CN106916394A - A kind of anti-slip carpet is material modified and preparation method thereof with PVC - Google Patents
A kind of anti-slip carpet is material modified and preparation method thereof with PVC Download PDFInfo
- Publication number
- CN106916394A CN106916394A CN201710254441.8A CN201710254441A CN106916394A CN 106916394 A CN106916394 A CN 106916394A CN 201710254441 A CN201710254441 A CN 201710254441A CN 106916394 A CN106916394 A CN 106916394A
- Authority
- CN
- China
- Prior art keywords
- parts
- pvc
- weight
- material modified
- mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention relates to PVC material technical field, and in particular to a kind of anti-slip carpet is material modified and preparation method thereof with PVC, the anti-slip carpet material modified raw materials including following weight portion of PVC：80 120 parts of polyvinyl chloride resin, 40 60 parts of plasticizer, 10 15 parts of powdered whiting, 5 15 parts of precipitated calcium carbonate, 37 parts of compound stabilizer high, 13 parts of haloflex, 13 parts of abrasion resistance modifier, 0.3 0.7 parts of antilubricant, 0.6 1.0 parts of UV resistant agent, 0.3 0.7 parts of antioxidant, 0.3 0.7 parts of lubricant.Anti-slip carpet of the invention is material modified with preferable anti-wear performance with PVC, and anti-skidding and antiageing effect is good, environmental protection, and resistance to gentle weather resistance is excellent, and intensity is high, and excellent shock resistance, good flame retardation effect, processing characteristics is excellent, excellent combination property.
Description
Technical field
The present invention relates to PVC material technical field, and in particular to a kind of anti-slip carpet is with PVC is material modified and its preparation side
Method.
Background technology
Polyvinyl chloride（PVC）One of industrialization earliest, widely used general-purpose thermoplastic plastic, it have light weight,
Intensity is high, insulation, fire-retardant, corrosion-resistant, high comprehensive performance, cheap and extensive raw material sources the advantages of；But there is also
Following shortcoming：1st, poor toughness, easily embrittlement when being hit, therefore structural material is cannot act as, in addition, the fragility of polyvinyl chloride is received
Temperature influence is very big, and general PVC product is -15 DEG C using lower limit, and the use lower limit of flexible PVC is -30 DEG C；2nd, heat endurance
Difference, it begins to decomposite HCl at 100 DEG C, decomposes more rapid during higher than 150 DEG C, and the melt temperature of PVC is about 210
℃；3rd, the viscosity of PVC is high, mobility extreme difference, it is limited to a certain extent and is used.People are frequently with addition filler, bullet
The methods such as gonosome, plasticizer, heat stabilizer, processing aid, heat-proof modifier and flow ability modifying agent improve the performance of PVC.
But the existing carpet PVC material defect such as have anti-skidding, wear-resisting and ageing resistace poor, to a certain extent
It is limited to use.
The content of the invention
In order to overcome shortcoming and defect present in prior art, used it is an object of the invention to provide a kind of anti-slip carpet
PVC is material modified, and the anti-slip carpet is material modified with preferable anti-wear performance with PVC, and anti-skidding and antiageing effect is good, ring
Protect, and resistance to gentle weather resistance is excellent, intensity is high, and excellent shock resistance, good flame retardation effect, processing characteristics is excellent, comprehensive
Can be excellent.
Another object of the present invention is to provide a kind of material modified preparation methods of anti-slip carpet PVC, the preparation side
Method step is simple, and convenient operation and control, steady quality, production efficiency is high, low production cost, is produced up to technical scale metaplasia.
The purpose of the present invention is achieved through the following technical solutions：A kind of anti-slip carpet is material modified with PVC, including following weight
Measure the raw material of part：
Polyvinyl chloride resin 80-120 parts
Plasticizer 40-60 parts
Powdered whiting 10-15 parts
Precipitated calcium carbonate 5-15 parts
It is high compound stabilizer 3-7 parts
Haloflex 1-3 parts
Abrasion resistance modifier 1-3 parts
Antilubricant 0.3-0.7 parts
UV resistant agent 0.6-1.0 parts
Antioxidant 0.3-0.7 parts
Lubricant 0.3-0.7 parts.
Preferably, the polyvinyl chloride resin is SG-5 type polyvinyl chloride resin of the degree of polymerization in 1000-1100.The present invention is by using upper
Polyvinyl chloride resin is stated, obtained PVC is material modified with light weight, intensity high, insulation, fire-retardant, corrosion-resistant, high comprehensive performance etc.
Advantage.
The plasticizer is by epoxidized soybean oil, synthesizes vegetable esters and hexamethylene 1, and 2- dioctyl phthalate diisononyl esters are with weight
Compare 1-2:0.8-1.2:The mixture of 1 composition.The present invention, can by the strict species for controlling plasticizer, compounding and weight proportion
To reduce the active force of plastic molecules interchain, the glass transition temperature of plastics, flowing temperature is set to be reduced with the fusing point of contained crystallite,
The plasticity of resin can be improved, makes product softness, resistance to low temperature good.
Preferably, the powdered whiting is that particle diameter is treated in 100-500nm and by modified by maleic acid anhydride graft
Powdered whiting.
The particle diameter of filler is smaller, and the tensile strength and impact strength to packing material are more beneficial, and the present invention is by selecting
Powdered whiting is as filler and controls its particle diameter in 100-500nm, and its crystal structure and Electronic Structure there occurs change
Change, generate quantum size effect, small-size effect, skin effect and macroscopic quantum effect that common powdered whiting does not have
Should, therefore with good toughened and reinforced effect, it can improve bending strength and bending bullet in adding edge band of the invention
The stability of property modulus and heat distortion temperature and size；Filler is to play its effect and control with the good compatibility of resin
The key of addition, the present invention can carry heavy carbonic acid using the powdered whiting treated by modified by maleic acid anhydride graft
The compatibility of calcium and polyvinyl chloride resin, so as to improve the intensity of material.
The precipitated calcium carbonate is the precipitated calcium carbonate that particle diameter is treated in 10-100nm and by silane coupler.
