1 composition it is mixed
Compound.
The external lubricant is with weight ratio 1 by chlorinated paraffin, microcrystalline wax and OPE:1:1.8 compositions
Mixture.
The sunlight fabric is material modified also including 1 part of cold-resistant toughened dose 4 parts, 2 parts of compatilizer and antiseptic with PVC.
Described cold-resistant toughened dose is with weight ratio 1 by amide-type beta crystal-type nucleater and dicarboxylic acids salt beta crystal-type nucleater：
The mixture of 1.5 compositions.
The compatilizer is with weight ratio 1 by maleic anhydride inoculated polypropylene and styrene-grafted polypropylene：1.8 compositions
Mixture.
The antiseptic is by zeolite with carrying silver and carries silver-colored cobalt phosphate with weight ratio 2：The mixture of 1 composition.
The sunlight fabric also includes 1 part of 3 parts of fire retardant, 1 part of slipping agent and pigment powder with PVC is material modified.
The fire retardant is with weight ratio 1 by antimony oxide and Firebrake ZB：The mixture of 1 composition.
The slipping agent is to compare 2 by erucyl amide, oleamide and N, N'- ethylene bis stearamide with weight：1：1 composition
Mixture.
The pigment powder is titanium dioxide of the particle diameter at 3 μm；The titanium dioxide is by rutile type titanium white and anatase titanium dioxide titanium
White powder compares 1 with weight：The mixture of 2 compositions.
A kind of sunlight fabric is comprised the following steps with preparation method material modified PVC：
（1）Above-mentioned raw materials are weighed by the parts by weight of constitutive material, are mixed；
（2）Mixed raw material is put into high speed blender, 20min is stirred at a temperature of 120 DEG C；
（3）By the raw material after stirring by double screw extruder extruding pelletization, sunlight fabric is made material modified with PVC；It is described
The extruder temperature of double screw extruder is：One 149 DEG C of area's temperature, 147 DEG C of two area's temperature, 145 DEG C of three area's temperature, four area's temperature
139 DEG C of 141 DEG CHe, five area's temperature.
Embodiment 4
A kind of sunlight fabric is material modified with PVC, includes the raw material of following parts by weight：
110 parts of PVC with high
55 parts of polymeric plasticizer
14 parts of Anti- tarnishing calcium powder
High 4 parts of compound stabilizer
1.3 parts of haloflex
1.8 parts of modifying agent
2 parts of age resistor
0.9 part of UV resistant agent
0.4 part of antioxidant
0.9 part of external lubricant.
The PVC with high is SG-0 type polyvinyl chloride resin of the degree of polymerization 1950；The polymeric plasticizer be by
Epoxidized soybean oil, synthesis vegetable esters and polyester plasticizer are with weight ratio 1.8:1.1:The mixture of 1 composition.
The Anti- tarnishing calcium powder is the precipitated calcium carbonate that particle diameter is handled at 8 μm and through chelating agent.
The high compound stabilizer is with weight ratio 2.2 by calcium stearate, zinc stearate and beta-diketon and zeolite:1.8:1:
The mixture of 1.2 compositions.
The haloflex is haloflex of the chlorinty 40%；The modifying agent is by butyl acrylate/methyl
Methyl acrylate copolymer and methyl methacrylate/butadiene/styrene copolymers are with weight ratio 2.2:The mixing of 1 composition
Thing.
The age resistor is with weight ratio 1.1 by antioxidant A, antioxidant A W and anti-aging agent RD:1:The mixing of 2.2 compositions
Thing.
The ultra-violet absorber is by ultra-violet absorber UV-9, ultra-violet absorber UVP-327 and light stabilizer
HPT compares 1.1 with weight:1:The mixture of 1.2 compositions.
The antioxidant is with weight ratio 1.8 by antioxidant 1010, antioxidant 1076 and irgasfos 168:1.1:1 composition
Mixture.
The external lubricant is to compare 0.8-1.2 by chlorinated paraffin, microcrystalline wax and OPE with weight:1:1.4-
The mixture of 2.2 compositions.
The sunlight fabric is material modified also including cold-resistant toughened dose 5 parts, 2.5 parts of compatilizer and antiseptic 1.2 with PVC
Part.
