CN103694685A - White anti-UV (ultraviolet) nylon color masterbatch - Google Patents

White anti-UV (ultraviolet) nylon color masterbatch Download PDF

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Publication number
CN103694685A
CN103694685A CN201310737914.1A CN201310737914A CN103694685A CN 103694685 A CN103694685 A CN 103694685A CN 201310737914 A CN201310737914 A CN 201310737914A CN 103694685 A CN103694685 A CN 103694685A
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CN
China
Prior art keywords
nylon
stabilizer
antioxidant
masterbatch
white
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Pending
Application number
CN201310737914.1A
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Chinese (zh)
Inventor
张春琦
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NINGBO JINFULIANG PLASTIC SCIENCE & TECHNOLOGY Co Ltd
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NINGBO JINFULIANG PLASTIC SCIENCE & TECHNOLOGY Co Ltd
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Priority to CN201310737914.1A priority Critical patent/CN103694685A/en
Publication of CN103694685A publication Critical patent/CN103694685A/en
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/36—Silica
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2227—Oxides; Hydroxides of metals of aluminium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2310/00—Masterbatches

Abstract

The invention discloses a white anti-UV (ultraviolet) nylon color masterbatch which comprises the following components: a white coloring agent, polyamide resin, a compound stabilizer, nano-powdery solid particles and a dispersant, wherein the compound stabilizer at least comprises two of a hindered phenol antioxidant, a phosphate antioxidant, a cupric halide stabilizer, a hindered amine stabilizer, a hydrolysis-resistant agent, diphenylmethanone and a benzotriazole ultraviolet absorber. Compared with the prior art, the nylon color masterbatch has the advantages that various stabilizers are compounded to generate a synergistic effect, the stability of materials in a processing process and an outdoor long-term use process is guaranteed, the mechanical performance of the materials is better, and the nylon color masterbatch is suitable for design and application of high-end nylon products with long-term weather-resistant requirements. Meanwhile, the nano-powdery solid particles are added, so that the wear resistance of nylon can be improved, the service life of the nylon is greatly prolonged, and the safety of the nylon is greatly improved.