The particle diameter of filler is smaller, and the tensile strength and impact strength to packing material are more beneficial, and the present invention is by selecting
Precipitated calcium carbonate is as filler and controls its particle diameter in 10-100nm, and its crystal structure and Electronic Structure there occurs change
Change, generate quantum size effect, small-size effect, skin effect and macroscopic quantum effect that conventional lightweight calcium carbonate does not have
Should, therefore with good toughened and reinforced effect, it can improve bending strength and bending bullet in adding edge band of the invention
The stability of property modulus and heat distortion temperature and size；Filler is to play its effect and control with the good compatibility of resin
The key of addition, the present invention can carry precipitated calcium carbonate and PVC using the precipitated calcium carbonate treated by silane coupler
The compatibility of resin, so as to improve the intensity of material.
Preferably, the compound stabilizer high is with weight ratio by calcium stearate, zinc stearate and beta-diketon and zeolite
1.5-2.5:1-2:1:The mixture of 0.5-1.5 compositions.
The present invention is used as main body heat stabilizer by strict using calcium stearate, zinc stearate, using beta-diketon and zeolite
Used as auxiliary heat stabilizer, main body heat stabilizer and auxiliary heat stabilizer compounding use make material good heat stability, with height
Effect weatherability, can also make material have good dispersiveness, compatibility and processing fluidity in process.
Preferably, the haloflex is haloflex of the chlorinty in 25%-45%.
The present invention, in the haloflex of 25%-45%, can improve the impact strength of material by using chlorinty, improve
The high temperature resistant and resistance to low temperature of material.
The abrasion resistance modifier is to compare 1 with weight by butadiene-styrene rubber and natural rubber:The mixture of 1.8-2.6 compositions.
The present invention is by the species of strict control abrasion resistance modifier, compounding and matches, and can improve material modified resistance to of PVC
Mill performance.
Preferably, the antilubricant is to compare 1 with weight by rubber particles, zeolite granular and glass microsphere:0.5-1.5：
The mixture of 1.5-2.5 compositions.
The present invention is by the strict species for controlling antilubricant, compounding and matches, and obtained PVC is material modified with preferable
Skidproof effect.
Preferably, the UV resistant agent is by ultra-violet absorber UV-5411, ultra-violet absorber UVP-327 and light
Stabilizer HPT compares 0.8-1.2 with weight:1:The mixture of 0.5-1.5 compositions.
The present invention can strongly absorb ultraviolet by the strict species for controlling ultra-violet absorber, compounding and weight proportion,
With excellent cooperative effect.
Preferably, the antioxidant is to compare 1-2 with weight by antioxidant 1010, irgasfos 168 and antioxidant MB:0.8-
1.2:The mixture of 1 composition.
The present invention can delay or suppress material oxidation by the strict species for controlling antioxidant, compounding and weight proportion
The carrying out of process, so as to prevent the aging of material and extend its service life.
Preferably, the lubricant be by OPE, pentaerythritol stearate and ethylene bis stearamide with
Weight compares 1.5-2.5:1:The mixture of 0.5-1.5 compositions.
The present invention is by the strict species for controlling lubricant, compounding and matches, and material can be made to improve in process
The mobility of material and the release property of product, can reduce difficulty of processing, save energy consumption.
The anti-slip carpet also includes cold-resistant toughened dose 2-6 parts, compatilizer 1-3 parts and antiseptic with PVC is material modified
0.5-1.5 parts.
Described cold-resistant toughened dose is to compare 1 with weight by amide-type beta crystal-type nucleater and dicarboxylic acids salt beta crystal-type nucleater：
The mixture of 1.2-1.8 compositions.
The present invention is used as cold-resistant toughened dose by using amide-type beta crystal-type nucleater and dicarboxylic acids salt beta crystal-type nucleater
Compounding use, and it is 1 to control its weight ratio：1.2-1.8 so that material in -20 DEG C of low temperature toughening effect substantially, more than normal temperature
When impact strength, while rigidly being significantly improved under normal temperature.
The compatilizer is to compare 1 with weight by maleic anhydride inoculated polypropylene and styrene-grafted polypropylene：1.4-2.2 groups
Into mixture.
The present invention is used as compatilizer compounding use by using maleic anhydride inoculated polypropylene and styrene-grafted polypropylene,
And it is 1 to control its weight ratio：1.4-2.2, can improve inorganic filler and organic resin compatibility, improve stretching, the impact of product
Intensity, realizes filling high, reduces resin demand, improves rheological performance, improves surface smoothness.
The antiseptic is to compare 1.5-2.5 with weight by zeolite with carrying silver and the silver-colored cobalt phosphate of load：The mixture of 1 composition.
The present invention controls its weight ratio to be by using zeolite with carrying silver and carrying silver cobalt phosphate and being used as antiseptic compounding use
1.5-2.5：1 so that not only tinting strength, tinting power is high for material, good dispersion, spinnability are good, also with preferable sterilized, fungistatic effect.
The anti-slip carpet also includes fire retardant 1-5 parts, slipping agent 0.5-1.5 parts and pigment powder with PVC is material modified
0.5-1.5 parts.
The fire retardant is to compare 0.5-1.5 with weight by antimony oxide and Firebrake ZB：The mixture of 1 composition.
Antimony oxide and line borate are inorganic environment-friendly fire retardant, and the present invention is by using antimony oxide and Firebrake ZB
Used as fire retardant compounding use, and it is 0.5-1.5 to control its weight ratio：1, good flame retardant effect can be reached, moreover it is possible to improve
The processing characteristics and mechanical performance of material.
The slipping agent is to compare 1.5-2.5 with weight by erucyl amide, oleamide and N, N'- ethylene bis stearamide：
0.8-1.2：The mixture of 1 composition.
The present invention passes through using erucyl amide, oleamide and N, N'- ethylene bis stearamide are as slipping agent and control
Its weight ratio is 1.5-2.5：0.8-1.2：1, mechanical resistant stirring capacity and fingerprinting stress, finished product good forming effect, table can be strengthened
Face is bright and clean, moreover it is possible to strengthen the extensibility of finished product, easy-to-draw not easily broken.
The pigment powder is titanium dioxide of the particle diameter at 1-5 μm；The titanium dioxide is by rutile type titanium white and anatase titanium dioxide
Titanium dioxide compares 1 with weight：The mixture of 1.5-2.5 compositions.