Described cold-resistant toughened dose is with weight ratio 1 by amide-type beta crystal-type nucleater and dicarboxylic acids salt beta crystal-type nucleater：
The mixture of 1.6 compositions.
The compatilizer is with weight ratio 1 by maleic anhydride inoculated polypropylene and styrene-grafted polypropylene：2 compositions it is mixed
Compound.
The antiseptic is by zeolite with carrying silver and carries silver-colored cobalt phosphate with weight ratio 2.2：The mixture of 1 composition.
The sunlight fabric also includes 1.2 parts of 4 parts of fire retardant, 1.2 parts of slipping agent and pigment powder with PVC is material modified.
The fire retardant is with weight ratio 1.2 by antimony oxide and Firebrake ZB：The mixture of 1 composition.
The slipping agent is to compare 2.2 by erucyl amide, oleamide and N, N'- ethylene bis stearamide with weight：1.1：1
The mixture of composition.
The pigment powder is titanium dioxide of the particle diameter at 4 μm；The titanium dioxide is by rutile type titanium white and anatase titanium dioxide titanium
White powder compares 1 with weight：The mixture of 2.2 compositions.
A kind of sunlight fabric is comprised the following steps with preparation method material modified PVC：
（1）Above-mentioned raw materials are weighed by the parts by weight of constitutive material, are mixed；
（2）Mixed raw material is put into high speed blender, 22min is stirred at a temperature of 130 DEG C；
（3）By the raw material after stirring by double screw extruder extruding pelletization, sunlight fabric is made material modified with PVC；It is described
The extruder temperature of double screw extruder is：One 155 DEG C of area's temperature, 153 DEG C of two area's temperature, 150 DEG C of three area's temperature, four area's temperature
144 DEG C of 145 DEG CHe, five area's temperature.
Embodiment 5
A kind of sunlight fabric is material modified with PVC, includes the raw material of following parts by weight：
120 parts of PVC with high
60 parts of polymeric plasticizer
15 parts of Anti- tarnishing calcium powder
High 5 parts of compound stabilizer
1.4 parts of haloflex
2 parts of modifying agent
2.2 parts of age resistor
1.0 parts of UV resistant agent
0.5 part of antioxidant
1.0 parts of external lubricant.
The PVC with high is SG-0 type polyvinyl chloride resin of the degree of polymerization 2000；The polymeric plasticizer be by
Epoxidized soybean oil, synthesis vegetable esters and polyester plasticizer are with weight ratio 2:1.2:The mixture of 1 composition.
The Anti- tarnishing calcium powder is the precipitated calcium carbonate that particle diameter is handled at 10 μm and through chelating agent.
The high compound stabilizer is with weight ratio 2.5 by calcium stearate, zinc stearate and beta-diketon and zeolite:2:1:
The mixture of 1.5 compositions.
The haloflex is haloflex of the chlorinty 45%；The modifying agent is by butyl acrylate/methyl
Methyl acrylate copolymer and methyl methacrylate/butadiene/styrene copolymers are with weight ratio 2.5:The mixing of 1 composition
Thing.
The age resistor is with weight ratio 1.2 by antioxidant A, antioxidant A W and anti-aging agent RD:1:The mixing of 2.4 compositions
Thing.
The ultra-violet absorber is by ultra-violet absorber UV-9, ultra-violet absorber UVP-327 and light stabilizer
HPT compares 1.2 with weight:1:The mixture of 1.5 compositions.
The antioxidant is with weight ratio 2 by antioxidant 1010, antioxidant 1076 and irgasfos 168:1.2:1 composition it is mixed
Compound.
The external lubricant is with weight ratio 1.2 by chlorinated paraffin, microcrystalline wax and OPE:1:2.2 compositions
Mixture.
The sunlight fabric is material modified also including 1.5 parts of cold-resistant toughened dose 6 parts, 3 parts of compatilizer and antiseptic with PVC.
Described cold-resistant toughened dose is with weight ratio 1 by amide-type beta crystal-type nucleater and dicarboxylic acids salt beta crystal-type nucleater：
The mixture of 1.8 compositions.