Description

The anti-UV nylon of a kind of white Masterbatch
Technical field
The invention belongs to the technical field of coloring plastic, relate in particular to the anti-UV nylon of a kind of white Masterbatch.
Background technology
Masterbatch is a kind of plastics of the sixties in 20th century exploitation, the painted product innovation of fiber, and it is that pigment super quantity is attached in resin and the mixture of the polymkeric substance making uniformly.Masterbatch chief component is tinting material, carrier, dispersion agent three parts.
According to related data, learn that the average annual growth rate of demand about 7%-9% of the other countries of Asia to Masterbatch can China be 20% left and right to the average annual growth rate of demand of Masterbatch.Estimate that China will become the fastest-rising market of Masterbatch demand.Particularly colored and add master batch, China wants dependence on import.China has become the largest production state in Masterbatch market, Asia and has consumed state.Relevant expert thinks, following Masterbatch will be towards multifunction, high color content and high technology content future development.
And common nylon master batch adds in nylon raw material, cannot guarantee the stability in material work in-process and outdoor use, generally all can reduce the mechanical property of material, thereby reduce the design and use life-span of product.
Summary of the invention
The present invention is directed to deficiency of the prior art, provide a kind of add rear to the anti-UV nylon of the little white of nylon Effect on Mechanical Properties Masterbatch.
In order to solve the problems of the technologies described above, the present invention is solved by following technical proposals: the anti-UV nylon of a kind of white Masterbatch, it is characterized in that by weight percentage, composed of the following components: white color agents 15%-35%, polyamide resin 25%-35%, one package stabilizer 5%-15%, nanoscale powder shape solid particulate 20%-30%, dispersion agent 3%-10%; Described one package stabilizer at least comprises two kinds in Hinered phenols antioxidant, phosphite ester kind antioxidant, copper halide class stablizer, hindered amine light stabilizer, hydrolysis-resisting agent, benzophenone, Benzotriazole Ultraviolet Stabilizer.Compared with prior art, the present invention mainly adopts the composite of plurality of stable agent, make various stablizers produce synergistic effect, guarantee that material neutralizes out of doors and can guarantee stability in life-time service in the course of processing, the mechanical property of material is better, is applicable to high-end nylon product design and the application of long-term weather-proof requirement.Meanwhile, in the present invention, added nanoscale powder shape solid particulate, contributed to improve the wear resisting property of nylon, the work-ing life of nylon and security are improved greatly.
As preferred version: above-mentioned one package stabilizer at least comprises two kinds in Hinered phenols antioxidant, hindered amine light stabilizer, Benzotriazole Ultraviolet Stabilizer and phosphite ester kind antioxidant.Hinered phenols antioxidant and hindered amine light stabilizer be hydroperoxide decomposition and Trapped free radical effectively, and both are a bit similar, but hindered amine light stabilizer can cyclic regeneration, and Hinered phenols antioxidant is disposable; UV light absorber can effectively absorb sunlight middle-ultraviolet lamp, reduces by UV-induced photoaging; Phosphite ester kind antioxidant is brought into play antioxidant effect as hydrogen peroxide decomposition agent and radical trapping agent in polymkeric substance, use substantially without obvious effect separately, but play synergy with Hinered phenols antioxidant, obviously reinforcement material neutralizes out of doors and can guarantee stability in life-time service in the course of processing.
As preferably, above-mentioned one package stabilizer is comprised of Hinered phenols antioxidant, hindered amine light stabilizer, Benzotriazole Ultraviolet Stabilizer and phosphite ester kind antioxidant; By weight percentage, Hinered phenols antioxidant 25%-35% wherein, hindered amine light stabilizer 15%-25%, Benzotriazole Ultraviolet Stabilizer 20%-30%, phosphite ester kind antioxidant 20%-30%.By Hinered phenols antioxidant, phosphite ester kind antioxidant ,the quaternary system that hindered amine light stabilizer, Benzotriazole Ultraviolet Stabilizer form has good stabilising effect to the long-term weatherability of nylon product.Only use Hinered phenols antioxidant and hindered amine light stabilizer binary system, during nylon material tensile strength retention rate 50%, the required burn-in test time is 2450 hours, while containing the nylon product tensile strength retention rate 70% that above-mentioned quaternary system forms, the required burn-in test time is 6200 hours, Each performs its own functions for four kinds of stablizers, has significantly collaborative synergistic effect.
As preferably, above-mentioned nanoscale powder shape solid particulate is a kind of in silicon rubber, silicon-dioxide, silicon carbide and aluminum oxide.
As preferably, above-mentioned dispersion agent at least comprises a kind of in ethene-vinyl acetate wax, ethylene bis stearic amide, pentaerythritol stearate.
As preferably, above-mentioned white color agents is a kind of in titanium dioxide, zinc sulphide.
The present invention compared with prior art, there is following beneficial effect: the present invention mainly adopts the composite of plurality of stable agent, make various stablizers produce synergistic effect, guarantee that material neutralizes out of doors and can guarantee stability in life-time service in the course of processing, the mechanical property of material is better, is applicable to high-end nylon product design and the application of long-term weather-proof requirement.Meanwhile, in the present invention, added nanoscale powder shape solid particulate, contributed to improve the wear resisting property of nylon, the work-ing life of nylon and security are improved greatly.
Embodiment
Below in conjunction with embodiment, the present invention is described in further detail: embodiment 1.
The anti-UV nylon of a white Masterbatch, by weight percentage, composed of the following components: zinc sulphide 20%, polyamide resin 35%, one package stabilizer 10%, nanoscale powder shape solid particulate 30%, dispersion agent 5%; Wherein, one package stabilizer is comprised of Hinered phenols antioxidant and phosphite ester kind antioxidant, and by weight, Hinered phenols antioxidant is one package stabilizer 60%, and phosphite ester kind antioxidant is one package stabilizer 40%; Dispersion agent is ethene-vinyl acetate wax.
Above-mentioned nanoscale powder shape solid particulate can be any one in silicon rubber, silicon-dioxide, silicon carbide and aluminum oxide.
Embodiment 2.
The anti-UV nylon of a white Masterbatch, by weight percentage, composed of the following components: titanium dioxide 30%, polyamide resin 25%, one package stabilizer 15%, nanoscale powder shape solid particulate 20%, dispersion agent 10%.
Wherein, one package stabilizer is comprised of Hinered phenols antioxidant, hindered amine light stabilizer, Benzotriazole Ultraviolet Stabilizer and phosphite ester kind antioxidant; By weight percentage, wherein Hinered phenols antioxidant 35%, hindered amine light stabilizer 15%, Benzotriazole Ultraviolet Stabilizer 30%, phosphite ester kind antioxidant 20%; Dispersion agent is pentaerythritol stearate.
Above-mentioned nanoscale powder shape solid particulate can be a kind of in silicon rubber, silicon-dioxide, silicon carbide and aluminum oxide.
Comparative example 1.
Titanium dioxide 30%, polyamide resin 25%, Hinered phenols antioxidant 15%, silicon rubber 20%, dispersion agent 10%.
Comparative example 2.
Titanium dioxide 20%, polyamide resin 35%, phosphite ester kind antioxidant 10%, aluminum oxide 30%, dispersion agent 5%.
Experimental result: embodiment 1, during nylon material tensile strength retention rate 50%, the required burn-in test time is 2190 hours; Embodiment 2, and during nylon material tensile strength retention rate 70%, the required burn-in test time is 5140 hours; Comparative example 1, during nylon material tensile strength retention rate 50%, the required burn-in test time is, 1620 hours; Comparative example 2, during nylon material tensile strength retention rate 50%, the required burn-in test time is, 1680 hours.