The present invention using particle diameter in 1-5 μm of titanium dioxide as pigment powder, further using rutile type titanium white and sharp
Titanium-type titanium dioxide compounding use, and it is 1 to control its weight ratio：1.5-2.5, with superior whiteness, tinting strength, tinting power, covering power, resistance to
Hou Xing, heat resistance and chemical stability, particularly no toxicity.
A kind of anti-slip carpet is comprised the following steps with PVC material modified preparation method：
（1）Above-mentioned raw materials are weighed by the weight portion of constitutive material, is mixed；
（2）Mixed raw material is put into high speed blender, 15-25min is stirred at a temperature of 100-140 DEG C；
（3）By the raw material after stirring by double screw extruder extruding pelletization, anti-slip carpet is obtained material modified with PVC；It is described
The extruder temperature of double screw extruder is：One 138-160 DEG C of area's temperature, two 135-160 DEG C of area's temperature, three area temperature 135-155
DEG C, 130-148 DEG C of the area's temperature of four area temperature 132-150 DEG CHe five.
The beneficial effects of the present invention are：Anti-slip carpet of the invention is material modified with preferable anti-wear performance with PVC,
Anti-skidding and antiageing effect is good, environmental protection, and resistance to gentle weather resistance is excellent, and intensity is high, excellent shock resistance, flame retardant effect
Good, processing characteristics is excellent, excellent combination property.
The present invention uses the anti-slip carpet material modified smooth in appearance of PVC obtained in various high-environmental materials, without adjacent benzene
Diformate, without polycyclic aromatic hydrocarbon, without free phenol, not halogen-containing flame retardant, without boron compound, environmental protection better than European Union ROHS,
The international standards such as DEHP, ATBC, can be widely applied to the sphere of lifes such as carpet.
Preparation method step of the invention is simple, and convenient operation and control, steady quality, production efficiency is high, low production cost,
Produced up to technical scale metaplasia.
Specific embodiment
For the ease of the understanding of those skilled in the art, with reference to embodiment, the present invention is further illustrated, real
The content that the mode of applying is referred to not limitation of the invention.
Embodiment 1
A kind of anti-slip carpet is material modified with PVC, including following weight portion raw material：
80 parts of polyvinyl chloride resin
40 parts of plasticizer
10 parts of powdered whiting
5 parts of precipitated calcium carbonate
3 parts of compound stabilizer high
1 part of haloflex
1 part of abrasion resistance modifier
0.3 part of antilubricant
0.6 part of UV resistant agent
0.3 part of antioxidant
0.3 part of lubricant.
The polyvinyl chloride resin is SG-5 type polyvinyl chloride resin of the degree of polymerization 1000；The plasticizer is by epoxidized soybean oil, closes
Into vegetable esters and hexamethylene 1,2- dioctyl phthalate diisononyl esters compare 1 with weight:0.8:The mixture of 1 composition.
The powdered whiting is the powdered whiting that particle diameter is treated in 100nm and by modified by maleic acid anhydride graft；
The precipitated calcium carbonate is the precipitated calcium carbonate that particle diameter is treated in 10nm and by silane coupler.
The compound stabilizer high is to compare 1.5 with weight by calcium stearate, zinc stearate and beta-diketon and zeolite:1:1:
The mixture of 0.5 composition.
The haloflex is haloflex of the chlorinty 25%；The abrasion resistance modifier be by butadiene-styrene rubber and
Natural rubber compares 1 with weight:The mixture of 1.8 compositions.
The antilubricant is to compare 1 with weight by rubber particles, zeolite granular and glass microsphere:0.5：The mixing of 1.5 compositions
Thing.
The UV resistant agent is by ultra-violet absorber UV-5411, ultra-violet absorber UVP-327 and light stabilizer
HPT compares 0.8 with weight:1:The mixture of 0.5 composition.
The antioxidant is to compare 1 with weight by antioxidant 1010, irgasfos 168 and antioxidant MB:0.8:1 composition it is mixed
Compound.
The lubricant is with weight ratio by OPE, pentaerythritol stearate and ethylene bis stearamide
1.5:1:The mixture of 0.5 composition.
The anti-slip carpet is material modified also including 0.5 part of cold-resistant toughened dose 2 parts, 1 part of compatilizer and antiseptic with PVC.
Described cold-resistant toughened dose is to compare 1 with weight by amide-type beta crystal-type nucleater and dicarboxylic acids salt beta crystal-type nucleater：
The mixture of 1.2 compositions.
The compatilizer is to compare 1 with weight by maleic anhydride inoculated polypropylene and styrene-grafted polypropylene：1.4 compositions
Mixture.
The antiseptic is to compare 1.5 with weight by zeolite with carrying silver and the silver-colored cobalt phosphate of load：The mixture of 1 composition.
The anti-slip carpet also includes 0.5 part of 1 part of fire retardant, 0.5 part of slipping agent and pigment powder with PVC is material modified.
The fire retardant is to compare 0.5 with weight by antimony oxide and Firebrake ZB：The mixture of 1 composition.
The slipping agent is to compare 1.5 with weight by erucyl amide, oleamide and N, N'- ethylene bis stearamide：0.8：1
The mixture of composition.
The pigment powder is titanium dioxide of the particle diameter at 1 μm；The titanium dioxide is by rutile type titanium white and anatase titanium dioxide titanium
White powder compares 1 with weight：The mixture of 1.5 compositions.
A kind of anti-slip carpet is comprised the following steps with PVC material modified preparation method：
（1）Above-mentioned raw materials are weighed by the weight portion of constitutive material, is mixed；
（2）Mixed raw material is put into high speed blender, 15min is stirred at a temperature of 100 DEG C；
（3）By the raw material after stirring by double screw extruder extruding pelletization, anti-slip carpet is obtained material modified with PVC；It is described
The extruder temperature of double screw extruder is：One 138 DEG C of area's temperature, 135 DEG C of two area's temperature, 135 DEG C of three area's temperature, four area's temperature
130 DEG C of 132 DEG CHe, five area's temperature.
Embodiment 2
A kind of anti-slip carpet is material modified with PVC, including following weight portion raw material：
90 parts of polyvinyl chloride resin
45 parts of plasticizer
11 parts of powdered whiting
8 parts of precipitated calcium carbonate
4 parts of compound stabilizer high
1.5 parts of haloflex
1.5 parts of abrasion resistance modifier
0.4 part of antilubricant
0.7 part of UV resistant agent
0.4 part of antioxidant
0.4 part of lubricant.