The compatilizer is with weight ratio 1 by maleic anhydride inoculated polypropylene and styrene-grafted polypropylene：2.2 compositions
Mixture.
The antiseptic is by zeolite with carrying silver and carries silver-colored cobalt phosphate with weight ratio 2.5：The mixture of 1 composition.
The sunlight fabric also includes 1.5 parts of 5 parts of fire retardant, 1.5 parts of slipping agent and pigment powder with PVC is material modified.
The fire retardant is with weight ratio 1.5 by antimony oxide and Firebrake ZB：The mixture of 1 composition.
The slipping agent is to compare 2.5 by erucyl amide, oleamide and N, N'- ethylene bis stearamide with weight：1.2：1
The mixture of composition.
The pigment powder is titanium dioxide of the particle diameter at 5 μm；The titanium dioxide is by rutile type titanium white and anatase titanium dioxide titanium
White powder compares 1 with weight：The mixture of 2.5 compositions.
A kind of sunlight fabric is comprised the following steps with preparation method material modified PVC：
（1）Above-mentioned raw materials are weighed by the parts by weight of constitutive material, are mixed；
（2）Mixed raw material is put into high speed blender, 25min is stirred at a temperature of 140 DEG C；
（3）By the raw material after stirring by double screw extruder extruding pelletization, sunlight fabric is made material modified with PVC；It is described
The extruder temperature of double screw extruder is：One 160 DEG C of area's temperature, 160 DEG C of two area's temperature, 155 DEG C of three area's temperature, four area's temperature
148 DEG C of 150 DEG CHe, five area's temperature.
Sunlight fabric made from embodiment 1-5 is as shown in table 1 with the material modified mechanical and physical performances of PVC：
Table 1
| Test event | Standard value | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 |
| Tensile strength（MPa） | ≥15.0 | 37.8 | 39.3 | 39.7 | 36.8 | 38.5 |
| Bending strength（MPa） | ≥15.0 | 62.5 | 65.3 | 67.1 | 58.9 | 63.7 |
| Elongation at break（%） | ≥150 | 312 | 319 | 331 | 309 | 325 |
| Heat distortion temperature（℃） | ≥50.0 | 127.6 | 129.8 | 131.4 | 125.6 | 128.9 |
| Impact brittle temperature（℃） | ≤-20 | -35 | -40 | -40 | -35 | -40 |
| Heat-stable time at 200 DEG C（min） | ≥60 | 120 | 130 | 130 | 110 | 120 |
| Hardness/Shore D | ≥50 | 88 | 90 | 91 | 86 | 89 |
| It is fire-retardant | V0 | V0 | V0 | V0 | V0 | V0 |
| Anti- tarnishing effect | It is poor | Preferably | Preferably | Preferably | Preferably | Preferably |
| Ultraviolet light and aging is tested（h） | ≥504 | 1008 | 1008 | 1008 | 1008 | 1008 |
| Oxidation Resistance Test（h） | ≥504 | 1008 | 1008 | 1008 | 1008 | 1008 |
As it can be seen from table 1 sunlight fabric produced by the present invention is good with the material modified Anti- tarnishings of PVC and antiageing effect, environmental protection,
And resistance to gentle weather resistance is excellent, intensity is high, and excellent shock resistance, good flame retardation effect, processing characteristics is excellent, and combination property is excellent
It is different.
Above-described embodiment is the present invention preferably implementation, and in addition, the present invention can be realized with other manner,
Any obvious replacement is within protection scope of the present invention on the premise of not departing from present inventive concept.
Claims (10)
1. a kind of sunlight fabric is material modified with PVC, it is characterised in that：Include the raw material of following parts by weight：
80-120 parts of PVC with high
40-60 parts of polymeric plasticizer
10-15 parts of Anti- tarnishing calcium powder
It is high compound stabilizer 2-5 parts
1.0-1.4 parts of haloflex
1-2 parts of modifying agent
1.4-2.2 parts of age resistor
0.6-1.0 parts of UV resistant agent
0.1-0.5 parts of antioxidant
0.6-1.0 parts of external lubricant.