Claims (6)

1. the anti-UV nylon of a white Masterbatch, is characterized in that by weight percentage, composed of the following components: white color agents 15%-35%, polyamide resin 25%-35%, one package stabilizer 5%-15%, nanoscale powder shape solid particulate 20%-30%, dispersion agent 3%-10%; Described one package stabilizer at least comprises two kinds in Hinered phenols antioxidant, phosphite ester kind antioxidant, copper halide class stablizer, hindered amine light stabilizer, hydrolysis-resisting agent, benzophenone, Benzotriazole Ultraviolet Stabilizer.
2. the anti-UV nylon of a kind of white according to claim 1 Masterbatch, is characterized in that: described one package stabilizer at least comprises two kinds in Hinered phenols antioxidant, hindered amine light stabilizer, Benzotriazole Ultraviolet Stabilizer and phosphite ester kind antioxidant.
3. the anti-UV nylon of a kind of white according to claim 2 Masterbatch, is characterized in that: described one package stabilizer is comprised of Hinered phenols antioxidant, hindered amine light stabilizer, Benzotriazole Ultraviolet Stabilizer and phosphite ester kind antioxidant; By weight percentage, Hinered phenols antioxidant 25%-35% wherein, hindered amine light stabilizer 15%-25%, Benzotriazole Ultraviolet Stabilizer 20%-30%, phosphite ester kind antioxidant 20%-30%.
4. the anti-UV nylon of a kind of white according to claim 1 Masterbatch, is characterized in that: described nanoscale powder shape solid particulate is a kind of in silicon rubber, silicon-dioxide, silicon carbide and aluminum oxide.
5. according to the anti-UV nylon of a kind of white Masterbatch described in arbitrary claim in claim 1 to 4, it is characterized in that: described dispersion agent at least comprises a kind of in ethene-vinyl acetate wax, ethylene bis stearic amide, pentaerythritol stearate.
6. the anti-UV nylon of a kind of white according to claim 5 Masterbatch, is characterized in that: described white color agents is a kind of in titanium dioxide, zinc sulphide.
CN201310737914.1A 2013-12-28 2013-12-28 White anti-UV (ultraviolet) nylon color masterbatch Pending CN103694685A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106589914A (en) * 2016-11-03 2017-04-26 苏州圣鑫莱新材料有限公司 Nano PA color master batch
CN110922749A (en) * 2019-10-26 2020-03-27 张家港大塚化学有限公司 Preparation method of high-weather-resistance and high-reflectivity polyamide composite material for LED
CN113861672A (en) * 2021-10-12 2021-12-31 惠州市华聚塑化科技有限公司 Anti-aging halogen-free flame-retardant nylon composite material and preparation method thereof