The polyvinyl chloride resin is SG-5 type polyvinyl chloride resin of the degree of polymerization 1020；The plasticizer is by epoxidized soybean oil, closes
Into vegetable esters and hexamethylene 1,2- dioctyl phthalate diisononyl esters compare 1.2 with weight:0.9:The mixture of 1 composition.
The powdered whiting is the powdered whiting that particle diameter is treated in 200nm and by modified by maleic acid anhydride graft；
The precipitated calcium carbonate is the precipitated calcium carbonate that particle diameter is treated in 30nm and by silane coupler.
The compound stabilizer high is to compare 1.8 with weight by calcium stearate, zinc stearate and beta-diketon and zeolite:1.2:1:
The mixture of 0.8 composition.
The haloflex is haloflex of the chlorinty 30%；The abrasion resistance modifier be by butadiene-styrene rubber and
Natural rubber compares 1 with weight:The mixture of 2 compositions.
The antilubricant is to compare 1 with weight by rubber particles, zeolite granular and glass microsphere:0.8：The mixing of 1.8 compositions
Thing.
The UV resistant agent is by ultra-violet absorber UV-5411, ultra-violet absorber UVP-327 and light stabilizer
HPT compares 0.9 with weight:1:The mixture of 0.8 composition.
The antioxidant is to compare 1.2 with weight by antioxidant 1010, irgasfos 168 and antioxidant MB:0.9:1 composition
Mixture.
The lubricant is with weight ratio by OPE, pentaerythritol stearate and ethylene bis stearamide
1.8:1:The mixture of 0.8 composition.
The anti-slip carpet is material modified also including cold-resistant toughened dose 3 parts, 1.5 parts of compatilizer and antiseptic 0.8 with PVC
Part.
Described cold-resistant toughened dose is to compare 1 with weight by amide-type beta crystal-type nucleater and dicarboxylic acids salt beta crystal-type nucleater：
The mixture of 1.4 compositions.
The compatilizer is to compare 1 with weight by maleic anhydride inoculated polypropylene and styrene-grafted polypropylene：1.6 compositions
Mixture.
The antiseptic is to compare 1.8 with weight by zeolite with carrying silver and the silver-colored cobalt phosphate of load：The mixture of 1 composition.
The anti-slip carpet also includes 0.8 part of 2 parts of fire retardant, 0.8 part of slipping agent and pigment powder with PVC is material modified.
The fire retardant is to compare 0.8 with weight by antimony oxide and Firebrake ZB：The mixture of 1 composition.
The slipping agent is to compare 1.8 with weight by erucyl amide, oleamide and N, N'- ethylene bis stearamide：0.9：1
The mixture of composition.
The pigment powder is titanium dioxide of the particle diameter at 2 μm；The titanium dioxide is by rutile type titanium white and anatase titanium dioxide titanium
White powder compares 1 with weight：The mixture of 1.8 compositions.
A kind of anti-slip carpet is comprised the following steps with PVC material modified preparation method：
（1）Above-mentioned raw materials are weighed by the weight portion of constitutive material, is mixed；
（2）Mixed raw material is put into high speed blender, 18min is stirred at a temperature of 110 DEG C；
（3）By the raw material after stirring by double screw extruder extruding pelletization, anti-slip carpet is obtained material modified with PVC；It is described
The extruder temperature of double screw extruder is：One 144 DEG C of area's temperature, 141 DEG C of two area's temperature, 140 DEG C of three area's temperature, four area's temperature
135 DEG C of 136 DEG CHe, five area's temperature.
Embodiment 3
A kind of anti-slip carpet is material modified with PVC, including following weight portion raw material：
100 parts of polyvinyl chloride resin
50 parts of plasticizer
12 parts of powdered whiting
10 parts of precipitated calcium carbonate
5 parts of compound stabilizer high
2 parts of haloflex
2 parts of abrasion resistance modifier
0.5 part of antilubricant
0.8 part of UV resistant agent
0.5 part of antioxidant
0.5 part of lubricant.
The polyvinyl chloride resin is SG-5 type polyvinyl chloride resin of the degree of polymerization 1050；The plasticizer is by epoxidized soybean oil, closes
Into vegetable esters and hexamethylene 1,2- dioctyl phthalate diisononyl esters compare 1.5 with weight:1:The mixture of 1 composition.
The powdered whiting is the powdered whiting that particle diameter is treated in 300nm and by modified by maleic acid anhydride graft；
The precipitated calcium carbonate is the precipitated calcium carbonate that particle diameter is treated in 50nm and by silane coupler.
The compound stabilizer high is to compare 2 with weight by calcium stearate, zinc stearate and beta-diketon and zeolite:1.5:1:1
The mixture of composition.
The haloflex is haloflex of the chlorinty 35%；The abrasion resistance modifier be by butadiene-styrene rubber and
Natural rubber compares 1 with weight:The mixture of 2.2 compositions.
The antilubricant is to compare 1 with weight by rubber particles, zeolite granular and glass microsphere:1：The mixture of 2 compositions.
The UV resistant agent is by ultra-violet absorber UV-5411, ultra-violet absorber UVP-327 and light stabilizer
HPT compares 1 with weight:1:The mixture of 1 composition.
The antioxidant is to compare 1.5 with weight by antioxidant 1010, irgasfos 168 and antioxidant MB:1:1 composition it is mixed
Compound.
The lubricant is to compare 2 with weight by OPE, pentaerythritol stearate and ethylene bis stearamide:
1:The mixture of 1 composition.
The anti-slip carpet is material modified also including 1 part of cold-resistant toughened dose 4 parts, 2 parts of compatilizer and antiseptic with PVC.
Described cold-resistant toughened dose is to compare 1 with weight by amide-type beta crystal-type nucleater and dicarboxylic acids salt beta crystal-type nucleater：
The mixture of 1.5 compositions.
The compatilizer is to compare 1 with weight by maleic anhydride inoculated polypropylene and styrene-grafted polypropylene：1.8 compositions
Mixture.
