CN103694681A - Green UV (Ultraviolet)-resisting color master batch for nylon - Google Patents
Green UV (Ultraviolet)-resisting color master batch for nylon Download PDFInfo
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- CN103694681A CN103694681A CN201310736782.0A CN201310736782A CN103694681A CN 103694681 A CN103694681 A CN 103694681A CN 201310736782 A CN201310736782 A CN 201310736782A CN 103694681 A CN103694681 A CN 103694681A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/17—Amines; Quaternary ammonium compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/315—Compounds containing carbon-to-nitrogen triple bonds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3472—Five-membered rings
- C08K5/3475—Five-membered rings condensed with carbocyclic rings
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/524—Esters of phosphorous acids, e.g. of H3PO3
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2310/00—Masterbatches
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- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a green UV (Ultraviolet)-resisting color master batch for nylon. The green UV-resisting color master batch consists of the following ingredients: 15-35% of green coloring agent, 40-55% of polyamine resin, 5-15% of composite stabilizer, 5-10% of alpha-cypermethrin and 3-10% of dispersant, wherein the composite stabilizer at least comprises two of a hindered phenol antioxidant, a phosphite ester antioxidant, a cupric halide stabilizer, a hindered amine light stabilizer, a hydrolysis resistant, a diphenyl ketone ultraviolet absorbent and a benzotriazole ultraviolet absorbent. Compared with the prior art, the green UV-resisting color master batch has the advantages that a synergistic effect is produced by the multiple stabilizers through the compounding of the stabilizers, and the stability of the material is ensured no matter in the processing process or during the long-term outdoor use; the mechanical performance of the material is better; the green UV-resisting color master batch is suitable for the design and application of high-end nylon products having requirements on long-term weather-proofing. Meanwhile, due to the adding of the alpha-cypermethrin, the green UV-resisting color master batch can perform a function of dispelling mosquitoes with the slow release of the alpha-cypermethrin.
Description
Technical field
The invention belongs to the technical field of coloring plastic, relate in particular to the anti-UV nylon of a kind of green Masterbatch.
Background technology
Masterbatch is a kind of plastics of the sixties in 20th century exploitation, the painted product innovation of fiber, and it is that pigment super quantity is attached in resin and the mixture of the polymkeric substance making uniformly.Masterbatch chief component is tinting material, carrier, dispersion agent three parts.
According to related data, learn that the average annual growth rate of demand about 7%-9% of the other countries of Asia to Masterbatch can China be 20% left and right to the average annual growth rate of demand of Masterbatch.Estimate that China will become the fastest-rising market of Masterbatch demand.Particularly colored and add master batch, China wants dependence on import.China has become the largest production state in Masterbatch market, Asia and has consumed state.Relevant expert thinks, following Masterbatch will be towards multifunction, high color content and high technology content future development.
And common nylon master batch adds in nylon raw material, cannot guarantee the stability in material work in-process and outdoor use, generally all can reduce the mechanical property of material, thereby reduce the design and use life-span of product.
Summary of the invention
The present invention is directed to deficiency of the prior art, provide a kind of add rear to the anti-UV nylon of the little green of nylon Effect on Mechanical Properties Masterbatch.
In order to solve the problems of the technologies described above, the present invention is solved by following technical proposals: the anti-UV nylon of a kind of green Masterbatch, it is characterized in that by weight percentage, composed of the following components: green colourant 15%-35%, polyamide resin 40%-55%, one package stabilizer 5%-15%, alphacypermethrin 5%-10%, dispersion agent 3%-10%; Described one package stabilizer at least comprises two kinds in Hinered phenols antioxidant, phosphite ester kind antioxidant, copper halide class stablizer, hindered amine light stabilizer, hydrolysis-resisting agent, benzophenone, Benzotriazole Ultraviolet Stabilizer.Compared with prior art, the present invention mainly adopts the composite of plurality of stable agent, make various stablizers produce synergistic effect, guarantee that material neutralizes out of doors and can guarantee stability in life-time service in the course of processing, the mechanical property of material is better, is applicable to high-end nylon product design and the application of long-term weather-proof requirement.Meanwhile, added alphacypermethrin in the present invention, alphacypermethrin slowly discharges, and has the effect of mosquito repellent.
As preferred version: above-mentioned one package stabilizer at least comprises two kinds in Hinered phenols antioxidant, hindered amine light stabilizer, Benzotriazole Ultraviolet Stabilizer and phosphite ester kind antioxidant.Hinered phenols antioxidant and hindered amine light stabilizer be hydroperoxide decomposition and Trapped free radical effectively, and both are a bit similar, but hindered amine light stabilizer can cyclic regeneration, and Hinered phenols antioxidant is disposable; UV light absorber can effectively absorb sunlight middle-ultraviolet lamp, reduces by UV-induced photoaging; Phosphite ester kind antioxidant is brought into play antioxidant effect as hydrogen peroxide decomposition agent and radical trapping agent in polymkeric substance, use substantially without obvious effect separately, but play synergy with Hinered phenols antioxidant, obviously reinforcement material neutralizes out of doors and can guarantee stability in life-time service in the course of processing.