2. a kind of sunlight fabric according to claim 1 is material modified with PVC, it is characterised in that：The high DP PVC
Resin is SG-0 type polyvinyl chloride resin of the degree of polymerization in 1800-2000；The polymeric plasticizer is by epoxidized soybean oil, synthesizes plant
Thing ester and polyester plasticizer compare 1-2 with weight:0.8-1.2:The mixture of 1 composition.
3. a kind of sunlight fabric according to claim 1 is material modified with PVC, it is characterised in that：The Anti- tarnishing calcium powder
The precipitated calcium carbonate handled for particle diameter at 1-10 μm and through chelating agent.
4. a kind of sunlight fabric according to claim 1 is material modified with PVC, it is characterised in that：The high stable composition
Agent is to compare 1.5-2.5 by calcium stearate, zinc stearate and beta-diketon and zeolite with weight:1-2:1:The mixing of 0.5-1.5 compositions
Thing.
5. a kind of sunlight fabric according to claim 1 is material modified with PVC, it is characterised in that：The haloflex
For chlorinty 25%-45% haloflex；The modifying agent be by butyl acrylate/methylmethacrylate copolymer and
Methyl methacrylate/butadiene/styrene copolymers compare 1.5-2.5 with weight:The mixture of 1 composition.
6. a kind of sunlight fabric according to claim 1 is material modified with PVC, it is characterised in that：The age resistor be by
Antioxidant A, antioxidant A W and anti-aging agent RD compare 0.8-1.2 with weight:1:The mixture of 1.6-2.4 compositions.
7. a kind of sunlight fabric according to claim 1 is material modified with PVC, it is characterised in that：The ultraviolet radiation absorption
Agent is to compare 0.8-1.2 by ultra-violet absorber UV-9, ultra-violet absorber UVP-327 and light stabilizer HPT with weight:1:
The mixture of 0.5-1.5 compositions.
8. a kind of sunlight fabric according to claim 1 is material modified with PVC, it is characterised in that：The antioxidant be by
Antioxidant 1010, antioxidant 1076 and irgasfos 168 compare 1-2 with weight:0.8-1.2:The mixture of 1 composition.
9. a kind of sunlight fabric according to claim 1 is material modified with PVC, it is characterised in that：The external lubricant is
0.8-1.2 is compared with weight by chlorinated paraffin, microcrystalline wax and OPE:1:The mixture of 1.4-2.2 compositions.
10. a kind of sunlight fabric as described in claim any one of 1-9 is existed with preparation method material modified PVC, its feature
In：Comprise the following steps：
（1）Above-mentioned raw materials are weighed by the parts by weight of constitutive material, are mixed；
（2）Mixed raw material is put into high speed blender, 15-25min is stirred at a temperature of 100-140 DEG C；
（3）By the raw material after stirring by double screw extruder extruding pelletization, sunlight fabric is made material modified with PVC；It is described
The extruder temperature of double screw extruder is：One 138-160 DEG C of area's temperature, two 135-160 DEG C of area's temperature, three area temperature 135-155
DEG C, 130-148 DEG C of the area's temperature of four area temperature 132-150 DEG CHe five.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710253975.9A CN106947187A (en) | 2017-04-18 | 2017-04-18 | A kind of sunlight fabric is material modified and preparation method thereof with PVC |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710253975.9A CN106947187A (en) | 2017-04-18 | 2017-04-18 | A kind of sunlight fabric is material modified and preparation method thereof with PVC |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106947187A true CN106947187A (en) | 2017-07-14 |
Family
ID=59476240
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710253975.9A Pending CN106947187A (en) | 2017-04-18 | 2017-04-18 | A kind of sunlight fabric is material modified and preparation method thereof with PVC |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106947187A (en) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107254124A (en) * | 2017-07-31 | 2017-10-17 | 广东祺龙科技有限公司 | A kind of sofa is material modified and preparation method thereof with PVC |