The antiseptic is to compare 2 with weight by zeolite with carrying silver and the silver-colored cobalt phosphate of load：The mixture of 1 composition.
The anti-slip carpet also includes 1 part of 3 parts of fire retardant, 1 part of slipping agent and pigment powder with PVC is material modified.
The fire retardant is to compare 1 with weight by antimony oxide and Firebrake ZB：The mixture of 1 composition.
The slipping agent is to compare 2 with weight by erucyl amide, oleamide and N, N'- ethylene bis stearamide：1：1 composition
Mixture.
The pigment powder is titanium dioxide of the particle diameter at 3 μm；The titanium dioxide is by rutile type titanium white and anatase titanium dioxide titanium
White powder compares 1 with weight：The mixture of 2 compositions.
A kind of anti-slip carpet is comprised the following steps with PVC material modified preparation method：
（1）Above-mentioned raw materials are weighed by the weight portion of constitutive material, is mixed；
（2）Mixed raw material is put into high speed blender, 20min is stirred at a temperature of 120 DEG C；
（3）By the raw material after stirring by double screw extruder extruding pelletization, anti-slip carpet is obtained material modified with PVC；It is described
The extruder temperature of double screw extruder is：One 149 DEG C of area's temperature, 147 DEG C of two area's temperature, 145 DEG C of three area's temperature, four area's temperature
139 DEG C of 141 DEG CHe, five area's temperature.
Embodiment 4
A kind of anti-slip carpet is material modified with PVC, including following weight portion raw material：
110 parts of polyvinyl chloride resin
55 parts of plasticizer
14 parts of powdered whiting
12 parts of precipitated calcium carbonate
6 parts of compound stabilizer high
2.5 parts of haloflex
2.5 parts of abrasion resistance modifier
0.6 part of antilubricant
0.9 part of UV resistant agent
0.6 part of antioxidant
0.6 part of lubricant.
The polyvinyl chloride resin is SG-5 type polyvinyl chloride resin of the degree of polymerization 1080；The plasticizer is by epoxidized soybean oil, closes
Into vegetable esters and hexamethylene 1,2- dioctyl phthalate diisononyl esters compare 1.8 with weight:1.1:The mixture of 1 composition.
The powdered whiting is the powdered whiting that particle diameter is treated in 400nm and by modified by maleic acid anhydride graft；
The precipitated calcium carbonate is the precipitated calcium carbonate that particle diameter is treated in 80nm and by silane coupler.
The compound stabilizer high is to compare 2.2 with weight by calcium stearate, zinc stearate and beta-diketon and zeolite:1.8:1:
The mixture of 1.2 compositions.
The haloflex is haloflex of the chlorinty 40%；The abrasion resistance modifier be by butadiene-styrene rubber and
Natural rubber compares 1 with weight:The mixture of 2.4 compositions.
The antilubricant is to compare 1 with weight by rubber particles, zeolite granular and glass microsphere:1.2：The mixing of 2.2 compositions
Thing.
The UV resistant agent is by ultra-violet absorber UV-5411, ultra-violet absorber UVP-327 and light stabilizer
HPT compares 1.1 with weight:1:The mixture of 1.2 compositions.
The antioxidant is to compare 1.8 with weight by antioxidant 1010, irgasfos 168 and antioxidant MB:1.1:1 composition
Mixture.
The lubricant is with weight ratio by OPE, pentaerythritol stearate and ethylene bis stearamide
2.2:1:The mixture of 1.2 compositions.
The anti-slip carpet is material modified also including cold-resistant toughened dose 5 parts, 2.5 parts of compatilizer and antiseptic 1.2 with PVC
Part.
Described cold-resistant toughened dose is to compare 1 with weight by amide-type beta crystal-type nucleater and dicarboxylic acids salt beta crystal-type nucleater：
The mixture of 1.6 compositions.
The compatilizer is to compare 1 with weight by maleic anhydride inoculated polypropylene and styrene-grafted polypropylene：2 compositions it is mixed
Compound.
The antiseptic is to compare 2.2 with weight by zeolite with carrying silver and the silver-colored cobalt phosphate of load：The mixture of 1 composition.
The anti-slip carpet also includes 1.2 parts of 4 parts of fire retardant, 1.2 parts of slipping agent and pigment powder with PVC is material modified.
The fire retardant is to compare 1.2 with weight by antimony oxide and Firebrake ZB：The mixture of 1 composition.
The slipping agent is to compare 2.2 with weight by erucyl amide, oleamide and N, N'- ethylene bis stearamide：1.1：1
The mixture of composition.
The pigment powder is titanium dioxide of the particle diameter at 4 μm；The titanium dioxide is by rutile type titanium white and anatase titanium dioxide titanium
White powder compares 1 with weight：The mixture of 2.2 compositions.
A kind of anti-slip carpet is comprised the following steps with PVC material modified preparation method：
（1）Above-mentioned raw materials are weighed by the weight portion of constitutive material, is mixed；
（2）Mixed raw material is put into high speed blender, 22min is stirred at a temperature of 130 DEG C；
（3）By the raw material after stirring by double screw extruder extruding pelletization, anti-slip carpet is obtained material modified with PVC；It is described
The extruder temperature of double screw extruder is：One 155 DEG C of area's temperature, 153 DEG C of two area's temperature, 150 DEG C of three area's temperature, four area's temperature
144 DEG C of 145 DEG CHe, five area's temperature.
Embodiment 5
A kind of anti-slip carpet is material modified with PVC, including following weight portion raw material：
120 parts of polyvinyl chloride resin
60 parts of plasticizer
15 parts of powdered whiting
15 parts of precipitated calcium carbonate
7 parts of compound stabilizer high
3 parts of haloflex
3 parts of abrasion resistance modifier
0.7 part of antilubricant
1.0 parts of UV resistant agent
0.7 part of antioxidant
0.7 part of lubricant.
The polyvinyl chloride resin is SG-5 type polyvinyl chloride resin of the degree of polymerization 1100；The plasticizer is by epoxidized soybean oil, closes
Into vegetable esters and hexamethylene 1,2- dioctyl phthalate diisononyl esters compare 2 with weight:1.2:The mixture of 1 composition.