As preferably, above-mentioned one package stabilizer is comprised of Hinered phenols antioxidant, hindered amine light stabilizer, Benzotriazole Ultraviolet Stabilizer and phosphite ester kind antioxidant; By weight percentage, Hinered phenols antioxidant 25%-35% wherein, hindered amine light stabilizer 15%-25%, Benzotriazole Ultraviolet Stabilizer 20%-30%, phosphite ester kind antioxidant 20%-30%.By Hinered phenols antioxidant, phosphite ester kind antioxidant
,the quaternary system that hindered amine light stabilizer, Benzotriazole Ultraviolet Stabilizer form has good stabilising effect to the long-term weatherability of nylon product.Only use Hinered phenols antioxidant and hindered amine light stabilizer binary system, during nylon material tensile strength retention rate 50%, the required burn-in test time is 2450 hours, while containing the nylon product tensile strength retention rate 70% that above-mentioned quaternary system forms, the required burn-in test time is 6200 hours, Each performs its own functions for four kinds of stablizers, has significantly collaborative synergistic effect.
As preferably, above-mentioned dispersion agent at least comprises a kind of in ethene-vinyl acetate wax, ethylene bis stearic amide, pentaerythritol stearate.
As preferably, above-mentioned green colourant is a kind of in phthalocyanine green, cobalt green, chromoxide green.
The present invention compared with prior art, there is following beneficial effect: the present invention mainly adopts the composite of plurality of stable agent, make various stablizers produce synergistic effect, guarantee that material neutralizes out of doors and can guarantee stability in life-time service in the course of processing, the mechanical property of material is better, is applicable to high-end nylon product design and the application of long-term weather-proof requirement.Meanwhile, added alphacypermethrin in the present invention, alphacypermethrin slowly discharges, and has the effect of mosquito repellent.
Embodiment
Below in conjunction with embodiment, the present invention is described in further detail: embodiment 1.
The anti-UV nylon of a green Masterbatch, by weight percentage, composed of the following components: phthalocyanine green 20%, polyamide resin 55%, one package stabilizer 10%, alphacypermethrin 10%, dispersion agent 5%; Wherein, one package stabilizer is comprised of Hinered phenols antioxidant and phosphite ester kind antioxidant, and by weight, Hinered phenols antioxidant is one package stabilizer 60%, and phosphite ester kind antioxidant is one package stabilizer 40%; Dispersion agent is ethene-vinyl acetate wax.
Embodiment 2.
The anti-UV nylon of a green Masterbatch, by weight percentage, composed of the following components: chromoxide green 30%, polyamide resin 40%, one package stabilizer 15%, alphacypermethrin 5%, dispersion agent 10%.
Wherein, one package stabilizer is comprised of Hinered phenols antioxidant, hindered amine light stabilizer, Benzotriazole Ultraviolet Stabilizer and phosphite ester kind antioxidant; By weight percentage, wherein Hinered phenols antioxidant 35%, hindered amine light stabilizer 15%, Benzotriazole Ultraviolet Stabilizer 30%, phosphite ester kind antioxidant 20%; Dispersion agent is pentaerythritol stearate.
Comparative example 1.
Chromoxide green 30%, polyamide resin 25%, Hinered phenols antioxidant 15%, alphacypermethrin 20%, dispersion agent 10%.
Comparative example 2.
Chromoxide green 20%, polyamide resin 35%, phosphite ester kind antioxidant 10%, alphacypermethrin 30%, dispersion agent 5%.
Experimental result: embodiment 1, during nylon material tensile strength retention rate 50%, the required burn-in test time is 2620 hours; Embodiment 2, and during nylon material tensile strength retention rate 70%, the required burn-in test time is 5640 hours; Comparative example 1, during nylon material tensile strength retention rate 50%, the required burn-in test time is, 1760 hours; Comparative example 2, during nylon material tensile strength retention rate 50%, the required burn-in test time is, 1830 hours.
Claims (5)
1. the anti-UV nylon of a green Masterbatch, is characterized in that by weight percentage, composed of the following components: green colourant 15%-35%, polyamide resin 40%-55%, one package stabilizer 5%-15%, alphacypermethrin 5%-10%, dispersion agent 3%-10%; Described one package stabilizer at least comprises two kinds in Hinered phenols antioxidant, phosphite ester kind antioxidant, copper halide class stablizer, hindered amine light stabilizer, hydrolysis-resisting agent, benzophenone, Benzotriazole Ultraviolet Stabilizer.
2. the anti-UV nylon of a kind of green according to claim 1 Masterbatch, is characterized in that: described one package stabilizer at least comprises two kinds in Hinered phenols antioxidant, hindered amine light stabilizer, Benzotriazole Ultraviolet Stabilizer and phosphite ester kind antioxidant.