| CN108360086A (en) * | 2018-01-26 | 2018-08-03 | 飞佛特种纺织品（宁波）有限公司 | A kind of sunlight fabric and preparation method thereof of high oxygen index (OI) |
| CN110396261A (en) * | 2019-09-03 | 2019-11-01 | 苏州华盟塑化有限公司 | A kind of preparation process of high-strength corrosion-resisting PVC particle |
| CN110629358A (en) * | 2019-09-19 | 2019-12-31 | 飞佛特种纺织品（宁波）有限公司 | Superfine glass fiber sunlight fabric with high oxygen index and preparation method thereof |
| CN110845916A (en) * | 2019-12-11 | 2020-02-28 | 苏州聚威共混材料有限公司 | Polyvinyl chloride modified material used for fabric weaving and having leather touch feeling and preparation method thereof |
| CN111518348A (en) * | 2020-05-25 | 2020-08-11 | 苏州德加画材科技有限公司 | PVC (polyvinyl chloride) environment-friendly color paste and preparation method thereof |
| CN113072740A (en) * | 2021-03-25 | 2021-07-06 | 台州联成新材料有限公司 | Anti-aging stabilizer and anti-aging sunlight fabric using same |
| CN113429705A (en) * | 2021-07-20 | 2021-09-24 | 江苏佳创纳米科技有限公司 | Low-cost high-performance PVC waterproof coiled material and preparation method thereof |
| CN113736193A (en) * | 2021-10-19 | 2021-12-03 | 广东全丰新材料科技有限公司 | Weather-resistant polymer color-changing film and preparation method thereof |
| CN114685094A (en) * | 2022-04-24 | 2022-07-01 | 广东祺龙科技有限公司 | Preparation method of flexible atmosphere lamp and flexible atmosphere lamp |
| CN116178852A (en) * | 2022-09-05 | 2023-05-30 | 江苏盐城朗创纳米新材料有限公司 | Impact-resistant PVC cable material and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103059466A (en) * | 2012-12-25 | 2013-04-24 | 东莞市祺龙电业有限公司 | Ultraviolet-proof environmental-friendly polyvinyl chloride (PVC) modified material and preparation method thereof |
| CN103059464A (en) * | 2012-12-25 | 2013-04-24 | 东莞市祺龙电业有限公司 | High tenacity and environment-friendly polyvinyl chloride (PVC) modified materials and preparation method thereof |
| CN105153576A (en) * | 2015-08-21 | 2015-12-16 | 飞佛特种纺织品（宁波）有限公司 | Bio-based environment-friendly sunscreen fabric coating formula |
-
2017
- 2017-04-18 CN CN201710253975.9A patent/CN106947187A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103059466A (en) * | 2012-12-25 | 2013-04-24 | 东莞市祺龙电业有限公司 | Ultraviolet-proof environmental-friendly polyvinyl chloride (PVC) modified material and preparation method thereof |
| CN103059464A (en) * | 2012-12-25 | 2013-04-24 | 东莞市祺龙电业有限公司 | High tenacity and environment-friendly polyvinyl chloride (PVC) modified materials and preparation method thereof |
| CN105153576A (en) * | 2015-08-21 | 2015-12-16 | 飞佛特种纺织品（宁波）有限公司 | Bio-based environment-friendly sunscreen fabric coating formula |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107254124A (en) * | 2017-07-31 | 2017-10-17 | 广东祺龙科技有限公司 | A kind of sofa is material modified and preparation method thereof with PVC |
| CN108360086A (en) * | 2018-01-26 | 2018-08-03 | 飞佛特种纺织品（宁波）有限公司 | A kind of sunlight fabric and preparation method thereof of high oxygen index (OI) |
| CN110396261A (en) * | 2019-09-03 | 2019-11-01 | 苏州华盟塑化有限公司 | A kind of preparation process of high-strength corrosion-resisting PVC particle |
| CN110629358A (en) * | 2019-09-19 | 2019-12-31 | 飞佛特种纺织品（宁波）有限公司 | Superfine glass fiber sunlight fabric with high oxygen index and preparation method thereof |
| CN110845916A (en) * | 2019-12-11 | 2020-02-28 | 苏州聚威共混材料有限公司 | Polyvinyl chloride modified material used for fabric weaving and having leather touch feeling and preparation method thereof |
| CN111518348A (en) * | 2020-05-25 | 2020-08-11 | 苏州德加画材科技有限公司 | PVC (polyvinyl chloride) environment-friendly color paste and preparation method thereof |
| CN113072740A (en) * | 2021-03-25 | 2021-07-06 | 台州联成新材料有限公司 | Anti-aging stabilizer and anti-aging sunlight fabric using same |