The powdered whiting is the powdered whiting that particle diameter is treated in 500nm and by modified by maleic acid anhydride graft；
The precipitated calcium carbonate is the precipitated calcium carbonate that particle diameter is treated in 100nm and by silane coupler.
The compound stabilizer high is to compare 2.5 with weight by calcium stearate, zinc stearate and beta-diketon and zeolite:2:1:
The mixture of 1.5 compositions.
The haloflex is haloflex of the chlorinty 45%；The abrasion resistance modifier be by butadiene-styrene rubber and
Natural rubber compares 1 with weight:The mixture of 2.6 compositions.
The antilubricant is to compare 1 with weight by rubber particles, zeolite granular and glass microsphere:1.5：The mixing of 2.5 compositions
Thing.
The UV resistant agent is by ultra-violet absorber UV-5411, ultra-violet absorber UVP-327 and light stabilizer
HPT compares 1.2 with weight:1:The mixture of 1.5 compositions.
The antioxidant is to compare 2 with weight by antioxidant 1010, irgasfos 168 and antioxidant MB:1.2:1 composition it is mixed
Compound.
The lubricant is with weight ratio by OPE, pentaerythritol stearate and ethylene bis stearamide
2.5:1:The mixture of 1.5 compositions.
The anti-slip carpet is material modified also including 1.5 parts of cold-resistant toughened dose 6 parts, 3 parts of compatilizer and antiseptic with PVC.
Described cold-resistant toughened dose is to compare 1 with weight by amide-type beta crystal-type nucleater and dicarboxylic acids salt beta crystal-type nucleater：
The mixture of 1.8 compositions.
The compatilizer is to compare 1 with weight by maleic anhydride inoculated polypropylene and styrene-grafted polypropylene：2.2 compositions
Mixture.
The antiseptic is to compare 2.5 with weight by zeolite with carrying silver and the silver-colored cobalt phosphate of load：The mixture of 1 composition.
The anti-slip carpet also includes 1.5 parts of 5 parts of fire retardant, 1.5 parts of slipping agent and pigment powder with PVC is material modified.
The fire retardant is to compare 1.5 with weight by antimony oxide and Firebrake ZB：The mixture of 1 composition.
The slipping agent is to compare 2.5 with weight by erucyl amide, oleamide and N, N'- ethylene bis stearamide：1.2：1
The mixture of composition.
The pigment powder is titanium dioxide of the particle diameter at 5 μm；The titanium dioxide is by rutile type titanium white and anatase titanium dioxide titanium
White powder compares 1 with weight：The mixture of 2.5 compositions.
A kind of anti-slip carpet is comprised the following steps with PVC material modified preparation method：
（1）Above-mentioned raw materials are weighed by the weight portion of constitutive material, is mixed；
（2）Mixed raw material is put into high speed blender, 25min is stirred at a temperature of 140 DEG C；
（3）By the raw material after stirring by double screw extruder extruding pelletization, anti-slip carpet is obtained material modified with PVC；It is described
The extruder temperature of double screw extruder is：One 160 DEG C of area's temperature, 160 DEG C of two area's temperature, 155 DEG C of three area's temperature, four area's temperature
148 DEG C of 150 DEG CHe, five area's temperature.
Anti-slip carpet obtained in embodiment 1-5 is as shown in table 1 with the material modified mechanical and physical performances of PVC：
Table 1
| Test event | Standard value | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 |
| Tensile strength（MPa） | ≥15.0 | 35.3 | 36.6 | 37.1 | 34.2 | 35.8 |
| Bending strength（MPa） | ≥15.0 | 58.1 | 61.2 | 63.8 | 54.6 | 59.4 |
| Elongation at break（%） | ≥150 | 312 | 319 | 330 | 309 | 325 |
| Heat distortion temperature（℃） | ≥50.0 | 128.5 | 130.7 | 133.3 | 126.4 | 129.8 |
| Impact brittle temperature（℃） | ≤-20 | -35 | -40 | -40 | -35 | -40 |
| Heat-stable time at 200 DEG C（min） | ≥60 | 120 | 130 | 130 | 110 | 120 |
| Hardness/Shore D | ≥50 | 93 | 95 | 96 | 91 | 94 |
| It is fire-retardant | V0 | V0 | V0 | V0 | V0 | V0 |
| Abrasion resistance | ≥2500 | 5100 | 5300 | 5500 | 5400 | 5200 |
| Skidproof effect | It is poor | Preferably | Preferably | Preferably | Preferably | Preferably |
| Ultraviolet light and aging is tested（h） | ≥504 | 1008 | 1008 | 1008 | 1008 | 1008 |
| Oxidation Resistance Test（h） | ≥504 | 1008 | 1008 | 1008 | 1008 | 1008 |
As it can be seen from table 1 the obtained anti-slip carpet of the present invention is material modified with preferable anti-wear performance with PVC, it is anti-skidding and
Antiageing effect is good, environmental protection, and resistance to gentle weather resistance is excellent, and intensity is high, excellent shock resistance, good flame retardation effect, processing
Function admirable, excellent combination property.
Above-described embodiment is the present invention preferably implementation, and in addition, the present invention can be realized with other manner,
Any obvious replacement is within protection scope of the present invention on the premise of not departing from present inventive concept.
Claims (10)
1. a kind of anti-slip carpet is material modified with PVC, it is characterised in that：Raw material including following weight portion：
Polyvinyl chloride resin 80-120 parts
Plasticizer 40-60 parts
Powdered whiting 10-15 parts
Precipitated calcium carbonate 5-15 parts
It is high compound stabilizer 3-7 parts
Haloflex 1-3 parts
Abrasion resistance modifier 1-3 parts
Antilubricant 0.3-0.7 parts
UV resistant agent 0.6-1.0 parts
Antioxidant 0.3-0.7 parts
Lubricant 0.3-0.7 parts.
2. a kind of anti-slip carpet according to claim 1 is material modified with PVC, it is characterised in that：The polyvinyl chloride resin is poly-
The right SG-5 type polyvinyl chloride resins in 1000-1100；The plasticizer is by epoxidized soybean oil, synthesizes vegetable esters and hexamethylene 1,
2- dioctyl phthalate diisononyl esters compare 1-2 with weight:0.8-1.2:The mixture of 1 composition.