3. the anti-UV nylon of a kind of green according to claim 2 Masterbatch, is characterized in that: described one package stabilizer is comprised of Hinered phenols antioxidant, hindered amine light stabilizer, Benzotriazole Ultraviolet Stabilizer and phosphite ester kind antioxidant; By weight percentage, Hinered phenols antioxidant 25%-35% wherein, hindered amine light stabilizer 15%-25%, Benzotriazole Ultraviolet Stabilizer 20%-30%, phosphite ester kind antioxidant 20%-30%.
4. according to the anti-UV nylon of a kind of green Masterbatch described in arbitrary claim in claims 1 to 3, it is characterized in that: described dispersion agent at least comprises a kind of in ethene-vinyl acetate wax, ethylene bis stearic amide, pentaerythritol stearate.
5. the anti-UV nylon of a kind of green according to claim 4 Masterbatch, is characterized in that: described green colourant is a kind of in phthalocyanine green, cobalt green, chromoxide green.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310736782.0A CN103694681A (en) | 2013-12-28 | 2013-12-28 | Green UV (Ultraviolet)-resisting color master batch for nylon |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310736782.0A CN103694681A (en) | 2013-12-28 | 2013-12-28 | Green UV (Ultraviolet)-resisting color master batch for nylon |
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| CN103694681A true CN103694681A (en) | 2014-04-02 |
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| CN201310736782.0A Pending CN103694681A (en) | 2013-12-28 | 2013-12-28 | Green UV (Ultraviolet)-resisting color master batch for nylon |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105400184A (en) * | 2015-12-21 | 2016-03-16 | 慈溪康氏新材料有限公司 | Polyamide color master batch, and preparation method thereof |
| CN106497035A (en) * | 2016-10-19 | 2017-03-15 | 苏州瑞斯格电子科技有限公司 | A kind of PA Masterbatch with dust-proof antibiotic aging-resistant function |
| CN107022140A (en) * | 2017-04-14 | 2017-08-08 | 宿迁万康新材料有限公司 | The special anti-UV master batches of fly net |
Citations (5)
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|---|---|---|---|---|
| CN1649970A (en) * | 2002-05-01 | 2005-08-03 | 西巴特殊化学品控股有限公司 | Pigment preparations |
| CN101596383A (en) * | 2009-05-28 | 2009-12-09 | 佛山市顺德区阿波罗环保器材有限公司 | A kind of insect-resisting filter screen and manufacture method thereof |
| EP2502965A1 (en) * | 2004-11-01 | 2012-09-26 | Basf Se | Highly concentrated flowable pigment composition and process for its manufacture |
| CN103275370A (en) * | 2012-12-28 | 2013-09-04 | 东莞市普凯塑料科技有限公司 | Ultraviolet light shielding, anti-bacterial, antifouling multifunctional color master batch and preparation method thereof |
| CN103289389A (en) * | 2013-05-31 | 2013-09-11 | 上海彩艳实业有限公司 | Color master batch of chinlon BCF (bulked continuous filament) carpet yarn and preparation method of color master batch |
-
2013
- 2013-12-28 CN CN201310736782.0A patent/CN103694681A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1649970A (en) * | 2002-05-01 | 2005-08-03 | 西巴特殊化学品控股有限公司 | Pigment preparations |
| EP2502965A1 (en) * | 2004-11-01 | 2012-09-26 | Basf Se | Highly concentrated flowable pigment composition and process for its manufacture |
| CN101596383A (en) * | 2009-05-28 | 2009-12-09 | 佛山市顺德区阿波罗环保器材有限公司 | A kind of insect-resisting filter screen and manufacture method thereof |
| CN103275370A (en) * | 2012-12-28 | 2013-09-04 | 东莞市普凯塑料科技有限公司 | Ultraviolet light shielding, anti-bacterial, antifouling multifunctional color master batch and preparation method thereof |
| CN103289389A (en) * | 2013-05-31 | 2013-09-11 | 上海彩艳实业有限公司 | Color master batch of chinlon BCF (bulked continuous filament) carpet yarn and preparation method of color master batch |
Non-Patent Citations (1)
| Title |
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| 杨明: "《塑料添加剂应用手册》", 28 February 2002, 江苏科学技术出版社 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105400184A (en) * | 2015-12-21 | 2016-03-16 | 慈溪康氏新材料有限公司 | Polyamide color master batch, and preparation method thereof |
| CN106497035A (en) * | 2016-10-19 | 2017-03-15 | 苏州瑞斯格电子科技有限公司 | A kind of PA Masterbatch with dust-proof antibiotic aging-resistant function |
| CN107022140A (en) * | 2017-04-14 | 2017-08-08 | 宿迁万康新材料有限公司 | The special anti-UV master batches of fly net |
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Application publication date: 20140402 |