| CN113429705A (en) * | 2021-07-20 | 2021-09-24 | 江苏佳创纳米科技有限公司 | Low-cost high-performance PVC waterproof coiled material and preparation method thereof |
| CN113736193A (en) * | 2021-10-19 | 2021-12-03 | 广东全丰新材料科技有限公司 | Weather-resistant polymer color-changing film and preparation method thereof |
| CN114685094A (en) * | 2022-04-24 | 2022-07-01 | 广东祺龙科技有限公司 | Preparation method of flexible atmosphere lamp and flexible atmosphere lamp |
| CN116178852A (en) * | 2022-09-05 | 2023-05-30 | 江苏盐城朗创纳米新材料有限公司 | Impact-resistant PVC cable material and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106947187A (en) | A kind of sunlight fabric is material modified and preparation method thereof with PVC | |
| CN105440505A (en) | PVC (polyvinyl chloride) foam material for sole and preparation method of PVC foam material | |
| CN106977848A (en) | A kind of automotive line is material modified and preparation method thereof with PVC | |
| CN106905641A (en) | A kind of wallpaper cloth is material modified and preparation method thereof with PVC | |
| CN106977849A (en) | A kind of curtain is material modified and preparation method thereof with PVC | |
| CN105504584A (en) | Tasteless PVC modified material and preparation method thereof | |
| CN106947185A (en) | A kind of table mat is material modified and preparation method thereof with PVC | |
| CN104109323B (en) | A kind of environment-friendly PVC of resistance to migration is material modified and preparation method thereof | |
| CN105419167A (en) | Carpet environmental protection PVC modified material and preparation method therefor | |
| CN105419168A (en) | Medical environmental protection PVC modified material and preparation method therefor | |
| CN106188987A (en) | A kind of Lunettes modifying character for PVC material and preparation method thereof | |
| CN105566805A (en) | Anticorrosive PVC modified material and preparation method thereof | |
| CN105482309A (en) | Radiation-proofing PVC modified material and preparation method thereof | |
| CN107266825A (en) | One kind diving mouth mask is material modified and preparation method thereof with PVC | |
| CN107011622A (en) | A kind of super abrasive POM/PTFE sheet materials and preparation method thereof | |
| CN107189282A (en) | A kind of fire-barrier ceiling is material modified and preparation method thereof with PVC | |
| CN106977846A (en) | A kind of waterproof oil resistant carpet is material modified and preparation method thereof with PVC | |
| CN106916394A (en) | A kind of anti-slip carpet is material modified and preparation method thereof with PVC | |
| CN109608833A (en) | A kind of high-strength anti-flaming PCT engineering plastics and preparation method thereof | |
| CN106928596A (en) | A kind of anti-oxidant ground cushion of uvioresistant and preparation method thereof | |
| CN107383683A (en) | A kind of electric wire is material modified and preparation method thereof with transparent shading PVC | |
| CN108623979A (en) | A kind of high temperature resistant environment-protective ABS/PVC alloy materials and preparation method thereof | |
| CN106947186A (en) | A kind of beach chair cloth is material modified and preparation method thereof with PVC | |
| CN106977853A (en) | A kind of antistatic mould proof ground cushion and preparation method thereof | |
| CN106905642A (en) | A kind of anti-skid wearable ground cushion and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB02 | Change of applicant information |
Address after: Ye Wu industrial zone Dalingshan Meilin Village 523000 Guangdong city of Dongguan Province Applicant after: Guangdong Qi Long Technology Co., Ltd. Address before: Ye Wu industrial zone Dalingshan Meilin Village 523820 Guangdong city of Dongguan Province Applicant before: Dongguan Qilong Electricity Co., Ltd. |
|
| CB02 | Change of applicant information | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170714 |
|
| RJ01 | Rejection of invention patent application after publication |