3. a kind of anti-slip carpet according to claim 1 is material modified with PVC, it is characterised in that：The powdered whiting
For the powdered whiting that particle diameter is treated in 100-500nm and by modified by maleic acid anhydride graft；The precipitated calcium carbonate is grain
The precipitated calcium carbonate that footpath treats in 10-100nm and by silane coupler.
4. a kind of anti-slip carpet according to claim 1 is material modified with PVC, it is characterised in that：The stable composition high
Agent is to compare 1.5-2.5 with weight by calcium stearate, zinc stearate and beta-diketon and zeolite:1-2:1:The mixing of 0.5-1.5 compositions
Thing.
5. a kind of anti-slip carpet according to claim 1 is material modified with PVC, it is characterised in that：The haloflex
It is chlorinty in the haloflex of 25%-45%；The abrasion resistance modifier is to compare 1 with weight by butadiene-styrene rubber and natural rubber:
The mixture of 1.8-2.6 compositions.
6. a kind of anti-slip carpet according to claim 1 is material modified with PVC, it is characterised in that：The antilubricant be by
Rubber particles, zeolite granular and glass microsphere compare 1 with weight:0.5-1.5：The mixture of 1.5-2.5 compositions.
7. a kind of anti-slip carpet according to claim 1 is material modified with PVC, it is characterised in that：The UV resistant agent
It is that 0.8-1.2 is compared with weight by ultra-violet absorber UV-5411, ultra-violet absorber UVP-327 and light stabilizer HPT:1:
The mixture of 0.5-1.5 compositions.
8. a kind of anti-slip carpet according to claim 1 is material modified with PVC, it is characterised in that：The antioxidant be by
Antioxidant 1010, irgasfos 168 and antioxidant MB compare 1-2 with weight:0.8-1.2:The mixture of 1 composition.
9. a kind of anti-slip carpet according to claim 1 is material modified with PVC, it is characterised in that：The lubricant be by
OPE, pentaerythritol stearate and ethylene bis stearamide compare 1.5-2.5 with weight:1:0.5-1.5 compositions
Mixture.
10. with PVC material modified preparation method, its feature exists a kind of anti-slip carpet as described in claim any one of 1-9
In：Comprise the following steps：
（1）Above-mentioned raw materials are weighed by the weight portion of constitutive material, is mixed；
（2）Mixed raw material is put into high speed blender, 15-25min is stirred at a temperature of 100-140 DEG C；
（3）By the raw material after stirring by double screw extruder extruding pelletization, anti-slip carpet is obtained material modified with PVC；It is described
The extruder temperature of double screw extruder is：One 138-160 DEG C of area's temperature, two 135-160 DEG C of area's temperature, three area temperature 135-155
DEG C, 130-148 DEG C of the area's temperature of four area temperature 132-150 DEG CHe five.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710254441.8A CN106916394A (en) | 2017-04-18 | 2017-04-18 | A kind of anti-slip carpet is material modified and preparation method thereof with PVC |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710254441.8A CN106916394A (en) | 2017-04-18 | 2017-04-18 | A kind of anti-slip carpet is material modified and preparation method thereof with PVC |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106916394A true CN106916394A (en) | 2017-07-04 |
Family
ID=59568912
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710254441.8A Pending CN106916394A (en) | 2017-04-18 | 2017-04-18 | A kind of anti-slip carpet is material modified and preparation method thereof with PVC |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106916394A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107189278A (en) * | 2017-07-18 | 2017-09-22 | 合肥峰腾节能科技有限公司 | A kind of sound-absorbing damping flame-proof environmental protection carpet backing material and preparation method thereof |
| CN107254124A (en) * | 2017-07-31 | 2017-10-17 | 广东祺龙科技有限公司 | A kind of sofa is material modified and preparation method thereof with PVC |
| CN107383683A (en) * | 2017-07-31 | 2017-11-24 | 广东祺龙科技有限公司 | A kind of electric wire is material modified and preparation method thereof with transparent shading PVC |
| EP3470455A1 (en) * | 2017-10-13 | 2019-04-17 | Shin-Etsu Chemical Co., Ltd. | Polyvinyl chloride-based resin molded product and method for manufacturing the same |
Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20060111472A1 (en) * | 2004-11-01 | 2006-05-25 | Tonia Boutelle | Impact resistant PVC formulations and methods of manufacturing thereof |
| KR100868433B1 (en) * | 2008-04-10 | 2008-11-11 | 이재춘 | Poly vinyl chloride composition for glass encapsulation injection molding of vehicle |
| CN101397382A (en) * | 2007-09-29 | 2009-04-01 | 苏州工业园区凯维新材料有限公司 | Anti-yellowing polyvinyl chloride |
| CN103059466A (en) * | 2012-12-25 | 2013-04-24 | 东莞市祺龙电业有限公司 | Ultraviolet-proof environmental-friendly polyvinyl chloride (PVC) modified material and preparation method thereof |
| CN103059464A (en) * | 2012-12-25 | 2013-04-24 | 东莞市祺龙电业有限公司 | High tenacity and environment-friendly polyvinyl chloride (PVC) modified materials and preparation method thereof |
| CN103073816A (en) * | 2012-12-25 | 2013-05-01 | 东莞市祺龙电业有限公司 | Heat-resisting and cold-resisting environment-friendly PVC (polyvinyl chloride) modified material and preparation method thereof |
| CN105419167A (en) * | 2015-12-31 | 2016-03-23 | 东莞市祺龙电业有限公司 | Carpet environmental protection PVC modified material and preparation method therefor |
| CN105482309A (en) * | 2015-12-31 | 2016-04-13 | 东莞市祺龙电业有限公司 | Radiation-proofing PVC modified material and preparation method thereof |
| CN105482310A (en) * | 2015-12-31 | 2016-04-13 | 东莞市祺龙电业有限公司 | Antistatic PVC (polyvinyl chloride) modified material and preparation method thereof |
| CN105566805A (en) * | 2015-12-31 | 2016-05-11 | 东莞市祺龙电业有限公司 | Anticorrosive PVC modified material and preparation method thereof |