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1649970A (en) * 2002-05-01 2005-08-03 西巴特殊化学品控股有限公司 Pigment preparations
CN102449029A (en) * 2009-03-30 2012-05-09 东丽株式会社 Polyamide resin, polyamide resin composition, and molded article comprising same
EP2502965A1 (en) * 2004-11-01 2012-09-26 Basf Se Highly concentrated flowable pigment composition and process for its manufacture
CN102838828A (en) * 2011-06-20 2012-12-26 上海安凸塑料添加剂有限公司 Bright-black functional black masterbatch for ABS engineering plastics and preparation method thereof
CN103073771A (en) * 2012-12-28 2013-05-01 东莞市普凯塑料科技有限公司 Ultraviolet shielding, anti-bacterial and anti-fouling multifunctional color masterbatch and preparation method thereof
CN103073867A (en) * 2012-12-28 2013-05-01 东莞市普凯塑料科技有限公司 Light diffusion master batch for transparent plastics and preparation method thereof
CN103087517A (en) * 2013-02-20 2013-05-08 上海俊尔新材料有限公司 Glass-reinforced nylon 6 material and preparation method thereof

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1649970A (en) * 2002-05-01 2005-08-03 西巴特殊化学品控股有限公司 Pigment preparations
EP2502965A1 (en) * 2004-11-01 2012-09-26 Basf Se Highly concentrated flowable pigment composition and process for its manufacture
CN102449029A (en) * 2009-03-30 2012-05-09 东丽株式会社 Polyamide resin, polyamide resin composition, and molded article comprising same
CN102838828A (en) * 2011-06-20 2012-12-26 上海安凸塑料添加剂有限公司 Bright-black functional black masterbatch for ABS engineering plastics and preparation method thereof
CN103073771A (en) * 2012-12-28 2013-05-01 东莞市普凯塑料科技有限公司 Ultraviolet shielding, anti-bacterial and anti-fouling multifunctional color masterbatch and preparation method thereof
CN103073867A (en) * 2012-12-28 2013-05-01 东莞市普凯塑料科技有限公司 Light diffusion master batch for transparent plastics and preparation method thereof
CN103087517A (en) * 2013-02-20 2013-05-08 上海俊尔新材料有限公司 Glass-reinforced nylon 6 material and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
杨明: "《塑料添加剂应用手册》", 28 February 2001, 江苏科学技术出版社 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106589914A (en) * 2016-11-03 2017-04-26 苏州圣鑫莱新材料有限公司 Nano PA color master batch
CN110922749A (en) * 2019-10-26 2020-03-27 张家港大塚化学有限公司 Preparation method of high-weather-resistance and high-reflectivity polyamide composite material for LED
CN113861672A (en) * 2021-10-12 2021-12-31 惠州市华聚塑化科技有限公司 Anti-aging halogen-free flame-retardant nylon composite material and preparation method thereof
CN113861672B (en) * 2021-10-12 2023-10-27 惠州市华聚塑化科技有限公司 Anti-aging halogen-free flame-retardant nylon composite material and preparation method thereof

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Application publication date: 20140402