| KR101675990B1 (en) * | 2015-06-05 | 2016-11-15 | 주식회사 위스컴 | High functional resin composition for insert molding of encapsulation |
-
2017
- 2017-04-18 CN CN201710254441.8A patent/CN106916394A/en active Pending
Patent Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20060111472A1 (en) * | 2004-11-01 | 2006-05-25 | Tonia Boutelle | Impact resistant PVC formulations and methods of manufacturing thereof |
| CN101397382A (en) * | 2007-09-29 | 2009-04-01 | 苏州工业园区凯维新材料有限公司 | Anti-yellowing polyvinyl chloride |
| KR100868433B1 (en) * | 2008-04-10 | 2008-11-11 | 이재춘 | Poly vinyl chloride composition for glass encapsulation injection molding of vehicle |
| CN103059466A (en) * | 2012-12-25 | 2013-04-24 | 东莞市祺龙电业有限公司 | Ultraviolet-proof environmental-friendly polyvinyl chloride (PVC) modified material and preparation method thereof |
| CN103059464A (en) * | 2012-12-25 | 2013-04-24 | 东莞市祺龙电业有限公司 | High tenacity and environment-friendly polyvinyl chloride (PVC) modified materials and preparation method thereof |
| CN103073816A (en) * | 2012-12-25 | 2013-05-01 | 东莞市祺龙电业有限公司 | Heat-resisting and cold-resisting environment-friendly PVC (polyvinyl chloride) modified material and preparation method thereof |
| KR101675990B1 (en) * | 2015-06-05 | 2016-11-15 | 주식회사 위스컴 | High functional resin composition for insert molding of encapsulation |
| CN105419167A (en) * | 2015-12-31 | 2016-03-23 | 东莞市祺龙电业有限公司 | Carpet environmental protection PVC modified material and preparation method therefor |
| CN105482309A (en) * | 2015-12-31 | 2016-04-13 | 东莞市祺龙电业有限公司 | Radiation-proofing PVC modified material and preparation method thereof |
| CN105482310A (en) * | 2015-12-31 | 2016-04-13 | 东莞市祺龙电业有限公司 | Antistatic PVC (polyvinyl chloride) modified material and preparation method thereof |
| CN105566805A (en) * | 2015-12-31 | 2016-05-11 | 东莞市祺龙电业有限公司 | Anticorrosive PVC modified material and preparation method thereof |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107189278A (en) * | 2017-07-18 | 2017-09-22 | 合肥峰腾节能科技有限公司 | A kind of sound-absorbing damping flame-proof environmental protection carpet backing material and preparation method thereof |
| CN107254124A (en) * | 2017-07-31 | 2017-10-17 | 广东祺龙科技有限公司 | A kind of sofa is material modified and preparation method thereof with PVC |
| CN107383683A (en) * | 2017-07-31 | 2017-11-24 | 广东祺龙科技有限公司 | A kind of electric wire is material modified and preparation method thereof with transparent shading PVC |
| EP3470455A1 (en) * | 2017-10-13 | 2019-04-17 | Shin-Etsu Chemical Co., Ltd. | Polyvinyl chloride-based resin molded product and method for manufacturing the same |
| US10717860B2 (en) | 2017-10-13 | 2020-07-21 | Shin-Etsu Chemical Co., Ltd. | Polyvinyl chloride-based resin molded product and method for manufacturing the same |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106977848A (en) | A kind of automotive line is material modified and preparation method thereof with PVC | |
| CN106947187A (en) | A kind of sunlight fabric is material modified and preparation method thereof with PVC | |
| CN105440505A (en) | PVC (polyvinyl chloride) foam material for sole and preparation method of PVC foam material | |
| CN106977849A (en) | A kind of curtain is material modified and preparation method thereof with PVC | |
| CN106916394A (en) | A kind of anti-slip carpet is material modified and preparation method thereof with PVC | |
| CN106905641A (en) | A kind of wallpaper cloth is material modified and preparation method thereof with PVC | |
| Murphy | Additives for plastics handbook | |
| CN106947185A (en) | A kind of table mat is material modified and preparation method thereof with PVC | |
| CN105482310A (en) | Antistatic PVC (polyvinyl chloride) modified material and preparation method thereof | |
| CN105419167A (en) | Carpet environmental protection PVC modified material and preparation method therefor | |
| CN105504584A (en) | Tasteless PVC modified material and preparation method thereof | |
| CN106928596A (en) | A kind of anti-oxidant ground cushion of uvioresistant and preparation method thereof | |
| CN106905642A (en) | A kind of anti-skid wearable ground cushion and preparation method thereof | |
| CN106977846A (en) | A kind of waterproof oil resistant carpet is material modified and preparation method thereof with PVC | |
| WO2022246778A1 (en) | Preparation method for special nano-modified polyethylene material for resisting aging | |
| CN105566805A (en) | Anticorrosive PVC modified material and preparation method thereof | |
| CN105482309A (en) | Radiation-proofing PVC modified material and preparation method thereof | |
| CN107011622A (en) | A kind of super abrasive POM/PTFE sheet materials and preparation method thereof | |
| WO2014178490A1 (en) | Toughened epoxy resin composition, preparation method therefor, and toughened epoxy resin | |
| CN106947186A (en) | A kind of beach chair cloth is material modified and preparation method thereof with PVC | |
| CN106977853A (en) | A kind of antistatic mould proof ground cushion and preparation method thereof | |
| CN106916395A (en) | A kind of waterproof oil resistant ground cushion and preparation method thereof | |
| CN106928597A (en) | A kind of fire-retardant ground cushion of high resiliency and preparation method thereof | |
| CN109233072A (en) | A kind of PE plastic barrel | |
| CN106928668A (en) | A kind of modified PET slab and its extruding forming method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB02 | Change of applicant information |
Address after: Ye Wu industrial zone Dalingshan Meilin Village 523000 Guangdong city of Dongguan Province Applicant after: Guangdong Qi Long Technology Co., Ltd. Address before: Ye Wu industrial zone Dalingshan Meilin Village 523820 Guangdong city of Dongguan Province Applicant before: Dongguan Qilong Electricity Co., Ltd. |
|
| CB02 | Change of applicant information | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170704 |
|
| RJ01 | Rejection of invention patent application after publication |